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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

Radiative lifetime of the 3s3p exp 3(exp 5 S sub 2 exp 0) metastable level of P(+)

The present experimental and theoretical results for the radiative lifetime of the 3s3p exp 3(exp 5 S sub 2 exp 0) metastable level of P(+) encompass an experimental determination of the (exp 5 S sub 2 exp 0) lifetime which represents the first measured lifetime of a low charge-state ion in the Si I sequence. This constitutes a fundamental test of the theoretical methods used to determine transition possibilities for intercombination lines involving this level, and suggests that theoretical techniques used to determine such transition probabilities in low-Z species of the Si I isoelectronic sequence should be reevaluated.

Calamai, Anthony G.↗

Radiative lifetimes of the CN (A 2 Pi i) electronic state

Radiative lifetimes have been measured for CN (A 2 Pi i v-prime = 2...7). Ground-state radicals formed in the 193 nm photolysis of C2N2 and ClCN were excited to A 2 Pi i v-prime = 2...7 vibrational levels. The decay was monitored by following the fluorescence. Cascading effects were eliminated by working at low pressures and monitoring emission from a single vibrational band. Quenching rates and zero-pressure radiative lifetimes were obtained from Stern-Volmer plots. The lifetimes are significantly lower than previous measurements and theoretical calculations for vibrational states v-prime over 2.

Lu, Richang↗

Radiative lifetimes in B I using ultraviolet and vacuum-ultraviolet laser-induced fluorescence

Radiative lifetimes of the eight lowest even parity levels in the doublet system of B I are measured using time-resolved laser-induced fluorescence in the UV and VUV on an atomic beam of boron. The accurate lifetimes provide a base for improved determination of absolute transition probabilities in B I. The techniques described are broadly applicable to measurement of lifetimes of levels with transitions in the visible, UV, and VUV in almost any element.

O'Brian, T. R.↗

Development of a simplified gravitational model for lifetime studies of lunar satellite orbits

Future lunar missions will involve long stay times in orbit about the moon. The moon's nonspherical gravitational field is the primary perturbation on a low altitude parking orbit. The objective of this study is to determine the orbital lifetime of a nearly circular low altitude parking orbit. In the present analysis, a simplified gravitational model of the moon is introduced which will enable mission designers to easily predict long term changes in lunar parking orbits at the preliminary design level. The development of a simplified gravitational model with sufficient accuracy is necessary to investigate orbital lifetimes for the large number of orbital parameters possible. Utilization of a simplified model will significantly reduce the required computational time needed to perform this analysis. By investigating the effects of the lunar gravity model on the various parking orbits, the parameters which are important in determining lifetime predictions are identified.

Meyer, Kurt W.↗

5-year lifetime hybrid superfluid helium dewar for the AXAF X-Ray Spectrometer (XRS)

The focal plane of the AXAF X-Ray Spectrometer requires an operating temperature of 0.1 K with a mission lifetime of 5 yrs. This demanding task is accomplished with a hybrid cryogenic subsystem consisting of mechanical coolers, a superfluid helium dewar and an adiabatic demagnetization refrigerator. By using mechanical coolers to remove heat from the dewar outer vapor-cooled shield, a 5-yr lifetime is achievable with only a 483-liter tank. This approach takes advantage of flight-proven, high-performance dewar technology and recent success in the development of split, Stirling-cycle mechanical coolers. Although the dewar design principles are similar to those used previously, parasitic heat flow is reduced to a new level by an optimized tension strap support system and careful attention to insulation system details. The benefit of the mechanical coolers is maximized by dewar interface design features that minimize parasitic heating and thermal impedance of the coupling. The dewar design and thermal performance analysis are discussed. Helium lifetime sensitivities and the effects of mechanical cooler failures are predicted.

Nieczkoski, Stephen J.↗

Investigation of the Compressive Strength and Creep Lifetime of 2024-T3 Aluminum-Alloy Plates at Elevated Temperatures

The results of elevated-temperature compressive strength and creep tests of 2024-t3 (formerly 24s-t3) aluminum alloy plates supported in v-grooves are presented. The strength-test results indicate that a relation previously developed for predicting plate compressive strength for plates of all materials at room temperature is also satisfactory for determining elevated-temperature strength. Creep-lifetime results are presented for plates in the form of master creep-lifetime curves by using a time-temperature parameter that is convenient for summarizing tensile creep-rupture data. A comparison is made between tensile and compressive creep lifetime for the plates and a method that made use of isochronous stress-strain curves for predicting plate-creep failure stresses is investigated.

Mathauser, Eldon E↗

Preliminary investigation of the compressive strength and creep lifetime of 2024-T3 (formerly 24S-T3) aluminum-alloy plates at elevated temperatures

The results of elevated-temperature compressive strength and creep tests of 2024-T3 (formerly 23S-T3) aluminum-alloy plates supported in V-grooves are presented. For determining elevated-temperature strength, where creep effects are negligible, a relation previously developed for predicting plate compressive strength at room temperature was satisfactory. Creep-lifetime results are presented for the plates in the form of master creep-lifetime curves by using a time-temperature parameter that is convenient for summarizing tensile creep-rupture data. A comparison is made between tensile and compressive creep lifetime for the plates, and the magnitude by which the design stress is decreased because of material creep and loss of strength due to exposure at elevated temperatures is indicated.

Mathauser, Eldon E↗

Microstructural Characterization of Thin Polyimide Films by Positron Lifetime Spectroscopy

Positron lifetimes have been measured in a series of thin aromatic polyimide films. No evidence of positronium formation was observed in any of the films investigated. All test films exhibited only two positron lifetime components, the longer component corresponding to the positrons annihilating at shallow traps. Based on these trapped positron lifetimes, free volume fractions have been calculated for all the films tested. A free volume model has been developed to calculate the dielectric constants of thin polyimide films. The experimental and the calculated values for the dielectric constants of the films tested are in reasonably good agreement. It has been further noted that the presence of bulky CF(sub 3) groups and meta linkages in the polyimide structure results in higher free volume fraction and, consequently, lower dielectric constant values for the films studied.

Eftekhari, A.↗

Infrared Radiative Forcing and Atmospheric Lifetimes of Trace Species Based on Observations from UARS

Observations from instruments on the Upper Atmosphere Research Satellite (UARS) have been used to constrain calculations of infrared radiative forcing by CH4, CCl2F2 and N2O, and to determine lifetimes Of CCl2F2 and N2O- Radiative forcing is calculated as a change in net infrared flux at the tropopause that results from an increase in trace gas amount from pre-industrial (1750) to contemporary (1992) times. Latitudinal and seasonal variations are considered explicitly, using distributions of trace gases and temperature in the stratosphere from UARS measurements and seasonally averaged cloud statistics from the International Satellite Cloud Climatology Project. Top-of-atmosphere fluxes calculated for the contemporary period are in good agreement with satellite measurements from the Earth Radiation Budget Experiment. Globally averaged values of the radiative forcing are 0.536, 0.125, and 0.108 W m-2 for CH4, CCl2F2, and N2O, respectively. The largest forcing occurs near subtropical latitudes during summer, predominantly as a result of the combination of cloud-free skies and a high, cold tropopause. Clouds are found to play a significant role in regulating infrared forcing, reducing the magnitude of the forcing by 30-40% compared to the case of clear skies. The vertical profile of CCl2F2 is important in determining its radiative forcing; use of a height-independent mixing ratio in the stratosphere leads to an over prediction of the forcing by 10%. The impact of stratospheric profiles on radiative forcing by CH4 and N2O is less than 2%. UARS-based distributions of CCl2F2 and N2O are used also to determine global destruction rates and instantaneous lifetimes of these gases. Rates of photolytic destruction in the stratosphere are calculated using solar ultraviolet irradiances measured on UARS and a line-by-line model of absorption in the oxygen Schumann-Runge bands. Lifetimes are 114 +/- 22 and 118 +/- 25 years for CCl2F2 and N2O, respectively.

Minschwaner, K.↗

Theoretical Determination of Lifetime of Compressed Plates at Elevated Temperatures

A method for the theoretical determination of the lifetime of com- pressed plates at elevated temperatures is presented. In this approach, linearized equations are used throughout with the assumption that the plate material is a standard linear solid. The critical time (lifetime) is determined by reducing the time-dependent behavior to the time- independent response of purely elastic buckling. Theoretically predicted lifetimes of 2024-T3 (formerly 24S-T3) aluminum-alloy plates at 450 F are compared with experimental values obtained in previous work.

Herrmann, George↗

Long-Term Reliability of SiGe/Si HBTs From Accelerated Lifetime Testing

Accelerated lifetime tests were performed on double-mesa structure Si(0.7)Ge(0.3)/Si npn heterojunction bipolar transistors, grown by molecular beam epitaxy, in the temperature range of 175 C-275 C. The transistors (with 5x20 sq micron emitter area) have DC current gains approx. 40-50 and f(sub T) and f(sub max) of up to 22 GHz and 25 GHz, respectively. It is found that a gradual degradation in these devices is caused by the recombination enhanced impurity diffusion (REID) of boron atoms from the p-type base region and the associated formation of parasitic energy barriers to electron transport from the emitter to collector layers. This REED has been quantitatively modeled and explained, to the first order of approximation, and the agreement with the measured data is good. The mean time to failure (MTTF) of these devices at room temperature under 1.35 x 10(exp 4) A/sq cm current density operation is estimated from the extrapolation of the Arrhenius plots of device lifetime versus reciprocal temperature. The results of the reliability tests offer valuable feedback for SiGe heterostructure design in order to improve the long-term reliability of the devices and circuits made with them. Hot electron induced degradation of the base-emitter junction was also observed during the accelerated lifetime testing. In order to improve the HBT reliability endangered by the hot electrons, deuterium sintered techniques have been proposed. The preliminary results from this study show that a deuterium-sintered HBT is, indeed, more resistant to hot-electron induced base-emitter junction degradation.

Bhattacharya, Pallab↗

Supergranule Rotation Rates and Lifetimes

Previous measurements of the rotation rate of the supergranule Doppler pattern have revealed three interesting characteristics. 1) The supergranule pattern rotates faster than the plasma at the surface and, at each latitude, it rotates faster than the plasma at any level below the surface. 2) Larger cells rotate more rapidly than smaller cells. 3) Faster rotation rates are found when using larger time lags between Doppler images. These last two characteristics are consistent with the idea that large cells live longer and extend deeper into the Sun where the rotation rate is faster. A re-examination of the rotation rates and lifetimes of the Doppler patterns seen with the Michelson Doppler Imager (MDI) instrument on Solar and Heliospheric Observatory (SOHO) confirms these characteristics. However, a simulation of the data using a spectrum for the cellular flows that matches the observed spectrum shows that these characteristics can be largely reproduced by cellular patterns that rotate at the same rate without any dependence upon cell size, The rotation rate , and its dependence on latitude, is nonetheless still faster than the surface or internal rotation rate. The difference in rotation rates as functions of cell size and time lag between observations is attributed to projection effects on the line-of-sight Doppler signal. This data simulation is also used to determine characteristic lifetimes for the cellular patterns as a function of cell size. These lifetime determinations are also affected by projection effects on the line-of-sight Doppler signal.

Hathaway, David H.↗

Relative Lifetimes of MAPLUB Greases for Space Applications

A Spiral Orbit Tribometer was employed to evaluate the tribological behavior and relative lifetimes of several commercially available greases under ultrahigh vacuum. These greases are either based on a multiply alkylated cyclopentane oil, or a perfluoropolyalkylether oil, and a thickener made of polytetrafluoroethylene (PTFE) telomer. The multiply alkylated cyclopentane (MAC) greases yielded long lifetimes, while perfluoropolyalkylether (PFPE) greases yielded short lifetimes.

Marchetti, Mario↗

Pt and Hf Additions to NiAl Bond Coats and Their Effect on the Lifetime of Thermal Barrier Coatings

The lifetimes of thermal barrier coatings (TBC's) with various NiAlPt(HfZr) bond coats were determined by cyclic oxidation testing at 1163 C (2125 F). The bond coats were sprayed from powders by low pressure plasma spraying onto Rene N5 superalloy substrates. Yttria stabilized zirconia (8YSZ) top coats were applied by air plasma spraying. Surprisingly, there was not a strong correlation between TBC lifetime and Pt or Hf content although Zr additions decreased lifetimes. TBC failure morphologies and bond coat microstructures were examined and are discussed with respect to the bond coat compositions.

Nesbitt, J. A.↗

The Relationship of Loss, Mean Age of Air and the Distribution of CFC's to Stratospheric Circulation and Implications for Atmospheric Lifetimes

Model-derived estimates of the annually integrated destruction and lifetime for various ozone depleting substances (ODSs) depend on the simulated stratospheric transport and mixing in the global model used to produce the estimate. Observations in the middle and high latitude lower stratosphere show that the mean age of an air parcel (i.e., the time since its stratospheric entry) is related to the fractional release for the ODs (i.e., the amount of the ODS that has been destroyed relative to the amount at the time of stratospheric entry). We use back trajectory calculations to produce an age spectrum, and explain the relationship between the mean age and the fractional release by showing that older elements in the age spectrum have experienced higher altitudes and greater ODs destruction than younger elements. In our study, models with faster circulations produce distributions for the age-of-air that are 'young' compared to a distribution derived from observations. These models also fail to reproduce the observed relationship between the mean age of air and the fractional release. Models with slower circulations produce both realistic distributions for mean age and a realistic relationship between mean age and fractional release. These models also produce a CFCl3 lifetime of approximately 56 years, longer than the 45 year lifetime used to project future mixing ratios. We find that the use of flux boundary conditions in assessment models would have several advantages, including consistency between ODS evolution and simulated loss even if the simulated residual circulation changes due to climate change.

Douglas, A. R.↗

Effect of Nitrogen Gas on the Lifetime of Carbon Nanotube Field Emitters for Electron-Impact Ionization Mass Spectrometry

The lifetime of a patterned carbon nanotube film is evaluated for use as the cold cathode field emission ionization source of a miniaturized mass spectrometer. Emitted current is measured as a function of time for varying partial pressures of nitrogen gas to explore the robustness and lifetime of carbon nanotube cathodes near the expected operational voltages (70-100 eV) for efficient ionization in mass spectrometry. As expected, cathode lifetime scales inversely with partial pressure of nitrogen. Results are presented within the context of previous carbon nanotube investigations, and implications for planetary science mass spectrometry applications are discussed.

Getty, Stephanie A.↗

Lifetime Assessment of the NEXT Ion Thruster

Ion thrusters are low thrust, high specific impulse devices with required operational lifetimes on the order of 10,000 to 100,000 hr. The NEXT ion thruster is the latest generation of ion thrusters under development. The NEXT ion thruster currently has a qualification level propellant throughput requirement of 450 kg of xenon, which corresponds to roughly 22,000 hr of operation at the highest throttling point. Currently, a NEXT engineering model ion thruster with prototype model ion optics is undergoing a long duration test to determine wear characteristics and establish propellant throughput capability. The NEXT thruster includes many improvements over previous generations of ion thrusters, but two of its component improvements have a larger effect on thruster lifetime. These include the ion optics with tighter tolerances, a masked region and better gap control, and the discharge cathode keeper material change to graphite. Data from the NEXT 2000 hr wear test, the NEXT long duration test, and further analysis is used to determine the expected lifetime of the NEXT ion thruster. This paper will review the predictions for all of the anticipated failure mechanisms. The mechanisms will include wear of the ion optics and cathode s orifice plate and keeper from the plasma, depletion of low work function material in each cathode s insert, and spalling of material in the discharge chamber leading to arcing. Based on the analysis of the NEXT ion thruster, the first failure mode for operation above a specific impulse of 2000 sec is expected to be the structural failure of the ion optics at 750 kg of propellant throughput, 1.7 times the qualification requirement. An assessment based on mission analyses for operation below a specific impulse of 2000 sec indicates that the NEXT thruster is capable of double the propellant throughput required by these missions.

VanNoord, Jonathan L.↗

Application of the NEXT Ion Thruster Lifetime Assessment to Thruster Throttling

Ion thrusters are low thrust, high specific impulse devices with typical operational lifetimes of 10,000 to 30,000 hr over a range of throttling conditions. The NEXT ion thruster is the latest generation of ion thrusters under development. The NEXT ion thruster currently has a qualification level propellant throughput requirement of 450 kg of xenon, which corresponds to roughly 22,000 hr of operation at the highest input power throttling point. This paper will provide a brief review the previous life assessment predictions for various throttling conditions. A further assessment will be presented examining the anticipated accelerator grid hole wall erosion and related electron backstreaming limit. The continued assessment of the NEXT ion thruster indicates that the first failure mode across the throttling range is expected to be in excess of 36,000 hr of operation from charge exchange induced groove erosion. It is at this duration that the groove is predicted to penetrate the accelerator grid possibly resulting in structural failure. Based on these lifetime and mission assessments, a throttling approach is presented for the Long Duration Test to demonstrate NEXT thruster lifetime and validate modeling.

VanNoord, Jonathan L.↗