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All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

Evaluating the Information Content of Newly Retrieved SAGEII NO2 Measurements in the Lower Stratosphere

The objective of this research project is: to calculate ozone trends in the stratosphere from Dobson Umkehr measurements, to determine the vertical profile of trends at Arosa by using a sophisticated statistical model (MARCH) to separate solar, aerosol, and QBO effects on Dobson Umkehr measurements, and to compare Umkehr trends with SBUV and SAGE I/II trends in the stratosphere.

Newchurch, Michael J.↗
NASA NTRS2003

Distributions of Trace Gases and Aerosols during the Dry Biomass Burning Season in Southern Africa

Vertical profiles in the lower troposphere of temperature, relative humidity, sulfur dioxide (SO2), ozone (O3), condensation nuclei (CN), and carbon monoxide (CO), and horizontal distributions of twenty gaseous and particulate species, are presented for five regions of southern Africa during the dry biomass burning season of 2000. The regions are the semiarid savannas of northeast South Africa and northern Botswana, the savanna-forest mosaic of coastal Mozambique, the humid savanna of southern Zambia, and the desert of western Namibia. The highest average concentrations of carbon dioxide (CO2), CO, methane (CH4), O3, black particulate carbon, and total particulate carbon were in the Botswana and Zambia sectors (388 and 392 ppmv, 369 and 453 ppbv, 1753 and 1758 ppbv, 79 and 88 ppbv, 2.6 and 5.5 micrograms /cubic meter and 13.2 and 14.3 micrograms/cubic meter). This was due to intense biomass burning in Zambia and surrounding regions. The South Africa sector had the highest average concentrations of SO2, sulfate particles, and CN (5.1 ppbv, 8.3 micrograms/cubic meter, and per 6400 cubic meter , respectively), which derived from biomass burning and electric generation plants and mining operations within this sector. Air quality in the Mozambique sector was similar to the neighboring South Africa sector. Over the arid Namibia sector there were polluted layers aloft, in which average SO2, O3, and CO mixing ratios (1.2 ppbv, 76 ppbv, and 3 10 ppbv, respectively) were similar to those measured over the other more polluted sectors. This was due to transport of biomass smoke from regions of widespread savanna burning in southern Angola. Average concentrations over all sectors of CO2 (386 +/- 8 ppmv), CO (261 +/- 81 ppbv), SO2 (2.5 +/- 1.6 ppbv), O3 (64 +/- 13 ppbv), black particulate carbon (2.3 +/- 1.9 microgram/cubic meter), organic particulate carbon (6.2 +/- 5.2 microgram/cubic meter), total particle mass (26.0 +/- 4.7 microgram/cubic meter), and potassium particles (0.4 +- 0.1 microgram/cubic meter) were comparable to those in polluted, urban air. Since the majority of the measurements in this study were obtained in locations well removed from industrial sources of pollution, the high average concentrations of pollutants reflect the effects of widespread biomass burning. On occasions, relatively thin (-0.5 km) layers of remarkably clean air were located at -3 km above mean sea level, sandwiched between heavily polluted air. The data presented here can be used for inputs to and validation of regional and global atmospheric chemical models.

Sinha, Parikhit↗
NASA NTRS2006

Mission Operations Insights

The mission description Polar Operational Environmental Satellites (POES): I) Collect and disseminate worldwide meteorological and environmental data: a) Provide day and night information (AVHRR): 1) cloud cover distribution and type; 2) cloud top temperature; 3) Moisture patterns and ice/snow melt. b) Provide vertical temperature and moisture profiles of atmospheres (HIRS, AMSU, MHS. c) Measure global ozone distribution and solar UV radiation (SBUV). d) Measure proton, electro, and charged particle density to provide solar storm warnings (SEM). d) Collect environmental data (DCS): 1) Stationary platforms in remote locations; 2) Free floating platforms on buoys, balloons, migratory animals. II) Provide Search and Rescue capabilities (SARR, SARP): a) Detection and relay of distress signals. b) Has saved thousands of lives around the world.

Littman, Dave↗
NASA NTRS2010

Evolution of Satellite Imagers and Sounders for Low Earth Orbit and Technology Directions at NASA

Imagers and Sounders for Low Earth Orbit (LEO) provide fundamental global daily observations of the Earth System for scientists, researchers, and operational weather agencies. The imager provides the nominal 1-2 km spatial resolution images with global coverage in multiple spectral bands for a wide range of uses including ocean color, vegetation indices, aerosol, snow and cloud properties, and sea surface temperature. The sounder provides vertical profiles of atmospheric temperature, water vapor cloud properties, and trace gases including ozone, carbon monoxide, methane and carbon dioxide. Performance capabilities of these systems has evolved with the optical and sensing technologies of the decade. Individual detectors were incorporated on some of the first imagers and sounders that evolved to linear array technology in the '80's. Signal-to-noise constraints limited these systems to either broad spectral resolution as in the case of the imager, or low spatial resolution as in the case of the sounder. Today's area 2-dimensional large format array technology enables high spatial and high spectral resolution to be incorporated into a single instrument. This places new constraints on the design of these systems and enables new capabilities for scientists to examine the complex processes governing the Earth System.

remote sensing↗
NASA NTRS2019

Mars Atmospheric Chemistry Simulations with the GEM-Mars General Circulation Model

General Circulation Models with interactive physical and chemistry processes are the state-of-the-art tools for an integrated view and understanding of the Martian atmosphere and climate system. The GEM-Mars model currently includes 16 tracers for chemical composition and applies a fully online, interactive calculation of the photo- and gas phase chemistry of carbon dioxide (CO2) and water vapor (H2O). These species largely control the chemical composition of the neutral Mars atmosphere through their photolysis products and their subsequent interactions. Water vapor undergoes a complex cycle on Mars as it is transported and interacts with ice reservoirs both at the planet's surface and at water ice clouds, which in turn provide radiative feedbacks. In the photochemical cycles involving CO2 and H2O, the abundances of 5 species have been reported by previous investigations with significant spatio-temporal coverage: CO2, H2O, CO, O3 and H2O2. This paper presents the current status of the atmospheric chemistry simulations in GEM-Mars by comparing them to a selection of these observational datasets as well as to oxygen dayglow emission from O2(a1∆g). The results are consistent with previous model-data comparisons and illustrate that the water cycle and the photochemistry are well implemented in the model. In particular, the simulation of the key reservoir species H2O2 provides a good match to the available data. Model-data biases for ozone columns and oxygen airglow are related to the simulated water vapor vertical profile, as these species have important column contributions from vertical layers at the top of the hygropause.

F Daerden↗
NASA NTRS2018

Decadal Changes in Summertime Reactive Oxidized Nitrogen and Surface Ozone over the Southeast United States

Widespread efforts to abate ozone (O3) smog have significantly reduced emissions of nitrogen oxides (NOx) over the past 2 decades in the Southeast US, a place heavily influenced by both anthropogenic and biogenic emissions. How reactive nitrogen speciation responds to the reduction in NOx emissions in this region remains to be elucidated. Here we exploit aircraft measurements from ICARTT (International Consortium for Atmospheric Research on Transport and Transformation - July-August 2004), SENEX (Southeast Nexus - June-July 2013), and SEAC4RS (Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys - August-September 2013) and long-term ground measurement networks alongside a global chemistry-climate model to examine decadal changes in summertime reactive oxidized nitrogen (RON) and ozone over the Southeast US. We show that our model can reproduce the mean vertical profiles of major RON species and the total (NO (sub y)) in both 2004 and 2013. Among the major RON species, nitric acid (HNO3) is dominant (approximately 42-45 percent), followed by NOx (31 percent), total peroxy nitrates (Sigma PNs; 14 percent), and total alkyl nitrates (Sigma ANs; 9-12 percent) on a regional scale. We find that most RON species, including NOx, Sigma PNs, and HNO3, decline proportionally with decreasing NOx emissions in this region, leading to a similar decline in NO (sub y). This linear response might be in part due to the nearly constant summertime supply of biogenic VOC (Volatile Organic Compounds) emissions in this region. Our model captures the observed relative change in RON and surface ozone from 2004 to 2013. Model sensitivity tests indicate that further reductions of NOx emissions will lead to a continued decline in surface ozone and less frequent high-ozone events.

Li, Jingyi↗
NASA NTRS2004

Note on the Effect of Horizontal Gradients for Nadir-Viewing Microwave and Infrared Sounders

Passive microwave and infrared nadir sounders such as the Advanced Microwave Sounding Unit A (AMSU-A) and the Atmospheric InfraRed Sounder (AIRS), both flying on NASA s EOS Aqua satellite, provide information about vertical temperature and humidity structure that is used in data assimilation systems for numerical weather prediction and climate applications. These instruments scan cross track so that at the satellite swath edges, the satellite zenith angles can reach approx. 60 deg. The emission path through the atmosphere as observed by the satellite is therefore slanted with respect to the satellite footprint s zenith. Although radiative transfer codes currently in use at operational centers use the appropriate satellite zenith angle to compute brightness temperature, the input atmospheric fields are those from the vertical profile above the center of the satellite footprint. If horizontal gradients are present in the atmospheric fields, the use of a vertical atmospheric profile may produce an error. This note attempts to quantify the effects of horizontal gradients on AIRS and AMSU-A channels by computing brightness temperatures with accurate slanted atmospheric profiles. We use slanted temperature, water vapor, and ozone fields from data assimilation systems. We compare the calculated slanted and vertical brightness temperatures with AIRS and AMSU-A observations. We show that the effects of horizontal gradients on these sounders are generally small and below instrument noise. However, there are cases where the effects are greater than the instrument noise and may produce erroneous increments in an assimilation system. The majority of the affected channels have weighting functions that peak in the upper troposphere (water vapor sensitive channels) and above (temperature sensitive channels) and are unlikely t o significantly impact tropospheric numerical weather prediction. However, the errors could be significant for other applications such as stratospheric analysis. Gradients in ozone and tropospheric temperature appear to be well captured by the analyses. In contrast, gradients in upper stratospheric and mesospheric temperature as well as upper tropospheric humidity are less well captured. This is likely due in part to a lack of data to specify these fields accurately in the analyses. Advanced new sounders, like AIRS, may help to better specify these fields in the future.

Joiner, J.↗
NASA NTRS2002

Sensitivity Studies for Assimilated Ozone Profiles

An ozone data assimilation system at the NASA/Goddard Data Assimilation Office (DAO) produces three-dimensional global ozone fields. They are obtained by assimilating ozone retrieved from the Solar Backscatter UltraViolet/2 (SBUV/2) instrument and the Earth Probe Total Ozone Mapping Spectrometer (EP TOMS) measurements into an off-line parameterized chemistry and transport model. In this talk we focus on the quality of lower stratospheric assimilated ozone profiles. Ozone in the lower stratosphere plays a key role in the forcing of climate. A biased ozone field in this region will adversely impact calculations of the stratosphere-troposphere exchange and, when used as a first guess in retrievals, the values determined from satellite observations. The SBUV/2 ozone data have a coarse vertical resolution with increased uncertainty below the ozone maximum, and TOMS provides only total ozone columns. Thus, the assimilated ozone profiles in the lower stratosphere are only weakly constrained by the incoming SBUV and TOMS data. Consequently, the assimilated ozone distribution should be sensitive to changes in inputs to the statistical analysis scheme. We investigate the sensitivity of assimilated ozone profiles to changes in a variety of system inputs: TOMS and SBUV/2 data selection, forecast and observations error covariance models, inclusion or omission of a parameterized chemistry model, and different versions of DAO assimilated wind fields used to drive the transport model. Comparisons of assimilated ozone fields with independent observations, primarily ozone sondes, are used to determine the impact of each of these changes.

Stajner, Ivanka↗
NASA NTRS1982

Forward scattering and backscattering of solar radiation by the stratospheric limb after Mount St. Helens eruption

Stratospheric limb radiance profiles versus altitude of closest approach of the line of sight to the Earth's surface have been measured before and after the Mount St. Helens eruptions by means of photographs taken from a Sun-oriented balloon gondola floating above 35 km altitude over France. Preliminary data were reported for flights in October 1979 and in May and June 1980. The radiance integrated along the line of sight as in-situ radiance (R) can be derived taking into account absorption by ozone and air. The onion peeling inversion method was used to derive the vertical radiance (R) profiles respectively. The values of R were determined in the solar azimuth. The solar elevation angles are chosen larger for the backscattering observation than for the forward scattering observation to deal with as similar illumination conditions as possible despite the Earth's sphericity.

Ackerman, M.↗
NASA NTRS2004

The Atmospheric Infrared Sounder- An Overview

The Atmospheric Infrared Sounder (AIRS) was launched in May 2002. Along with two companion microwave sensors, it forms the AIRS Sounding Suite. This system is the most advanced atmospheric sounding system to date, with measurement accuracies far surpassing those available on current weather satellites. The data products are calibrated radiances from all three sensors and a number of derived geophysical parameters, including vertical temperature and humidity profiles, surface temperature, cloud fraction, cIoud top pressure, and profiles of ozone. These products are generated under cloudy as well as clear conditions. An ongoing calibration validation effort has confirmed that the system is very accurate and stable, and many of the geophysical parameters have been validated. AIRS is in some cases more accurate than any other source and can therefore be difficult to validate, but this offers interesting new research opportunities. The applications for the AIRS products range from numerical weather prediction to atmospheric research - where the AIRS water vapor products near the surface and in the mid to upper troposphere will make it possible to characterize and model phenomena that are key for short-term atmospheric processes, such as weather patterns, to long-term processes, such as interannual cycles (e.g., El Nino) and climate change.

microwave↗
NASA NTRS2012

Standardization of the Definitions of Vertical Resolution and Uncertainty in the NDACC-archived Ozone and Temperature Lidar Measurements

The international Network for the Detection of Atmospheric Composition Change (NDACC) is a global network of high-quality, remote-sensing research stations for observing and understanding the physical and chemical state of the Earth atmosphere. As part of NDACC, over 20 ground-based lidar instruments are dedicated to the long-term monitoring of atmospheric composition and to the validation of space-borne measurements of the atmosphere from environmental satellites such as Aura and ENVISAT. One caveat of large networks such as NDACC is the difficulty to archive measurement and analysis information consistently from one research group (or instrument) to another [1][2][3]. Yet the need for consistent definitions has strengthened as datasets of various origin (e.g., satellite and ground-based) are increasingly used for intercomparisons, validation, and ingested together in global assimilation systems.In the framework of the 2010 Call for Proposals by the International Space Science Institute (ISSI) located in Bern, Switzerland, a Team of lidar experts was created to address existing issues in three critical aspects of the NDACC lidar ozone and temperature data retrievals: signal filtering and the vertical filtering of the retrieved profiles, the quantification and propagation of the uncertainties, and the consistent definition and reporting of filtering and uncertainties in the NDACC- archived products. Additional experts from the satellite and global data standards communities complement the team to help address issues specific to the latter aspect.

Detection of Atmospheric Composition Change (NDACC↗
NASA NTRS2016

Physical Processes Controlling the Distribution of Relative Humidity in the Tropical Tropopause Layer over the Pacific

The distribution of relative humidity with respect to ice (RHI) in the Boreal wintertime Tropical Tropopause Layer (TTL - about 14-19 km) over the Pacific is examined with the extensive dataset of measurements from the NASA Airborne Tropical TRopopause EXperiment (ATTREX). Multiple deployments of the Global Hawk during ATTREX provided hundreds of vertical profiles spanning the Pacific with accurate measurements of temperature, pressure, water vapor concentration, ozone concentration, and cloud properties. We also compare the measured RHI distributions with results from a transport and microphysical model driven by meteorological analysis fields. Notable features in the distribution of RHI versus temperature and longitude include (1) the common occurrence of RHI values near ice saturation over the western Pacific in the lower TTL (temperatures greater than 200 K) and in airmasses with low ozone concentrations indicating recent detrainment from deep convection; (2) low RHI values in the lower TTL over the eastern Pacific where deep convection is infrequent; (3) RHI values following a constant H2O mixing ratio in the upper TTL (temperatures below about 195 degrees Kelvin), particularly for samples with ozone mixing ratios greater than about 50-100 parts-per-billion-volume indicating mixtures of tropospheric and stratospheric air, and (4) RHI values typically near ice saturation in the coldest airmasses sampled (temperatures less than about 190 degrees Kelvin). We find that the typically saturated air in the lower TTL over the western Pacific is largely driven by the frequent occurrence of deep convection in this region. The nearly-constant water vapor mixing ratios in the upper TTL result from the combination of slow ascent (resulting in long residence times) and wave-driven temperature variability on a range of time scales (resulting in most air parcels having experienced low temperature and dehydration).

ozone↗
NASA NTRS1999

An Evaluation of the Quality of Halogen Occultation Experiment Ozone Profiles in the Lower Stratosphere

The archived ozone profiles from the Halogen Occultation Experiment (HALOE) have already been corrected for the effects of the spectrally varying, interfering absorption due to aerosols composed of aqueous sulfuric acid, and agreement with correlative measurements in the stratosphere is generally excellent. However, comparisons of sets of coincident HALOE and ozonesonde profiles indicate occasional large differences at the lowest levels of the stratosphere. Most of those instances occur at altitudes just below a well-defined minimum in the 5.26 microns channel aerosol extinction profile, whose wavelength dependence is not represented by a sulfuric acid aerosol model. Further, when the aerosol extinction exceeds about 10(exp 3)/ km, the aerosol correction to the ozone channel transmittances is both large and uncertain. After screening out the HALOE ozone profile segments whose corresponding aerosol/cirrus corrections are likely uncertain and after averaging lie ozonesonde profiles into 2.5 km thick layers, we find that the HALOE ozone areas, on average, to within 10% of their coincident ozonesonde measurements down to 100 hPa at tropical/subtropical latitudes and to 200 hPa at extratropical latitudes. A tightening of the coincidence criteria for the comparisons does not improve the mean differences for the sets nearly as much. Part of the variance of the paired differences was also accounted for when the ozonesonde profile values were integrated into those 2.5 km layers, prior to taking differences. This improvement is due mainly to the vertical averaging of the local, higher-resolution ozonesonde data, matching the lower resolution for HALOE ozone in the lower stratosphere. It is concluded that HALOE is providing accurate ozone profiles throughout the lower stratosphere, when its correction for interfering aerosols has been well characterized and when cirrus layers are not indicated.

Bhatt, Praful P.↗
NASA NTRS1978

Seasonal variation of the vertical distribution of stratospheric ozone as observed with the Umkehr and BUV methods

Month-to-month variations evidenced by ozone profiles inferred from the classical Umkehr observations and from the back-scattered ultraviolet (BUV) satellite observations made from the Nimbus 4 satellite are examined. Upper stratospheric ozone profiles derived from BUV and Umkehr data display similar seasonal variations of about the same phase and magnitude for the 38 km to 50 km region. Between 28 km and 38 km, the seasonal variations are less marked, but the same rough picture emerges for both data sets. If both data sets indicate an increasing (or decreasing) trend over a period of years, it is not possible to conclude that a trend exists unless separate means exists for monitoring stratospheric dust. Because of the stratosphere well above the Junge layer seems less likely to be affected by volcanic debris, BUV data should be superior to Umkehr data for monitoring trends in the 38 km to 50 km range, provided that the calibration problems of flying such a monitoring instrument in space can be overcome.

Mateer, C. L.↗
NASA NTRS1981

Satellite profile measurements of stratospheric ozone

A description is presented of preliminary results obtained in connection with the Stratospheric Aerosol and Gas Experiment (SAGE). SAGE, which uses a limb scanning solar radiometer, is an experiment aboard the Applications Explorer Mission 2 spacecraft which was launched on February 18, 1979. The instrument utilizes the technique of solar occultation to measure limb-path atmospheric extinction profiles which are inverted to yield vertical profiles of various atmospheric constituents in the latitude range from 79 deg South to 79 deg North. The ozone spectral channel is centered at 0.60 micrometers in the middle of the Chappuis absorption band. The general characteristics of the ozone profile measurements are shown in a graph. Each profile represents a day's average of approximately 15 measurements at the latitude band indicated. The SAGE ozone measurements are generating a highly detailed picture of the stratospheric ozone distribution.

Mccormick, M. P.↗
NASA NTRS1984

Satellite and correlative measurements of stratospheric ozone - Comparison of measurements made by SAGE, ECC balloons, chemiluminescent, and optical rocketsondes

The validity of ozone-profile data from the satellite sensor SAGE was tested in a series of correlative experiments conducted at five fixed sites between 6 deg S and 65 deg N during 1979-1980. The intercomparisons included data taken with electrochemical ozone (ECC) balloonsondes and chemiluminescent and optical rocketsondes. The average mean difference for 17 separate comparisons between the SAGE and ECC balloonsonde observations over the altitudes 18-28 km was 9.3 percent with a standard deviation of 2.8 percent. Excluding comparisons separated by greater than 500 km reduces the average mean difference to 8.9 percent and the standard deviation to 2.1 percent. The average mean difference between SAGE and three optical rocketsonde observations over the altitudes 25-50 km was 11 percent, and between SAGE and two chemiluminescent rocketsondes over the altitudes 20-60 km it was 13.5 percent. Considering the differences in vertical resolution, experimental errors, and ozone time and space gradients, the agreement between SAGE-derived ozone profiles and these correlative measurements is considered very good. In addition, isopleths of ozone mixing ratio versus latitude and altitude are in good agreement with previously published results.

Mccormick, M. P.↗
DOE OSTI2020

Comparison of aircraft measurements during GoAmazon2014/5 and ACRIDICON-CHUVA

The indirect effect of atmospheric aerosol particles on the Earth's radiation balance remains one of the most uncertain components affecting climate change throughout the industrial period. The large uncertainty is partly due to the incomplete understanding of aerosol–cloud interactions. One objective of the GoAmazon2014/5 and the ACRIDICON (Aerosol, Cloud, Precipitation, and Radiation Interactions and Dynamics of Convective Cloud Systems)-CHUVA (Cloud Processes of the Main Precipitation Systems in Brazil) projects was to understand the influence of emissions from the tropical megacity of Manaus (Brazil) on the surrounding atmospheric environment of the rainforest and to investigate its role in the life cycle of convective clouds. During one of the intensive observation periods (IOPs) in the dry season from 1 September to 10 October 2014, comprehensive measurements of trace gases and aerosol properties were carried out at several ground sites. In a coordinated way, the advanced suites of sophisticated in situ instruments were deployed aboard both the US Department of Energy Gulfstream-1 (G1) aircraft and the German High Altitude and Long-Range Research Aircraft (HALO) during three coordinated flights on 9 and 21 September and 1 October. Here, we report on the comparison of measurements collected by the two aircraft during these three flights. Such comparisons are challenging but essential for assessing the data quality from the individual platforms and quantifying their uncertainty sources. Similar instruments mounted on the G1 and HALO collected vertical profile measurements of aerosol particle number concentrations and size distribution, cloud condensation nuclei concentrations, ozone and carbon monoxide mixing ratios, cloud droplet size distributions, and downward solar irradiance. We find that the above measurements from the two aircraft agreed within the measurement uncertainties. The relative fraction of the aerosol chemical composition measured by instruments on HALO agreed with the corresponding G1 data, although the total mass loadings only have a good agreement at high altitudes. Furthermore, possible causes of the discrepancies between measurements on the G1 and HALO are examined in this paper. Based on these results, criteria for meaningful aircraft measurement comparisons are discussed.

47 OTHER INSTRUMENTATION↗
NASA NTRS1978

The effect of increased carbon dioxide concentrations on stratospheric ozone

Consideration is given to the influence on ozone of an increased carbon dioxide concentration, for which a measurable growth has been observed in the recent past. Increased carbon dioxide can indirectly affect ozone by perturbing atmospheric temperatures, which will alter ozone production, whose rate displays a fairly strong temperature dependence. This paper presents one-dimensional model results for the steady state ozone behavior when the CO2 concentration is twice its ambient level; the results account for coupling between chemistry and temperature. When the CO2 level doubled, the total ozone burden increased in relation to the ambient burden by 1.2-2.5%, depending on the vertical diffusion coefficient used. Above 30 km, ozone concentrations were larger than the ambient values, a maximum increase of 16% being reached at 43 km. In this region the relative variations were insensitive to the choice of diffusion coefficient. Below 30 km, ozone concentrations were smaller than the unperturbed values and were sensitive to the vertical diffusion profile in this region (10-30 km).

Boughner, R. E.↗