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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

A functional modeling approach for quality assurance in metal additive manufacturing

Purpose: Due to the complexity of and variations in additive manufacturing (AM) processes, there is a level of uncertainty that creates critical issues in quality assurance (QA), which must be addressed by time-consuming and cost-intensive tasks. This deteriorates the process repeatability, reliability and part reproducibility. So far, many AM efforts have been performed in an isolated and scattered way over several decades. Here, a systematically integrated holistic view is proposed to achieve QA for AM. Design/methodology/approach: A systematically integrated view is presented to ensure the predefined part properties before/during/after the AM process. It consists of four stages, namely, QA plan, prospective validation, concurrent validation and retrospective validation. As a foundation for QA planning, a functional workflow and the required information flows are proposed by using functional design models: Icam DEFinition for Function Modeling. Findings: The functional design model of the QA plan provides the systematically integrated view that can be the basis for inspection of AM processes for the repeatability and qualification of AM parts for reproducibility. Research limitations/implications: A powder bed fusion process was used to validate the feasibility of this QA plan. Feasibility was demonstrated under many assumptions; real validation is not included in this study. Social implications: This study provides an innovative and transformative methodology that can lead to greater productivity and improved quality of AM parts across industries. Furthermore, the QA guidelines and functional design models provide the foundation for the development of a QA architecture and management system. Originality/value: This systematically integrated view and the corresponding QA plan can pose fundamental questions to the AM community and initiate new research efforts in the in-situ digital inspection of AM processes and parts.

36 MATERIALS SCIENCE↗

Hourly Carbon Fluxes Estimation Using the GOES Advanced Baseline Imager (ABI) Data Over the Conterminous USA

Tremendous efforts by Fluxnet scientists over the past few decades have made thousands of site-years of carbon flux observations available for advancing our understanding of carbon cycling in terrestrial ecosystems. One of key Fluxnet measurements is net ecosystem exchange (NEE) as it is directly related to carbon budget of terrestrial ecosystems. However, carbon flux estimation studies using satellite remote sensing have focused mainly on daily Gross Primary Production (GPP). The satellite based carbon flux estimation used the polar orbiting satellite sensors (e.g., Moderate Resolution Imaging Spectroradiometer (MODIS)), which allow us to observe target regions only once during the day. Because daily NEE is close to zero value, the carbon flux models using the polar orbiting satellite data have not been well used for NEE estimation. The new generation of geostationary satellite sensors (e.g., GOES Advanced Baesline Imager (ABI) and Himawari Advanced Himawari Imager (AHI)) provide frequent observations, often less than every 10 minutes. Here, we use GOES ABI data to estimate hourly NEE over the conterminous USA. We used the Terrestrial Observation Prediction System (TOPS) model for estimating hourly NEE. TOPS is a diagnostic ecosystem process model that simulates the fluxes of carbon and water through vegetation in response to climate variability. For the climate input, we developed hourly climate data using the same algorithm with NASA Earth Exchange Gridded Daily Meteorology (NEX-GDM) datasets based on machine learning techniques. The hourly climate data includes precipitation, maximum temperature, minimum temperature, dew point temperature, and, in particular, solar radiation that is directly derived from the Geostationary observations. The spatial patterns of ecosystem parameters used in TOPS are optimized using satellite Solar Induced Fluorescence (SIF) data. The high frequency GPP estimations from geostationary satellite sensors make it comparable to the instantaneous SIF data than daily GPP. We also used Fluxnet data for optimization of model parameters and the validation of the output. The derived data addresses the diurnal dynamics of carbon cycling at large scales and should help in reducing the uncertainties in carbon budget studies.

Geostationary satellite↗

Northeast US Ecological Forecasting: Modeling Invasive Plant Habitat Suitability to Support Management Efforts in the American Northeast

Invasive plant species threaten environmental and economic interests when they spread into new areas, outcompete native species, and disrupt ecosystem services. If the spread is not controlled early, species can become well-established and increasingly difficult to manage. The National Park Service (NPS) Invasive Plant Management Teams (IPMTs) strive for an “early detection, rapid response” approach to reducing invasive species spread. Management teams can better prioritize their work with the help of species distribution models (SDMs), which map habitat suitability by combining species occurrences with environmental predictor variables. Scarce invaded range data for newly arrived invasive species presents a particular challenge for producing accurate models. To improve future modeling efforts, this project compared SDM methods using different spatial scales to model two plant species invasive to the Northeast US: the well-established Japanese stiltgrass (Microstegium vimineum) and newer invasive species wavyleaf basketgrass (Oplismenus undulatifolius). The team used NASA Earth observations and climate datasets to model occurrence data and predictor layers at a US-specific extent (90m2 spatial resolution) and global extent (1 km2 spatial resolution). Landsat 5 Thematic Mapper (TM), Landsat 7 Enhanced Thematic Mapper Plus (ETM+), and Landsat 8 Operational Land Imager (OLI) provided data for US Normalized Difference Moisture Indices (NDMI), while global NDMI and topographic predictor layers were derived from Shuttle Radar Topography Mission (SRTM) and Terra Moderate Resolution Imaging Spectroradiometer (MODIS). The resulting models indicated important predictor variables for each species and explored the benefits and tradeoffs of using global data to model habitat suitability for new-arrival invasive species.

Rebecca Ohman↗

Assessing the Effects of Temperature and Oxygen Vacancy on Band Gap Renormalization in LaCrO 3-δ : First-Principles and Experimental Corroboration [plus supplemental information]

Understanding the temperature dependence of functional properties in high-temperature gas sensors is vital for applications in combustion environments. Temperature effect on the electronic structure due to electron-phonon coupling is a key property of interest as this influences other responses of sensors. In this work, we assess the impact of temperature on band gap renormalization of pristine and oxygen-vacant LaCrO 3–δ perovskite employing Allen–Heine–Cardona theory with first-principles simulations and corroborate with experimental observation. Antiferromagnetic cubic LaCrO 3 shows a direct ground-state band gap of 2.62 eV that is reduced by over 1 eV due to the presence of oxygen vacancies, which can form endothermically. We find excellent agreement in temperature-dependent band gap shift in LaCrO 3 between theory and an in-house experiment, proving that the theory can adequately predict renormalization on the band gap in a magnetic system. Band gaps in cubic LaCrO 3–δ are found to monotonically narrow by 1.13 eV in pristine and by around 0.62 eV in oxygen-vacant structures as temperature increases from 0 to 1500 K. The predicted band gap variations are rationalized using an analytical model. Furthermore, the experimental zero-temperature band gaps are extracted from the model fits that can provide useful insights on the simulated band gaps.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dynamical evolution of topology of large-scale structure

The nonlinear effects of statistical biasing and gravitational evolution on the genus are studied. The biased galaxy subset is picked for the first time by actually identifying galaxy-sized peaks above a fixed threshold in the initial conditions, and their subsequent evolution is followed. It is found that in the standard cold dark matter (CDM) model the statistical biasing in the locations of galaxies produces asymmetry in the genus curve and coupling with gravitational evolution gives rise to a shift in the genus curve to the left in moderately nonlinear regimes. Gravitational evolution alone reduces the amplitude of the genus curve due to strong phase correlations in the density field and also produces asymmetry in the curve. Results on the genus of the mass density field for both CDM and hot dark matter models are consistent with previous work by Melott, Weinberg, and Gott (1987).

Park, Changbom↗

Experiment and simulation for CSI: What are the missing links?

Viewgraphs on experiment and simulation for control structure interaction (CSI) are presented. Topics covered include: control structure interaction; typical control/structure interaction system; CSI problem classification; actuator/sensor models; modeling uncertainty; noise models; real-time computations; and discrete versus continuous.

Belvin, W. Keith↗

Lattice Boltzmann simulation of the dissolution of slag in alkaline solution using real-shape particles

Highlights: • A dissolution numerical model was proposed to capture the real dissolution kinetics of slag in alkaline solution. • The log forward dissolution rate of Si was described as a function of NBO/T and solution pH. • A threshold solid volume fraction of 0.688 was found for a voxel in 3D, 63.8% larger than that for a pixel in 2D. • The proposed dissolution numerical model provides a reliable alternative to study the dissolution kinetics of slag. A dissolution numerical model was proposed in this study to capture the real dissolution kinetics of slag in alkaline solution. It consists of three modules, i.e. (i) simulation of the initial particle parking structure of slag in alkaline solution using real-shape particles of slag, (ii) simulation of the chemical reactions between slag and solution based on the transition state theory, and (iii) simulation of the physical transport of aqueous ions using the lattice Boltzmann method. This dissolution numerical model was verified using experimental results, showing reasonable accuracy. After verification, the dissolution numerical model was implemented to study the influences of temperature and particle shape using a proper recipe of slag in alkaline solution. This recipe was designed to avoid solid phase precipitation or gel formation via thermodynamic analysis. The simulation results showed faster dissolution kinetics of slag when using higher temperatures and more irregular particle shapes.

36 MATERIALS SCIENCE↗

Comparing Proxy and Model Estimates of Hydroclimate Variability and Change over the Common Era

Water availability is fundamental to societies and ecosystems, but our understanding of variations in hydroclimate (including extreme events, flooding, and decadal periods of drought) is limited because of a paucity of modern instrumental observations that are distributed unevenly across the globe and only span parts of the 20th and 21st centuries. Such data coverage is insufficient for characterizing hydroclimate and its associated dynamics because of its multidecadal to centennial variability and highly regionalized spatial signature. High-resolution (seasonal to decadal) hydroclimatic proxies that span all or parts of the Common Era (CE) and paleoclimate simulations from climate models are therefore important tools for augmenting our understanding of hydroclimate variability. In particular, the comparison of the two sources of information is critical for addressing the uncertainties and limitations of both while enriching each of their interpretations. We review the principal proxy data available for hydroclimatic reconstructions over the CE and highlight the contemporary understanding of how these proxies are interpreted as hydroclimate indicators. We also review the available last-millennium simulations from fully coupled climate models and discuss several outstanding challenges associated with simulating hydroclimate variability and change over the CE. A specific review of simulated hydroclimatic changes forced by volcanic events is provided, as is a discussion of expected improvements in estimated radiative forcings, models, and their implementation in the future. Our review of hydroclimatic proxies and last-millennium model simulations is used as the basis for articulating a variety of considerations and best practices for how to perform proxy-model comparisons of CE hydroclimate. This discussion provides a framework for how best to evaluate hydroclimate variability and its associated dynamics using these comparisons and how they can better inform interpretations of both proxy data and model simulations.We subsequently explore means of using proxy-model comparisons to better constrain and characterize future hydroclimate risks. This is explored specifically in the context of several examples that demonstrate how proxy-model comparisons can be used to quantitatively constrain future hydroclimatic risks as estimated from climate model projections.

Common Era↗

Critically assessing sodium-ion technology roadmaps and scenarios for techno-economic competitiveness against lithium-ion batteries

Sodium-ion batteries have garnered notable attention as a potentially low-cost alternative to lithium-ion batteries, which have experienced supply shortages and price volatility for key minerals. Here we assess their techno-economic competitiveness against incumbent lithium-ion batteries using a modelling framework incorporating componential learning curves constrained by minerals prices and engineering design floors. We compare projected sodium-ion and lithium-ion price trends across over 6,000 scenarios while varying Na-ion technology development roadmaps, supply chain scenarios, market penetration and learning rates. Assuming that substantial progress can be made along technology roadmaps via targeted research and development, we identify several sodium-ion pathways that might reach cost-competitiveness with low-cost lithium-ion variants in the 2030s. In addition, we show that timelines are highly sensitive to movements in critical minerals supply chains—namely that of lithium, graphite and nickel. Our modelled outcomes suggest that being price advantageous against low-cost lithium-ion variants in the near term is challenging and increasing sodium-ion energy densities to decrease materials intensity is among the most impactful ways to improve competitiveness.

25 ENERGY STORAGE↗

Distinguishing Electron and Hole Dynamics in Functionalized CdSe/CdS Core/Shell Quantum Dots Using Complementary Ultrafast Spectroscopies and Kinetic Modeling

The evolution of excitation energy and photogenerated charges in semiconductor quantum dots (QDs) functionalized with molecular acceptors can be probed on ultrafast time scales using techniques such as transient absorption (TA) spectroscopy. However, historical interpretations that the 1S(e)-1S 3/2 (h) transition in Cd-chalcogenide QDs is fully attributable to electrons may be misleading, and multiexponential models used to fit TA kinetics do not correspond directly to specific photophysical processes. Here, we present visible-wavelength and mid-IR TA and time-resolved photoluminescence measurements to inform a comprehensive kinetic model of the photoexcited CdSe/CdS core/shell QDs functionalized with passivating oleic acid (OA), hole-accepting ferrocene, or electron-accepting naphthalene bisimide (NBI). We show that ~30% of the 1S signal and 72% of the IR signal can originate from holes in well-passivated core/shell QDs. We also demonstrate evidence of electron trapping in OA-capped core/shell QDs, with additional electron transfer and hole trapping in the QDs functionalized with NBI. Electron (hole) trapping and detrapping occur in 450 ± 100 ps (430 ± 70 ps) and 340 ± 100 ps (1.1 ± 0.4 ns) respectively, while the time constant for electron transfer to NBI is ~1.8 ns. The comprehensive picture of photophysical processes provided by the complementary ultrafast techniques and kinetic modeling can accelerate both the fundamental science and application development of nanostructured and molecular systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Recent Advanced Reactor Multiphysics Model Highlights in the Virtual Test Bed (VTB)

The Virtual Test Bed (VTB) host over 30 distinct simulations that showcase state-of-the art capabilities across the national lab complex. An update on the status of models on the VTB is summarized here, along with a more detailed overview of select recent new capabilities to showcase. All of the major advanced reactor types are represented in the VTB. The first example consists of a multiphysics simulation to track the transport of species in Molten Salt Reactors using depletion, advection, and thermochemical calculations. The second consists of a coupled neutronic and thermal hydraulic simulation to validate a gas cooled reactor. The third consist of pebble-bed equilibrium model for a fluoride high-temperature reactor. The fourth is a high-fidelity neutronic and thermal hydraulic model of a liquid metal reactor assembly. And lastly the fifth consists of transient multiphysics simulations of heat pipe microreactors.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

2010-2012 California Household Travel Survey

The 2010-2012 California Household Travel Survey (CHTS) was administered by the California Department of Transportation, which collected demographic and travel behavior characteristics for residents across the entire state. At the time, it was the largest such regional or statewide survey ever conducted in the United States. Detailed travel behavior information was obtained from more than 42,500 households via multiple data-collection methods, including computer-assisted telephone interviewing, online and mail surveys, wearable (7,574 participants) and in-vehicle (2,910 vehicles) global positioning system devices, and on-board diagnostic sensors that gathered data directly from a vehicle's engine. Details of personal travel behavior were gathered within the region of residence, inter-regionally within the state, and in adjoining states and Mexico. The survey sampling plan was designed to ensure an accurate representation of the entire population of the state. The CHTS included additional features, such as vehicle-acquisition decisions, parking choices, work schedules and flexibility, use of toll lanes/priced facilities, and walk and bicycle trips, to support advanced model development.

1Hz data↗

Experimental studies of radiative base heating of a Jovian entry model

A scale model of the Jovian entry vehicle of 6.4 cm diameter is tested in an electric-arc-driven shock tube while a sphere model of 5 cm diameter is tested in a combustion-driven shock tube and an electric-arc-driven shock tunnel. The radiative heat-transfer rate and pressure on the front and the base regions are measured in the absence of ablation with sensors imbedded in the models in a stream consisting of 10% hydrogen in a bath of either neon or argon. The measured radiative heat-transfer rates and pressures are up to about 22 kW/sq cm and 12 atm, respectively, at the front stagnation point. The ratio of the base-to-stagnation-point radiative heat-transfer rates is found to be about 1/4 for the sphere at Mach 1.8, about 1/30 for the sphere at Mach 4.8, and about 1/6 for the scale model at Mach 1.7. When the effects of model geometry and Mach number are accounted for, the present experimental results agree well with the theoretical prediction of Park.

Shirai, H.↗

Process-Based Cost Estimation for Ramjet/Scramjet Engines

Process-based cost estimation plays a key role in effecting cultural change that integrates distributed science, technology and engineering teams to rapidly create innovative and affordable products. Working together, NASA Glenn Research Center and Boeing Canoga Park have developed a methodology of process-based cost estimation bridging the methodologies of high-level parametric models and detailed bottoms-up estimation. The NASA GRC/Boeing CP process-based cost model provides a probabilistic structure of layered cost drivers. High-level inputs characterize mission requirements, system performance, and relevant economic factors. Design alternatives are extracted from a standard, product-specific work breakdown structure to pre-load lower-level cost driver inputs and generate the cost-risk analysis. As product design progresses and matures the lower level more detailed cost drivers can be re-accessed and the projected variation of input values narrowed, thereby generating a progressively more accurate estimate of cost-risk. Incorporated into the process-based cost model are techniques for decision analysis, specifically, the analytic hierarchy process (AHP) and functional utility analysis. Design alternatives may then be evaluated not just on cost-risk, but also user defined performance and schedule criteria. This implementation of full-trade study support contributes significantly to the realization of the integrated development environment. The process-based cost estimation model generates development and manufacturing cost estimates. The development team plans to expand the manufacturing process base from approximately 80 manufacturing processes to over 250 processes. Operation and support cost modeling is also envisioned. Process-based estimation considers the materials, resources, and processes in establishing cost-risk and rather depending on weight as an input, actually estimates weight along with cost and schedule.

Singh, Brijendra↗

Everglades Ecological Forecasting II: Utilizing NASA Earth Observations to Enhance the Capabilities of Everglades National Park to Monitor & Predict Mangrove Extent to Aid Current Restoration Efforts

Mangroves act as a transition zone between fresh and salt water habitats by filtering and indicating salinity levels along the coast of the Florida Everglades. However, dredging and canals built in the early 1900s depleted the Everglades of much of its freshwater resources. In an attempt to assist in maintaining the health of threatened habitats, efforts have been made within Everglades National Park to rebalance the ecosystem and adhere to sustainably managing mangrove forests. The Everglades Ecological Forecasting II team utilized Google Earth Engine API and satellite imagery from Landsat 5, 7, and 8 to continuously create land-change maps over a 25 year period, and to allow park officials to continue producing maps in the future. In order to make the process replicable for project partners at Everglades National Park, the team was able to conduct a supervised classification approach to display mangrove regions in 1995, 2000, 2005, 2010 and 2015. As freshwater was depleted, mangroves encroached further inland and freshwater marshes declined. The current extent map, along with transition maps helped create forecasting models that show mangrove encroachment further inland in the year 2030 as well. This project highlights the changes to the Everglade habitats in relation to a changing climate and hydrological changes throughout the park.

Kirk, Donnie↗