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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Siloxane Deposition on the Ni-YSZ Solid Oxide Fuel Cell Anode Exposed to Bio-Syngas

Siloxane, a common contaminant present in biogas, is known for adverse effects on cogeneration prime movers. In this study, the siloxane deposition products and mechanism in the solid oxide fuel cell nickel-yttria stabilized zirconia (Ni-YSZ) anode are investigated analytically and experimentally. An SOFC with Ni-YSZ anode and pure Ni/YSZ pellets were exposed to a simulated biogas-reformate fuel with octamethylcyclotetrasiloxane (D4) contamination at 750 °C. The electrochemical characterization results show that the SOFCs performance degradation caused by D4 contamination is irreversible. Morphology and XRD results illustrate that silicon and carbon deposition can both be detected in the anode and pellets. Graphite, SiC and SiO2 are all possible products based on the results of XRD test. Here, according to the formation of graphite and SiC, the new mechanism suggests that carbon is also an essential factor in siloxane contamination of Ni-YSZ anodes besides silicon, which can be explained by the catalytic and electrochemical analysis.

25 ENERGY STORAGE↗
DOE OSTI2021

Oxygenated Fuel Blending Effects in a Mixing-Controlled Compression-Ignition Engine Equipped with Ducted Fuel Injection [Slides]

Continued creation of harmful emissions such as NO x and soot from compression-ignition engines utilizing mixing-controlled combustion systems (i.e., diesel engines) remains a problem and is the subject of on-going research. The inherently high efficiency, relatively low cost, and numerous other desirable attributes of such engines, coupled with a widely supported infrastructure, motivates their continued advancement. Recently, a scientifically distinct and mechanically simple technology called ducted fuel injection (DFI) has shown a robust ability to allow such engines to operate with simultaneously low engine-out soot and NO x emissions when it is employed with simulated exhaust-gas recirculation. To better understand the property ranges of sustainable, oxygenated-fuel blending stocks that will most improve engine performance, two oxygenated blendstocks were separately blended with a commercial diesel base fuel and tested within a heavy-duty diesel optical engine equipped with a four-duct DFI configuration. Conventional and crank-angle-resolved optical diagnostics were used to elucidate the effects of fuel ignition quality, oxygenate molecular structure, and overall oxygen content on engine performance.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2023

Techno-Economic Analysis of Hydrogen-Fueled Solid Oxide Fuel Cell Systems

This technical report presents findings from a techno-economic analysis that assessed the cost and performance implications of fueling solid oxide fuel cell (SOFC) technology with hydrogen fuel. The exothermic hydrogen oxidation reaction results in various impacts when compared to a natural gas SOFC system, which benefits from an endothermic methane reforming reaction. The excess heat generated from the system requires management, thereby increasing system costs. An application where the excess heat can be used in a combined heat and power application seems to be the most economical use of a hydrogen fueled SOFC system.

08 HYDROGEN↗
DOE OSTI2022

Point Cloud Based Mapping of Understory Shrub Fuel Distribution, Estimation of Fuel Consumption and Relationship to Pyrolysis Gas Emissions on Experimental Prescribed Burns

Forest fires spread via production and combustion of pyrolysis gases in the understory. The goal of the present paper is to understand the spatial location, distribution, and fraction (relative to the overstory) of understory plants, in this case, sparkleberry shrub, namely its degree of understory consumption upon burn, and to search for correlations between the degree of shrub consumption to the composition of emitted pyrolysis gases. Data were collected in situ at seven small experimental prescribed burns at Ft. Jackson, an army base in South Carolina, USA. Using airborne laser scanning (ALS) to map overstory tree crowns and terrestrial laser scanning (TLS) to characterize understory shrub fuel density, both pre- and postburn estimates of sparkleberry coverage were obtained. Sparkleberry clump polygons were manually digitized from a UAV-derived orthoimage of the understory and intersected with the TLS point cloud-derived rasters of pre- and postburn shrub fuel bulk density; these were compared in relation to overstory crown cover as well as to ground truth. Shrub fuel consumption was estimated from the digitized images; sparkleberry clump distributions were generally found to not correlate well to the overstory tree crowns, suggesting it is shade-tolerant. Moreover, no relationship was found between the magnitude of the fuel consumption and the chemical composition of pyrolysis gases, even though mixing ratios of 25 individual gases were measured.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1972

A fuel conservation study for transport aircraft utilizing advanced technology and hydrogen fuel

The conservation of fossil fuels in commercial aviation was investigated. Four categories of aircraft were selected for investigation: (1) conventional, medium range, low take-off gross weight; (2) conventional, long range, high take-off gross weights; (3) large take-off gross weight aircraft that might find future applications using both conventional and advanced technology; and (4) advanced technology aircraft of the future powered with liquid hydrogen fuel. It is concluded that the hydrogen fueled aircraft can perform at reduced size and gross weight the same payload/range mission as conventionally fueled aircraft.

Berry, W.↗
NASA NTRS1973

Optimal dual-fuel propulsion for minimum inert weight or minimum fuel cost

An analytical investigation of single-stage vehicles with multiple propulsion phases has been conducted with the phasing optimized to minimize a general cost function. Some results are presented for linearized sizing relationships which indicate that single-stage-to-orbit, dual-fuel rocket vehicles can have lower inert weight than similar single-fuel rocket vehicles and that the advantage of dual-fuel vehicles can be increased if a dual-fuel engine is developed. The results also indicate that the optimum split can vary considerably with the choice of cost function to be minimized.

Martin, J. A.↗
NASA NTRS1982

Low NO sub x heavy fuel combustor concept program. Phase 1A: Combustion technology generation coal gas fuels

Combustion tests of two scaled burners using actual coal gas from a 25 ton/day fluidized bed coal gasifier are described. The two combustor configurations studied were a ceramic lined, staged rich/lean burner and an integral, all metal multiannual swirl burner (MASB). The tests were conducted over a range of temperature and pressures representative of current industrial combustion turbine inlet conditions. Tests on the rich lean burner were conducted at three levels of product gas heating values: 104, 197 and 254 btu/scf. Corresponding levels of NOx emissions were 5, 20 and 70 ppmv. Nitrogen was added to the fuel in the form of ammonia, and conversion efficiencies of fuel nitrogen to NOx were on the order of 4 percent to 12 percent, which is somewhat lower than the 14 percent to 18 percent conversion efficiency when src-2 liquid fuel was used. The MASB was tested only on medium btu gas (220 to 270 btu/scf), and produced approximately 80 ppmv NOx at rated engine conditions. Both burners operated similarly on actual coal gas and erbs fuel, and all heating values tested can be successfully burned in current machines.

Sherlock, T. P.↗
NASA NTRS1981

Deposit formation in liquid fuels. I - Effect of coal-derived Lewis bases on storage stability of Jet A turbine fuel

The development of reasonably precise techniques for the measurement of storage stability of jet aviation fuel is described. Lewis bases, extracted by ligand-exchange from a coal-derived liquid, are shown to adversely affect storage stability (as determined by an accelerated storage test) when added to Jet A turbine fuel. JFTOT results suggesting slight decreases in thermal stability of fuel 'spiked' (i.e., contaminated with a measured quantity of reagent) with extract are reported. Addition to Jet A turbine fuel of individual heterocyclic nitrogen compounds is shown to produce comparable decreases in storage stability.

Dahlin, K. E.↗
NASA NTRS1984

Analysis of fuel system technology for broad property fuels

An analytical study was performed in order to assess relative performance and economic factors involved with alternative advanced fuel systems for future commercial aircraft operating with broad property fuels. Significant results, with emphasis on design practicality from the engine manufacturer' standpoint, are highlighted. Several advanced fuel systems were modeled to determine as accurately as possible the relative merits of each system from the standpoint of compatibility with broad property fuel. Freezing point, thermal stability, and lubricity were key property issues. A computer model was formulated to determine the investment incentive for each system. Results are given.

Coffinberry, G. A.↗
NASA NTRS1956

Performance of Pentaborane, Pentaborane - JP-4 Fuel Mixtures, and Trimethylborate Azeotrope Fuel in a Full-scale Turbojet Engine

This report summarizes the full-scale engine tests of pentaborane, pentaborane - JP-4 fuel mixtures, and trimethylborate azeotrope fuel. The tests were conducted in a full-scale turbojet engine at a simulated altitude of 50,000 feet and Mach number of 0.08. Engine speeds were 90 to 100 percent of rated speed. Pentaborane reduced the the specific fuel consumption to two-thirds that of JP-4 fuel. However, because boron oxide collected in the engine, the performance deteriorated with continued operation of pentaborane in each of the short-duration tests reported.

Breitwiesser, Roland↗
NASA NTRS1933

Experiments on the Distribution of Fuel in Fuel Sprays

The distribution of fuel in sprays for compression-ignition engines was investigated by taking high-speed spark photographs of fuel sprays reproduced under a wide variety of conditions, and also by injecting them against pieces of plasticine. A photographic study was made of sprays injected into evacuated chambers, into the atmosphere, into compressed air, and into transparent liquids. Pairs of identical sprays were injected counter to each other and their behavior analyzed. Small high velocity air jets were directed normally to the axes of fuel sprays, with the result that the envelope of spray which usually obscures the core was blown aside, leaving the core exposed on one side. The results showed that the distribution of the fuel within the sprays was very uneven.

Lee, Dana W↗
NASA NTRS1995

Dimethoxymethane: A Fuel For Direct-Oxidation Fuel Cells

Dimethoxymethane (DMM) identified as one of several high-energy fuels for direct-oxidation fuel cells. Found to undergo facile electro-oxidation to carbon dioxide and water, with methanol as possible intermediate product. Fuel electro-oxidized at sustained high rates without poisoning electrodes. Performance superior to that of methanol at same temperature. Synthesized from natural gas (methane) and is thus viable alternative to methanol in direct-oxidation fuel cells. Better performance expected at higher temperature and by use of Pt/Sn catalyst. Alternatively, low boiling temperature of DMM also makes it candidate for gas-feed operation.

Olah, George A.↗
NASA NTRS1995

Trioxane: A Fuel For Direct-Oxidation Fuel Cells

Trioxane identified as high-energy, nontoxic, solid substitute for formaldehyde as water-soluble fuel for use in direct-oxidation fuel cells. Found to undergo facile electrochemical oxidation to water and carbon dioxide at platinum and platinum-alloy electrodes in liquid-feed-type fuel cells that contain acid electrolytes or solid proton-exchange membrane electrolytes. Exhibits less crossover than do such conventional fuels as methanol and formaldehyde. Being solid at ambient temperature, trioxane offers significant advantages in handling and transportation. Synthesized from natural gas with relative ease.

Olah, George A.↗
NASA NTRS1999

Effects of Passive Fuel-Air Mixing Control on Burner Emissions Via Lobed Fuel Injectors

The present experimental study examines the effects of differing levels of passive fuel-air premixing on flame structures and their associated NO(x) and CO emissions. Four alternative fuel injector geometries were explored, three of which have lobed shapes. These lobed injectors mix fuel and air and strain species inter-faces to differing extents due to streamwise vorticity generation, thus creating different local or core equivalence ratios within flow regions upstream of flame ignition and stabilization. Prior experimental studies of two of these lobed injector flowfields focused on non-reactive mixing characteristics and emissions measurements for the case where air speeds were matched above and below the fuel injector, effectively generating stronger streamwise vorticity than spanwise vorticity. The present studies examine the effects of airstream mismatch (and hence additional spanwise vorticity generation), effects of confinement of the crossflow to reduce the local equivalence ratio, and the effects of altering the geometry and position of the flameholders. NO(x) and CO emissions as well as planar laser-induced fluorescence imaging (PLIF) of seeded acetone are used to characterize injector performance and reactive flow evolution.

Mitchell, M. G.↗
NASA NTRS2018

Flame Tube Testing of a GEA TAPS Injector: Effects of Fuel Staging on Combustor Fuel Spray Patterns, Flow Structure, and Speciation

This paper presents results in which we compare fuel staging and its effect on fuel spray pattern, velocity and speciation during combustion for several inlet conditions using a GE TAPS injector configuration. Planar laser-induced fluorescence (PLIF), particle image velocimetry (PIV) and phase Doppler interferometry (PDI) were used to investigate spray patterns and velocity. The 2D PIV provides slices in the flow of axial-vertical or axial horizontal velocity components. With 3D PDI, we obtained 3 components of velocity, and fuel drop sizes. Chemiluminescence imaging and spontaneous Raman scattering (SRS) were used to investigate flame structure, species location and relative species concentration. Phase Doppler and PIV data were acquired using scatter from fuel droplets; therefore, those data were obtained only at the pilot-only test points. Raman measurements were acquired only at 10/90 split points to avoid droplets.

GE TAPS↗
NASA NTRS2020

Simulation of Hydrogen Flow in a Nuclear-Thermal Propulsion Reactor Subsystem: Conjugate Heat Transfer in Surrogate Fuel Elements and Flow Through the Dome Inlet to the Fuel Elements

NASA is performing research related to a Nuclear-Thermal Propulsion (NTP) engine as a step toward future manned missions to Mars. BWX Technologies (BWXT), in conjunction with NASA, is developing the reactor subsystem for that NTP engine design. As a subset of the reactor subsystem, the fuel elements have continued to evolve in design, as well. A set of experiments within the Nuclear Thermal Reactor Element Environmental Simulator at NASA Marshall has been developed to compliment that design process, including a series of surrogate fuel elements. Before the experiments of each surrogate can be completed, they must be deemed safe using structural analysis, which itself requires thermal and conjugate heat transfer analyses of the articles. Therefore, conjugate heat transfer simulations of the hydrogen flow through the test article fuel element surrogates were developed to provide estimates of heating, as well as to provide assessments of the fluid flow through the elements. The set of simulations involved not only the separate test conditions, but also a sensitivity study to estimate the effect of physical parameter uncertainty on the selected quantities of interest. Additionally, the fluid flow through the fore section inner plenum dome to the entrances of the fuel elements, another section of the reactor subsystem still under active development, was simulated and analyzed. The simulations show the extent of non-uniformity in the mass flow distribution across the dome outlets. Furthermore, additional analyses estimate the effects of required flow blockages on the potential development of flow dynamics. These analyses were used in the design cycle to make improvements to the reactor subsystem design.

Kalen E. Braman↗
DOE OSTI2023

Nuclear fuel elements including protective structures, and related method of forming a nuclear fuel element

A nuclear fuel element includes a core comprising a fissile element and an additional element. A protective structure surrounds the core and comprises at least a first material surrounding the nuclear fuel. The first material comprises the fissile element and the additional element and comprises a greater than stoichiometric amount of the additional element. An outer portion of the nuclear fuel element comprises a metal. Related nuclear fuel elements, and related methods are also disclosed.

Griffith, George W.↗