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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

It takes a village: using a crowdsourced approach to investigate organic matter composition in global rivers through the lens of ecological theory

Though community-based scientific approaches are becoming more common, many scientific efforts are conducted by small groups of researchers that together develop a concept, analyze data, and interpret results that ultimately translate into a publication. Here, we present a community effort that breaks these traditional boundaries of the publication process by engaging the scientific community from initial hypothesis generation to final publication. We leverage community-generated data from the Worldwide Hydrobiogeochemistry Observation Network for Dynamic River Systems (WHONDRS) consortium to study organic matter composition through the lens of ecological theory. This community endeavor will use a suite of paired physical and chemical datasets collected from 97 river corridors across the globe. With our first step aimed at ideation, we engaged a community of scientists from 20 countries and 60 institutions, spanning disciplines and career stages by holding a virtual workshop (April 2021). In the workshop, participants generated content for questions, hypotheses, and proposed analyses based on the WHONDRS dataset. These ideation efforts resulted in several narratives investigating different questions led by different teams, which will be the basis for research articles in a Frontiers in Water collection. Currently, the community is collectively analyzing, interpreting, and synthesizing these data that will result in seven crowdsourced articles using a single, existing WHONDRS dataset. The use of a shared dataset across articles not only lowers barriers for broad participation by not requiring generation of new data, but also provides unique opportunities for emergent learning by connecting outcomes across studies. Here we will explain methods used to enable this community endeavor aimed to promote a greater diversity of thinking on river corridor biogeochemistry through community science.

Borton, Mikayla A.↗

The Mira-Titan Universe. II. Matter Power Spectrum Emulation

We introduce a new cosmic emulator for the matter power spectrum covering eight cosmological parameters. Targeted at optical surveys, the emulator provides accurate predictions out to a wavenumber k ~ 5Mpc -1 and redshift z ≤ 2. Besides covering the standard set of CDM parameters, massive neutrinos and a dynamical dark energy of state are included. The emulator is built on a sample set of 36 cosmological models, carefully chosen to provide accurate predictions over the wide and large parameter space. For each model, we have performed a high-resolution simulation, augmented with sixteen medium-resolution simulations and TimeRG perturbation theory results to provide accurate coverage of a wide k-range; the dataset generated as part of this project is more than 1.2Pbyte. With the current set of simulated models, we achieve an accuracy of approximately 4%. Because the sampling approach used here has established convergence and error-control properties, follow-on results with more than a hundred cosmological models will soon achieve ~1% accuracy. We compare our approach with other prediction schemes that are based on halo model ideas and remapping approaches. The new emulator code is publicly available.

97 MATHEMATICS AND COMPUTING↗

Potential bioavailability of representative pyrogenic organic matter compounds in comparison to natural dissolved organic matter pools

Abstract. Pyrogenic organic matter (PyOM) from wildfires impacts river corridors globally and is widely regarded as resistant to biological degradation. Though recent work suggests PyOM may be more bioavailable than historically perceived, estimating bioavailability across its chemical spectrum remains elusive. To address this knowledge gap, we assessed potential bioavailability of representative PyOM compounds relative to ubiquitous dissolved organic matter (DOM) with a substrate-explicit model. The range of potential bioavailability of PyOM was greater than natural DOM; however, the predicted thermodynamics, metabolic rates, and carbon use efficiencies (CUEs) overlapped significantly between all OM pools. Compound type (e.g., natural versus PyOM) had approximately 6-fold less impact on predicted respiration rates than simulated carbon and oxygen limitations. Within PyOM, the metabolism of specific chemistries differed strongly between unlimited and oxygen-limited conditions – degradations of anhydrosugars, phenols, and polycyclic aromatic hydrocarbons (PAHs) were more favorable under oxygen limitation than other molecules. Notably, amino sugar-like, protein-like, and lignin-like PyOM had lower carbon use efficiencies relative to natural DOM of the same classes, indicating potential impacts in process-based model representations. Overall, our work illustrates how similar PyOM bioavailability may be to that of natural DOM in the river corridor, furthering our understanding of how PyOM may influence riverine biogeochemical cycling.

59 BASIC BIOLOGICAL SCIENCES↗

A model for the distribution of dark matter, galaxies, and the intergalactic medium in a cold dark matter-dominated universe

The spatial distribution of the cold-dark-matter (CDM) and baryonic components of CDM-dominated cosmological models are characterized, summarizing the results of recent theoretical investigations. The evolution and distribution of matter in an Einstein-de Sitter universe on length scales small enough so that the Newtonian approximation is valid is followed chronologically, assuming (1) that the galaxies, CDM, and the intergalactic medium (IGM) are coupled by gravity, (2) that galaxies form by taking mass and momentum from the IGM, and (3) that the IGM responds to the energy input from the galaxies. The results of the numerical computations are presented in extensive graphs and discussed in detail.

Ryu, Dongsu↗

Unified halo-independent formalism from convex hulls for direct dark matter searches

Using the Fenchel-Eggleston theorem for convex hulls (an extension of the Caratheodory theorem), we prove that any likelihood can be maximized by either a dark matter 1- speed distribution F ( v ) in Earth's frame or 2- Galactic velocity distribution f gal ( ) , consisting of a sum of delta functions. The former case applies only to time-averaged rate measurements and the maximum number of delta functions is ( -1) , where is the total number of data entries. The second case applies to any harmonic expansion coefficient of the time-dependent rate and the maximum number of terms is . Using time-averaged rates, the aforementioned form of F ( v ) results in a piecewise constant unmodulated halo function 0 BF ( v min ) (which is an integral of the speed distribution) with at most ( -1) downward steps. The authors had previously proven this result for likelihoods comprised of at least one extended likelihood, and found the best-fit halo function to be unique. This uniqueness, yet, cannot be guaranteed in the more general analysis applied to arbitrary likelihoods. Thus we introduce a method for determining whether there exists a unique best-fit halo function, and provide a procedure for constructing either a pointwise confidence band, if the best-fit halo function is unique, or a degeneracy band, if it is not. Using measurements of modulation amplitudes, the aforementioned form of f gal ( ) , which is a sum of Galactic streams, yields a periodic time-dependent halo function BF ( v min , t ) which at any fixed time is a piecewise constant function of v min with at most downward steps. In this case, we explain how to construct pointwise confidence and degeneracy bands from the time-averaged halo function. Lastly, we show that requiring an isotropic Galactic velocity distribution leads to a Galactic speed distribution F ( u ) that is once again a sum of delta functions, and produces a time-dependent BF ( v min , t ) function (and a time-averaged 0 BF ( v min )) that is piecewise linear, differing significantly from best-fit halo functions obtained without the assumption of isotropy.

79 ASTRONOMY AND ASTROPHYSICS↗

Geochemical drivers of organic matter decomposition in Arctic tundra soils

Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO 2 ) and methane (CH 4 ) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns of dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH 4 increased relative to dissolved CO 2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.

58 GEOSCIENCES↗

Soil porous microstructure control over soil organic matter mobility: A multimethod workflow for understanding chemistry-dependent organic matter binding in soil

Soil organic matter (SOM) has attracted a great deal of interest; particularly for its potential to mitigate human derived CO 2 emissions. Studies have demonstrated that SOM plays a critical role in carbon storage and CO 2 sequestration. However, the sorption properties of SOM, which influence its transport in pore water and stabilization within the soil, remain poorly understood. This study develops a workflow to: (1) examine compound-specific advective and diffusive transport and desorption behaviors, (2) quantify desorption rates through stop-flow and continuous-flow column experiments, and (3) evaluate the impact of soil microporosity on SOM mobility using high-resolution imaging and extractions. Intact core column experiments were conducted on Uncultivated (Natural) and Cultivated soil samples, both were arid soils, collected in Washington State. X-ray computed tomography was employed to measure porosity and pore connectivity, while Fourier-transform ion cyclotron resonance mass spectrometry was used to analyze SOM composition. The findings revealed that cultivation increased total carbon and nitrogen levels due to irrigation and fertilization, enhancing carbon capture potential in arid soils. In contrast, the Natural soil, characterized by higher porosity and connectivity, contained more oxidized carbon. Pore network analysis indicated that soil compaction in the Cultivated soil may lead to longer diffusion pathways, significantly influencing SOM transport and stability.

Hydraulic Properties↗

Bio-reduction of ferrihydrite-montmorillonite-organic matter complexes: Effect of montmorillonite and fate of organic matter

Organic matter (OM) is often associated with Fe (hydr)oxides such as ferrihydrite (Fh) in soils and sediments, forming binary Fh-OM complexes. Microbial reduction of Fh results in destabilization of the complexes and mineral/OM transformation. However, little is known about the role of clay minerals in such processes, despite their common co-existence with Fh and OM in natural environments. Here Fh-OM complexes were synthesized in the presence of montmorillonite (SWy-2), forming ternary Fh-(SWy-2)-OM complexes. A metal-reducing bacterium Geobacter sulfurreducens was used to reduce Fh in the complexes under circumneutral pH and anoxic conditions with or without H 2 as extra electron donor. Various spectroscopy and mass spectrometry methods were used to monitor the progress of Fh bio-reduction and mineral/OM transformation. Results showed that G. sulfurreducens utilized mineral-bound OM as electron donor and/or carbon source to couple with Fh reduction. Relative to Fh-OM complex, Addition of SWy-2 to Fh-OM complex enhanced the bio-reduction extent of Fh by increasing the proportion of bioavailable OM that was weakly bound to SWy-2. However, its effect on the bio-reduction rate was variable. SWy-2 initially decreased the rate, because it spatially separated OM (electron donor) from Fh (electron acceptor). During later incubation, SWy-2 increased the reduction rate by sorbing biogenic Fe 2+ that would otherwise passivate the Fh and cell surfaces. Bio-reduction transformed mineral-bound OM to microbial products (e.g. necromass, extracellular polymeric substances), but organic compounds with aromatic structures, carboxyl groups and large molecular weight were more resistant to desorption and oxidation. The persistence of these compounds against bio-reduction induced transformation is likely due to their stronger binding with minerals and/or lower nominal oxidation states of carbon relative to other compounds. Our results provide new insights into the role of clay minerals in regulating biogeochemical cycling of solid-phase Fe and transformation of mineral-associated OM in anoxic soil environments.

58 GEOSCIENCES↗

Isotropic extragalactic flux from dark matter annihilations: lessons from interacting dark matter scenarios

The extragalactic γ-ray and neutrino emission may have a contribution from dark matter (DM) annihilations. In the case of discrepancies between observations and standard predictions, one could infer the DM pair annihilation cross section into cosmic rays by studying the shape of the energy spectrum. So far all analyses of the extragalactic DM signal have assumed the standard cosmological model (ΛCDM) as the underlying theory. However, there are alternative DM scenarios where the number of low-mass objects is significantly suppressed. Therefore the characteristics of the γ-ray and neutrino emission in these models may differ from ΛCDM as a result. Here we show that the extragalactic isotropic signal in these alternative models has a similar energy dependence to that in ΛCDM, but the overall normalisation is reduced. The similarities between the energy spectra combined with the flux suppression could lead one to misinterpret possible evidence for models beyond ΛCDM as being due to CDM particles annihilating with a much weaker cross section than expected.

79 ASTRONOMY AND ASTROPHYSICS↗

Gravitational wave signatures of inflationary models from Primordial Black Hole dark matter

Primordial Black Holes (PBH) could be the cold dark matter of the universe. They could have arisen from large (order one) curvature fluctuations produced during inflation that reentered the horizon in the radiation era. At reentry, these fluctuations source gravitational waves (GW) via second order anisotropic stresses. These GW, together with those (possibly) sourced during inflation by the same mechanism responsible for the large curvature fluctuations, constitute a primordial stochastic GW background (SGWB) that unavoidably accompanies the PBH formation. We study how the amplitude and the range of frequencies of this signal depend on the statistics (Gaussian versus χ{sup 2}) of the primordial curvature fluctuations, and on the evolution of the PBH mass function due to accretion and merging. We then compare this signal with the sensitivity of present and future detectors, at PTA and LISA scales. We find that this SGWB will help to probe, or strongly constrain, the early universe mechanism of PBH production. The comparison between the peak mass of the PBH distribution and the peak frequency of this SGWB will provide important information on the merging and accretion evolution of the PBH mass distribution from their formation to the present era. Different assumptions on the statistics and on the PBH evolution also result in different amounts of CMB μ-distortions. Therefore the above results can be complemented by the detection (or the absence) of μ-distortions with an experiment such as PIXIE.

79 ASTRONOMY AND ASTROPHYSICS↗

Enhancement of the dark matter abundance before reheating: Applications to gravitino dark matter

In the first stages of inflationary reheating, the temperature of the radiation produced by inflaton decays is typically higher than the commonly defined reheating temperature T RH ~ (Γ φ M P ) 1/2 where Γ φ is the inflaton decay rate. Here we consider the effect of particle production at temperatures at or near the maximum temperature attained during reheating. We show that the impact of this early production on the final particle abundance depends strongly on the temperature dependence of the production cross section. For $\langle$σv$\rangle$ ~ T n /M n + 2 , and for n < 6, any particle produced at T max is diluted by the later generation of entropy near T RH . This applies to cases such as gravitino production in low scale supersymmetric models (n = 0) or NETDM models of dark matter (n = 2). However, for n ≥ 6 the net abundance of particles produced during reheating is enhanced by over an order of magnitude, dominating over the dilution effect. This applies, for instance to gravitino production in high scale supersymmetry models where n = 6.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Early-Universe constraints on dark matter-baryon scattering and their implications for a global 21 cm signal

Here we present and compare several cosmological constraints on the cross section for elastic scattering between dark matter (DM) and baryons, for cross sections with a range of power-law dependences on the DM-baryon relative velocity v , especially focusing on the case of σ ∝ v - 4 . We study constraints spanning a wide range of epochs in cosmological history, from prerecombination distortions to the blackbody spectrum and anisotropies of the cosmic microwave background (CMB), to modifications to the intergalactic medium temperature and the resulting 21 cm signal, and discuss the allowed signals in the latter channels given the constraints from the former. Furthermore, we improve previous constraints on DM-baryon scattering from the CMB anisotropies, demonstrate via principal component analysis that the effect on the CMB can be written as a simple function of DM mass for v - 4 scattering, and map out the redshifts dominating this signal. We show that given high-redshift constraints on DM-baryon scattering, a v - 4 scaling of the cross section for light DM would be sufficient to explain the deep 21 cm absorption trough recently claimed by the Experiment to Detect the Reionization Step, if 100% of the DM scatters with baryons; we estimate the minimal necessary velocity scaling and find that it is close to v - 4 . For millicharged DM models proposed to explain the observation, where only a small fraction of the DM interacts, we estimate that a PIXIE-like future experiment measuring CMB spectral distortion could test the relevant parameter space.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Very Degenerate Higgsino Dark Matter

In this paper, we present a study of the Very Degenerate Higgsino Dark Matter (DM), whose mass splitting between the lightest neutral and charged components is O(1) MeV, much smaller than radiative splitting of 355 MeV. The scenario is realized in the minimal supersymmetric standard model by small gaugino mixings. In contrast to the pure Higgsino DM with the radiative splitting only, various observable signatures with distinct features are induced. First of all, the very small mass splitting makes (a) sizable Sommerfeld enhancement and Ramsauer-Townsend (RT) suppression relevant to ~1 TeV Higgsino DM, and (b) Sommerfeld-Ramsauer-Townsend effect saturate at lower velocities v/c ≲ 10 -3 . As a result, annihilation signals can be large enough to be observed from the galactic center and/or dwarf galaxies, while the relative signal sizes can vary depending on the locations of Sommerfeld peaks and RT dips. In addition, at collider experiments, stable chargino signatures can be searched for to probe the model in the future. Finally, DM direct detection signals, however, depend on the Wino mass; even no detectable signals can be induced if the Wino is heavier than about 10 TeV.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Fine particulate matters: The impact of air quality standards on cardiovascular mortality

Highlights: • PM{sub 2.5} decreased following implementation of annual PM{sub 2.5} standard. • Cardiovascular mortality decreased with a decrease in PM{sub 2.5}. • Attainment counties had greater health benefit compared to nonattainment counties. • Associations were not statistically different. • Health benefits were shown even in counties below the current standard. In 1997 the U.S. Environmental Protection Agency set the first annual National Ambient Air Quality Standard (NAAQS) for fine particulate matter (PM{sub 2.5}). Although the weight of scientific evidence has determined that a causal relationship exists between PM{sub 2.5} exposures and cardiovascular effects, few studies have concluded whether NAAQS-related reductions in PM{sub 2.5} led to improvements in public health.

54 ENVIRONMENTAL SCIENCES↗