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At least 271 records · Page 15

Globally Gridded Groundwater Extraction Volumes and Costs under Six Depletion and Ponded Depth Targets

This repository contains simulated outputs from superwell – a hydro-economic tool for long-term assessment of groundwater cost and supply – providing globally gridded groundwater extractable volumes and associated unit costs ($/km³) for accessible groundwater production, based on a variety of user-defined depletion and ponded depth scenarios. Key model documentation: Niazi, H., Ferencz, S. B., Graham, N. T., Yoon, J., Wild, T. B., Hejazi, M., Watson, D. J., & Vernon, C. R. (2025). Long-term hydro-economic analysis tool for evaluating global groundwater cost and supply: Superwell v1.1. Geoscientific Model Development, 18(5), 1737-1767. https://doi.org/10.5194/gmd-18-1737-2025 Find the source code of the superwell model on GitHub: https://github.com/JGCRI/superwell Repository Overview Main output: superwell_outputs.7z contains 6 files (4.5 GB) named as superwell_py_deep_all_0.*PD_0.*DL.csv. These files present superwell outputs of global groundwater extraction volumes and cost estimates on a 0.5° scale for six scenarios with different Ponded Depth (PD; 0.3 and 0.6 m) and Depletion Limit (DL; 5%, 25%, and 40% of available volume) targets over the entire pumping lifetime of a grid cell superwell_py_deep_all_0.3PD_0.25DL_sample_100.csv contains superwell outputs for 100 data points sampled to match the global inputs' distribution superwell_py_deep_all_0.3PD_0.25DL_Grid_72548.csv contains superwell output for a single grid cell concept_v5.png provides an overview of the superwell workflow Outputs Description year_number: year of pumping depletion_limit: set depletion limit (DL) as a volume fraction of total available groundwater Mappings: continent, country, gcam_basin_id, Basin_long_name, grid_id: geographic identifiers and basin information Inputs: grid_area (km²): area of the grid cell whyclass: hydrogeological classification of the aquifer permeability (m/day), porosity (%), total_thickness (m), depth_to_water (m): aquifer properties. The geo-processed input data has been published separately: https://doi.org/10.57931/2307831 Model outputs: orig_aqfr_sat_thickness (m), aqfr_sat_thickness (m): original and remaining/instantaneous saturated thickness of the aquifer hydraulic_conductivity (m/day), transmissivity (m²/day): hydraulic properties of the aquifer radius_of_influence (m), areal_extent (km²): well radius and area of influence from the center of the well number_of_wells (-): number of wells in a grid cell determined by a ratio of well area and grid area max_drawdown (m), drawdown (m), drawdown_interference (m): well and aquifer drawdown during extraction total_head (m): total lift for the groundwater (depth to water plus drawdown) total_well_length (m): total depth of wells drilled well_yield (m³/day): pumping rate or well yield power (kW), energy (kWh): power and energy required for pumping groundwater Volume Outputs: volume_produced_perwell (m³), cumulative_vol_produced_perwell (m³): production volume metrics per well volume_produced_allwells (m³), cumulative_vol_produced_allwells (m³): aggregate extraction volumes for all wells in a grid cell available_volume (m³): available groundwater in storage for the grid cell as determined by aquifer properties depleted_vol_fraction: fraction of total volume pumped over available volumes in a grid cell (same as depletion limit) Cost Outputs: well_installation_cost ($): well installation cost based on the hydrogeological complexity of the aquifer annual_capital_cost, maintenance_cost, nonenergy_cost ($): nonenergy costs energy_cost_rate ($/kWh): electricity rate energy_cost ($): energy cost of pumping groundwater total_cost_perwell ($), total_cost_allwells ($): total annual energy and non-energy cost for each and all wells in a grid cell a unit_cost ($/m³), unit_cost_per_km3 ($/km³), unit_cost_per_acreft ($/acre-ft): total cost of pumping a unit of groundwater, indicated for different spatial units Key Resources Model documentation: Niazi, H., Ferencz, S., Graham, N., Yoon, J., Wild, T., Hejazi, M., Watson, D., & Vernon, C. (2024; In-prep). Long-term Hydro-economic Assessment Tool for Evaluating Global Groundwater Cost and Supply: Superwell v1. Geoscientific Model Development. Input data: Niazi, H., Watson, D., Hejazi, M., Yonkofski, C., Ferencz, S., Vernon, C., Graham, N., Wild, T., & Yoon, J. (2024). Global Geo-processed Data of Aquifer Properties by 0.5° Grid, Country and Water Basins. MSD-LIVE Data repository. https://doi.org/10.57931/2307831 superwell source code: https://github.com/JGCRI/superwell Cite as Niazi, H., Ferencz, S., Yoon, J., Graham, N., Wild, T., Hejazi, M., Watson, D., & Vernon, C. (2024). Globally Gridded Groundwater Extraction Volumes and Costs under Six Depletion and Ponded Depth Targets. MSD-LIVE Data repository. https://doi.org/10.57931/2307832 Contact Reach out to Hassan Niazi or Stephen Ferencz or open an issue in the superwell repository for questions or suggestions.

Earth Systems↗

Fluoride-Cooled High-Temperature Pebble-Bed Reactor Reference Plant Model Updates

This work presents the latest improvements to, and investigations performed with, the Fluoride-Cooled High-Temperature Pebble-Bed Reactor reference plant models for the United States Nuclear Regulatory Commission. These models, developed with the Comprehensive Reactor Analysis Bundle, or BlueCRAB, serve as the foundation for the future development of detailed design evaluation models based on license applications. BlueCRAB is the code suite proposed for non-light-water reactor systems safety analyses, and it incorporates various simulation tools developed by the Nuclear Energy Advance Modeling and Simulation program, including the Griffin code for reactor physics, the Pronghorn and SAM codes for core thermal fluids, the BISON code for solid conduction and fuel performance, and the SAM code for system analysis. The primary objective of this work is to assess the level of readiness of BlueCRAB for modeling fluoride-cooled high-temperature pebble-bed reactors. We first developed numerical models in BlueCRAB that include the key physics for this technology, ensuring an adequate level of fidelity for modeling the core performance during accident scenarios. This was followed by simulation of transient scenarios, two loss-of-forced-cooling events (one protected and one unprotected), and two control rod withdrawal events (one delayed and one prompt supercritical reactivity insertion). The analysis includes comparisons between the 2-D thermal fluid porous media models in Pronghorn and SAM, comparisons between coupled Pronghorn-Griffin and coupled SAM-Griffin models for two loss-of-forced cooling events and one control rod withdrawal event, and comparisons between SAM single-solve and domain-overlapping approaches for multi-scale thermal fluid coupling. In addition, we performed comparisons between 3-D, 2-D, and 0-D neutronic models for the two control rod withdrawal scenarios with Pronghorn-Griffin. The results show that the BlueCRAB models led to physically intuitive solutions for the scenarios examined. The changes in the various scalar and vector fields such as the neutron flux, power, temperatures, densities, pressures, and velocities are all within the expected ranges, and their distributions can be explained from the system response of the transients and the geometric and material variations. Several comparisons suggest that the porous media models in Pronghorn and SAM can lead to similar solutions, even though they are based on different methodologies. The simulations demonstrate that there are differences between the various levels of fidelity, and it is advisable to have flexible tools that can cover the breadth and depth of needs that may arise in future technical evaluations. We believe that BlueCRAB’s capabilities represent a significant asset for confirmatory analyses aimed at resolving important safety questions.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Evaluating Production Implications of Pressure Maintenance in Unconventional Oil and Gas Wells using a Machine Learning Modeling Approach: Case Study in the Permian Basin

This study implements the proprietary machine learning-based model (model) developed under the 2022 study titled “Evaluating the Impact of Proprietary Oil & Gas Data on Machine Learning Model Performance Using a Quasi-Experimental Analytical Approach” for forecasting unconventional oil and gas production using well data from the Permian Basin. The model, developed using an exclusive dataset that includes time series production data from an operator in the Permian Basin, is designed to jointly predict daily oil, gas, and water production for horizontal wells as a function of bottomhole pressure drawdown, spatial placement across the study domain, and well-completion attributes. In this study, the model was explicitly applied to explore its utility to evaluate the impact of varying drawdown strategies on the production forecast of a well in the Permian Basin dataset. Managing pressure drawdown has been identified as a way to improve estimated ultimate recovery (EUR) from unconventional shale wells due to the stress-dependent nature of fractures in shale reservoirs. Research has shown that applying a lower pressure drawdown helps to maintain the reservoir conductivity, resulting in higher productivity over the life of a well. Historic bottomhole pressure data from the well over time was used as a benchmark from which to set more and less aggressive pressure decline rates as bounding modeling cases. All pressure decline rates/strategies were forecasted over 5 years, and the model was used to generate oil, water, and gas prediction over the same timeframe. This report presents the results from the production forecast and discusses potential operational and economic implications, with contrasting perspectives between well productivity and profitability given typical oil and gas economics and the volatility in the oil and gas market.

02 PETROLEUM↗

An Open-Source Virtual Testbed for a Real Net-Zero Energy Community

Net zero energy communities (NZECs) are critical to ensure sustainability and resilience of modernized power systems. System modeling helps overcome technical challenges in designing and operating NZECs. In this paper, we present the modeling work based on a real NZEC. Two sets of models are developed: higher-fidelity physics-based models considering the interaction between subsystems of the studied NZEC and capturing fast-dynamics; and lower-fidelity data-driven models requiring less resource to establish and/or run. All models are validated against measurements from this real NZEC. In addition, we create a simulation framework which streamlines the processes for simulation and thus allows using developed models to form a virtual testbed. To demonstrate the usage of the virtual testbed, a case study is conducted where a building-to-grid integration control is evaluated via simulation. The evaluation results suggest that the tested control significantly smooths the power draw of the studied community and doesn’t sacrifice the thermal comfort to a great extent.

Huang, Sen↗

Enhanced HLW Glass Property-Composition Models – Phase 2

As a continuation of the Phase 1 HLW model development work as part of a phased approach to enhance and expand HLW glass property-composition models, additional data were collected for the HLW glass dataset and used to revise the models developed during Phase 1. These data are for glasses that are collectively referred to as ORP-2014 glasses. The sources of additional data for the Phase 2 work included: (i) actively designed glasses formulated to support various glass studies at VSL since the completion of Phase 1; and (ii) glasses from two statistically designed matrices to supplement the existing HLW compositional space. The Phase 2 matrix design was intended to augment and improve the coverage in the high aluminum region.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Process-Oriented Diagnostics: Principles, Practice, Community Development, and Common Standards

Process-oriented diagnostics (PODs) aim to provide feedback for model developers through model analysis based on physical hypotheses. However, the step from a diagnostic based on relationships among variables, even when hypothesis driven, to specific guidance for revising model formulation or parameterizations can be substantial. The POD may provide more information than a purely performance-based metric, but a gap between POD principles and providing actionable information for specific model revisions can remain. Furthermore, in coordinating diagnostics development, there is a trade-off between freedom for the developer, aiming to capture innovation, and near-term utility to the modeling center. Best practices that allow for the former, while conforming to specifications that aid the latter, are important for community diagnostics development that leads to tangible model improvements. Promising directions to close the gap between principles and practice include the interaction of PODs with perturbed physics experiments and with more quantitative process models as well as the inclusion of personnel from modeling centers in diagnostics development groups for immediate feedback during climate model revisions. Examples are provided, along with best-practice recommendations, based on practical experience from the NOAA Model Diagnostics Task Force (MDTF). Common standards for metrics and diagnostics that have arisen from a collaboration between the MDTF and the Department of Energy’s Coordinated Model Evaluation Capability are advocated as a means of uniting community diagnostics efforts.

58 GEOSCIENCES↗

Bulb-style Kaplan Turbine - Run-of-the-river (ror) Hydro Governor And Turbine Model

This software package includes hydro governor and turbine models developed in Simulink (Mathworks Inc.) and RSCAD (RTDS Technologies) for low-head bulb-style Kaplan turbine hydropower plants. The model developed in Simulink has been designed and tuned to match the governor-turbine response for a real-world hydropower unit owned by Idaho Falls Power (IFP). The Simulink and RSCAD models enable real-time testing in a hardware-in-the-loop (HIL) implementation using OPAL-RT and RTDS digital real-time simulators, respectively. An automatic initialization for dynamic simulation has also been integrated to each model in both Simulink and RSCAD. The RSCAD initialization involves a novel python-based interfacing for automatic modification of the initial conditions in the model. The parameters of these models can be tuned to match other hydropower plants in this class.

Alam, SMShafiul↗

Quality Assurance Project Plan for the Salish Sea Model – Continuing Development of New Capabilities and Applications: European Green Crab (EGC) Larval Transport, Coupling to VELMA and Atlantis, Performance Improvements and Diagnostic Applications

This quality assurance project plan (QAPP) is for proposed FY24-FY27 efforts to (a) develop/expand a predictive European Green Crab (EGC) larval dispersal model for the Salish Sea, (b) add linkage between VELMA (Visualizing Ecosystem Land Management Assessments) watershed model and Atlantis model (ecosystem dynamics and food web) through SSM, and (c) continue SSM capability development through the addition of metals, harmful algal blooms (HABs), and FVCOM-LTRANS (Lagrangian Larval Transport) modules.

54 ENVIRONMENTAL SCIENCES↗

Land Model Testbed: Accelerating Development, Benchmarking and Analysis of Land Surface Models

A Land Model Testbed (LMT), designed to provide a computational framework for systematically assessing model fidelity and supporting rapid development of complex multiscale models, offers a general-purpose workflow for conducting large ensemble simulations of multiple land surface models, post-processing large volumes of model output, and evaluating model results. It leverages existing tools for launching model simulations and the International Land Model Benchmarking (ILAMB) package for assessing model fidelity through comparison with best-available observational datasets. Increased complexity and proliferation of uncertain parameters in process representations in land surface models has driven the need for frequent and intensive testing and evaluating of models to quantify uncertainties and optimize parameters such that results are consistent with observations. The LMT described here meets these needs by providing tools to run thousands of ensemble simulations simultaneously and post-process their output files, by automating execution of an enhanced version of ILAMB with site-specific benchmarks and multivariate functional relationships, and by offering ensemble diagnostics and a customizable dashboard for displaying model performance metrics and associated graphics. We envision the LMT capabilities will serve as a foundational computational resource for a proposed user facility focused on terrestrial multiscale model--data integration.

Sreepathi, Sarat↗

Fast and accurate influenza forecasting in the United States with Inferno

Infectious disease forecasting is an emerging field and has the potential to improve public health through anticipatory resource allocation, situational awareness, and mitigation planning. By way of exploring and operationalizing disease forecasting, the U.S. Centers for Disease Control and Prevention (CDC) has hosted FluSight since the 2013/14 flu season, an annual flu forecasting challenge. Since FluSight’s onset, forecasters have developed and improved forecasting models in an effort to provide more timely, reliable, and accurate information about the likely progression of the outbreak. While improving the predictive performance of these forecasting models is often the primary objective, it is also important for a forecasting model to run quickly, facilitating further model development and improvement while providing flexibility when deployed in a real-time setting. In this vein I introduce Inferno, a fast and accurate flu forecasting model inspired by Dante, the top performing model in the 2018/19 FluSight challenge. When pseudoprospectively compared to all models that participated in FluSight 2018/19, Inferno would have placed 2nd in the national and regional challenge as well as the state challenge, behind only Dante. Inferno, however, runs in minutes and is trivially parallelizable, while Dante takes hours to run, representing a significant operational improvement with minimal impact to performance. Forecasting challenges like FluSight should continue to monitor and evaluate how they can be modified and expanded to incentivize the development of forecasting models that benefit public health.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Hydrogen Dispersion Modeling for Development of Smart Distributed Monitoring

Studying hydrogen dispersion is crucial for ensuring the safe and effective deployment of hydrogen as an energy carrier. This study presents a comprehensive CFD modeling framework for simulating hydrogen dispersion at a real-world hydrogen production, storage, and utilization facility. Utilizing the Hydrogen Research Facility under the Advanced Research on Integrated Energy Systems (ARIES) at the National Renewable Energy Laboratory's (NREL) Flatirons campus, controlled hydrogen releases at 27 kg-H2/hr were simulated. The model incorporated site-specific atmospheric conditions, including hourly wind speeds and temperatures recorded between 8 AM and 8 PM from October to December 2023. To reduce computational demands, a statistical reduction technique was applied to condense the dataset to 100 representative scenarios, validated by statistical tests for wind speeds and power law coefficients. Simulations were conducted using the Reynolds-Averaged Navier-Stokes equations. Results demonstrated that wind speed substantially influences hydrogen dispersion, with low wind conditions forming concentrated clouds and higher wind speeds stretching the plume. Additionally, clustering analysis informed optimal sensor placement at various elevations with up to 10 sensor locations on each elevation. This framework offers a robust approach for understanding hydrogen behavior in ambient conditions and informing detection strategies.

08 HYDROGEN↗

Evaluation of a cloudy cold-air pool in the Columbia River basin in different versions of the High-Resolution Rapid Refresh (HRRR) model

The accurate forecast of persistent orographic cold-air pools in numerical weather prediction models is essential for the optimal integration of wind energy into the electrical grid during these events. Model development efforts during the second Wind Forecast Improvement Project (WFIP2) aimed to address the challenges related to this. We evaluated three versions of the National Oceanic and Atmospheric Administration (NOAA) High-Resolution Rapid Refresh model with two different horizontal grid spacings against in situ and remote sensing observations to investigate how developments in physical parameterizations and numerical methods targeted during WFIP2 impacted the simulation of a persistent cold-air pool in the Columbia River basin. Differences amongst model versions were most apparent in simulated temperature and low-level cloud fields during the persistent phase of the cold-air pool. The model developments led to an enhanced low-level cloud cover, resulting in better agreement with the observations. This removed a diurnal cycle in the near-surface temperature bias at stations throughout the basin by reducing a cold bias during the night and a warm bias during the day. However, low-level clouds did not clear sufficiently during daytime in the newest model version, which leaves room for further model developments. The model developments also led to a better representation of the decay of the cold-air pool by slowing down its erosion.

54 ENVIRONMENTAL SCIENCES↗

Emulation Modeling for Development of Cyber-Defense Capabilities for Satellite Systems

The objective of this project was to develop a novel capability to generate synthetic data sets for the purpose of training Machine Learning (ML) algorithms for the detection of malicious activities on satellite systems. The approach experimented with was to a) generate sparse data sets using emulation modeling and b) enlarge the sparse data using Generative Adversarial Networks (GANs). We based our emulation modeling on the Open Source NASA Operational Simulator for Small Satellites (NOS3) developed by the Katherine Johnson Independent Verification and Validation (IV&V) program in West Virginia. Significant new capabilities on NOS3 had to be developed for our data set generation needs. To expand these data sets for the purpose of training ML, we experimented with a) Extreme Learning Machines (ELMs) and b) Wasserstein-GANs (WGAN-GP).

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Pellet cladding mechanical interaction as a potential failure mechanism during a control rod drop accident in a boiling water reactor

Boiling water reactors (BWRs) represent approximately one-third of the operating fleet in the United States, contributing significantly towards the global effort in reducing carbon emissions. Even though most of the operating fleet has been in operation for quite some time, continued advancements in new nuclear fuel (such as accident tolerant fuel) or operating regimes (such as power up-rates and higher burnup operation) necessitates similar advancements in modeling and simulation capabilities. Bison, a component of the Virtual Environment for Reactor Applications (VERA), is a high-fidelity fuel performance code able to explore the fuel performance of a wide variety of fuel types in one-, two-, and three-dimensions. Until recently, the code had not been used for analyses of BWRs. Modeling capabilities have been added for Gd-bearing UO{sub 2} and pure zirconium liners. New models have been added based upon the U.S. Nuclear Regulatory Commission (NRC) guide-lines for hydrogen pickup in Zircaloy-2 claddings and pellet-clad mechanical interaction (PCMI) failure during a reactivity insertion accident (RIA), known as a rod drop accident (CRDA) in BWRs. Implementing and/or improving Bison modeling capabilities extended its analytical reach to areas beyond its original intended purpose. This paper demonstrates one of these capabilities as a proof of concept. Recently developed models enable Bison to provide an alternate approach for cladding integrity determination in CRDA evaluations, which currently use bounding conservative estimates. As part of this demonstration, NRC guidance on hydrogen-pickup and PCMI failure models were utilized in this research. Even though more research is needed in establishing right inputs and process in this area, this paper demonstrates Bison's ability to determine cladding integrity in a CRDA evaluation. This first of a kind demonstration is a proof of concept in this area, which could potentially be extended to a number of other areas where a more accurate cladding integrity determination would be needed. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

The ARM Data-oriented Metrics and Diagnostics Package for Climate Models - A New Tool for Evaluating Climate Models with Field Data

The U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) program User Facility produces ground-based long-term continuous unique measurements for atmospheric state, precipitation, turbulent fluxes, radiation, aerosol, cloud and the land surface, which are collected at multiple sites. These comprehensive datasets have been widely used to calibrate climate models and are proven to be invaluable for climate model development and improvement. This article introduces an evaluation package to facilitate the use of ground-based ARM measurements in climate model evaluation. The ARM data-oriented metrics and diagnostics package (ARM-DIAGS) includes both ARM observational datasets and a Python-based analysis toolkit for computation and visualization. The observational datasets are compiled from multiple ARM data products and specifically tailored for use in climate model evaluation. In addition, ARM-DIAGS also includes simulation data from models participating the Coupled Model Inter-comparison Project (CMIP), which will allow climate-modeling groups to compare a new, candidate version of their model to existing CMIP models. The analysis toolkit is designed to make the metrics and diagnostics quickly available to the model developers.

54 ENVIRONMENTAL SCIENCES↗

Macro Analysis to Estimate Electric Vehicles Fast-Charging Infrastructure Requirements in Small Urban Areas

Electric vehicles (EVs) are known to reduce emissions and fossil fuel dependency. However, the limited range, long charging time, and inadequate charging infrastructure have hampered the adoption of EVs. The current EV charging infrastructure planning studies and tools require detailed information, extensive resources, and skills that can be a significant barrier to urban areas for finding the required charging infrastructure to support a targeted EV market share. This study generates regression models to estimate the number of direct current fast charging stations and the chargers to support the EV charging demand for urban areas. These models provide macro-level estimates of the required infrastructure investment in urban areas, which can be easily implemented by policy-makers and city planners. This study incorporates data obtained from applying a disaggregate optimization-based charger placement model, developed recently by the same authors, for multiple case studies to generate the required data to calibrate the macro-level models, in the state of Michigan. This simulated data set includes the number of charging stations and chargers for each market share, technology advancement scenario, and the transportation network topology. The results show that the number of charging stations reduces with battery size and charging power and increases with EV market share and the road network lane length. The number of chargers reduces with charging power, whereas it increases with battery size, EV market share, and vehicle miles traveled in the system. The model developed here can be applied to any state having urban characteristics and weather conditions similar to Michigan.

Engineering↗

Spatiotemporal forecasting of the edge localized modes in tokamak plasmas using neural networks

Artificial intelligence techniques have been increasingly adopted by the plasma and fusion science to address problems like plasma reconstruction, surrogate modeling, and tokamak/stellarator optimization. A key focus in sustained fusion research is the prediction and mitigation of edge-localized-modes (ELMs), instabilities that occur in short, periodic bursts and can cause erosion to the tokamak vessel wall. Recent research has demonstrated the power of neural networks in approximating continuous functions. In this work, we build spatiotemporal forecasting models that can predict the onset of ELMs and their evolution at early stages. We leverage recent advances in generative modeling, sequence-to-sequence modeling, and Fourier neural operators to propose architectures and training strategies that can learn to forecast short to long term dynamics of the noisy signals due to ELMs. We benchmark the developed model against a state-of-the-art foundation model using the beam emission spectroscopy (BES) data that captures the plasma fluctuations due to ELMs over a 8 x 8 spatial grid. Our models demonstrate high accuracy, outperforming the baselines, in predicting the evolution of BES signals during ELM events. Furthermore, the developed models exhibit high accuracy in predicting the rapid rise and relaxation of the signals due to ELMs within 30–80 µs.

edge localized modes↗

Measurement Acceptance Region (MAR) Assessment Results Based On Sludge Batch 10 Projections from December 2021, February 2022 and August 2022

The Defense Waste Processing Facility (DWPF) is currently preparing to initiate processing of Sludge Batch 10 (SB10), which is comprised of material from Tanks 11H, 13H, 15H, and 26F, Alternate Feed Stock-2 and Sodium Reactor Experiment material from H-Canyon. Frit 473 (8B 2 O 3 -8Li 2 O-5Na 2 O-79SiO 2 , in weight percent) was recommended for sludge-only (SO) and coupled processing with the Salt Waste Processing Facility (SWPF) based on previous assessments of SB10 projections with the DWPF Product Composition Control System (PCCS) glass property models and their associated Measurement Acceptance Region (MAR) constraints. Due to the lower processing rate of Sludge Batch 9 (SB9), the heel in Tank 40 is anticipated to be greater than 40 inches at the projected start of SB10 processing to meet the upcoming Accelerated Basin Deinventory addition dates in Tank 51 for Sludge Batch 11. In December 2021 and February 2022, Savannah River Remediation System Planning provided updated SB10 Tank 40 blend projections based on heels of 74 inches, 84 inches, 94 inches and 103.4 inches. Savannah River Mission Completion (SRMC) subsequently pursued Wash Cycle Y to further reduce the total sulfur in the sludge batch and increase processing flexibility at DWPF. In August 2022, SRMC System Planning provided an updated SB10 Tank 40 blend projection with a 76 inch-heel representing Decant Y2 and 60 kilogallons of bearing water inleakage that is anticipated during the Tank 51 to Tank 40 transfer. The objectives of this task were to: • Determine the impact on the operating windows for SO and coupled processing • Determine whether any composition gaps exist between the already completed SB10 variability study and the reprojected SB10 glass composition region • Compare the SB10 reprojected glass composition region to the DWPF PCCS model development and validation ranges to ensure that compositional gaps do not exist between the data sets. This report documents the results of these evaluations. Calculation-based frit assessments were performed using the DWPF PCCS glass property models and their associated MAR constraints. Evaluated parameters for coupled processing included the following transfer volumes per Sludge Receipt and Adjustment Tank batch: 5700 gallons of Tank 40 sludge, 2400-4500 gallons of the SWPF monosodium titanate (MST) and sludge solids stream, and 15,000 gallons of strip effluent. Based on these MAR assessment results, Frit 473 remains viable for SB10 processing. A target waste loading (WL) of 36% is possible for SO operation and single strike (0.4 g/L MST) coupled processing up to 600 mg/L of SB9 insoluble sludge solids at a nominal transfer volume of ~2800 gallons. Increasing the single strike transfer volume to 4500 gallons may reduce the maximum WL below 40%. Operating windows are 12 percentage points for SO processing and 14-16 percentage points for coupled processing. Frit 625 allows for a target WL of 36% and is acceptable for use during the SB9 to SB10 transition to deplete remaining inventory as needed. Operating windows are 8 percentage points for SO processing and 12-14 percentage points for coupled processing. Predictive PCCS evaluations performed at DWPF will provide insight into batch-specific acceptability at desired WLs for compositions having expected oxide ratios during processing versus the extreme vertices (corner points) evaluated in this study. The reprojected SB10 glass composition region generally overlaps the previously evaluated SB10 variability study composition region. Thus, the minor composition shift of these updated SB10 projections indicates that no additional glasses are necessary to demonstrate acceptability relative to the chemical durability of the Environmental Assessment benchmark glass and predictability using the current PCCS models for durability. Based on a comparison of the PCCS model development and validation data to the reprojected SB10 glass composition region, the viscosity and liquidus temperature models will reliably predict SB10 compositions. No additional glasses are necessary to demonstrate predictability of these models.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗