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At least 271 records · Page 15

Condition-Based Maintenance of a Circulating Water System of a Canadian Nuclear Power Plant using Machine Learning and Statistical Tools

Canada Deuterium Uranium pressurized-heavy-water reactors (PHWR) are a type of nuclear power plant that generate clean and reliable energy. The scope of this work is to automate data analysis methodologies to inform a condition-based maintenance strategy of a circulating water system (CWS) of a PHWR. The multiunit CWS provides a continuous supply of water to cool steam condensers, even during transient scenarios, thereby improving the thermal efficiency. This work aims to develop a machine learning (ML) based approach to detect anomalies in heterogeneous data of a CWS in a PHWR to help inform a predictive maintenance strategy. The heterogeneous data include textual and numeric time series data for a PHWR. Natural-language-processing (NLP)-based models are used to analyze textual data contained in work orders and operator logs and an event-timeseries correlation detection method is applied to assist anomalies diagnoses for CWS. An ML model Robust Linear Model (RLM) is also used to remove the seasonal variations in the system variable distributions based on distributions of environmental variables. A machine learning model, Density-Based Spatial Clustering of Applications with Noise (DBSCAN), trained on both original data and data without any seasonal variations will then be used to detect if an anomaly exists. Thus, by moving to an automated methodology to detect, classify, and forecast anomalies, the maintenance strategy would be based on component condition instead of a time-based schedule.

97 - MATHEMATICS AND COMPUTING↗

A Dream of a Mission: Stellar Imager and Seismic Probe

The Stellar Imager and Seismic Probe (SISP) is a mission to understand the various effects of magnetic fields of stars, the dynamos that generate them, and the internal structure and dynamics of the stars in which they exist. The ultimate goal is to achieve the best-possible forecasting of solar activity on times scales ranging up to decades, and an understanding of the impact of stellar magnetic activity on astrobiology and life in the Universe. The road to that goal will revolutionize our understanding of stars and stellar systems, the building blocks of the Universe. SISP will zoom in on what today - with few exceptions - we only know as point sources, revealing processes never before seen, thus providing a tool to astrophysics as fundamental as the microscope is to the study of life on Earth. SISP is an ultraviolet aperture-synthesis imager with 8-10 telescopes with meter-class apertures, and a central hub with focal-plane instrumentation that allows spectrophotometry in passbands as narrow as a few Angstroms up to hundreds of Angstroms. SISP will image stars and binaries with one hundred to one thousand resolution elements on their surface, and sound their interiors through asteroseismology to image internal structure, differential rotation, and large-scale circulations; this will provide accurate knowledge of stellar structure and evolution and complex transport processes, and will impact numerous branches of (astro)physics ranging from the Big Bang to the future of the Universe. Fitting naturally within the NASA long-term time line, SISP complements defined missions, and with them will show us entire other solar systems, from the central star to their orbiting planets.

Carpenter, Kenneth G.↗

Time Variations of Mars' Gravitational Field and Seasonal Changes in the Masses of the Polar Ice Caps

Tracking of the Mars Global Surveyor spacecraft has been used to measure changes in the long-wavelength gravity field of Mars and to estimate the seasonal mass of carbon dioxide that is deposited in the polar regions each fall and winter and sublimed back into the atmosphere every spring and summer. Observations spanning 4 Mars years have been analyzed. A clear and well-defined seasonal signal, composed of annual and semiannual periods, is seen in the lowest odd degree 3 coefficient but with less confidence in the lowest even degree 2, which is expected to be smaller and is also much more difficult to observe. Direct estimation of the seasonal mass exchange employing a simple, seasonally varying model of the size and height of each cap provides values that indicate some systematic departures from the deposition predicted by a general circulation model. Estimates are also obtained for the precession and nutation of the pole of rotation of Mars, the degree 2 tidal Love number, k2, and the mass of Phobos, the larger of Mars' two natural satellites.

Smith, David E.↗

Observations of the dynamics of the polar thermosphere

The dynamics of the polar thermosphere are examined by using observations made from the Dynamics Explorer 2 satellite. The results used in this study were obtained primarily from the Fabry-Perot interferometer (FPI) and the wind and temperature spectrometer (WATS) during the time period from September 1981 through January 1982. Two primary geophysical conditions were examined: these were the southern summer and the northern winter polar regions. The results support the conclusion that above 60 degrees of latitude the neutral winds are strongly controlled by ion/neutral frictional momentum transfer resulting from magnetospheric convection. This implies that the natural coordinate system within which to display the neutral winds in the high polar thermosphere is magnetic. The collected observations of this study were used to assess the validity of two of the large thermospheric general circulation models. The result of this assessment was that the models reasonably represent the vector winds at high altitudes but do not, at present, accurately simulate the thermodynamics of that regime.

Hays, P. B.↗

A climatology of stratospheric aerosol

A global climatology of stratospheric aerosol is created by combining nearly a decade (1979-1981 and 1984-1990) of contemporaneous observations from the Stratospheric Aerosol and Gas Experiment (SAGE I and II) and Stratospheric Aerosol Measurement (SAM II) instruments. One goal of this work is to provide a representative distribution of the aerosol layer for use in radiative and chemical modeling. A table of decadal average 1 micron extinction values is included, extending from the tropopause to 35 km and 80 deg S to 85 deg N, which allows estimation of surface area density. We find that the aerosol layer is distinctly volcanic in nature and suggest that the decadal average is a more useful estimate of future aerosol loading than a 'background' loading, which is never clearly achieved during the data record. This climatology lends insight into the general circulation of the stratosphere. Latitude - altitude sections of extinction radio at 1 micron are shown, average by decade, season, and phase of the quasi-biennial oscillation (QBO). A tropical reservoir region is diagnosed, with an 'upper' and a 'lower' transport regime. In the tropics above 22 km (upper regime), enhanced lofting occurs in the summer, with suppressed lofting or eddy dilution in the winter. In the extratropics within two scale heights of the tropopause (lower regime), poleward and downward transport is most robust during winter, especially in the northern hemisphere. The transport patterns persist into the subsequent equinoctial season. Ascent associated with QBO easterly shear favors detrainment in the upper regime, while relative descent and poleward spreading during QBO westerly shear favors detrainment in the lower regime. Extinction radio differences between the winter-spring and summer-fall hemispheres, and differences between the two phases of the QBO, are typically 20-50%. Dynamical implications of the aerosol distributions are explored, with focus on interhemispheric differences, strong subtropical gradients, and the pronounced annual cycle.

Hitchman, Matthew H.↗

A sensitive radioimmunoassay for fludrocortisone in human plasma

Fludrocortisone has been a mainstay of therapy for orthostatic hypotension for many years. Clinical experience suggests that there exists a substantial interindividual variation in responsiveness to the drug. To assess this, we have developed an assay that permits measurement of the low concentrations of fludrocortisone found in human plasma. Fludrocortisone was detected by radioimmunoassay. A polyclonal rabbit antibody, raised against dexamethasone which cross-reacts strongly with fludrocortisone, was reacted with either standard or unknown samples in the presence of [125I]fludrocortisone-3-TyrNH2 (synthesized by coupling tyrosine amide to fludrocortisone-3-oxime and iodinating with chloramine T oxidation). The ED10, ED50, and ED80 were 0.34, 5.0, and 30 ng/mL of plasma, respectively. The cross reactivity with other 9-fluorinated steroids was found as follows: dexamethasone, 340%; betamethasone, 230%; and triamicinolone, 8%. To preclude an erroneous result, subjects who were pregnant or receiving any steroid medication were excluded from the study. The percent cross-reactivity with the main naturally occurring steroids was as follows: 11-desoxycortisol 3.2%, cortisol 1.1%, DOC 0.3%, pregnenolone 0.1%, corticosterone 0.06%, progesterone 0.05%, and aldosterone < 0.05%. The only compound with potential for interference, because of its high level in the circulation in the early morning, was cortisol.(ABSTRACT TRUNCATED AT 250 WORDS).

Non-NASA Center↗

ENSO/PDO-Like Variability of Tropical Ocean Surface Energy Fluxes Over the Satellite Era

Recent variations of tropical climate on interannual to near-decadal scales have provided a useful target for studying the nature of climate feedback processes. A strong warm / cold ENSO couplet (e.g. 1997-2000) along with several subsequent weaker events are prominent interannual signals that are part of an apparent longer term strengthening of the Walker circulation during the mid to late 1990's with some weakening thereafter. Decadal scale changes in tropical SST structure during the 1990s are accompanied by focusing of precipitation over the Indo-Pacific warm pool and an increase in tropical ocean evaporation of order 1.0 % /decade. Associated with ENSO and PDO-like tropical SST changes are surface freshwater and radiative fluxes which have important implications for heat and energy transport variations. In this study we examine how surface fluxes attending interannual to decadal SST fluctuations, e.g. precipitation (GPCP, TRMM), turbulent fluxes (OAFlux), and radiative fluxes (ERBE/CERES, SRB) are coupled. Using these data we analyze vertically-integrated divergence of moist static energy, divMSE, and its dry static energy and latent energy components. We examine consistency between these data sets and explore relationships between SST variations, flux changes and modulation of tropical Walker and Hadley circulations. Strong signatures ofMSE flux transport linking ascending and descending regions of tropical circulations are found. Relative strengths of these fluxes and transports are interpreted as a measure of efficiency in the overall process of tropical heat balance during episodes of warm or cold tropical SST.

Robertson, F. R.↗

Establishing reference ranges for circulating biomarkers of drug‐induced liver injury in healthy human volunteers 1

Aims The potential of mechanistic biomarkers to improve prediction of drug‐induced liver injury (DILI) and hepatic regeneration is widely acknowledged. We sought to determine reference intervals for new biomarkers of DILI and regeneration, as well as to characterize their natural variability and impact of diurnal variation. Methods Serum samples from 227 healthy volunteers were recruited as part of a cross‐sectional study; of these, 25 subjects had weekly serial sampling over 3 weeks, while 23 had intensive blood sampling over a 24h period. Alanine aminotransferase (ALT), MicroRNA‐122 (miR‐122), High Mobility Group Box‐1 (HMGB1), total Keratin‐18 (K18), caspase‐cleaved Keratin‐18 (ccK18), Glutamate Dehydrogenase (GLDH) and Macrophage Colony‐Stimulating Factor‐1 (CSF‐1) were assayed. Results Reference intervals were established for each biomarker based on the 97.5% quantile (90% CI) following the assessment of fixed effects in univariate and multivariable models. Intra‐individual variability was found to be non‐significant, and there was no significant impact of diurnal variation. Conclusion Reference intervals for novel DILI biomarkers have been described. An upper limit of a reference range might represent the most appropriate mechanism to utilize these data. These data can now be used to interpret data from exploratory clinical DILI studies and to assist their further qualification as required by regulatory authorities.

Jorgensen, Andrea L. [Department of Health Data Sc↗

Airborne Radar Observations of Hurricane Georges during Landfall over the Dominican Republic

On 22 September 1998 hurricane Georges made landfall on the Dominican Republic (DR). Georges cost the DR at least 500 lives, made more than 155,000 people homeless and caused extensive damage to the country's main industries, tourism and agriculture. There was considerable wind damage, with wind gusts up to 58 m/s in Santa Domingo on the south coast, but most of the damage and deaths resulted from mudslides and the flooding of rivers. While this may have been the worst natural disaster to strike the DR, the sustained rapid storm movement saved the island from worse damage. Georges had previously affected several islands in the Lesser Antilles and Puerto Rico, but it had retained much of its circulation strength. Forty raingauge stations across the DR measured rainfall totals from Georges between 0.7 and 41 cm, the latter at the capital Santo Domingo, located on the south coast. At Herrera the maximum 1 h rainfall rate was 72 mm/h. It is suspected that much higher rain rates occurred in DR's mountainous interior. Before landfall the eye was clearly evident in satellite imagery. When the eye moved over southeastern DR, it filled rapidly, and the cloud top height decreased in all storm sectors except in the southern inflow sector, where a long-lived MCS, with a diameter larger than that of the eyewall, slowly became enwrapped in the hurricane circulation. The eye closure was most rapid between 16-18 UTC, when the eyewall circulation felt the mountainous terrain of the Cordillera Central, which rises up to 3,093 m. The estimated central pressure increased from 962 hPa at 15 UTC to 986 hPa at 03Z on 23 Sept, and the maximum sustained surface wind speed decreased from 54 to 36 in s-1 during the same period. The island of Hispaniola has a cross-track width of about 250 km, much wider than the diameter of the eyewall anvil (about 100 km before landfall). So the event can truly be considered to be a landfalling case, even though Georges recovered after crossing Hispaniola, albeit never to the same strength. This talk will summarize satellite and ground observations of Georges, as it passed the DR, and it will focus on EDOP data. In particular, we will try to estimate the rainfall rate over the mountainous terrain of the DR. And we will use detailed sounding data to explain the presence and characteristics of the massive MCS to the south, as well as the upper-level updrafts apparent over this MCS and over the mountains of the DR.

Geerts, B.↗

Advances and Challenges in Observations and Modeling of the Global-Sun Dynamics and Dynamo

Computational heliophysics has shed light on the fundamental physical processes inside the Sun, such as the differential rotation, meridional circulation, and dynamo-generation of magnetic fields. However, despite the substantial advances, the current results of 3D MHD simulations are still far from reproducing helioseismic inferences and surface observations. The reason is the multi-scale nature of the solar dynamics, covering a vast range of scales, which can-not be solved with the current computational resources. In such a situation, significant progress has been achieved by the mean-field approach, based on the separation of small-scale turbulence and large-scale dynamics. The mean-field simulations can reproduce solar observations, qualitatively and quantitatively, and uncover new phenomena. However, they do not reveal the complex physics of large-scale convection, solar magnetic cycles, and the magnetic self-organization that causes sunspots and solar eruptions. Thus, developing a synergy of these approaches seems to be a necessary but very challenging task.

SMD↗

Design Approach for Circulating Fluidized Bed Riser Reactors such as NETL ASURE: A Review for Clustering Flow

Circulating fluidized bed riser reactors have been a commercial reality for some 80 to 90 years. Through all this time and hundreds if not thousands of research papers on the topic, no clear understanding exists on what is required to design and build a process reactor. There are numerous reasons for this, but the most significant reason is likely that riser reactors are chaotic in nature and unless this chaotic behavior is accounted for, there will be wide discrepancies in the predicted performance and in attempts to scale these reactors without significant trial and error. This work puts forth a new methodology to design riser reactors based upon the desired operating range using the chaotic microstructure behavior. This is accomplished through the use of a nondimensional regime map that was developed using chaotic parameters of memory and order/disorder along with higher moments of skewness and kurtosis. Validation of the approach is provided with circulating fluidized bed combustors and applied to the design of the NETL ASURE facility.

42 ENGINEERING↗

Contributions of GRACE to Climate Monitoring

The NASA/German Gravity Recovery and Climate Experiment (GRACE) was launched in March 2002. Rather than looking downward, GRACE continuously monitors the locations of and precise distance between twin satellites which orbit in tandem about 200 km apart. Variations in mass near Earth's surface cause heterogeneities in its gravity field, which in turn affect the orbits of satellites. Thus scientists can use GRACE data to map Earth's gravity field with enough accuracy to discern month to month changes caused by ocean circulation and redistribution of water stored on and in the land. Other gravitational influences, such as atmospheric circulation, post-glacial rebound, and solid earth movements are either independently determined and removed or are negligible on a monthly to sub-decadal timescale. Despite its coarse spatial (>150,000 sq km at mid-latitudes) and temporal (approx monthly) resolutions, GRACE has enabled significant advancements in the oceanic, hydrologic, and cryospheric science, and has great potential for climate monitoring, because it is the only global observing system able to measure ocean bottom pressures, total terrestrial water storage, and ice mass changes. The best known GRACE results are estimates of Greenland and Antarctic ice sheet loss rates. Previously, scientists had estimated ice mass losses using ground and satellite based altimetry and surface mass balance estimates based on snowfall accumulation and glacier discharge. While such measurements are still very useful for their spatial detail, they are imperfectly correlated with large-scale ice mass changes, due to snow and ice compaction and incomplete spatial coverage. GRACE enables scientists to generate monthly time series of Greenland and Antarctic ice mass, which have confirmed the shrinking of the polar ice sheets, one of the most obvious and indisputable manifestations of climate change. Further, GRACE has located and quantified hot spots of ice loss in southeastern Greenland and western Antarctica. For 2002 to present, the rate of ice mass loss has been 200 to 300 GT/yr in Greenland and 70 to 210 GT/yr in Antarctica, and some scientists are suggesting that the rates are accelerating. Similarly, GRACE has been used to monitor mass changes in alpine glaciers. Tamisiea et al. first characterized glacier melt along the southern coast of Alaska, more recently estimated to be occurring at a rate of 84 GT/yr. Chen et al. estimated that Patagonian glaciers are melting at a rate of 28 GT/yr, and estimated that the high mountains of central Asia lose ice at a rate of 47 GT/yr. Tapley et al. and Wahr et al. presented the first GRACE based estimates of changes in column-integrated terrestrial water storage (TWS; the sum of ground-water, soil moisture, surface waters, snow, ice, and water stored in vegetation) at continental scales. Since then, dozens of studies have shown that GRACE based estimates of regional to continental scale TWS variations agree with independent information, and some innovative uses of GRACE data have been developed. Rodell et al. (2004) and Swenson and Wahr (2006) demonstrated that by combining GRACE derived terrestrial water storage changes with observations of precipitation and runoff in a river basin scale water budget, it was possible to produce new estimates of evapotranspiration and atmospheric moisture convergence, essential climate variables that are difficult to estimate accurately. Similarly, GRACE has been used to constrain estimates of global river discharge and the contribution of changes in TWS to sea level rise. Crowley et al. observed a negative correlation between interannual TWS anomalies in the Amazon and the Congo River basin. Yeh et al. and Rodell et al. estimated regionally averaged groundwater storage variations based on GRACE and auxiliary observations. Rodell et al. and Tiwari et al. applied that method to quantify massive groundwater depletion in northern India caused by over reliance on aquifers for irration, and Famiglietti et al. found a similar situation in California's Central Valley. Zaitchik et al. and Lo et al. described approaches to use GRACE to constrain hydrological models, enabling integration of GRACE data with other observations and achieving much higher spatial and temporal resolutions than GRACE alone. Such approaches are now supporting applications including drought and water resources monitoring. Oceanography has likewise benefitted from the independent nature of GRACE observations. One application is measurement of the mass component of sea level rise, which complements radar altimetry and in situ measurements. GRACE also measures ocean bottom pressures (OBP), which help to refine understanding and modeling of ocean circulation and the ocean's fresh water budget, among other things. For example, Hayakawa et al. showed that GRACE observes OBP patterns absent from the background models of oceanic variability. Morison et al. used GRACE to describe important decadal scale shifts in circulation and an ongoing trend of freshening of the western Arctic, important indicators of climate variability. The research of Song and Zlotnicki and Chambers and Willis on GRACE-derived ocean bottom pressures in the sub-polar gyre led to the discovery of an ENSO teleconnection and a long-term change in OBP in the North Pacific sub-polar gyre that was not predicted by an ocean model. Further, Chambers and Willis were able to identify an internal redistribution of mass between Atlantic and Pacific Oceans lasting at least six years, which was not predicted by ocean models and was the first direct evidence of sustained mass transport from one ocean basin to another on periods longer than a year. Boening et al. observed a record increase in OBP over part of the southeastern Pacific in late 2009 and early 2010, primarily caused by wind stress curl associated with a strong and persistent anticyclone and likely related to the concurrent Central Pacific El Nino. GRACE has far surpassed its 5-year design lifetime, but it will likely succumb to the aging of batteries and instrument systems sometime in the next few years. NASA has begun initial development of a follow-on to GRACE with very similar design, which could launch as soon as 2016 and would provide continuity in the data record while improving resolution slightly. Higher resolution time variable gravity missions are also on the drawing board .

Rodell, Matthew↗

An experimental investigation of supersonic swirling jets

The addition of swirl to scramjet fuel jets has been proposed as a method of enhancing fuel mixing, but little of a fundamental nature is known about supersonic swirling flows. This is a study of mixing in supersonic swirling air jets created by tangential injection and acceleration through a convergent-divergent nozzle into stagnant air. Several cases with different vortex circulations were investigated using pitot, cone and total-temperature probes, and Rayleigh scattering from a laser light sheet. The results show that tangential injection is an efficient method for generating swirling jets; that the swirling jets mix much more rapidly with the ambient air than comparable straight jets; and that when overexpanded, considerable turbulence and increased mixing is created as a result of vortex breakdown.

Cutler, Andrew D.↗

Oceanic Fluxes of Mass, Heat and Freshwater: A Global Estimate and Perspective

Data from fifteen globally distributed, modern, high resolution, hydrographic oceanic transects are combined in an inverse calculation using large scale box models. The models provide estimates of the global meridional heat and freshwater budgets and are used to examine the sensitivity of the global circulation, both inter and intra-basin exchange rates, to a variety of external constraints provided by estimates of Ekman, boundary current and throughflow transports. A solution is found which is consistent with both the model physics and the global data set, despite a twenty five year time span and a lack of seasonal consistency among the data. The overall pattern of the global circulation suggested by the models is similar to that proposed in previously published local studies and regional reviews. However, significant qualitative and quantitative differences exist. These differences are due both to the model definition and to the global nature of the data set.

MacDonald, Alison Marguerite↗

Impact of Land Surface Heterogeneity on Mesoscale Atmospheric Dispersion

Prior numerical modelling studies show that atmospheric dispersion is sensitive to surface heterogeneities, but past studies do not consider the impact of a realistic distribution of surface heterogeneities on mesoscale atmospheric dispersion. While these focussed on dispersion in the convective boundary layer, the present work also considers dispersion in the nocturnal boundary layer and above. Using a Lagrangian particle dispersion model (LPDM) coupled to the Eulerian Regional Atmospheric Modeling System (RAMS), the impact of topographic, vegetation, and soil moisture heterogeneities on daytime and nighttime atmospheric dispersion is examined. In addition, the sensitivity to the use of Moderate Resolution Imaging Spectroradiometer (MODIS)-derived spatial distributions of vegetation characteristics on atmospheric dispersion is also studied. The impact of vegetation and terrain heterogeneities on atmospheric dispersion is strongly modulated by soil moisture, with the nature of dispersion switching from non-Gaussian to near- Gaussian behaviour for wetter soils (fraction of saturation soil moisture content exceeding 40%). For drier soil moisture conditions, vegetation heterogeneity produces differential heating and the formation of mesoscale circulation patterns that are primarily responsible for non-Gaussian dispersion patterns. Nighttime dispersion is very sensitive to topographic, vegetation, soil moisture, and soil type heterogeneity and is distinctly non-Gaussian for heterogeneous land-surface conditions. Sensitivity studies show that soil type and vegetation heterogeneities have the most dramatic impact on atmospheric dispersion. To provide more skillful dispersion calculations, we recommend the utilisation of satellite-derived vegetation characteristics coupled with data assimilation techniques that constrain soil-vegetation-atmosphere transfer (SVAT) models to generate realistic spatial distributions of surface energy fluxes.

Wu, Yuling↗

Free convection in the Matian atmosphere

The 'free convective' regime for the Martian atmospheric boundary layer (ABL) was investigated. This state occurs when the mean windspeed at the top of the ABL drops below some critical value U(sub c) and positive buoyant forces are present. Such forces can arise either from vertical temperature or water vapor gradients across the atmospheric surface layer. During free convection, buoyant forces drive narrow plumes that ascend to the inversion height with a return circulation consisting of broad slower-moving downdraughts. Horizontal pressure, temperature, windspeed, and water vapor fluctuations resulting form this circulation pattern can be quite large adjacent to the ground (within the surface layer). The local turbulent fluctuations cause non-zero mean surface stresses, sensible heat fluxes, and latent heat fluxes, even when the mean regional windspeed is zero. Although motions above the surface layer are insensitive to the nature of the surface, the sensible and latent heat fluxes are primarily controlled by processes within the interfacial sublayer immediately adjacent to the ground during free convection. Thus the distinction between aerodynamically smooth and rough airflow within the interfacial sublayer is more important than for the more typical situation where the mean regional windspeed is greater than U(sub c). Buoyant forces associated with water vapor gradients are particularly large on Mars at low pressures and high temperatures when the surface relative humidity is 100 percent, enhancing the likelihood of free convection under these conditions. On this basis, Ingersol postulated the evaporative heat losses from an icy surface on Mars at 237 K and current pressures would exceed the available net radiative flux at the surface, thus prohibiting ice from melting at low atmospheric pressures. Schumann has developed equations describing the horizontal fluctuations and mean vertical gradients occurring during free convection. Schumann's model was generalized to include convection driven by water vapor gradients and to include the effects of circulation above both aerodynamically smooth and rough surfaces.

Clow, G. D.↗

A generalization of Petterssen's frontogenesis function and its relation to the forcing of vertical motion

The classic Peterssen frontogenesis function, defined as the Lagrangian rate of change of the magnitude of the potential temperature gradient, is generalized to apply to the vector potential temperature gradient. The derivation of vector frontogenesis in natural coordinates is shown, and analytical examples of frontal evolution in nondivergent horizontal velocity fields are given which suggest that both the frontogenetic and rotational components of the vector frontogenesis function F may be comparable in developing frontal zones observed in nature. The relative importance of the magnitude and direction contributions to F is quantitatively investigated, and it is found that the Lagrangian rates of change of the magnitude and direction of the potential temperature gradient are comparable. The frontal circulation is found to be related to the magnitude component of the Q vector, whereas the background circulation is related to the direction component.

Keyser, Daniel↗

Evidence for organic synthesis in high temperature aqueous media - facts and prognosis

Hydrothermal systems are common along the active tectonic areas of the earth. Potential sites being studied for organic matter alteration and possible organic synthesis are spreading ridges, off-axis systems, back-arc activity, hot spots, volcanism, and subduction. Organic matter alteration, primarily reductive and generally from immature organic detritus, occurs in these high temperature and rapid fluid flow hydrothermal regimes. Hot circulating water (temperature range - warm to greater than 400 C) is responsible for these molecular alterations, expulsion and migration. Compounds that are obviously synthesized are minor components because they are generally masked by the pyrolysis products formed from contemporary natural organic precursors. The reactivity of organic compounds in hot water (200-350 C) has been studied in autoclaves, and supercritical water as a medium for chemistry has also been evaluated. This high temperature aqueous organic chemistry and the strong reducing conditions of the natural systems suggest this as an important route to produce organic compounds on the primitive earth. Thus a better understanding of the potential syntheses of organic compounds in hydrothermal systems will require investigations of the chemistry of condensation, autocatalysis, catalysis and hydrolysis reactions in aqueous mineral buffered systems over a range of temperatures from warm to greater than 400 C.

Simoneit, Bernd R. T.↗