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At least 271 records · Page 15

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DOE OSTI2021

Diol isomer revealed as a source of methyl ketene from propionic acid unimolecular decomposition

Carboxylic acids are important combustion intermediates, especially regarding the combustion of oxygenates such as ethyl esters. The purpose of this study is to discern the unimolecular decomposition pathways of one such carboxylic acid, propionic acid, using microreactor flow experiments with line-tunable photoionization mass spectrometry and infrared spectroscopy, along with high-level electronic structure calculations (CCSD(T)/cc-pV∞Z//M06-2X/cc-pVTZ level of theory) and master equation theory. Here, microreactor experiments were performed at 300–1500 K, pressures decreasing from roughly 300 Torr to vacuum pressure, and around 100 μs residence times. Primary products are methyl ketene, ketene, ethylene, and methyl radical. Theory suggests the two lowest energy bond fissions are active at these conditions and responsible for the production of ketene, methyl radical, and some ethylene. Importantly, theory revealed the significance of the isomerization of propionic acid to propene-1,1-diol, and the subsequent dehydrogenation reaction of the diol as an alternative explanation for the unimolecular formation of methyl ketene. This is predicted to be the dominant thermal decomposition pathway at lower temperatures (up to ~850 K). Line-tunable VUV photons allowed for isomer resolution of the products and showed no evidence of the diol of propionic acid surviving until detection, suggesting propene-1,1-diol decomposes either to methyl ketene and water rapidly, fragments upon ionization to a distonic ion inseparable from methyl ketene through our detection methods, or never stabilizes as propionic acid well-skips directly to methyl ketene. Infrared spectroscopy showed no evidence of the decarboxylation of propionic acid at these conditions. Updated rate constants and branching ratios for propionic acid decomposition are calculated and provided for future modeling studies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2026

Measuring the Stress Factors for Photovoltaic (PV) Backsheet Degradation

Back sheet failure has resulted in power loss and large-scale recall of photovoltaic modules, resulting in billions of dollars in lost revenue. The light exposure on the backside of a photovoltaic module comes primarily from reflected light which alters the distribution of natural sunlight. Because of this, modelling the backside exposure and duplicating the exposure is much more difficult than modeling the frontside exposure. This project aims to study how various back sheets and junction box materials degrade under different conditions and to develop Python code to help model and predict degradation. The stress factors for back-sheet degradation must be quantified to extrapolate accelerated stress tests to the field. Test samples were placed in the A3, A4, and A5 conditions, as defined in IEC 62788-7-2, to assess the temperature and humidity dependence of ultraviolet (UV) induced degradation. We are utilizing a custom chamber with exposure from 0.5 UV-suns to 5 UV-suns to understand the dependence of degradation on light intensity. A group of samples put in the A3 condition had glass filters with 50% UV cut-offs of 320 nm, 335 nm, and 360 nm to assess the wavelength dependence of UV degradation. All this data is necessary to assess the impact of non-standard UV light exposure. The material evaluation tests include gloss measurements, attenuated total internal reflectance Fourier transform infrared spectroscopy (ATR-FTIR), UV-visible reflectance/transmittance utilizing a Cary Ci7000 spectrophotometer, and a nano-indenter for surface hardness and modulus measurements. Alongside the experimental work, there is a computational effort using raytracing and Python open-source tools in PVDeg , PVLib, and Bifacial_Radiance. This code will create specific exposure scenarios and enable the evaluation of chamber degradation relative to field degradation. Equation 1 is a strawman equation used to model degradation on the backside of a PV module. We will create simplified code, based on the results of ray-tracing calculations, which uses a view factor approach to provide fast calculations for the most common exposure scenarios.

14 SOLAR ENERGY↗

DOE OSTI2022

Intense infrared lasers for strong-field science

The advent of chirped-pulse amplification in the 1980s and femtosecond Ti:sapphire lasers in the 1990s enabled transformative advances in intense laser–matter interaction physics. Whereas most of experiments have been conducted in the limited near-infrared range of 0.8–1 μm, theories predict that many physical phenomena such as high harmonic generation in gases favor long laser wavelengths in terms of extending the high-energy cutoff. Significant progress has been made in developing few-cycle, carrier-envelope phase-stabilized, high-peak-power lasers in the 1.6–2 μm range that has laid the foundation for attosecond X ray sources in the water window. Even longer wavelength lasers are becoming available that are suitable to study light filamentation, high harmonic generation, and laser–plasma interaction in the relativistic regime. Long-wavelength lasers are suitable for sub-bandgap strong-field excitation of a wide range of solid materials, including semiconductors. In the strong-field limit, bulk crystals also produce high-order harmonics. In this review, we first introduce several important wavelength scaling laws in strong-field physics, then describe recent breakthroughs in short- (1.4–3 μm), mid- (3–8 μm), and long-wave (8–15 μm) infrared laser technology, and finally provide examples of strong-field applications of these novel lasers. Furthermore, some of the broadband ultrafast infrared lasers will have profound effects on medicine, environmental protection, and national defense, because their wavelengths cover the water absorption band, the molecular fingerprint region, as well as the atmospheric infrared transparent window.

43 PARTICLE ACCELERATORS↗

DOE OSTI2023

An investigation on the structural stability of $\mathrm{ZIF}$-8 in water versus water-derived oxidative species in aqueous environment

We report the zeolitic-imidazolate-framework-8 (ZIF-8) is one of the extensively studied metal-organic frameworks (MOF) materials because of its unique structure. For its potential applicability in numerous fields, it becomes crucial to have detailed studies on the structural stability of ZIF-8, especially in aqueous environments. A number of studies have been conducted to investigate the breakdown process of the ZIF-8 structure in water; which is known as the hydrolysis of ZIF-8. However, those studies reported different opposing experimental observations on the role of water on the structural stability of ZIF-8, which created obscurity in understanding this phenomenon. This study explored the effects of different water-derived species on the structural stability of ZIF-8; specifically, examined the effects of only water and water with different oxidative species that may be generated by water molecules' dissociation under external energy or catalyst presence. To this effort, we experimentally probed the physical and chemical structural changes of ZIF-8 in DI water and three different solutions of hydrogen peroxides (H 2 O 2 ); taking H 2 O 2 as the source of oxidative species. To assess the changes in elemental compositions, chemical bonds, functional groups, crystal structure, and morphology, all the samples were analyzed by X-ray photoelectron spectroscopy (XPS), energy-dispersive x-ray (EDX) spectroscopy, Fourier Transform Infrared (FTIR) spectroscope, X-ray diffractometer (XRD), and scanning electron microscope (SEM). Significant structural changes in ZIF-8 occurred mainly in the presence of oxidative species in water. Notably, oxidative species' concentration exceeding 1 M heightened the deformation of the ZIF-8 structure.

36 MATERIALS SCIENCE↗

DOE OSTI2025

Optimizing semi-hydrogenation of unsaturated hydrocarbons by electrolyte engineering approach

Electrochemical hydrogenation of unsaturated hydrocarbons, when powered by renewables, represents a unique opportunity to substitute current energy-intensive synthetic routes. Modulation of adsorption energies of the organic substrate and key intermediates of the reaction is critical for fine tuning of the yield, selectivity and kinetics of the reaction. Interestingly, mounting evidence exists regarding the role of electrolyte composition in the outcome of semi-hydrogenation reactions. Nevertheless, electrolyte optimization is a complex task, owing to its hybrid nature. Indeed, it is composed of water serving as a proton source, an organic solvent necessary to dissolve the organic substrate and a conducting salt. Herein, we demonstrate that varying conducting salt and organic solvent has a dramatic impact on the outcomes of semi-hydrogenation of alkynes. By varying salt and water concentrations, we demonstrate that water does not serve as a proton source, and instead addition of an acid is necessary. While increasing the acid concentration increases the yield of the reaction, at too large concentrations the hydrogen evolution reaction becomes predominant. Furthermore, by combining electrochemical measurements with spectroscopic techniques including Fourier transform infrared (FTIR) spectroscopy and small angle X-ray spectroscopy (SAXS), we demonstrate that the electrolyte solvation structure dramatically impacts the yield of the reaction. Organic solvents weakly interacting with water, including acetonitrile, form aqueous nanoheterogeneities that prevent the organic substrate from accessing the catalyst interface and thus lead to limited yields. Instead, solvents such as dimethylformamide form homogeneous mixtures with which all reactants can access the interface, leading to yields greater than 80% for optimized compositions.

Zhang, Rongyu↗

DOE OSTI2023

High-resolution rovibrational spectroscopy of trans -formic acid in the v 1 OH stretching fundamental: Dark state coupling and evidence for charge delocalization dynamics

High-resolution infrared (IR) reduced-Doppler absorption spectra of jet-cooled gas phase trans-formic acid in the v 1 OH stretching fundamental region are reported for the first time, obtained by supersonically expanding trans- formic acid/Ar mixtures through a slit jet nozzle source and rotationally cooling to T rot ≈ 10.9(5) K, with ab- sorption signals recorded by high-resolution difference-frequency IR absorption spectroscopy. Two a/b-type rovibrational bands of comparable intensity, one ~10-fold weaker b-type band, and one ~6-fold weaker a-type band are observed, with vibrational band origins at 3570.493(5), 3566.793(5), 3560.032(9), and 3534.6869(2) cm –1 , respectively. Based on previous Raman jet spectroscopic work by Nejad and Sibert [A. Nejad, E.L. Sibert III, The Raman jet spectrum of trans-formic acid and its deuterated isotopologs: Combining theory and experi- ment to extend the vibrational database, J. Chem. Phys. 154(6) (2021) 064301.], these four rovibrational bands have been assigned to v 1 , (v 2 + v 7 ), (v 6 + 2v 7 + 2v 9 ), and 2v 3 , respectively. Specifically, two of the three upper dark states (2 1 7 1 (a') and 6 1 7 2 9 2 (a')) are close enough to the “bright” 1 1 (a') state to facilitate strong anharmonic resonance interactions, which results in intensity mixing into the two zero-order bands that would otherwise be “dark”. Furthermore, our high-resolution spectral analysis reveals that there are local rotational crossings be- tween these zero-order 1 1 and 2 1 7 1 states resulting in extra lines (i.e., some upper levels in the nominally v 1 band have majority zero-order 2 1 7 1 state character). This motivates development of a 3 coupled state (1 1 , 2 1 7 1 , and 6 1 7 2 9 2 ) picture to aid in the spectral analysis, which is able to match all 3 observed band origins and relative band intensities, as well as indicate the necessity of multistate (> 2) coupling. Though limited by range of J and Ka levels (J’ ≤ 9 and K a ’ ≤ 3) populated at supersonic jet temperatures, this work offers first precision spec- troscopic analysis of trans-formic acid in the v 1 OH stretch region, which should aid in assignment of the more complete yet highly congested room temperature FTIR spectra. Lastly, and in sharp contrast to the spectral complexity in the three predominantly b-type bands, the lone a-type 2v 3 rovibrational band at 3534.6869(2) cm –1 is well described by a simple, rigid asymmetric top Hamiltonian.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

Radio AGN selection in LoTSS DR2

ABSTRACT The wide-area component of the LOFAR Two-Metre Sky Survey (LoTSS) is currently the largest radio survey ever carried out, and a large fraction of the 4.5 million radio sources it contains have been optically identified with galaxies or quasars with spectroscopic or photometric redshifts. Identification of radio-luminous active galactic nucleus (AGN) from this LoTSS source catalogue is not only important from the point of view of understanding the accretion history of the universe, but also enables a wide range of other science. However, at present the vast majority of the optical identifications lack spectroscopic information or well-sampled spectral energy distributions. We show that colour and absolute magnitude information from the Wide-Field Infrared Survey Explorer (WISE) allows for the robust and efficient selection of radio AGN candidates, generating a radio AGN candidate sample of around 600 000 objects with flux density $> 1.1$ mJy, spanning 144-MHz luminosities between $10^{21}$ and $10^{29}$ W Hz$^{-1}$. We use the catalogue to constrain the total sky density of radio-luminous AGN and the evolution of their luminosity function between $z=0$ and $z\approx 1$, and show that the typical mass of their host galaxies, around $10^{11} {\rm M}_\odot$, is essentially independent of radio luminosity above around $L_{144} \approx 10^{24}$ W Hz$^{-1}$. Combining with Very Large Array Sky Survey (VLASS) data, we show that the core prominences, radio spectral indices and variability of extended sources from the sample are qualitatively consistent with the expectations from unified models. A catalogue of the radio AGN candidates is released with this paper.

Hardcastle, M. J. (ORCID:0000000342231117)↗

DOE OSTI2020

Spectral Variability of VHS J1256–1257b from 1 to 5 μm

Multiwavelength time-resolved observations of rotationally modulated variability from brown dwarfs and giant exoplanets are the most effective method for constraining their heterogeneous atmospheric structures. In a companion paper, we reported the discovery of strong near-infrared variability in HST/WFC3/G141 light curves of the very red L-dwarf companion VHS J1256–1257b. In this paper, we present a follow-up 36 hr Spitzer/IRAC Channel 2 light curve together with an in-depth analysis of the Hubble space telescope (HST) and the Spitzer data. The combined data set provides time-resolved light curves of VHS1256b sampling 1.1 to 4.5 μm. The Spitzer light curve is best fit with a single sine wave with a period of 22.04 ± 0.05 hr and a peak-to-peak amplitude of 5.76 ± 0.04%. Combining the period with a previously measured projected rotational velocity (v sin i), we find that VHS1256b is most consistent with equatorial viewing geometry. The HST/G141+Spitzer spectral energy distribution favors a model with a T{sub eff} of 1000 K and low surface gravity with disequilibrium chemistry. The spectral variability of VHS1256b is consistent with predictions from partly cloudy models, suggesting that heterogeneous clouds are the dominant source of the observed modulations. We find evidence at the 3.3σ level for amplitude variations within the 1.67 μm CH{sub 4} band, which is the first such detection for a variable L-dwarf. We compare the HST/G141 time-resolved spectra of three red L-dwarfs with high-amplitude near-infrared rotational modulations and find that although their time-averaged spectra are similar, their spectroscopic variabilities exhibit notable differences. This diversity reinforces the advantage of time-resolved spectroscopic observations for understanding the atmospheres of brown dwarfs and directly imaged exoplanets.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2023

A Dive into Underwater Solar Cells

Our oceans are vast, mostly unexplored and difficult to monitor. Large-scale implementation of a fully autonomous 'Internet of Underwater Things' would transform how we collect and share data from this domain; however, deployment is prohibited by the lack of persistent power sources. In principle, underwater solar-energy generation can complement the use of batteries and provide a solution, although dedicated research is needed since traditional silicon solar cells do not perform well underwater due to water's strong absorption of near-infrared light. In this Perspective we present examples of solar-powered underwater applications and discuss which types of solar-harvesting materials could be appropriate, including GaInP variants, CdTe, organic semiconductors, and perovskite semiconductors. We also discuss challenges that need to be addressed, such as the development of effective antifouling coatings and new certification standards given that underwater conditions are starkly different from those in terrestrial environments.

antifouling coatings↗

DOE OSTI2022

Effect of amine type on acidic toxic gas adsorption at ambient conditions on modified CuBTC

We report two amine-modified copper-based Metal Organic Frameworks (MOF (CuBTC)) of different surface chemical and textural features were synthesized and used as adsorbents of acidic toxic gases (NO 2 and H 2 S) in both moist (71% relative humidity (R.H.)) and dry conditions. The initial and exhausted samples were characterized by nitrogen adsorption, powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analysis and Fourier transform infrared spectroscopy. The addition of melamine prevented full growth of CuBTC crystals and resulted in amorphous-like particles with sizes less than 200 nm. The material was non-porous with a small surface area. When urea was used as an amine source, the resulting particles maintained the overall octahedral shape of the parent CuBTC MOF and the material was more porous than the parent MOF. While the urea-modified CuBTC sample performed well as an NO 2 adsorbent in the presence of moisture, the reactivity of the melamine-modified sample and its physical properties provided a favorable environment for the removal of H 2 S. The incorporation of amines into the MOF structure also resulted in surface defects /open copper sites that favored the removal of toxic gases in dry conditions. The reactivity of the adsorbents with toxic gases was demonstrated by the changes in the adsorbent colors, in texture, and in surface chemistry (organic salts, complexes, sulfides and nitrates were formed).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Fraction of broad absorption line quasars in different radio morphologies

ABSTRACT In this study, we investigated the orientation model of Broad Absorption Line (BAL) quasars using a sample of sources that are common in Sloan Digital Sky Survey (SDSS) Data Release (DR)-16 quasar catalogue and Very Large Array (VLA)-Faint Images of the Radio Sky at Twenty Centimeters (FIRST) survey. Using the radio cut-out images from the FIRST survey, we first designed a deep-learning model using convolutional neural networks (CNN) to classify the quasar radio morphologies into the core-only, young jet, single lobe, or triples. These radio morphologies are further sub-classified into core-dominated and lobe-dominated sources. The CNN models can classify the sources with a high precision of >98 ${{\ \rm per\ cent}}$ for all the morphological sub-classes. The average BAL fraction in the resolved core, core-dominated, and lobe-dominated quasars are consistent with the BAL fraction inferred from radio and infrared surveys. We also present the distribution of BAL quasars as a function of quasar orientation by using the radio core-dominance as an orientation indicator. A similar analysis is performed for HiBALs, LoBALs, and FeLoBALs. All the radio morphological sub-classes and BAL sub-classes show an increase in BAL fraction at high orientation angles of the jets with respect to the line of sight. Our analysis suggests that BAL quasars are more likely to be found in viewing angles close to the equatorial plane of the quasar. However, a pure orientation model is inadequate, and a combination of orientation and evolution is probably the best way to explain the complete BAL phenomena.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2026

Deep X-Ray Observation of NGC 3221: Everything Everywhere All at Once

We present a comprehensive analysis of 475 ks (438 ks unpublished and 37 ks archival) XMM-Newton/EPIC-pn observations of a nearby, highly inclined, star-forming, luminous infrared galaxy NGC 3221 through spatial, temporal, and spectral information. We confirm the presence of a low-luminosity (presumably Compton-thick) active galactic nucleus (AGN). The 0.4–12 keV luminosity and the hardness ratio of the six ultraluminous X-ray sources previously identified in Chandra data exhibit diverse variability on day scales. The collective emission from unresolved sources exhibits a different day-scale variability. We have also discovered two new predominantly soft (<1 keV) sources. One of these has an enigmatic spectral shape featuring a soft component, which we interpret as a superbubble in NGC 3221, and a variable hard component from a compact object, unresolved from the superbubble. We do not confidently detect any X-ray emission from SN 1961L. The hot gas in the interstellar medium (ISM, out to ±6 kpc from the disk plane) and that in the extraplanar region (6–12 kpc) both require two thermal phases at ∼0.15 keV and ∼0.55 keV. The ∼0.55 keV component is fainter in the ISM than the ∼0.15 keV component, but the emission from the latter falls off more steeply with disk height than the emission from the former. This makes the extraplanar region hotter and less dense than the ISM. The proximity of NGC 3221 and the occurrence of the underluminous AGN offer a unique observing opportunity to study the hot diffuse medium along with nuclear and diskwide point sources.

Das, Sanskriti [Stanford Univ., CA (United States)↗

DOE OSTI2026

Magnetic brightening and nanoscale imaging of spin-polarized helical edge modes in ZrTe 5

Efficient charge transport remains a fundamental challenge for nanoelectronic devices, as their performance is constrained by high dissipation and the impedance mismatch between high-frequency signal sources and nanoscale circuit interfaces. Although topologically protected helical edge modes offer a dissipationless and backscattering-resilient alternative, achieving nanoscale control over these modes requires direct visualization of their spatial electrodynamics, especially under high-frequency operation. Here, by utilizing cryogenic magneto-infrared scattering-type scanning near-field optical microscopy (cm-IR-sSNOM), we image spin-polarized helical edge channels in ZrTe 5 at the nanoscale, revealing magnetic-field-induced brightening as a high-frequency electrodynamic signature of robust topological edge modes. Operating at 1.8 K and under a magnetic field of up to 5 T, we observe the emergence of edge-state polarizability at infrared frequencies that is notably resilient to the magnetic gaps that typically quench d.c. and microwave edge transport. Our results reveal a topological ‘two-lane’ spatial reorganization in which an external magnetic field induces a spin-population imbalance between counterpropagating edge modes. Favoured helical branches are confined against physical boundaries to activate a net infrared near-field contrast. This electrodynamic response scales linearly with the number of atomic layers, which confirms that individual layers in ZrTe 5 preserve their discrete quantum spin Hall identities. These findings may be useful for developing topological spintronic devices, as the magnetic infrared tunability of helical edge channels provides a pathway for low-loss nanoscale interconnects and high-speed information processing.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Shooter Alarm System Final Report FY23

Lawrence Livermore National Laboratory (LLNL) is developing a multiphysics sensor package for automatic live arms fire detection for use in schools, houses of worship, hospi tals, etc. The goal is to have a package the size of a common smoke or CO2 detector with a price point of $50 or less which may be deployed throughout the aforementioned facilities. The commercial device will detect live gun fire with low probability of false alarm and auto matically alert first responders. A prototype board with four accelerometers, two infrared (IR) and two microphones has been developed and deployed at two experiments at LLNL’s Small Firearms Training Facility (SFTF). The device successfully and consistently measured signals on the accelerometer and acoustic channels. IR responses were measured depending upon the environment and sound source.

42 ENGINEERING↗

DOE OSTI2022

High Carrier Lifetimes in Epitaxial Germanium-Tin/Al(In)As Heterostructures with Variable Tin Compositions

Group IV-based germanium-tin (Ge1-ySny) compositional materials have recently shown great promise for infrared detection, light emission and ultra-low power transistors. High carrier lifetimes are desirable for enhancing the detection limit and efficiency of photodetectors, low threshold current density in lasers, and low tunneling barrier height by lowering defects and dislocations at the heterointerface of a source and a channel. Here, carrier lifetimes in epitaxial germanium (Ge) and variable tin (Sn) compositional Ge1-ySny materials were experimentally determined on GaAs substrates using the contactless microwave photoconductive decay (u-PCD) technique at an excitation wavelength of 1500 nm. Sharp (2 x 2) reflection high energy electron diffraction patterns and low surface roughness were observed from the surface of the Ge0.97Sn0.03 epilayer. X-ray rocking curves from Ge0.97Sn0.03 and Ge0.94Sn0.06 layers demonstrated the pseudomorphic and lattice-matched growth on AlAs and In0.12Al0.88As buffers, respectively, further substantiated by reciprocal space maps and abrupt heterointerfaces evident from the presence of Pendellosung oscillations. High effective carrier lifetimes of 150 ns to 450 ns were measured for Ge1-ySny epilayers as a function of Sn composition, surface roughness, growth temperature, and layer thickness. The observed increase in the carrier lifetime with an increasing Ge layer thickness and a reducing surface roughness, by incorporating Sn, were explained. The enhancement of the carrier lifetime with an increasing Sn concentration was achieved by controlling the defects with lattice-matched Ge0.94Sn0.06/In0.12Al0.88As heterointerfaces or the pseudomorphic growth of Ge0.94Sn0.06 on GaAs. Therefore, our monolithic integration of variable Sn alloy compositional Ge1-ySny materials with high carrier lifetimes opens avenues to realize electronic and optoelectronic devices.

carrier lifetimes↗

DOE OSTI2020

The effects of warming and soil chemistry on bacterial community structure in Arctic tundra soils

Soil microbial communities in the Arctic play a critical role in regulating the global carbon (C) cycle. Vast amounts of C are stored in northern latitude soils, and rising temperatures in the Arctic threaten to thaw permafrost, making relatively inaccessible C sources more available for mineralization by soil microbes. Few studies have characterized how microbial community structure responds to thawing permafrost in the context of varying soil chemistries associated with contrasting tundra landscapes. Here, we subjected active layer and permafrost soils from upland and lowland tundra sites on the North Slope of Alaska to a soil-warming incubation experiment and compared soil bacterial community profiles (obtained by 16S rRNA amplicon sequencing) before and after incubation. The influence of soil composition (characterized by mid-infrared [MIR] spectroscopy) on bacterial community structure and class abundance was analyzed using redundancy and correlation analyses. We found increased abundances of Alphaproteobacteria, Gammaproteobacteria, and Bacteroidetes [Sphingobacteriia] post incubation, particularly in permafrost soils. The categorical descriptors site and soil layer had the most explanatory power in our predictive models of bacterial community structure, highlighting the close relationship between soil bacteria and the soil environment. Specific soil chemical attributes characterizing the soil environments that were found to be the best predictors include MIR spectral bands associated with inorganic C, silicates, amide II (C=N stretch), and carboxylics (C-O stretch), and MIR peak ratios representing C substrate quality. Overall, these results further characterize soil bacterial community shifts that may occur as a frozen environment with limited access to C sources, such as is found in undisturbed permafrost, transitions to warmer and more C-available environments, such as is predicted in thawing permafrost due to climate change.

16S rRNA sequencing↗

DOE OSTI2024

A More Transparent Infrared Window

The infrared window region (780–1,250 cm –1 , 12.8 to 8.0 μm) is of great importance to Earth's climate due to its high transparency and thermal energy. We present here a new investigation of the transparency of this spectral region based on observations by interferometers of downwelling surface radiance at two DOE Atmospheric Radiation Measurement program sites. We focus on the dominant source of absorption in this region, the water vapor continuum, and derive updated values of spectral absorption coefficients for both the self and foreign continua. Our results show that the self continuum is too strong in the previous version of Mlawer-Tobin_Clough-Kneizys-Davies (MT_CKD) water vapor continuum model, a result that is consistent with other recent analyses, while the foreign continuum is too weak in MT_CKD. In general, the weaker self continuum derived in this study results in an overall increase in atmospheric transparency in the window, although in atmospheres with low amounts of water vapor the transparency may slightly decrease due to the increase in foreign continuum absorption. These continuum changes lead to a significant decrease in downwelling longwave flux at the surface for moist atmospheres and a modest increase in outgoing longwave radiation. The increased fraction of surface-leaving radiation that escapes to space leads to a notable increase (~5–10%) in climate feedback, implying that climate simulations that use the new infrared window continuum will show somewhat less warming than before. This study also points out the possibly important role that aerosol absorption may play in the longwave radiative budget.

58 GEOSCIENCES↗

DOE OSTI2024

Data/code for Mlawer et al. 2024 (A more transparent infrared window)

54 ENVIRONMENTAL SCIENCES↗