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At least 271 records · Page 15

The temperature dependence of inelastic light scattering from small particles for use in combustion diagnostic instrumentation

A computer calculation of the expected angular distribution of coherent anti-Stokes Raman scattering (CARS) from micrometer size polystyrene spheres based on a Mie-type model, and a pilot experiment to test the feasibility of measuring CARS angular distributions from micrometer size polystyrene spheres by simply suspending them in water are discussed. The computer calculations predict a very interesting structure in the angular distributions that depends strongly on the size and relative refractive index of the spheres.

Cloud, Stanley D.↗

Optical Characterization of Fuel Injection in a Flame Tube Combustor Using a GE TAPS Injector Configuration

This paper presents results in which we compare fuel staging and its effect on fuel spray pattern, velocity and speciation during combustion for several inlet conditions using a GE TAPS injector configuration. Planar laser-induced fluorescence (PLIF), particle image velocimetry (PIV) and phase Doppler interferometry (PDI) were used to investigate spray patterns and velocity. The 2D PIV provides slices in the flow of axial-vertical or axial horizontal velocity components. With 3D PDI, we obtained 3 components of velocity, and fuel drop sizes. Chemiluminescence imaging and spontaneous Raman scattering (SRS) were used to investigate flame structure, species location and relative species concentration. Phase Doppler and PIV data were acquired using scatter from fuel droplets; therefore, those data were obtained only at the pilot-only test points. Raman measurements were acquired only at 10/90 split points to avoid droplets.

optical diagnostics↗

Flame Tube Testing of a GEA TAPS Injector: Effects of Fuel Staging on Combustor Fuel Spray Patterns, Flow Structure, and Speciation

This paper presents results in which we compare fuel staging and its effect on fuel spray pattern, velocity and speciation during combustion for several inlet conditions using a GE TAPS injector configuration. Planar laser-induced fluorescence (PLIF), particle image velocimetry (PIV) and phase Doppler interferometry (PDI) were used to investigate spray patterns and velocity. The 2D PIV provides slices in the flow of axial-vertical or axial horizontal velocity components. With 3D PDI, we obtained 3 components of velocity, and fuel drop sizes. Chemiluminescence imaging and spontaneous Raman scattering (SRS) were used to investigate flame structure, species location and relative species concentration. Phase Doppler and PIV data were acquired using scatter from fuel droplets; therefore, those data were obtained only at the pilot-only test points. Raman measurements were acquired only at 10/90 split points to avoid droplets.

GE TAPS↗

Ultra-high Information-content Chemical Imaging with Broadband Coherent Anti-Stokes Raman and Two-photon Fluorescence Lifetime Microscopy

Raman fingerprint spectroscopy and fluorescence lifetime imaging are emerging tools for studying metabolic profiles of biological specimens. While Raman fingerprint spectroscopy detects intrinsic molecular vibrations that reflect the molecular composition and chemical environment of a sample, fluorescence lifetime imaging measures changes in the excited-state lifetime of fluorophores that are sensitive to their microenvironments. Here, we present a multimodal imaging platform combining broadband coherent anti-Stokes Raman scattering (BCARS) and two-photon fluorescence lifetime imaging (2p-FLIM) microscopy that can acquire biologically relevant Raman fingerprint spectra and fluorescence lifetime signals in vivo and simultaneously. The tremendous chemical information obtained from spatially co-registered BCARS and 2p-FLIM images allows us to characterize the subtle differences between sub-cellular compartments and verify the potential false-positive results generated by fluorescence imaging alone. This is demonstrated by directly comparing the BCARS, 2p-FLIM, and two-photon excitation fluorescence(TPEF) signals simultaneously obtained from the same dye-stained organelle in the live, intact C. elegans expressing a green fluorescent protein (GFP) marker. In this work, we introduce the BCARS/2p-FLIM/TPEF setup scheme, the image acquisition steps, data processing, and representative results showing that the cross-modality imaging method enables rigorous characterization and in vivo detection at sub-cellular resolution. Furthermore, this protocol provides a framework for simultaneous chemical and fluorescence lifetime imaging to improve the accuracy of biological interpretation in complex living systems.

Xu, Haoyu [Georgia Institute of Technology, Atlant↗

Remote Measurement of Atmospheric Temperatures By Raman Lidar

The Raman shifted return of a lidar, or optical radar, system has been utilized to make atmospheric temperature measurements. These measurements were made along a horizontal path at temperatures between -20 C and +30 C and at ranges of about 100 meters. The temperature data were acquired by recording the intensity ratio of two portions of the Raman spectrum which were simultaneously sampled from a preset range. The lidar unit employed in this testing consisted of a 4 joule-10ppm laser operating at 694.3 nm, a 10-inch Schmidt-Cassegrain telescope, and a system of time-gated detection and signal processing electronics. The detection system processed three return signal wavelength intervals - two intervals along the rotational Raman scattered spectrum and one interval centered at the Rayleigh-Mie scattered wavelength. The wavelength intervals were resolved by using a pellicle beam splitter and three optical interference filters. Raman return samples were taken from one discrete range segment during each test shot and the signal intensities were displayed in digital format. The Rayleigh-Mie techniques. The test site utilized to evaluate this measurement technique encompassed a total path length of 200 meters. Major components of the test site included a trailer-van housing the lidar unit, a controlled environment test zone, and a beam terminator. The control zone which was located about 100 meters from the trailer was 12 meters in length, 2.4 meters in diameter, and was equipped with hinged doors at each end. The temperature of the air inside the zone could be either raised or lowered with respect to ambient air through the use of infrared heaters or a liquid-nitrogen cooling system. Conditions inside the zone were continuously monitored with a thermocouple rake assembly. The test path length was terminated by a 1.2 meter square array of energy absorbing cones and a flat black screen. Tests were initially conducted at strictly ambient conditions utilizing the normal outside air temperatures as a test parameter. These tests provided a calibration of the Raman intensity ratio as a function of' temperature for the particular optical-filter arrangement used in this system while also providing a test of' the theoretical prediction formulated in the design of the system. Later tests utilized zone temperatures above and below ambient to provide temperature gradient data. These tests indicate that ten shots, or one minute of' data acquisition, from a 100 meter range can provide absolute temperature measurements with an accuracy of + 30 C and a range resolution of about 5 meters. Because this measurement accuracy compares well with that predicted for this particular unit, it is suggested that a field-application system could be built with signif'icant improvements in both absolute accuracy and range.

Salzman, Jack A.↗

Towards quantifying mesoscale flows in the troposphere using Raman lidar and Sondes

Water vapor plays an important role in the energetics of the boundary layer processes which in turn play a key role in regulating regional and global climate. It plays a primary role in Earth's hydrological cycle, in radiation balance as a direct absorber of infrared radiation, and in atmospheric circulation as a latent heat energy source, as well as in determining cloud development and atmospheric stability. Water vapor concentration, expressed as a mass mixing ratio (g kg(exp -l)), is conserved in all meteorological processes except condensation and evaporation. This property makes it an ideal choice for studying many of the atmosphere's dynamic features. Raman scattering measurements from lidar also allow retrieval of water vapor mixing ratio profiles at high temporal and vertical resolution. Raman lidars sense water vapor to altitudes not achievable with towers and surface systems, sample the atmosphere at much higher temporal resolution than radiosondes or satellites, and do not require strong vertical gradients or turbulent fluctuations in temperature that is required by acoustic sounders and radars. Analysis of highly-resolved water vapor profiles are used here to characterize two important mesoscale flows: thunderstorm outflows and a cold front passage. The data were obtained at the Atmospheric Radiation Measurement Site (CART) by the groundbased Department of Energy/Sandia National Laboratories lidar (CART Raman lidar or CARL) and Goddard Space Flight Center Scanning Raman Lidar (SRL). A detailed discussion of the SRL and CARL performance during the IOPs is given by others in this meeting.

Demoz, B.↗

Investigation of breadboard temperature profiling system for SSME fuel preburner diagnostics

The feasibility of measuring temperatures in the space shuttle main engine (SSME) fuel preburner using spontaneous Raman scattering from molecular hydrogen was studied. Laser radiation is transmitted to the preburner through a multimode optical fiber. Backscattered Raman-shifted light is collected and focused into a second fiber which connects to a remote-located spectrograph and a mutlichannel optical detector. Optics collimate and focus laser light from the transmitter fiber defining the probe volume. The high pressure, high temperature preburner environment was simulated by a heated pressure cell. Temperatures determined by the distribution of Q-branch co-vibrational transitions demonstrate precision and accuracy of 3%. It is indicated heat preburner temperatures can be determined with 5% accuracy with spatial resolution less than 1 cm and temporal resolution of 10 millisec at the nominal preburner operation conditions.

Shirley, J. A.↗

Some optical and electron microscope comparative studies of excimer laser-assisted and nonassisted molecular-beam epitaxically grown thin GaAs films on Si

The quality of GaAs thin films grown via MBE under pulsed excimer laser irradiation on Si substrates is examined in both laser-irradiated and nonirradiated areas using Raman scattering, Rayleigh scattering, and by photoluminescence (PL), as a function of temperature, and by TEM. The temperature dependence of the PL and Raman peak positions indicates the presence of compressive stress in the thin GaAs films in both laser-irradiated and nonirradiated areas. This indicates incomplete homogeneous strain relaxation by dislocations at the growth temperature. The residual compressive strain at the growth temperature is large enough such that even with the introduction of tensile strain arising from the difference in thermal expansion coefficients of GaAs and Si, a compressive strain is still present at room temperature for these thin GaAs/Si films.

Lao, Pudong↗

A new effect in the depolarization of resonant light scattering from molecules in the vapor phase: I2

Theoretical discussions of the depolarization ratios in two types of resonance processes are given. These processes are discrete state resonance fluorescence, and Raman scattering when the resonance is between a bound state and evanescent-dissociative states. Theory predicts a dramatic difference for these two cases due to a quantum mechanical phase cancellation in the case of virtual dissociative states. The predictions have been verified experimentally.

Silverstein, S. D.↗

The oxidation of carbon monoxide using tin oxide based catalysts

The preparation conditions for precious metal/tin oxide catalysts were optimized for maximum carbon monoxide/oxygen recombination efficiency. This was achieved by controlling the tin digestion, the peptization to form the sol, the calcination process and the method of adding the precious metals. Extensive studies of the tin oxide structure were carried out over the temperature range 20 to 500 C in air or hydrogen environments using Raman scattering and X ray diffraction. Adsorbed species on tin oxide, generated in an environment containing carbon monoxide, gave rise to a Raman band at about 1600 cm(exp -1) which was assigned to carbonaceous groups, possible carbonate.

Sampson, Christopher F.↗

Raman Spectroscopy for Mineral Identification and Quantification for in situ Planetary Surface Analysis: A Point Count Method

Quantification of mineral proportions in rocks and soils by Raman spectroscopy on a planetary surface is best done by taking many narrow-beam spectra from different locations on the rock or soil, with each spectrum yielding peaks from only one or two minerals. The proportion of each mineral in the rock or soil can then be determined from the fraction of the spectra that contain its peaks, in analogy with the standard petrographic technique of point counting. The method can also be used for nondestructive laboratory characterization of rock samples. Although Raman peaks for different minerals seldom overlap each other, it is impractical to obtain proportions of constituent minerals by Raman spectroscopy through analysis of peak intensities in a spectrum obtained by broad-beam sensing of a representative area of the target material. That is because the Raman signal strength produced by a mineral in a rock or soil is not related in a simple way through the Raman scattering cross section of that mineral to its proportion in the rock, and the signal-to-noise ratio of a Raman spectrum is poor when a sample is stimulated by a low-power laser beam of broad diameter. Results obtained by the Raman point-count method are demonstrated for a lunar thin section (14161,7062) and a rock fragment (15273,7039). Major minerals (plagioclase and pyroxene), minor minerals (cristobalite and K-feldspar), and accessory minerals (whitlockite, apatite, and baddeleyite) were easily identified. Identification of the rock types, KREEP basalt or melt rock, from the 100-location spectra was straightforward.

Haskin, Larry A.↗

BCARS Simulated Phantom Dataset for Evaluation of Processing Pipelines

Broadband coherent anti-Stokes Raman scattering (BCARS) microscopy is a powerful label-free biological imaging technique, but the raw signal requires careful processing. The vibrationally resonant (Raman) fingerprint signal is usually small compared with instrumental noise sources and the nonresonant background (NRB) inherent in the BCARS signal. Fortunately, the NRB exhibits a systematic phase relationship with the coherent Raman response, acting as a heterodyne amplifier for the weak fingerprint signal. Due to this heterodyne effect, the Raman response can be recovered quantitatively and invariantly across different instruments, provided the NRB shape is known. Even with heterodyne amplification, the amplitudes of fingerprint signal components are often comparable to system noise. Singular value decomposition (SVD), which utilizes spatial information, is often employed for additional noise filtering. Consequently, finding optimal processing parameters to properly distinguish the NRB and Raman responses and suppress noise in the complex BCARS signal requires a reference system that realistically represents the spectral and spatial properties of BCARS signals obtained from biological samples. We present a digital tissue phantom that meets these criteria as a tool for testing candidate signal processing pipelines. The digital phantom is generated with simulated hyperspectral Raman images having system-specific noise and background characteristics. Here, we analyze phantom datasets with differing background and signal-to-noise conditions to evaluate their impact on the performance of multiple signal processing pipelines. Specifically, we investigate the application of a Butterworth filter-based routine to directly estimate the NRB from the BCARS signal. Additionally, we evaluate a Lorentzian wavelet transform as an alternative to the Hilbert transform for extracting the Raman spectrum from the BCARS signal. While we demonstrate this phantom for BCARS, it can be used for any spectroscopic Raman imaging approach.

Dixon, Jessica Z. [Georgia Institute of Technology↗

Studies of Minerals, Organic and Biogenic Materials through Time-Resolved Raman Spectroscopy

A compact remote Raman spectroscopy system was developed at NASA Langley Research center and was previously demonstrated for its ability to identify chemical composition of various rocks and minerals. In this study, the Raman sensor was utilized to perform time-resolved Raman studies of various samples such as minerals and rocks, Azalea leaves and a few fossil samples. The Raman sensor utilizes a pulsed 532 nm Nd:YAG laser as excitation source, a 4-inch telescope to collect the Raman-scattered signal from a sample several meters away, a spectrograph equipped with a holographic grating, and a gated intensified CCD (ICCD) camera system. Time resolved Raman measurements were carried out by varying the gate delay with fixed short gate width of the ICCD camera, allowing measurement of both Raman signals and fluorescence signals. Rocks and mineral samples were characterized including marble, which contain CaCO3. Analysis of the results reveals the short (approx.10-13 s) lifetime of the Raman process, and shows that Raman spectra of some mineral samples contain fluorescence emission due to organic impurities. Also analyzed were a green (pristine) and a yellow (decayed) sample of Gardenia leaves. It was observed that the fluorescence signals from the green and yellow leaf samples showed stronger signals compared to the Raman lines. Moreover, it was also observed that the fluorescence of the green leaf was more intense and had a shorter lifetime than that of the yellow leaf. For the fossil samples, Raman shifted lines could not be observed due the presence of very strong short-lived fluorescence.

Garcia, Christopher S.↗

Visible-infrared remote-sensing model and applications for ocean waters

Remote sensing has become important in the ocean sciences, especially for research involving large spatial scales. To estimate the in-water constituents through remote sensing, whether carried out by satellite or airplane, the signal emitted from beneath the sea surface, the so called water-leaving radiance (L(w)), is of prime importance. The magnitude of L(w) depends on two terms: one is the intensity of the solar input, and the other is the reflectance of the in-water constituents. The ratio of the water-leaving radiance to the downwelling irradiance (E(d)) above the sear surface (remote-sensing reflectance, R(sub rs)) is independent of the intensity of the irradiance input, and is largely a function of the optical properties of the in-water constituents. In this work, a model is developed to interpret r(sub rs) for ocean water in the visible-infrared range. In addition to terms for the radiance scattered from molecules and particles, the model includes terms that describe contributions from bottom reflectance, fluorescence of gelbstoff or colored dissolved organic matter (CDOM), and water Raman scattering. By using this model, the measured R(sub rs) of waters from the West Florida Shelf to the Mississippi River plume, which covered a (concentration of chlorophyll a) range of 0.07 - 50 mg/cu m, were well interpreted. The average percentage difference (a.p.d.) between the measured and modeled R(sub rs) is 3.4%, and, for the shallow waters, the model-required water depth is within 10% of the chart depth. Simple mathematical simulations for the phytoplankton pigment absorption coefficient (a(sub theta)) are suggested for using the R(sub rs) model. The inverse problem of R(sub rs), which is to analytically derive the in-water constituents from R(sub rs) data alone, can be solved using the a(sub theta) functions without prior knowledge of the in-water optical properties. More importantly, this method avoids problems associated with a need for knowledge of the shape and value of the chlorophyll-specific absorption coefficient. The simulation was tested for a wide range of water types, including waters from Monterey Bay, the West Florida Shelf, and the Mississippi River plume. Using the simulation, the R(sub rs)-derived in-water absorption coefficients were consistent with the values from in-water measurements (r(exp 2) greater than 0.94, slope approximately 1.0). In the remote-sensing applications, a new approach is suggested for the estimation of primary production based on remote sensing. Using this approach, the calculated primary production (PP) values based upon remotely sensed data were very close to the measured values for the euphotic zone (r(exp 2) = 0.95, slope 1.26, and 32% average difference), while traditional, pigment-based PP model provided values only one-third the size of the measured data. This indicates a potential to significantly improve the accuracy of the estimation of primary production based upon remote sensing.

Lee, Zhongping↗

The Sun among stars. IV - Albedos of Uranus and Neptune and the solar color

Geometric albedos in 48 adjacent 50 A bands from 3250 to 5600 A have been derived from observations of Uranus and Neptune. The solar analog found in earlier papers (Hardorp 1978, 1980) was chosen for these reductions, so these albedos are more reliable systematically than earlier ones and allow a choice among the scattering models of Savage et al. (1980). Green methane bands are stronger on Neptune. Strong solar absorption lines are found to be partially filled in by Raman-scattering. Neglect of this effect caused Croft et al. (1972) to find a solar color that is too blue. It probably also affected the classification of G-type stars in the Michigan Spectral Catalogue as well as Garrison's (1979) interpretation of IUE observations.

Hardorp, J.↗

Linewidth characteristics of Raman-shifted dye laser output at 720 and 940 nm

Existing DIAL systems for water vapor measurements in the troposphere operate at wavelengths near 720 nm. The use of stronger water vapor absorption lines in the range 930 to 960 nm will significantly improve DIAL measurements in the upper troposphere and lower stratosphere where water vapor concentrations are low. The generation of light at 940 nm using a frequency doubled Nd:YAG pumped dye laser is inefficient due to the small absorption if infrared dyes at the pump wavelength. However, 940 nm generation utilizing stimulated Raman scattering of dye lasers is attractive because of a potentially high conversion efficiency plus the possibility of retaining the narrow linewidth available from some dye lasers. The Raman conversion efficiency and line broadening are presented for first Stokes operation at 720 and 940 nm using hydrogen and deuterium as the Raman media.

Grossmann, B. E.↗

Coherent Pump-Probe Interactions and Terahertz Intersubband Gain in Semiconductor Quantum Wells

In recent years there has been considerable interest in intersubband-transition-based infrared semiconductor quantum well (QW) lasers because of their potential applications. In the mid-infrared range, both electrically-injected quantum cascade lasers [1] and optically-pumped multiple QW lasers [2] have been experimentally realized. In these studies, optical gain is due to population inversion between the lasing subbands. It was also proposed that stimulated Raman scattering in QW systems can produce net infrared optical gain [3j. In such a nonlinear optical scheme, the appearance of optical gain that may lead to intersubband Raman lasers does not rely on the population inversion. Since, in tile resonant Raman process (Raman gain is the largest in this case), the pump field induces population redistribution among subbands in the QW s ystem, it seems that a realistic estimate of the optical gain has to include this effect. Perturbative calculations used in the previous work [3] may overestimate the Raman gain. In this paper we present a nonperturbative calculation of terahertz gain of optically-pumped semiconductor step quantum wells. Limiting optical transitions within the conduction band of QW, we solve the pump-field-induced nonequilibrium distribution function for each subband of the QW system from a set of coupled rate equations. Both intrasubband and intersubband relaxation processes in the quantum well system are included. Taking into account the coherent interactions between pump and THz (signal) waves, we we derive the susceptibility of the QW system for the THz field. For a GaAs/AlGaAs step QW, we calculate the Thz gain spectrum for different pump frequencies and intensities. Under moderately strong pumping (approximately 0.3 MW/sq cm), a significant THz gain (approximately 300/m) is predicted. It is also shown that the coherent wave interactions (resonant stimulated Raman processes) contribute significantly to the THz gain.

Liu, Ansheng↗

Reduction of Raman Spectroscopy Data for H2-CO2-Air Tubular Flame Measurements

An approach of reducing spontaneous Raman spectroscopy data, based on the matrix inversion method which logically removes undesired sources of the Raman scattering signals including cross-talk due to the signals from other species, is discussed. The approach contains extensive calibration of temperature-dependent system response. The Raman spectra of several cold and hot calibration flames and their resulting calibration matrix are elaborated. The structure of H2-CO2-air tubular flames, in terms of major species (CO2, O2, N2, H2O, and H2) concentrations and temperature, was successfully measured with the optical technique. The Raman spectra data used in this study are taken from a uniquely designed experimental apparatus – a tubular burner and Raman spectroscopy system at Vanderbilt University. The characteristic uncertainties for chemical species are approximately ±2% by mole fraction for hot products and ±0.5% for room temperature reactants. The approach described here for hydrogen/air tubular flames may be adapted to hydrocarbon/air tubular flames when other necessary major species, for example, CH4 and CO for methane/air tubular flame, are considered in the whole process.

Raman Spectroscopy↗