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At least 271 records · Page 15

Forecasting Lightning Threat using Cloud-Resolving Model Simulations

Two new approaches are proposed and developed for making time and space dependent, quantitative short-term forecasts of lightning threat, and a blend of these approaches is devised that capitalizes on the strengths of each. The new methods are distinctive in that they are based entirely on the ice-phase hydrometeor fields generated by regional cloud-resolving numerical simulations, such as those produced by the WRF model. These methods are justified by established observational evidence linking aspects of the precipitating ice hydrometeor fields to total flash rates. The methods are straightforward and easy to implement, and offer an effective near-term alternative to the incorporation of complex and costly cloud electrification schemes into numerical models. One method is based on upward fluxes of precipitating ice hydrometeors in the mixed phase region at the-15 C level, while the second method is based on the vertically integrated amounts of ice hydrometeors in each model grid column. Each method can be calibrated by comparing domain-wide statistics of the peak values of simulated flash rate proxy fields against domain-wide peak total lightning flash rate density data from observations. Tests show that the first method is able to capture much of the temporal variability of the lightning threat, while the second method does a better job of depicting the areal coverage of the threat. Our blended solution is designed to retain most of the temporal sensitivity of the first method, while adding the improved spatial coverage of the second. Exploratory tests for selected North Alabama cases show that, because WRF can distinguish the general character of most convective events, our methods show promise as a means of generating quantitatively realistic fields of lightning threat. However, because the models tend to have more difficulty in predicting the instantaneous placement of storms, forecasts of the detailed location of the lightning threat based on single simulations can be in error. Although these model shortcomings presently limit the precision of lightning threat forecasts from individual runs of current generation models,the techniques proposed herein should continue to be applicable as newer and more accurate physically-based model versions, physical parameterizations, initialization techniques and ensembles of forecasts become available.

McCaul, Eugene W., Jr.

Two-Dimensional Model Simulations of Interannual Variability in the Tropical Stratosphere

Meteorological data from the United Kingdom Meteorological Office (UKMO) and constituent data from the Upper Atmospheric Research Satellite (UARS) are used to construct yearly zonal mean dynamical fields for the 1990s for use in the GSFC 2-D chemistry and transport model. This allows for interannual dynamical variability to be included in the model constituent simulations. In this study, we focus on the tropical stratosphere. We find that the phase of quasi-biennial oscillation (QBO) signals in equatorial CH4, and profile and total column 03 data is resolved quite well using this empirically- based 2-D model transport framework. However. the QBO amplitudes in the model constituents are systematically underestimated relative to the observations at most levels. This deficiency is probably due in part to the limited vertical resolutions of the 2-D model and the UKMO and UARS input data sets. We find that using different heating rate calculations in the model affects the interannual and QBO amplitudes in the constituent fields, but has little impact on the phase. Sensitivity tests reveal that the QBO in transport dominates the ozone interannual variability in the lower stratosphere. with the effect of the temperature QBO being dominant in the tipper stratosphere via the strong temperature dependence of the ozone loss reaction rates. We also find that the QBO in odd nitrogen radicals, which is caused by the QBO modulated transport of NOy, plays a significant but not dominant role in determining the ozone QBO variability in the middle stratosphere. The model mean age of air is in good overall agreement with that determined from tropical lower,middle stratospheric OMS balloon observations of SF6 and CO2. The interannual variability of tile equatorial mean age in the model increases with altitude and maximizes near 40 km, with a range, of 4-5 years over the 1993-2000 time period.

Fleming, Eric L.

Advancing the Understanding of Cloud Microphysical Processes and Aerosol Indirect Effects in High-Latitude Mixed-Phase Clouds by Linking ARM Measurements with Climate Model Simulations (Final Report)

The key objectives of this project were to advance our understanding of cloud microphysical characteristics and aerosol indirect effects on mixed-phase clouds in high latitudes. To improve the representation of ice and mixed-phase clouds in Earth System Models (ESMs), we propose an integrated observation and modeling study of cloud macro- and microphysical properties, including spatial heterogeneities, mass partitioning between ice crystals and supercooled liquid water, effects of ice nucleating particles (INPs), and efficiency of secondary ice production (SIP), etc. Specifically, we took four main approaches in this project: (1) examining macro- and microphysical properties of ice and mixed-phase clouds based on in-situ and ground-based observations from multiple field campaigns funded by the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) program, including the Mixed-Phase Arctic Cloud Experiment (M-PACE), Indirect and Semi-Direct Aerosol Campaign (ISDAC), Ice Nucleating Particle Sources at Oliktok Point (INPOP), ARM West Antarctic Radiation Experiment (AWARE), Measurements of Aerosols, Radiation, and Clouds over the Southern Ocean (MARCUS), and Macquarie Island Cloud and Radiation Experiment (MICRE); (2) evaluating the DOE Energy Exascale Earth System Model (E3SM) simulations based on observations, particularly for ice and mixed-phase cloud microphysical properties; (3) examining the impacts of INPs on ice and mixed-phase clouds. Specifically, a series of comparisons were conducted using observations over the Arctic, Southern Ocean, and Antarctica, including comparisons between the lower and higher southern latitudes as well as comparisons between the northern and southern hemispheres. In addition, aerosol indirect effects from distinct sources of dust particles were examined; and (4) investigating the impacts of SIP. Ultimately, these results helped to improve cloud microphysics and aerosol-cloud interaction parameterizations in the E3SM model. Overall, the project provided improved understanding regarding various factors, including thermodynamic, dynamic, and aerosol conditions, on the micro- and macrophysical properties of ice and mixed-phase clouds in the high latitudes. Resulting analysis helped to provide an improved physical basis for refining the current cloud microphysics parameterizations related to ice and mixed-phase clouds in E3SM.

54 ENVIRONMENTAL SCIENCES

Developing Flexible Discrete Event Simulation Models in an Uncertain Policy Environment

On February 1st, 2010 U.S. President Barack Obama submitted to Congress his proposed budget request for Fiscal Year 2011. This budget included significant changes to the National Aeronautics and Space Administration (NASA), including the proposed cancellation of the Constellation Program. This change proved to be controversial and Congressional approval of the program's official cancellation would take many months to complete. During this same period an end-to-end discrete event simulation (DES) model of Constellation operations was being built through the joint efforts of Productivity Apex Inc. (PAl) and Science Applications International Corporation (SAIC) teams under the guidance of NASA. The uncertainty in regards to the Constellation program presented a major challenge to the DES team, as to: continue the development of this program-of-record simulation, while at the same time remain prepared for possible changes to the program. This required the team to rethink how it would develop it's model and make it flexible enough to support possible future vehicles while at the same time be specific enough to support the program-of-record. This challenge was compounded by the fact that this model was being developed through the traditional DES process-orientation which lacked the flexibility of object-oriented approaches. The team met this challenge through significant pre-planning that led to the "modularization" of the model's structure by identifying what was generic, finding natural logic break points, and the standardization of interlogic numbering system. The outcome of this work resulted in a model that not only was ready to be easily modified to support any future rocket programs, but also a model that was extremely structured and organized in a way that facilitated rapid verification. This paper discusses in detail the process the team followed to build this model and the many advantages this method provides builders of traditional process-oriented discrete event simulations.

Miranda, David J.

A Study of Heavy Precipitation Events in Taiwan During 10-13 August, 1994: Mesoscale Model Simulations - Part 2

Several heavy precipitation episodes occurred over Taiwan from August 10 to 13, 1994. Precipitation patterns and characteristics are quite different between the precipitation events that occurred from August 10 and I I and from August 12 and 13. In Part I (Chen et al. 2001), the environmental situation and precipitation characteristics are analyzed using the EC/TOGA data, ground-based radar data, surface rainfall patterns, surface wind data, and upper air soundings. In this study (Part II), the Penn State/NCAR Mesoscale Model (MM5) is used to study the precipitation characteristics of these heavy precipitation events. Various physical processes (schemes) developed at NASA Goddard Space Flight Center (i.e., cloud microphysics scheme, radiative transfer model, and land-soil-vegetation surface model) have recently implemented into the MM5. These physical packages are described in the paper, Two way interactive nested grids are used with horizontal resolutions of 45, 15 and 5 km. The model results indicated that Cloud physics, land surface and radiation processes generally do not change the location (horizontal distribution) of heavy precipitation. The Goddard 3-class ice scheme produced more rainfall than the 2-class scheme. The Goddard multi-broad-band radiative transfer model reduced precipitation compared to a one-broad band (emissivity) radiation model. The Goddard land-soil-vegetation surface model also reduce the rainfall compared to a simple surface model in which the surface temperature is computed from a Surface energy budget following the "force-re store" method. However, model runs including all Goddard physical processes enhanced precipitation significantly for both cases. The results from these runs are in better agreement with observations. Despite improved simulations using different physical schemes, there are still some deficiencies in the model simulations. Some potential problems are discussed. Sensitivity tests (removing either terrain or radiative processes) are performed to identify the physical processes that determine the precipitation patterns and characteristics for heavy rainfall events. These sensitivity tests indicated that terrain can play a major role in determining the exact location for both precipitation events. The terrain can also play a major role in determining the intensity of precipitation for both events. However, it has a large impact on one event but a smaller one on the other. The radiative processes are also important for determining, the precipitation patterns for one case but. not the other. The radiative processes can also effect the total rainfall for both cases to different extents.

Tao, Wei Kuo

The effect of SST and soil moisture anomalies on GLA model simulations of the 1988 U.S. summer drought

A series of simulations of the late spring and early summer of 1988 were conducted in order to study the relative importance of different boundary forcings to the Goddard Laboratory for Atmospheres (GLA) model's simulation of the heat wave and drought over the Great Plains of the United States during this time period. Separate 60-day simulations were generated from 10, 20, and 30 May 1988 with a variety of boundary condition datasets. For the control experiment, climatological boundary conditions were used. This was followed by experiments in which either the observed 1988 sea surface temperatures (SST) or derived 1988 soil moisture values, or both, were used in place of the climatological fields. Additional experiments were conducted in which only tropical or midlatitude SST anomalies were used. The impact of the different boundary forcings was evaluated relative to the control simulations of the precipitation and surface air temperature over the Great Plains. It was found that the tropical SST anomalies had a significant effect in reducing precipitation in this area, while the midlatitude anomalies did not. Due to the prescribed climatological soil moistures for the SST experiments, a significant increase in surface temperature did not occur in these simulations. In contrast, the simulations with the anomalous 1988 soil moistures produced both a larger reduction of precipitation and a significant increase in surface temperature over the Great Plains. The simulations with both anomalous SST and soil moisture showed only a slight augmentation of the heat wave and drought relative to the experiments with anomalous soil moisture alone.

Atlas, R.

Operational implications of a cloud model simulation of space shuttle exhaust clouds in different atmospheric conditions

A three-dimensional cloud model was used to characterize the dominant influence of the environment on the Space Shuttle exhaust cloud. The model was modified to accept the actual heat and moisture from rocket exhausts and deluge water as initial conditions. An upper-air sounding determined the ambient atmosphere in which the cloud would grow. The model was validated by comparing simulated clouds with observed clouds from four actual Shuttle launches. Results are discussed with operational weather forecasters in mind. The model successfully produced clouds with dimensions, rise, decay, liquid water contents, and vertical motion fields very similar to observed clouds whose dimensions were calculated from 16 mm film frames. Once validated, the model was used in a number of different atmospheric conditions ranging from very unstable to very stable. Wind shear strongly affected the appearance of both the ground cloud and vertical column cloud. The ambient low-level atmospheric moisture governed the amount of cloud water in model clouds. Some dry atmospheres produced little or no cloud water. An empirical forecast technique for Shuttle cloud rise is presented and differences between natural atmospheric convection and exhaust clouds are discussed.

Zak, J. A.

Theory and observations: Model simulations of the period 1955-1985

The main objective of the theoretical studies presented here is to apply models of stratospheric chemistry and transport in order to understand the processes that control stratospheric ozone and that are responsible for the observed variations. The model calculations are intended to simulate the observed behavior of atmospheric ozone over the past three decades (1955-1985), for which there exists a substantial record of both ground-based and, more recently, satellite measurements. Ozone concentrations in the atmosphere vary on different time scales and for several different causes. The models described here were designed to simulate the effect on ozone of changes in the concentration of such trace gases as CFC, CH4, N2O, and CO2. Changes from year to year in ultraviolet radiation associated with the solar cycle are also included in the models. A third source of variability explicitly considered is the sporadic introduction of large amounts of NO sub x into the stratosphere during atmospheric nuclear tests.

Isaksen, Ivar S. A.

On the Sensitivity of Atmospheric Ensembles to Cloud Microphysics in Long-Term Cloud-Resolving Model Simulations

Month-long large-scale forcing data from two field campaigns are used to drive a cloud-resolving model (CRM) and produce ensemble simulations of clouds and precipitation. Observational data are then used to evaluate the model results. To improve the model results, a new parameterization of the Bergeron process is proposed that incorporates the number concentration of ice nuclei (IN). Numerical simulations reveal that atmospheric ensembles are sensitive to IN concentration and ice crystal multiplication. Two- (2D) and three-dimensional (3D) simulations are carried out to address the sensitivity of atmospheric ensembles to model dimensionality. It is found that the ensembles with high IN concentration are more sensitive to dimensionality than those with low IN concentration. Both the analytic solutions of linear dry models and the CRM output show that there are more convective cores with stronger updrafts in 3D simulations than in 2D, which explains the differing sensitivity of the ensembles to dimensionality at different IN concentrations.

Zeng, Xiping

OPSMODEL, an or-orbit operations simulation modeling tool for Space Station

The 'OPSMODEL' operations-analysis and planning tool simulates on-orbit crew operations for the NASA Space Station, furnishing a quantitative measure of the effectiveness of crew activities in various alternative Station configurations while supporting engineering and cost analyses. OPSMODEL is entirely data-driven; the top-down modeling structure of the software allows the user to control both the content and the complexity level of model definition during data base population. Illustrative simulation samples are given.

Davis, William T.

How Accurately Do Maize Crop Models Simulate the Interactions of Atmospheric CO2 Concentration Levels With Limited Water Supply on Water Use and Yield?

This study assesses the ability of 21 crop models to capture the impact of elevated CO2 concentration [CO2] on maize yield and water use as measured in a 2-year Free Air Carbon dioxide Enrichment experiment conducted at the Thunen Institute in Braunschweig, Germany (Manderscheid et al. 2014). Data for ambient [CO2] and irrigated treatments were provided to the 21 models for calibrating plant traits, including weather, soil and management data as well as yield, grain number, above ground biomass, leaf area index, nitrogen concentration in biomass and grain, water use and soil water content. Models differed in their representation of carbon assimilation and evapotranspiration processes. The models reproduced the absence of yield response to elevated [CO2] under well-watered conditions, as well as the impact of water deficit at ambient [CO2], with 50 percent of models within a range of plus/minus 1 Mg ha(exp. -1) around the mean. The bias of the median of the 21 models was less than 1 Mg ha(exp. -1). However under water deficit in one of the two years, the models captured only 30 percent of the exceptionally high [CO2] enhancement on yield observed. Furthermore the ensemble of models was unable to simulate the very low soil water content at anthesis and the increase of soil water and grain number brought about by the elevated [CO2] under dry conditions. Overall, we found models with explicit stomatal control on transpiration tended to perform better. Our results highlight the need for model improvement with respect to simulating transpirational water use and its impact on water status during the kernel-set phase.

grain number

A mathematical simulation model of a 1985-era tilt-rotor passenger aircraft

A mathematical model for use in real-time piloted simulation of a 1985-era tilt rotor passenger aircraft is presented. The model comprises the basic six degrees-of-freedom equations of motion, and a large angle of attack representation of the airframe and rotor aerodynamics, together with equations and functions used to model turbine engine performance, aircraft control system and stability augmentation system. A complete derivation of the primary equations is given together with a description of the modeling techniques used. Data for the model is included in an appendix.

Mcveigh, M. A.

Partitioning and packing mathematical simulation models for calculation on parallel computers

The development of multiprocessor simulations from a serial set of ordinary differential equations describing a physical system is described. Degrees of parallelism (i.e., coupling between the equations) and their impact on parallel processing are discussed. The problem of identifying computational parallelism within sets of closely coupled equations that require the exchange of current values of variables is described. A technique is presented for identifying this parallelism and for partitioning the equations for parallel solution on a multiprocessor. An algorithm which packs the equations into a minimum number of processors is also described. The results of the packing algorithm when applied to a turbojet engine model are presented in terms of processor utilization.

Arpasi, D. J.

A comparison between general circulation model simulations using two sea surface temperature datasets for January 1979

Simulations with the UCLA atmospheric general circulation model (AGCM) using two different global sea surface temperature (SST) datasets for January 1979 are compared. One of these datasets is based on Comprehensive Ocean-Atmosphere Data Set (COADS) (SSTs) at locations where there are ship reports, and climatology elsewhere; the other is derived from measurements by instruments onboard NOAA satellites. In the former dataset (COADS SST), data are concentrated along shipping routes in the Northern Hemisphere; in the latter dataset High Resolution Infrared Sounder (HIRS SST), data cover the global domain. Ensembles of five 30-day mean fields are obtained from integrations performed in the perpetual-January mode. The results are presented as anomalies, that is, departures of each ensemble mean from that produced in a control simulation with climatological SSTs. Large differences are found between the anomalies obtained using COADS and HIRS SSTs, even in the Northern Hemisphere where the datasets are most similar to each other. The internal variability of the circulation in the control simulation and the simulated atmospheric response to anomalous forcings appear to be linked in that the pattern of geopotential height anomalies obtained using COADS SSTs resembles the first empirical orthogonal function (EOF 1) in the control simulation. The corresponding pattern obtained using HIRS SSTs is substantially different and somewhat resembles EOF 2 in the sector from central North America to central Asia. To gain insight into the reasons for these results, three additional simulations are carried out with SST anomalies confined to regions where COADS SSTs are substantially warmer than HIRS SSTs. The regions correspond to warm pools in the northwest and northeast Pacific, and the northwest Atlantic. These warm pools tend to produce positive geopotential height anomalies in the northeastern part of the corresponding oceans. Both warm pools in the Pacific produce large-scale circulation anomalies with a pattern that resembles that obtained using COADS SSTs as well as EOF 1 of the control simulation; the warm pool in the Atlantic does not. These results suggest that the differences obtained with COADS SSTs and HIRS SSTs are mostly due to the differences in the datasets over the northern Pacific. There was a blocking episode near Greenland in late January 1979. Both simulations with warm SST anomalies over the northwest and northeast Pacific show a tendency toward increased incidence of North Atlantic blocking; the simulation with warm SST anomalies over the northwest Atlantic shows a tendency toward decreased incidence. These results suggest that features in both SST datasets that do not have a counterpart in the other dataset contribute signficantly to the differences between the simulated and observed fields. The results of this study imply that uncertainties in current SST distributions for the world oceans can be as important as the SST anomalies themselves in terms of their impact on the atmospheric circulation. Caution should be exercised, therefore, when linking anomalous circulation and SST patterns, especially in long-range prediction.

Ose, Tomoaki

Simulation Modeling Requirements for Loss-of-Control Accident Prevention of Turboprop Transport Aircraft

In-flight loss of control remains the leading contributor to aviation accident fatalities, with stall upsets being the leading causal factor. The February 12, 2009. Colgan Air, Inc., Continental Express flight 3407 accident outside Buffalo, New York, brought this issue to the forefront of public consciousness and resulted in recommendations from the National Transportation Safety Board to conduct training that incorporates stalls that are fully developed and develop simulator standards to support such training. In 2010, Congress responded to this accident with Public Law 11-216 (Section 208), which mandates full stall training for Part 121 flight operations. Efforts are currently in progress to develop recommendations on implementation of stall training for airline pilots. The International Committee on Aviation Training in Extended Envelopes (ICATEE) is currently defining simulator fidelity standards that will be necessary for effective stall training. These recommendations will apply to all civil transport aircraft including straight-wing turboprop aircraft. Government-funded research over the previous decade provides a strong foundation for stall/post-stall simulation for swept-wing, conventional tail jets to respond to this mandate, but turboprops present additional and unique modeling challenges. First among these challenges is the effect of power, which can provide enhanced flow attachment behind the propellers. Furthermore, turboprops tend to operate for longer periods in an environment more susceptible to ice. As a result, there have been a significant number of turboprop accidents as a result of the early (lower angle of attack) stalls in icing. The vulnerability of turboprop configurations to icing has led to studies on ice accumulation and the resulting effects on flight behavior. Piloted simulations of these effects have highlighted the important training needs for recognition and mitigation of icing effects, including the reduction of stall margins. This paper addresses simulation modeling requirements that are unique to turboprop transport aircraft and highlights the growing need for aerodynamic models suitable for stall training for these configurations. A review of prominent accidents that involved aerodynamic stall is used to illustrate various modeling features unique to turboprop configurations and the impact of stall behavior on susceptibility to loss of control that has led to new training requirements. This is followed by an overview of stability and control behavior of straight-wing turboprops, the related aerodynamic characteristics, and a summary of recent experimental studies on icing effects. In addition, differences in flight dynamics behavior between swept-wing jets and straight-wing turboprop configurations are discussed to compare and contrast modeling requirements. Specific recommendations for aerodynamic models along with further research needs and data measurements are also provided. 1

Crider, Dennis

Compilation of a Global Emission Inventory from 1980 to 2000 for Global Model Simulations of the Long-term Trend of Tropospheric Aerosols

The approach to create a comprehensive emission inventory for the time period 1980 to 2000 is described in this paper. We have recently compiled an emission database, which we will use for a 21 year simulation of tropospheric aerosols with the GOCART model. Particular attention was paid to the time-dependent SO2, black carbon and organic carbon aerosol emissions. For the emission of SO2 from sporadically erupting volcanoes, we assembled emission data from the Global Volcanism Program of the Smithsonian Institution, using the VEI to derive the volcanic cloud height and the SO2 amount, and amended this dataset by the SO2 emission data from the TOMS instrument when available. 3-dimensional aircraft emission data was obtained for a number of years from the AEAP project, converted from burned fuel to SO2 and interpolated to each year, taking the sparsity of the flight patterns into account. Other anthropogenic SO2 emissions are based on gridded emissions from the EDGAR 2000 database (excluding sources from aircraft, biomass burning and international ship traffic), which were scaled to individual years with country/regional based emission inventories. Gridded SO2 emissions from international ship traffic for 2000 and the scaling factors for other years are from [Eyring et al., 2005]. We used gridded anthropogenic black and organic carbon emissions for 1996 [Bond et al., 2005], again excluding aircraft, biomass burning and ship sources. These emissions were scaled with regional based emission inventories from 1980 to 2000 to derive gridded emissions for each year. The biomass burning emissions are based on a climatology, which is scaled with regional scaling factors derived from the TOMS aerosol index and the AVHRR/ASTR fire counts to each year [Duncan et al., 2003]. Details on the integration of the information from the various sources will be provided and the distribution patterns and total emissions in the final product will be discussed.

Diehl, Thomas L.

Compilation of a Global Emission Inventory from 1980 to 2000 for Global Model Simulations of the Long-term Trend of Tropospheric Aerosols

The approach to create a comprehensive emission inventory for the time period 1980 to 2000 is described in this paper. We have recently compiled an emission database, which we will use for a 21 year simulation of tropospheric aerosols with the GOCART model. Particular attention was paid to the time-dependent SO2, black carbon and organic carbon aerosol emissions. For the emission of SO2 from sporadically erupting volcanoes, we assembled emission data from the Global Volcanism Program of the Smithsonian Institution, using the VEI to derive the volcanic cloud height and the SO2 amount, and amended this dataset by the SO2 emission data from the TOMS instrument when available. 3-dimensional aircraft emission data was obtained for a number of years from the AEAP project, converted from burned fuel to SO2 and interpolated to each year, taking the sparsity of the flight patterns into account. Other anthopogenic SO2 emissions are based on gridded emissions from the EDGAR 2000 database (excluding sources from aircraft, biomass burning and international ship traffic), which were scaled to individual years with country/regional based emission inventories. Gridded SO2 emissions from international ship traffic for 2000 and the scaling factors for other years are from [Eyring et al., 2005]. We used gridded anthropogenic black and organic carbon emissions for 1996 [Bond et al., 2005], again excluding aircraft, biomass burning and ship sources. These emissions were scaled with regional based emission inventories from 1980 to 2000 to derive gridded emissions for each year. The biomass burning emissions are based on a climatology, which is scaled with regional scaling factors derived from the TOMS aerosol index and the AVHRR/ATSR fire counts to each year [Duncan et al., 2003]. Details on the integration of the information from the various sources will be provided and the distribution patterns and total emissions in the final product will be discussed.

Diehl, T. L.

Hydrological controls of a riparian wetland based on stable isotope data and model simulations

Isotopic evidence of groundwater and stream water is frequently used to investigate water exchanges with groundwater. Monthly sampling of rain, stream water, and groundwater was conducted at Tims Branch watershed in South Carolina for the oxygen and hydrogen stable isotope (δ 2 H and δ 18 O) measurement, as well as pH and oxidation–reduction potential (ORP). Together with a mass balance perspective, it was determined that it takes a few weeks to one month for groundwater in the hyporheic zone to fully exchange with stream water. From hydrodynamic modelling, we show that substantial (up to 70 %) groundwater exchange occurs at gaining and losing sites. Groundwater exfiltration, i.e. inflow into stream water, contributes up to 4 % to stream water, with the remainder from upstream exfiltration. A 2–4 % per day renewal rate of adjacent groundwater would indirectly indicate a groundwater residence time in the order of half a month to a full month (assuming either a well-mixed case or large dispersion rate in pulse flow case), in agreement with a greatly reduced variability of δ 2 H and δ 18 O of groundwater compared to stream water and rain. This reduced variability of stable isotope signal from groundwater confirms our hypothesis that riparian groundwater mixing at Tims Branch is more of a mixed type rather than a pulse flow type. As a result, a monthly time scale is sufficient for groundwater to become anoxic at exit points into stream water resulting in the episodic production of natural organic matter- and iron-rich flocs upon oxidation.

54 ENVIRONMENTAL SCIENCES