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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Tuning optical properties and local lone-pair off-centering in “hollow” FA 1− x { en } x Pb η−y Sn y Br 3 perovskites

Hollow metal halide perovskites, while a relatively recent discovery, have already been shown to push the boundaries of tuneability within an inherently limited compositional space. Here, we further expand our knowledge of these complex materials demonstrating the ability to control optical properties and local structure, notably lone-pair induced off-centering. We focus on the mixed metal FA 1−x en x Pb η−y Sn y Br 3 hollow perovskites. These compounds have wide ranging optical gaps from 1.9 eV (deep red) to 2.6 eV (light yellow), combining the anomalous bandgap red-shifting of Pb/Sn mixing with the blue-shifting effects of the organic substitution. Average and local structural studies employing single crystal X-ray diffraction and total X-ray scattering pair distribution function analyses respectively suggest strong incoherent off-centering distortions that are locally correlated with Sn concentration. The inclusion of ethylenediammonium dications appears to regulate metal off-centering, opening new opportunities of research into this phenomenon.

Balvanz, Adam [Northwestern University, Evanston, ↗
NASA NTRS2014

High Spectral Resolution Lidar and MPLNET Micro Pulse Lidar Aerosol Optical Property Retrieval Intercomparison During the 2012 7-SEAS Field Campaign at Singapore

From August 2012 to February 2013 a High Resolution Spectral Lidar (HSRL; 532 nm) was deployed at that National University of Singapore near a NASA Micro Pulse Lidar NETwork (MPLNET; 527 nm) site. A primary objective of the MPLNET lidar project is the production and dissemination of reliable Level 1 measurements and Level 2 retrieval products. This paper characterizes and quantifies error in Level 2 aerosol optical property retrievals conducted through inversion techniques that derive backscattering and extinction coefficients from MPLNET elastic single-wavelength datasets. MPLNET Level 2 retrievals for aerosol optical depth and extinction/backscatter coefficient profiles are compared with corresponding HSRL datasets, for which the instrument collects direct measurements of each using a unique optical configuration that segregates aerosol and cloud backscattered signal from molecular signal. The intercomparison is performed, and error matrices reported, for lower (0-5km) and the upper (>5km) troposphere, respectively, to distinguish uncertainties observed within and above the MPLNET instrument optical overlap regime.

MPL↗
NASA NTRS2020

Effect of Ram and Zenith Exposure on the Optical Properties of Polymers in Space

The temperature of spacecraft is influenced by the solar absorptance and thermal emittance of the external spacecraft materials in addition to heat generated within the spacecraft. Optical and thermal properties can degrade in the low Earth orbital (LEO) space environment where spacecraft external materials are exposed to various forms of radiation, thermal cycling, and atomic oxygen. One objective of the Polymers and Zenith Polymers Experiments was to determine the effect of LEO space exposure on the optical properties of various spacecraft polymers. These experiments were flown as part of the Materials International Space Station Experiment 7 (MISSE 7) mission on the exterior of the International Space Station (ISS) for 1.5 years. Samples were flown in ram, wake and zenith directions, receiving varying amounts of atomic oxygen and solar radiation. Total and diffuse reflectance, and transmittance, of flight and corresponding control samples were obtained using a Cary 5000 UV-Vis-NIR Spectrophotometer. Integrated air mass zero solar absorptance (as) of the flight and control ram and zenith samples were computed and compared. Optical and atomic oxygen erosion data are compared with similar MISSE 2 polymers exposed to space for four years. Results show that prolonged space exposure increases the solar absorptance of some materials. Knowing which polymers remain stable will benefit future spacecraft design.

Atomic oxygen, erosion, space radiation, optical p↗
DOE OSTI2025

Optical properties of hydrothermally synthesized Ti 3 C 2 T X MXene quantum dots and their application in biosensor

The remarkable properties of Ti 3 C 2 T X MXene quantum dots (MQDs) highlight their potential in diverse fields, including domains such as biocompatible nanoprobe, ion sensing, energy applications etc. Given their relevance in emerging technologies, a systematic study of their optical properties is crucial. MXene nanosheets were utilized in Acetylcholinesterase (AChE) based biosensors for the detection of organophosphate (OP) pesticides, this suggests there is significant potential for further development of electrochemical biosensor by incorporating MQDs in this field. The synthesis of MQDs has been achieved through various methods, either individually or in combination of methods, including hydrothermal, acoustic microfluidic, electrochemical, ball milling etc. Furthermore, we synthesized Ti 3 C 2 T X MQDs using hydrothermal method and characterized using atomic force microscopy, optical spectroscopy and cyclic voltammetry.

36 MATERIALS SCIENCE↗
NASA NTRS2000

An Airborne A-Band Spectrometer for Remote Sensing Of Aerosol and Cloud Optical Properties

Atmospheric remote sensing with the O2 A-band has a relatively long history, but most of these studies were attempting to estimate surface pressure or cloud-top pressure. Recent conceptual studies have demonstrated the potential of spaceborne high spectral resolution O2 A-band spectrometers for retrieval of aerosol and cloud optical properties. The physical rationale of this new approach is that information on the scattering properties of the atmosphere is embedded in the detailed line structure of the O2 A-band reflected radiance spectrum. The key to extracting this information is to measure the radiance spectrum at very high spectral resolution. Instrument performance requirement studies indicate that, in addition to high spectral resolution, the successful retrieval of aerosol and cloud properties from A-band radiance spectra will also require high radiometric accuracy, instrument stability, and high signal-to-noise measurements. To experimentally assess the capabilities of this promising new remote sensing application, the NASA Langley Research Center is developing an airborne high spectral resolution A-band spectrometer. The spectrometer uses a plane holographic grating with a folded Littrow geometry to achieve high spectral resolution (0.5 cm-1) and low stray light in a compact package. This instrument will be flown in a series of field campaigns beginning in 2001 to evaluate the overall feasibility of this new technique. Results from these campaigns should be particularly valuable for future spaceborne applications of A-band spectrometers for aerosol and cloud retrievals.

Pitts, Michael↗
NASA NTRS1987

Simulated space environment effects on the optical properties of poly(arylene ethers)

Results are reported from a study of the stability of poly(arylene ethers) formed in a reaction of 1,3 -bis(4-chlorobenzoyl)benzene and various bisphenols after experiencing long-term exposure to space conditions. Transparent poly(arylene ethers) films were subjected to separate electron and UV bombardments, as were polysulfone and Kapton films for comparisons. The order of exposure to the two types of radiation was reversed for two sample populations. The optical properties and glass transition temperatures of the samples were determined after irradiation. The poly(arylene ethers) films exhibited good resistance to the electron radiation but suffered severe degradation in the UV environment. The loss of optical transmissivity was proportional to the UV radiation dose.

Sykes, George F.↗
NASA NTRS2005

Optical and Thermo-optical Properties of Polyimide-Single-Walled Carbon Nanotube Films: Experimental Results and Empirical Equations

The incorporation of single-walled carbon nanotubes (SWNTs) into the bulk of space environmentally durable polymers at loading levels greater than or equal to 0.05 wt % has afforded thin films with surface and volume resistivities sufficient for electrostatic charge mitigation. However, the optical transparency at 500 nm decreased and the thermo-optical properties (solar absorptivity and thermal emissivity) increased with increaed SWNT loading. These properties were also dependent on film thickness. The absorbance characteristics of the films as a function of SWNT loading and film thickness were measured and determined to follow the classical Beer-Lambert law. Based on these results, an empirical relationship was derived and molar absorptivities determined for both the SWNTs and polymer matrix to provide a predictive approximation of these properties. The molar absorptivity determined for SWNTs dispersed in the polymer was comparable to reported solution determined values for HiPco SWNTs.

Smith, Joseph G., Jr.↗
DOE OSTI2025

Crystal Growth of Quaternary Rare Earth Selenosilicates by Using the Flux-Assisted Boron Chalcogen Mixture Method: Investigation of Their Magnetic and Optical Properties

A series of rare earth magnesium selenosilicates, RE3Mg 0.5 SiSe 7 (RE = Ce, Pr, Nd, Sm, Gd, Tb, Dy) were obtained as single crystal using the flux assisted boron chalcogen mixture (BCM) method. The structures of the crystals were determined by single-crystal X-ray diffraction. The RE3Mg 0.5 SiSe 7 series crystallizes in the hexagonal crystal system in the space group P6 3 . Polycrystalline powders were synthesized to perform physical property measurements. Magnetic measurements over the 2–300 K temperature range reveal that Ce 3 Mg 0.5 SiSe 7 and Gd 3 Mg 0.5 SiSe 7 exhibit paramagnetic behavior with negative Weiss constants (θ W = −14.50, θ W = −6.13 K, respectively). The optical properties of RE 3 Mg 0.5 SiSe 7 (RE = Ce, Pr, Nd, Sm, Gd) were measured by ultraviolet–visible (UV–vis) diffuse reflectance. Density functional theory (DFT) electronic structure calculations were performed. Furthermore, a second harmonic generation measurement was performed on a polycrystalline powder of Ce 3 Mg 0.5 SiSe 7 and was found to be SHG active with an efficiency of 0.11 times the standard potassium dihydrogen phosphate (KDP).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2003

Refinement of Protocols for Measuring the Apparent Optical Properties of Seawater

Ocean color satellite missions, like the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) or the Moderate Resolution Imaging Spectroradiometer (MODIS) projects, are tasked with acquiring a global ocean color data set, validating and monitoring the accuracy and quality of the data, processing the radiometric data into geophysical units using a set of atmospheric and bio-optical algorithms, and distributing the final products to the scientific community. The long-standing requirement of the SeaWiFS Project, for example, is to produce spectral water-leaving radiances, LW(lambda), to within 5% absolute (lambda denotes wavelength) and chlorophyll a concentrations to within 35% (Hooker and Esaias 1993), and most ocean color sensors have the same or similar requirements. Although a diverse set of activities are required to ensure the accuracy requirements are met (Hooker and McClain 2000), the perspective here is with field observations. The accurate determination of upper ocean apparent optical properties (AOPs) is essential for the vicarious calibration of ocean color data and the validation of the derived data products, because the sea-truth measurements are used to evaluate the satellite observations (Hooker and McClain 2000). The uncertainties with in situ AOP measurements have various sources: a) the sampling procedures used in the field, including the environmental conditions encountered; b) the absolute characterization of the radiometers in the laboratory; c) the conversion of the light signals to geophysical units in a processing scheme, and d) the stability of the radiometers in the harsh environment they are subjected to during transport and use. Assuming ideal environmental conditions, so this aspect can be neglected, the SeaWiFS ground-truth uncertainty budget can only be satisfied if each uncertainty is on the order of 1-2%, or what is generally referred to as 1% radiometry. In recent years, progress has been made in estimating the magnitude of some of these uncertainties and in defining procedures for minimizing them. For the SeaWiFS Project, the first step was to convene a workshop to draft the SeaWiFS Ocean Optics Protocols (hereafter referred to as the Protocols). The Protocols initially adhered to the Joint Global Ocean Flux Study (JGOFS) sampling procedures (JGOFS 1991) and defined the standards for optical measurements to be used in SeaWiFS calibration and validation activities (Mueller and Austin 1992). Over time, the Protocols were revised (Mueller and Austin 1995), and then recurringly updated on essentially an annual basis (Mueller 2000, 2002, and 2003) as part of the Sensor Inter-comparison and Merger for Biological and Interdisciplinary Oceanic Studies (SIMBIOS) project. 98

Hooker, Stanford B.↗
NASA NTRS2002

Optical properties of intact leaves for estimating chlorophyll concentration

Changes in leaf chlorophyll content can serve as relative indicators of plant vigor and environmental quality. This study identified reflectance, transmittance, and absorptance wavebands and band ratios within the 400- to 850-nm range for intact leaves that could be used to estimate extracted leaf chlorophyll per unit leaf area (areal concentration) with minimal error. Leaf optical properties along with chlorophyll a, b, and a + b concentrations were measured for the planar-leaved sweetgum (Liquidambar styraciflua L.), red maple (Acer rubrum L.), wild grape (Vitis rotundifolia Michx.), and switchcane [Arundinaria gigantea (Walter) Muhl.], and for needles of longleaf pine (Pinus palustris Miller). Generally, reflectance, transmittance, and absorptance corresponded most precisely with chlorophyll concentrations at wavelengths near 700 nm, although regressions were also strong in the 550- to 625-nm range. A power function was superior to a simple linear function in yielding low standard deviations of the estimate (s). When data were combined among the planar-leaved species, s values were low at approximately 50 mumol/m2 out of a 940 mumol/m2 range in chlorophyll a + b at best-fit wavelengths of 707 to 709 nm. Minimal s values for chlorophyll a + b ranged from 32 to 62 mumol/m2 across species when band ratios having numerator wavelengths of 693 to 720 nm were used with the application of a power function. Optimal denominator wavelengths for the band ratios were 850 nm for reflectance and transmittance and 400 nm for absorptance. This information can be applied in designing field portable chlorophyll meters and in the landscape-scale remote sensing of plant responses to the environment.

Chlorophyll/analysis↗
DOE OSTI2026

Impact of the Annealing Temperature on the Local Se Distribution and Optical Properties in CdSexTe1-x Solar Cells by Multimodal X-ray Microscopy

The introduction of Se in CdTe solar-cell absorbers has led to multiple beneficial effects in the devices, including an increased short-circuit current and an extended charge-carrier lifetime. A critical manufacturing step of CdSexTe1-x solar cells is CdCl2 annealing at high temperatures, during which Se diffuses through the absorber layer. Understanding the local Se distribution in the absorber and its impact on optical properties of the material is key for the further development of this thin-film solar cell technology. In a multimodal x-ray scanning microscopy approach, we investigated the impact of the annealing temperature of CdSexTe1-x solar cells on the Se distribution and on optical characteristics of the material. For this purpose, we exploited an upgraded x-ray excited optical luminescence (XEOL) detection unit that enables simultaneous spectrally and temporally resolved XEOL mapping at synchrotron facilities that are ideal for studying thin-film solar-cell materials with hard x-rays featuring high penetration depth and lateral resolution.

14 SOLAR ENERGY↗
NASA NTRS1994

Effect of the degree of disorder on electronic and optical properties in random superlattices

A three-dimensional tight-binding calculation is developed and used to study disorder effects in a realistic random superlattice. With increasing disorder, a tendency of possible indirect-direct band-gap transition is suggested. Direct evidence of mobility edges between localized and extended states in three-dimensional random systems is given. As system disorder increases, the optical absorption intensities increase dramatically from five to forty-five times stronger than the ordered (GaAs)(sub 1)/(AlAs)(sub 1) superlattice. It is believed that the degree of disorder significantly affects electronic and optical properties of GaAs/AlAs random superlattices.

Wang, E. G.↗
NASA NTRS1972

Surface truth measurements of optical properties of the waters in the northern Gulf of California

Gemini and Apollo flight photographs of the southwestern United States and northwestern Mexico, and especially of the Colorado River delta and the northwestern Gulf of California, are considered. The clearly discernible water coloration in the imagery led to the suggestion that remote sensing techniques may be usefully applied in such areas to determine bathymetric information. Measurements of the optical properties of the water in this region obtained in March 1971 showed that generally low transmissivities prevailed and at no station did the beam transmittance for the total water column exceed 2.5 x 10 to the -8th power. It was concluded that any correlation between water depth and spectral radiance at the surface must result from secondarily related phenomena.

Austin, R. W.↗
NASA NTRS2003

Optical Properties of Thin Film Molecular Mixtures

Thin films composed of molecular mixtures of metal and dielectric are being considered for use as solar selective coatings for a variety of space power applications. By controlling the degree of molecular mixing, the solar selective coatings can be tailored to have the combined properties of high solar absorptance, , and low infrared emittance, . On orbit, these combined properties would simultaneously maximize the amount of solar energy captured by the coating and minimize the amount of thermal energy radiated. Mini-satellites equipped with solar collectors coated with these cermet coatings may utilize the captured heat energy to power a heat engine to generate electricity, or to power a thermal bus that directs heat to remote regions of the spacecraft. Early work in this area identified the theoretical boundary conditions needed to operate a Carnot cycle in space, including the need for a solar concentrator, a solar selective coating at the heat inlet of the engine, and a radiator.1 A solar concentrator that can concentrate sunlight by a factor of 100 is ideal. At lower values, the temperature of the solar absorbing surface becomes too low for efficient heat engine operation, and at higher values, cavity type heat receivers become attractive. In designing the solar selective coating, the wavelength region yielding high solar absorptance must be separated from the wavelength region yielding low infrared emittance by establishing a sharp transition in optical properties. In particular, a sharp transition in reflectance is desired in the infrared to achieve the desired optical performance. For a heat engine operating at 450 C, a sharp transition at 1.8 micrometers is desired.2 The radiator completes the heat flow through the Carnot cycle.

Jaworske, Donald A.↗
NASA NTRS1973

Optical Properties of atmospheric dust from twilight observations

Three methods of approximation are described and used to separate the primary twilight brightness from the observed brightness. Photoelectric observations obtained are combined with observations from a balloon and from the observatory to derive the atmospheric scattering phase functions of 0.37 micron and 0.58 micron as a function of height. Comparison of these data with data for a Rayleigh atmosphere provide information on the optical properties of dust in the upper atmosphere.

Divari, N. B.↗
NASA NTRS2007

Optical Properties of High Area-to-Mass Objects at GEO

There exists at GEO a significant population of faint debris (R > 15th magnitude) with high area-to-mass ratios (AMR) (1 to 30 sq m/kg). Their orbital elements (particularly eccentricity and inclination) are observed to change on the time-scale of a week. The consensus is that these objects may be fragments of multi-layer insulation (MLI) blankets. Their orbits are primarily perturbed by solar radiation pressure. In this paper we will report preliminary results from an international collaboration to investigate the unresolved optical properties of these objects. This population was originally discovered by the ESA Space Debris Telescope, and the bulk of the objects to be described here are based on discoveries made with this telescope. Additional objects were supplied by both Russia and the US Air Force. Follow-up optical observations were obtained for a sample of a dozen objects by MODEST (the Michigan Orbital DEbris Survey Telescope) located at Cerro Tololo Inter-American Observatory in Chile. Sequences of calibrated observations in filters B, V, Broad R, and I were obtained under photometric conditions. Multi-color photometric observations in B, V, R, and I band of the same objects were also acquired at the Zimmerwald 1-meter telescope, located near Bern, Switzerland. Light curves of selected high AMR objects will be shown with a temporal resolution of a few seconds and typically span about 10 minutes. Photometric observations of these objects were acquired at the Crimean Astrophysical Observatory (CrAO). This data set includes light curves of objects having high variability of brightness and observed with 2.6 m and 0.64 m class instruments. We will present an analysis of the observed magnitudes and colors, and their correlations (or lack of correlation) with orbital elements, and with predicted values for MLI fragments. This represents the first such collaborative observational program on faint debris at GEO.

Seitzer, Patrick↗
NASA NTRS1993

Liquidus temperature and optical properties measurement by containerless techniques

Reactive alloy liquidus temperatures measured by conventional, contained techniques are often in error due to reactions with containers and gaseous impurities. This paper describes a new liquidus temperature measurement technique that avoids these problems by employing containerless processing. This technique relies on precise and accurate noncontact temperature measurements (NCTM), which are made possible by spectral emissivity values. The spectral emissivities, epsilon(sub lambda), are measured along with the optical properties (real, n, and imaginary, k, components of the index of refraction) using polarimetric techniques on electromagnetically levitated specimens. Results from work done at Vanderbilt University and Intersonics on the Ti-Al system are presented to demonstrate the above techniques.

Anderson, Collin D.↗
NASA NTRS2010

Optical Property Evaluation of Next Generation Thermal Control Coatings

Next generation white thermal control coatings were developed via the Small Business Innovative Research program utilizing lithium silicate chemistry as a binder. Doping of the binder with additives yielded a powder that was plasma spray capable and that could be applied to light weight polymers and carbon-carbon composite surfaces. The plasma sprayed coating had acceptable beginning-of-life and end-of-live optical properties, as indicated by a successful 1.5 year exposure to the space environment in low Earth orbit. Recent studies also showed the coating to be durable to simulated space environments consisting of 1 keV and 10 keV electrons, 4.5 MeV electrons, and thermal cycling. Large scale deposition was demonstrated on a polymer matrix composite radiator panel, leading to the selection of the coating for use on the Gravity Recovery And Interior Laboratory (GRAIL) mission.

Jaworske, Donald A.↗