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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

Study of the Aluminium Content in AGB Winds Using ALMA Indications for the Presence of Gas-Phase (Al2O3)n Clusters

Context: The condensation of inorganic dust grains in the winds of evolved stars is poorly understood. As of today, it is not yet known which molecular clusters form the first dust grains in oxygen-rich (C/O < 1) asymptotic giant branch (AGB) winds. Aluminium oxides and iron-free silicates are often put forward as promising candidates for the first dust seeds. Aims: We aim to constrain the dust formation histories in the winds of oxygen-rich AGB stars. Methods: We obtained Atacama Large Millimeter/sub-millimeter array (ALMA) observations with a spatial resolution of 120 × 150mas tracing the dust formation region of the low mass-loss rate AGB star, R Dor, and the high mass-loss rate AGB star, IK Tau. We detected emission line profiles of AlO, AlOH, and AlCl in the ALMA data and used these line profiles to derive a lower limit of atomic aluminium incorporated in molecules. This constrains the aluminium budget that can condense into grains. Results: Radiative transfer models constrain the fractional abundances of AlO, AlOH, and AlCl in IK Tau and R Dor. We show that the gas-phase aluminium chemistry is completely different in both stars with a remarkable difference in the AlO and AlOH abundance stratification. The amount of aluminium locked up in these three molecules is small, ≤1.1×10−7 w.r.t. H2, for both stars, i.e. only ≤2% of the total aluminium budget. An important result is that AlO and AlOH, which are the direct precursors of alumina (Al2O3) grains, are detected well beyond the onset of the dust condensation, which proves that the aluminium oxide condensation cycle is not fully efficient. The ALMA observations allow us to quantitatively assess the current generation of theoretical dynamical-chemical models for AGB winds. We discuss how the current proposed scenario of aluminium dust condensation for low mass-loss rate AGB stars within a few stellar radii from the star, in particular for R Dor and W Hya, poses a challenge if one wishes to explain both the dust spectral features in the spectral energy distribution (SED) in interferometric data and in the polarized light signal. In particular, the estimated grain temperature of Al2O3 is too high for the grains to retain their amorphous structure. We advocate that large gas-phase (Al2O3)n clusters (n > 34) can be the potential agents of the broad 11µm feature in the SED and in the interferometric data and we propose potential formation mechanisms for these large clusters.

stars↗
NASA NTRS2021

Optial Experiments and Model Validation of Perturbed Starshade Designs

Starshades are a leading technology to enable the direct detection and spectroscopic characterization of Earth- like exoplanets. Critical starshade technologies are currently being advanced through the S5 Project and at the Princeton starshade testbed. We report on the status of Milestone 2 of the S5 Project, optical model validation. We present results from optical experiments of starshades with intentional perturbations built into their design. These perturbations are representative of the type of perturbations possible in a flight design and serve as points of validation for dffraction models and error budgets. We show experimental results for two perturbed shapes, a mask with all petals shifted radially outward by 5 um and a mask with shallow sine waves built into two petals. We compare these data to outputs of the optical model and demonstrate better than 25% agreement. We also present images taken in crossed polarized light and use those data to constrain physical parameters of the optical edge. Bringing in previously obtained results for other perturbed shapes, we show an agreement between experiment and model of better than 25% and argue that this satisfies the Milestone 2 criteria.

Galvin, Michael↗
NASA NTRSDate not supplied

A Machine Learning Approach for the Remote Sensing Retrieval of Oil Spills from Polarimetric Measurements

The Fresnel laws of specular reflection directly connect remote sensing observations of light polarization within the sunglint region to the ocean surface refractive index. This parameter is instrumental to identify areas affected by oil, or any other floating substance capable of modifying the refractive index of pure seawater. In preparation for the NASA Plankton, Aerosol, ocean Ecosystem (PACE) mission, we are developing an advanced retrieval scheme that exploits such measurements to deliver the refractive index as an operational product. The original method was developed based on observations of the airborne Research Scanning Polarimeter. Here we present several aspects related to the extension of this technique to the PACE HARP-2 sensor (especially regarding the projected accuracy), and discuss preliminary results obtained by applying neural-network trainings to look-up tables produced with the forward radiative transfer code, with the goal of improving the computational performance. Success in the final implementation will guarantee a version of the retrieval algorithm suitable to fast-response needs and disaster management.

machine learning↗
NASA NTRS2024

PACE Technical Report Series, Volume 12: The PACE Level 1C data format

NASA's Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission will make global ocean color and atmospheric measurements to provide extended data records of ocean ecology and global biogeochemistry, along with polarimetric measurements for advanced observations of aerosols, clouds and the ocean. PACE will contain three instruments: the primary Ocean Color Instrument (OCI), and two multi-angle polarimeters (MAPs). The latter instruments are contributed under a ‘Do-No-Harm’ (to the rest of the PACE mission) principle, and the PACE Science Data Processing System (SDPS) is only required to produce Level-1b (geolocated radiances with calibration applied) data without performance requirements. However, there is a strong desire to produce data in a format that merges the disparate spatial resolutions, viewing geometry and sampling nature of the three instruments. Our terminology for this format is Level 1c (L1C). This format will be an input to Level 2 algorithms produced from standalone MAP instrument observations, or from algorithms employing multi-sensor fusion. Creating the L1C format has several components. This includes choice of projection method, the means by which multi-angle views are properly incorporated into that projection (‘aggregation’) the means to represent wavelength and light polarization state, the selection of data to be included within the L1C file, and the handling of ancillary data either required for L1C file generation or needed in that format for L2 processing.

PACE↗
NASA NTRSDate not supplied

Evaluating Crystallinity in Thermoplastic composites

Polymer matrix composites (PMCs) offer many benefits for the aerospace industry due to their potential for weight reduction when compared to metal or ceramic based materials. Most PMCs currently in flight use thermoset matrices, however, thermoplastic resins are being explored as alternatives due to their ability to be remelted, which is of particular interest due to the potential for in-situ repair and manufacturing required in space. Most thermoplastic resins are semicrystalline polymers. The properties of semicrystalline thermoplastics are largely influenced by their crystallinity, which can vary due to many factors including thermal treatments, environmental conditions, and mechanical deformation. Monitoring the crystallinity of thermoplastic composites is key to ensuring these materials reliably meet the high demands required by space exploration. This talk discusses the use of multiple techniques such as Polarized Light Optical Microscopy and Fourier-Transform Infrared Spectroscopy to characterize the crystallinity in various thermoplastic composites, including carbon fiber reinforced PMCs and novel bio-based Martian and Lunar regolith composites designed for in-situ manufacturing. This work aims to provide the fundamental data necessary to understand the effects of crystallinity on thermoplastic PMCs, which is key to advancing their use in space applications.

Thermoplastics↗
NASA NTRS2025

Lyotropic Liquid Crystalline Phase Behavior of Boron Nitride Nanotube Aqueous Dispersions

Boron nitride nanotubes (BNNTs) are gaining significant interest due to their outstanding mechanical and thermal properties, as well as their potential to serve as a model nanorod system. Processing BNNT liquid crystalline (LC) dispersions enables precise control over BNNT orientation in macroscopic assemblies, while their low absorption in the visible spectrum facilitates studying LCs at exceptionally high concentrations. Here, we investigate the behavior of BNNTs in aqueous solutions stabilized by the surfactant sodium deoxycholate (SDC), examining the effect of BNNT purity and BNNT−SDC concentrations on lyotropic LC formation. We disperse up to 15wt% BNNT in SDC solutions and use polarized light microscopy to detail the transition from an isotropic state to a biphasic regime, where isotropic and nematic domains coexist due to phase separation, to a single fully nematic phase. Cryogenic electron microscopy provides direct evidence of BNNT alignment within nematic domains. Our results show that enhanced depletion-induced attractions, driven by increased surfactant concentration, lower the threshold concentration of BNNT required to form nematic domains. In contrast, low surfactant concentrations relative to BNNT result in insufficiently coated nanotube surfaces, leading to poor dispersions and BNNT aggregation. Additionally, we fabricate well-aligned BNNT films from aqueous LC dispersions. Our findings advance the understanding of BNNT LCs, offering insight into controlling their orientation and highlighting their potential for high-performance materials.

Joe Khoury↗
NASA NTRSDate not supplied

Evaluating Crystallinity in Thermoplastic Composites for Aerospace Applications

Polymer matrix composites (PMCs) offer many benefits for the aerospace industry due to their potential for weight reduction when compared to metal or ceramic based materials. Most PMCs currently in flight use thermoset matrices, however, thermoplastic resins are being explored as alternatives due to their ability to be remelted, which is of particular interest due to the potential for in-situ repair and faster production. Most thermoplastic resins are semicrystalline polymers. The properties of semicrystalline thermoplastics are directly influenced by their crystallinity, which can vary due to many factors including thermal treatments, environmental conditions, and mechanical deformation. Within thermoplastic PMC parts, crystallinity gradients can arise due to variations in part geometry, across part thicknesses, and along bonded joints. Monitoring the crystallinity of thermoplastic composites is key to ensuring these materials meet the high demands required for aerospace. Several different analytical techniques exist that can be used to characterize the bulk crystallinity of thermoplastic materials. However, many existing methods lack the specificity required to identify the subtle variations in crystallinity that may play a significant role in the performance and durability of PMC parts. Because of this, a significant amount of work is still required to fully characterize and understand the crystallinity profiles of thermoplastic PMCs and the resulting impact to material properties. This talk discusses the use of multiple techniques such as Differential Scanning Calorimetry, Polarized Light Optical Microscopy, and Fourier-Transform Infrared Spectroscopy to characterize the crystallinity in carbon fiber/thermoplastic composites. Samples of different crystallinity profiles were manufactured using various cooling procedures. This work aims to provide the fundamental data necessary to understand the effects of crystallinity on thermoplastic PMCs, which is key to advancing their use in aerospace applications.

Thermoplastics↗
NASA NTRS1993

Optimal binary phase and amplitude correlation filters for polarization-rotating spatial light modulators

We investigate the optimal designs of binary phase and amplitude filters (BPAFs) for the key correlation metrics of peak intensity, peak-to-correlation energy, SNR, and discrimination. These filters may be implemented on binary polarization-rotating spatial light modulators. We present simulation results comparing performance to conventional binary phase-only filters (BPOFs) and illustrating trade-offs between the different performance criteria in terms of the filter design parameter. We also extend the generalization to three-level phase and amplitude filters with a nonzero region of support and demonstrate that optimal three-level BPAFs can provide clearly superior performance to optimal three-level BPOFs.

Downie, John D.↗
NASA NTRS1988

Direct emissivity measurements on liquids and corrections to multi-color pyrometers

Optical pyrometry provides a means for non-contact temperature measurements whose accuracy depends on the accuracy with which specimen emittance is known. Two methods for obtaining the required emittance data are discussed in which the emittance is determined from measurements of the wavelength or polarization dependence of light emitted by the specimen. The spectral technique, multi-color pyrometry, yields apparent values for specimen emittance and temperature from emitted intensity measurements at two or more wavelengths. Emittance corrections cannot be eliminated by increasing the number of spectral intensity measurements required by an n-color pyrometer. Even if this were possible, the accuracy of temperature measurements by n-color pyrometry decreases with n such that pyrometers that require four intensity measurements would be impractical. In contrast, emittance values and corrections for one-color pyrometers can be accurately measured by the polarized light technique. The polarized light technique involves measurement of the degree of polarization for light emitted at an angle of 45 deg to the specimen normal. The reflectivities (r) for light polarized parallel (p) and normal (n) to the plane of emission are related by r(p) = r(n) squared. This leads to a simple relation between the intensity ratio for light emitted in the two polarized states and the emittance, i.e., e(n) = 2 - I(p)/I(n). The true specimen temperature is also obtained if absolute intensities are measured. Delvelopment of the polarized light technique in combination with one-color optical pyrometry is recommended to achieve accurate non-contact temperature measurements on liquids.

Nordine, Paul C.↗
NASA NTRS1994

On the modulated light in the intermediate polar FO Aquarii/H 2215-086

The modulated light in the Intermediate Polar FO Aqr at the three periods P(sub spin) = 20.9 min, P(sub orb) = 4.85 hr and P(sub beat) = 22.5 min is studied in different spectral ranges to derive information on their nature. In this system the accretion geometry, with or without an accretion disk, is still a matter of debate (Hellier 1991; Norton et al. 1992). The different orbital behavior of phase coherence between the spin and beat pulses in the X-rays (Norton et al. 1992) and in the optical/IR regions cannot be easily accounted for by only a diskless dominated geometry where the accretion flow is switching from one pole to the other each half of the beat period. We therefore propose an accretion scenario where a non-axisymmetric disk is present. In such a non-standard accretion disk an azimuthal structure provides not only the source of variable mass transfer to the white dwarf, but also a reprocessing site which is mainly viewing the X-ray emission from the lower pole. Our spectral analysis shows that reprocessing is also occurring at the surface of the secondary star. The spin pulsation in the optical and IR continua can be explained by the so-called 'accretion curtain' model (Rosen et al. 1988) though an additional reprocessing component at the spin period cannot be excluded. In contrast to the X-rays, the beat optical/IR modulation is not intrinsic. Reprocessing at the surface of the secondary star and at the thickened part of the disk can also account for the orbital modulation in the UV, optical and IR regions.

Martino, D. DE↗
NASA NTRS1980

Visible and infrared polarization ratio spectroreflectometer

The instrument assists in determining the refractive index and absorption index, at different spectral frequencies, of a solid sample by illuminating the sample at various angles in incidence and measuring the corresponding reflected intensities at various spectral frequencies and polarization angles. The ratio of the intensity of the reflected light for parallel polarized light to that for perpendicular polarized light at two different angles of incidence can be used to determine the optical constants of the sample. The invention involves an apparatus for facilitating the utilization of a wide variety of angles of incidence. The light source and polarizing element are positioned on an outer platform; the sample is positioned on an inner platform. The two platforms rotate about a common axis and cooperate in their rotation such that the sample is rotated one degree for every two degrees of rotation of the light source. This maintains the impingement of the reflected light upon the detector for any angle of incidence without moving or adjusting the detector which allows a continuous change in the angle of incidence.

Batten, C. E.↗
NASA NTRS1976

Polarization of the reflected light of asteroid 433 Eros

Linear polarizations measured for asteroid 433 Eros at various wavelengths and at solar phase angles ranging from 9 to 53 deg are presented. The polarization results are entirely typical of main-belt S asteroids, and indicate a dusty surface with geometric albedo 0.20. The derived effective diameter at photometric maximum is 21 km. Eros is quite uniform polarimetrically; no dependence on aspect is detected, and the polarization is shown to be constant during a single rotation with a precision of one part in forty.

Zellner, B.↗
NASA NTRS2011

Gamma-Ray Pulsar Light Curves in Offset Polar Cap Geometry

Recent studies have shown that gamma-ray pulsar light curves are very sensitive to the geometry of the pulsar magnetic field. Pulsar magnetic field geometries, such as the retarded vacuum dipole and force-free magnetospheres, used to model high-energy light curves have distorted polar caps that are offset from the magnetic axis in the direction opposite to rotation. Since this effect is due to the sweepback of field lines near the light cylinder, offset polar caps are a generic property of pulsar magnetospheres and their effects should be included in gamma-ray pulsar light curve modeling. In slot gap models (having two-pole caustic geometry), the offset polar caps cause a strong azimuthal asymmetry of the particle acceleration around the magnetic axis. We have studied the effect of the offset polar caps in both retarded vacuum dipole and force-free geometry on the model high-energy pulse profile~. We find that. corn pared to the profile:-; derived from :-;ymmetric caps, the flux in the pulse peaks, which are caustics formed along the trailing magnetic field lines. increases significantly relative to the off-peak emission. formed along leading field lines. The enhanced contrast produces greatly improved slot gap model fits to Fermi pulsar light curves like Vela, which show very little off-peak emIssIon.

Harding, Alice K.↗
NASA NTRS2010

Chiral Biomarkers in Meteorites

The chirality of organic molecules with the asymmetric location of group radicals was discovered in 1848 by Louis Pasteur during his investigations of the rotation of the plane of polarization of light by crystals of sodium ammonium paratartrate. It is well established that the amino acids in proteins are exclusively Levorotary (L-aminos) and the sugars in DNA and RNA are Dextrorotary (D-sugars). This phenomenon of homochirality of biological polymers is a fundamental property of all life known on Earth. Furthermore, abiotic production mechanisms typically yield recemic mixtures (i.e. equal amounts of the two enantiomers). When amino acids were first detected in carbonaceous meteorites, it was concluded that they were racemates. This conclusion was taken as evidence that they were extraterrestrial and produced by abiologically. Subsequent studies by numerous researchers have revealed that many of the amino acids in carbonaceous meteorites exhibit a significant L-excess. The observed chirality is much greater than that produced by any currently known abiotic processes (e.g. Linearly polarized light from neutron stars; Circularly polarized ultraviolet light from faint stars; optically active quartz powders; inclusion polymerization in clay minerals; Vester-Ulbricht hypothesis of parity violations, etc.). This paper compares the measured chirality detected in the amino acids of carbonaceous meteorites with the effect of these diverse abiotic processes. IT is concluded that the levels observed are inconsistent with post-arrival biological contamination or with any of the currently known abiotic production mechanisms. However, they are consistent with ancient biological processes on the meteorite parent body. This paper will consider these chiral biomarkers in view of the detection of possible microfossils found in the Orgueil and Murchison carbonaceous meteorites. Energy dispersive x-ray spectroscopy (EDS) data obtained on these morphological biomarkers will be presented to show that the elemental compositions of these morphological biomarkers are not consistent with the compositions expected for modern (i.e. post-arrival) biological contaminants.

Hoover, Richard B.↗