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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

Time at Temperature Abstract and Intern Poster

Current NRC regulations for BWR operations dictate that any occurrence reaching the point of Departure from Nucleate Boiling (DNB) disqualifies the use of the fuel rod for further reactor operation. That criteria does not account for duration of rate of the power increase, the corresponding effects on material properties or rewetting that may occur. Previous Anticipated Operational Occurrences (AOOs) show short durations power increase that may require limited amounts of heat removal. Industrial experience has shown evidence that fuel can reach dryout yet continue to safely operate in regular reactor conditions. The gap in research into such occurrences is the motivation for a series of experiments, including this current work. Time-at-Temperature experiments aim to identify and characterize the microstructural changes in Zircaloy-2 under oxygen-free high temperatures. This work uses the FlashDSC instrument to rapidly ramp up and down the temperature of a focus ion beam (FIB) prepared large area lift-out (LALO) of Zircaloy-2 at a rate of 10,000 K/s to desired values. The focus is to characterize the microstructure evolution, if any, of Zircaloy-2 that may impact its performance under typical BWR conditions. This characterization includes analyzing grain structure and size, secondary phase particle (SPPs) size, shape, composition, and location using Transmission Electron Microscopy (TEM). Further data collection and analysis is in progress including diffraction pattern indexing and 4D STEM processing. While current results focus on the testing and characterizing unirradiated material, future plans include expansion to irradiated material to explore the effects of rapid transition rates seen in DNB and dryout conditions on irradiationg damage and defect annealing.

36 - MATERIALS SCIENCE↗

A reduced-order modeling of a tubular solar reactor for long duration thermochemical energy storage

The storage of solar energy in a solid form, referred to as a “solar fuel”, can be achieved through a process known as endothermic solar thermochemistry. This process transforms the absorbed solar energy into a stable and retrievable form that can be stored for extended periods of time. This paper presents a low–order heat transfer model of a counter–current tubular falling bed reactor designed to produce thermally reduced magnesium manganese oxide pellets for long duration thermochemical energy storage. The energy required for the endothermic reduction was supplied by concentrated solar energy or renewable electricity via indirect heating of the gas and solid reactants flowing in a ceramic tube. The counter-current gas flow enhances the mixing of the solid particles with the heat recuperation zone, allowing the gas and particles to enter and exit the tubular reactor close to room temperature. Further, the reactor was vertically oriented and was heated circumferentially by an adjustable level heat flux along a finite segment of its length. The temperature distribution of the reactor in response to transient changes along the tube was modeled by considering conduction, convection, and radiation heat transfer. Governing equations for the heat transfer model were solved by discretizing the reactor tube into a finite number of control volumes and using an energy balance for the heat exchange between the reactor wall, gas, and particles within the control volume. The energy absorbed during this endothermic reaction was modeled numerically by fitting the data of the chemical conversion rate with the corresponding temperature of particles in the heating zone. The numerical model has been experimentally validated using a reactor prototype made of a 121.92 cm alumina tube heated by a 7kW electric tube–furnace. The alumina tube receives magnesium manganese oxide pellets of 3.66±0.516 mm in diameter from the top, and a counter–current gas flow from the bottom. The reactor wall temperature was monitored by six thermocouples installed along the reactor tube length. The experimental procedure was numerically simulated, and the temperature variation along the reactor tube was compared with a matrix of experimental runs for a range of particles mass flowrates (0.75–1.25g/s) and corresponding gas flowrates (36–65 SLPM). The reactor system was heated gradually from room temperature to a steady state temperature of 1673K, and then cooled down to room temperature. The heating and cooling processes were simulated, and the numerical and experimental results were compared throughout processes. The numerical model showed similar trends to the experimental results, with an error of 0.69 to 7.9% for the particle inlet and 0.7 to 7.9% for the gas inlet during steady-state operation. The proposed numerical model can be implemented as a simplified physical model to design a feedback control system to regulate reactor temperature.

14 SOLAR ENERGY↗

Initial Assessment of CTF for Time-at-Temperature Applications

The US nuclear industry is interested in improving the economics of their fleet of light-water reactors (LWRs) by uprating US plants. One option being considered is to regain lost margin from overly conservative fuel safety limits. The current limit requires avoidance of critical heat flux (CHF) and prevents further operation of fuel that experiences a dry-out in boiling water reactors (BWRs) or departure from nucleate boiling (DNB) in pressurized water reactors (PWRs); however, it has been shown that temporary, mild dry-out of the fuel does not necessarily increase the risk of fuel failure during its normal anticipated operating life. Such mild dry-out or DNB events may occur during a plant anticipated operational occurrence (AOO), such as a locked rotor in a PWR or a pump trip in a BWR. The time-at-temperature (TAT) approach to regulating fuel operation aims to demonstrate that the fuel rod’s integrity is not challenged during such a mild transient that leads to CHF in which the fuel operates at an elevated temperature for a brief period of time. However, implementing this approach will require extensive fuel material experimental data, as well as supporting modeling and simulation (M&S) predictions, to ensure that the predicted fuel response during AOOs, with all applicable uncertainty considered, will not threaten the safety of the fuel during the transient or the remainder of its anticipated lifecycle. To address this need, a comprehensive effort is being proposed that includes generating cladding material data under TAT conditions, assessment of available code capabilities for TAT conditions, development of new mechanistic models, and demonstration of the M&S capabilities for AOOs of interest. This will require a joint effort between the Nuclear Energy Advanced Modeling and Simulation (NEAMS) and Advanced Fuels Campaign (AFC) programs, as well as close collaboration with nuclear industry stakeholders. The outcome of this collaboration will result in development and assessment of capabilities that can be used by the nuclear industry to support qualification of a TAT-based fuel failure criteria safety limit. This report focuses on the thermal hydraulics (T/H) modeling capabilities and summarizes currently available data for validating the T/H subchannel code CTF for TAT conditions, as well as preliminary assessment results of the code. The initial assessment also resulted in implementation of an alternative post-CHF heat transfer package, which has been shown to significantly improve accuracy. This report is not a final assessment and does not consider all available validation data; it is intended that a future assessment will more fully validate the code for this application.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Progress toward NIF opacity measurements

The opacities of iron and other mid-Z elements help to regulate the transport of energy in the sun. Recent experiments on the Sandia National Laboratories Z machine have shown large discrepancies between the measured and calculated opacities of iron at certain solar conditions. To replicate these opacity measurements a platform is being developed on the National Ignition Facility to measure the opacities of iron and other elements at the same conditions as in the Z experiments. The NIF platform consists of a hohlraum to heat the opacity sample to the desired conditions, a separate backlighter to radiograph the sample, and a spectrometer to give the spectrally resolved opacity. Not only must the opacity be measured but the temperature and density of the sample must also be accurately determined. This platform has now produced its first iron transmission measurements. Overall, these measurements will be presented along with plans for future measurements and details on how the measurements will be improved.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Saturation of magnetized plasma turbulence by propagating zonal flows

Strongly driven ion-scale turbulence in tokamak plasmas is shown to be regulated by a new propagating zonal flow mode, the toroidal secondary mode, which is nonlinearly supported by the turbulence. The mode grows and propagates due to the combined effects of zonal flow shearing and advection by the magnetic drift. Above a threshold in the turbulence level, small-scale toroidal secondary modes become unstable and shear apart turbulent eddies, forcing the turbulence level to remain near the threshold. This threshold condition is used to derive scaling laws for the turbulent heat flux, fluctuation spectra, and zonal flow amplitude, which are validated in nonlinear gyrokinetic simulations and explain previous experimental observations.

Nies, Richard [Princeton Univ., NJ (United States)↗

Contrasting Carbon–Water–Energy Dynamics in Perennial and Annual Bioenergy Agroecosystems Using Eddy Covariance and Interpretable Machine Learning

Understanding how agroecosystems respond to environmental variability is fundamental to predicting productivity and sustainability under a changing climate. We analyzed 55 site-years of high-frequency eddy covariance observations from five agroecosystems—two perennial grasses (miscanthus and switchgrass), two annual rotation systems (maize–soybean and sorghum–soybean), and a restored native prairie—to examine ecosystem-scale carbon, water, and energy fluxes. Using an interpretable machine-learning framework with regression tree ensembles, Shapley Additive Explanations, and Accumulated Local Effects, we quantified how environmental and temporal factors regulate gross primary productivity (GPP), evapotranspiration (ET), water-use efficiency, and the Bowen ratio. Perennials exhibited stronger physiological buffering and maintained fluxes across a broader range of temperature and moisture conditions, reflecting deeper rooting and persistent canopy cover. Annuals, in contrast, showed greater short-term variability and stronger coupling to atmospheric demand, with GPP and ET declining rapidly under low humidity or soil moisture. Differences in temperature sensitivity of Bowen ratio further revealed that perennials sustained proportionally greater sensible heat flux under cool conditions, whereas annuals exhibited constrained energy exchange when evaporative demand was low. Together, these results demonstrate that crop life cycle and canopy structure are fundamental determinants of ecosystem-scale carbon–water–energy coupling. By integrating long-term flux observations with interpretable machine learning, this study identifies the environmental drivers that shape agroecosystem function and highlights how conversion from annual to perennial feedstocks can enhance climatic resilience and alter land–atmosphere energy feedbacks. These findings provide a data-driven basis for improving crop and Earth-system models and for guiding bioenergy landscape design under future climate scenarios.

Accumulated Local Effects↗

Distinct Preflowering Drought Tolerance Strategies of Sorghum bicolor Genotype RTx430 Revealed by Subcellular Protein Profiling

Drought is the largest stress affecting agricultural crops, resulting in substantial reductions in yield. Plant adaptation to water stress is a complex trait involving changes in hormone signaling, physiology, and morphology. Sorghum (Sorghum bicolor (L.) Moench) is a C4 cereal grass; it is an agricultural staple, and it is particularly drought-tolerant. To better understand drought adaptation strategies, we compared the cytosolic- and organelle-enriched protein profiles of leaves from two Sorghum bicolor genotypes, RTx430 and BTx642, with differing preflowering drought tolerances after 8 weeks of growth under water limitation in the field. In agreement with previous findings, we observed significant drought-induced changes in the abundance of multiple heat shock proteins and dehydrins in both genotypes. Interestingly, our data suggest a larger genotype-specific drought response in protein profiles of organelles, while cytosolic responses are largely similar between genotypes. Organelle-enriched proteins whose abundance significantly changed exclusively in the preflowering drought-tolerant genotype RTx430 upon drought stress suggest multiple mechanisms of drought tolerance. These include an RTx430-specific change in proteins associated with ABA metabolism and signal transduction, Rubisco activation, reactive oxygen species scavenging, flowering time regulation, and epicuticular wax production. We discuss the current understanding of these processes in relation to drought tolerance and their potential implications.

59 BASIC BIOLOGICAL SCIENCES↗

The Future of Energy Efficiency for U.S. Buildings - Drivers and Market Scenarios

This paper identifies likely drivers of building efficiency over the next ten years and expectations for how efficiency markets may evolve over this period. To prepare these predictions, we conducted an extensive literature review, interviewed 22 experts, reviewed legislation and executive orders in 12 states, and implemented a detailed questionnaire completed by 41 efficiency practitioners. The two most important drivers revealed by our research are (1) public policies and regulations, particularly those associated with climate change mitigation and adaptation and (2) the cost of energy relative to the cost of delivering efficiency. Other important drivers are technology changes, economic conditions, social priorities, and industry (including utility) business practices for increasing the uptake of efficiency in buildings. Our research indicates that efficiency markets will increasingly focus on supporting building decarbonization and enabling demand flexibility through the use of controls in grid-interactive efficient buildings and communities. Efficiency improvements for specific technologies (e.g., heat pumps, controls, and windows) and technological advances not specific to energy technologies (e.g., interoperability, artificial intelligence, and universal internet access) will improve the efficacy of efficiency measures and actions. Marketing of efficient products and services will increasingly focus on grid services, decarbonization, non-energy benefits for consumers, and integration with other distributed energy resources (DERs). We anticipate increased investment in disadvantaged and historically underserved communities, recognizing the social, health, and safety benefits of efficient energy usage and remediating historical biases. Lastly, we predict that while state and local government actions will vary, jurisdictions will increase their efficiency goals overall.

Schiller, Steven R↗

Structural and magnetic properties of hard magnetic system Ce(Co 1 -Fe ) 4.4 Cu 0.6 (0 ≤ x ≤ 0.19)

The Ce(Co 1 -Fe ) 4.4 Cu 0.6 (0 ≤ x ≤ 0.19) is a composite, hard magnetic system that is based on the CaCu 5 -type structure (1:5). It shows both, unique magnetic and microstructural features that are essential for permanent magnets, e.g., exceptional squareness of the 2nd. quadrant of the magnetization loops and microstructural features typically needed for pinning. Samples solidified in alumina crucibles are coarse-grained and often clearly faceted and readily align in a magnetic field. X-ray, SEM, and TEM analyses show a 1:5-type single-phase material when quenched from high temperature, which, after heat treatment, transforms into a laminar coherent nanostructure through the formation of a dense array of extended intercalated regions. Furthermore, these extended intercalated regions are comprised of segments of the Ce 2 Ni 7 –type structure (2:7) which segregate into various closely related precipitates forming a nanostructure similar to the SmCo 5 - Sm 2 Co 17 composites seen in Sm-Co permanent magnets. Based on TEM and Lorentz microscopy of well-aligned single grain particles, the magnetic domains’ reversal mechanism is regulated by anisotropy fluctuations occurring along the easy direction of magnetization and strong exchange interactions between the matrix and defects (e.g.: stacking faults). Lorentz microscopy suggests the domain wall is not physically pinned by the defect, but rather is offset/deflected when it interacts with the defect. The Lorentz and magnetization data suggest that defects cause a bending of the moment away from the c axis inside the grains.

36 MATERIALS SCIENCE↗

Abrupt reduction in shipping emission as an inadvertent geoengineering termination shock produces substantial radiative warming

Abstract Human activities affect the Earth’s climate through modifying the composition of the atmosphere, which then creates radiative forcing that drives climate change. The warming effect of anthropogenic greenhouse gases has been partially balanced by the cooling effect of anthropogenic aerosols. In 2020, fuel regulations abruptly reduced the emission of sulfur dioxide from international shipping by about 80% and created an inadvertent geoengineering termination shock with global impact. Here we estimate the regulation leads to a radiative forcing of $$+0.2\pm 0.11$$ + 0.2 ± 0.11 Wm −2 averaged over the global ocean. The amount of radiative forcing could lead to a doubling (or more) of the warming rate in the 2020 s compared with the rate since 1980 with strong spatiotemporal heterogeneity. The warming effect is consistent with the recent observed strong warming in 2023 and expected to make the 2020 s anomalously warm. The forcing is equivalent in magnitude to 80% of the measured increase in planetary heat uptake since 2020. The radiative forcing also has strong hemispheric contrast, which has important implications for precipitation pattern changes. Our result suggests marine cloud brightening may be a viable geoengineering method in temporarily cooling the climate that has its unique challenges due to inherent spatiotemporal heterogeneity.

54 ENVIRONMENTAL SCIENCES↗

Bohm Criterion of Plasma Sheaths away from Asymptotic Limits

The plasma exit flow speed at the sheath entrance is constrained by the Bohm criterion. The so-called Bohm speed regulates the plasma particle and power exhaust fluxes to the wall, and it is commonly deployed as a boundary condition to exclude the sheath region in quasineutral plasma modeling. In this work, the Bohm criterion analysis is performed in the intermediate plasma regime away from the previously known limiting cases of adiabatic laws and the asymptotic limit of infinitesimal Debye length in a finite-size system, using the transport equations of an anisotropic plasma. The resulting Bohm speed has explicit dependence on local plasma heat flux, temperature isotropization, and thermal force. Comparison with kinetic simulations demonstrates its accuracy over the plasma-sheath transition region in which quasineutrality is weakly perturbed and the Bohm criterion applies.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Developing Practical Models of Complex Salts for Molten Salt Reactors

Molten salt reactors (MSRs) utilize salts as coolant or as the fuel and coolant together with fissile isotopes dissolved in the salt. It is necessary to therefore understand the behavior of the salts to effectively design, operate, and regulate such reactors, and thus there is a need for thermodynamic models for the salt systems. Molten salts, however, are difficult to represent as they exhibit short-range order that is dependent on both composition and temperature. A widely useful approach is the modified quasichemical model in the quadruplet approximation that provides for consideration of first- and second-nearest-neighbor coordination and interactions. Its use in the CALPHAD approach to system modeling requires fitting parameters using standard thermodynamic data such as phase equilibria, heat capacity, and others. A shortcoming of the model is its inability to directly vary coordination numbers with composition or temperature. Another issue is the difficulty in fitting model parameters using regression methods without already having very good initial values. The proposed paper will discuss these issues and note some practical methods for the effective generation of useful models.

Besmann, Theodore M. (ORCID:0000000155980550)↗

Physical protection regulates microbial thermal responses to chronic soil warming

Climate warming can affect the temperature sensitivity of microbial activity and growth efficiency, possibly explained by changes to microbially unavailable carbon (C) protected within in soil aggregates. Here, we assessed physical protection by crushing macroaggregates (250–2000 μm) and microaggregates (<250 μm) isolated from mineral soils exposed to 27 years of experimental warming (+5 °C). We hypothesized that removal of physical protection would increase microbial activity and reduce C use efficiency (CUE). We found that crushing increased microbial respiration and biomass turnover rate, but did not affect CUE. We also hypothesized that long-term warming would reduce the effect of physical protection on microbial activity, and that physical protection would attenuate microbial temperature sensitivity in heated compared to control soils. We found that long-term warming was associated with a smaller effect of physical protection for microbial respiration but with a larger effect for biomass turnover rate in macroaggregates. Physical protection reduced the temperature sensitivity of respiration but enhanced the temperature sensitivity of microbial biomass turnover rate in heated compared to control soils. Our work shows that long-term warming has contrasting effects on how microbial respiration, biomass turnover rate, and their thermal responses are mediated by physical protection within soil aggregates.

59 BASIC BIOLOGICAL SCIENCES↗

The role of the turbulence driving mode for the initial mass function

Turbulence is a critical ingredient for star formation, yet its role for the initial mass function (IMF) is not fully understood. Here we perform magnetohydrodynamical (MHD) simulations of star cluster formation including gravity, turbulence, magnetic fields, stellar heating, and outflow feedback to study the influence of the mode of turbulence driving on IMF. We find that simulations that employ purely compressive turbulence driving (COMP) produce a higher fraction of low-mass stars as compared to simulations that use purely solenoidal driving (SOL). The characteristic (median) mass of the sink particle (protostellar) distribution for COMP is shifted to lower masses by a factor of ∼1.5 compared to SOL. Our simulation IMFs capture the important features of the observed IMF form. We find that turbulence-regulated theories of the IMF match our simulation IMFs reasonably well in the high-mass and low-mass range, but underestimate the number of very low-mass stars, which form towards the later stages of our simulations and stop accreting due to dynamical interactions. Our simulations show that for both COMP and SOL, the multiplicity fraction is an increasing function of the primary mass, although the multiplicity fraction in COMP is higher than that of SOL for any primary mass range. We find that binary mass ratio distribution is independent of the turbulence driving mode. The average specific angular momentum of the sink particles in SOL is a factor of 2 higher than that for COMP. Overall, we conclude that the turbulence driving mode plays a significant role in shaping the IMF.

79 ASTRONOMY AND ASTROPHYSICS↗

Groundwater regulates interannual variations in evapotranspiration in a riparian semiarid ecosystem

Dryland ecosystems are an important component of Earth’s carbon, water, and energy budgets. Changes in hydroclimatic conditions can significantly alter land surface fluxes in these ecosystems. In regions with groundwater-river water exchange, land surface fluxes are strongly modulated by groundwater table fluctuations in response to river stage variations; however, interactions between fluxes and groundwater remain poorly understood in drylands. Here, we use eddy covariance data collected in paired upland and riparian semiarid ecosystems during two years with contrasting river flow conditions to examine interactions among river stage conditions, water table dynamics, meteorological drivers, and ecosystem fluxes. Elevated groundwater availability resulting from groundwater-surface water exchange at the riparian site enhanced the latent heat flux (LE, the energy form of evapotranspiration), which was sustained longer in the growing season during both years. At the upland site, mean LE during the dry season differed by less than 2% between the two years. In contrast, at the riparian site contrasting river flow conditions resulted in a 41% difference in peak monthly LE between the two years. The two-year mean LE in the summer at the riparian site was twice that at the upland site. Carbon uptake (NEP) and LE were well correlated at the upland site during both years, but at the riparian site enhanced summertime LE during the high river flow year did not correspond t enhanced NEP. Our results demonstrate that enhanced groundwater availability modulated by river stage variability is a critical driver of land surface fluxes in semiarid riparian ecosystems.

Missik, Justine E.↗

Radiological analysis and transmutation calculation of representative castable nanostructured alloys

In this work, radiological analysis regarding the waste management was performed on two current reduced-activation ferritic-martensitic (RAFM) steels Eurofer 97 and F82H and two castable nanostructured alloys (CNAs) CNA1 and CNA3 using the European DEMO first wall spectrum. CNA1 and CNA3 are a new generation of RAFM steels, which have increased amounts of nanoscale carbonitrides and carbides precipitates, respectively, via small composition modifications. Furthermore, the increased nitrogen in CNA1 leads to higher activity at ≥50 years, and thus to the disposal concern under the current NRC regulation. However, the calculation using Fetter’s evaluation leads to reduced waste disposal rating (WDR) of down to 0.25 depending on the damage dose from ~0.05 wt percent nitrogen in CNA1, and thus less concern on the waste disposal. Contact dose rate after 10 years from the first wall replacement primarily depends on the initial Co and Nb impurity levels. Other added elements, such as V and Si in CNA1 and Ti and Mn in CNA3, do not have significant effect on the specific activity, contact dose rate, or decay heat. Composition limits of CNAs are given based on the shallow burial disposal and materials recycling. In addition, composition evolution of typical precipitates in the CNAs was calculated using the DEMO first wall and the HFIR spectra. Larger transmutation-induced composition evolution occurs in the V/Ta-rich carbonitrides in CNA1 than that in the Ti-rich carbides in CNA3.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Benign termination of runaway electron beams on ASDEX Upgrade and TCV

Abstract This paper discusses the development of a benign termination scenario for runaway electron (RE) beams on ASDEX Upgrade and TCV. A systematic study revealed that a low electron density (n e ) companion plasma was required to achieve a large MHD instability, which expelled the confined REs over a large wetted area and allowed for the conversion of magnetic energy to radiation. Control of the companion plasma n e was achieved via neutral pressure regulation and was agnostic to material injection method. The neutral pressure required for recombination was found to be dependent on impurity species, quantity and RE current. On TCV,n e increased at neutral pressures above 1 Pa, indicating that higher collisionality between the REs and neutrals may lead to an upper pressure limit. The conversion of magnetic energy to radiated energy was measured on both machines and a decrease in efficiency was observed at high neutral pressure on TCV. The benign termination technique was able to prevent any significant increase in maximum heat flux on AUG from 200 to 600 kA of RE current, highlighting the ability of this approach to handle fully formed RE beams.

Physics↗

Structural and quantum chemical basis for OCP-mediated quenching of phycobilisomes

Cyanobacteria use large antenna complexes called phycobilisomes (PBSs) for light harvesting. However, intense light triggers non-photochemical quenching, where the orange carotenoid protein (OCP) binds to PBS, dissipating excess energy as heat. The mechanism of efficiently transferring energy from phycocyanobilins in PBS to canthaxanthin in OCP remains insufficiently understood. Using cryo–electron microscopy, we unveiled the OCP-PBS complex structure at 1.6- to 2.1-angstrom resolution, showcasing its inherent flexibility. Using multiscale quantum chemistry, we disclosed the quenching mechanism. Identifying key protein residues, we clarified how canthaxanthin’s transition dipole moment in its lowest-energy dark state becomes large enough for efficient energy transfer from phycocyanobilins. Our energy transfer model offers a detailed understanding of the atomic determinants of light harvesting regulation and antenna architecture in cyanobacteria.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗