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At least 271 records · Page 15

Refinements in an Mg/MgH2/H2O-Based Hydrogen Generator

Some refinements have been conceived for a proposed apparatus that would generate hydrogen (for use in a fuel cell) by means of chemical reactions among magnesium, magnesium hydride, and steam. The refinements lie in tailoring spatial and temporal distributions of steam and liquid water so as to obtain greater overall energy-storage or energy-generation efficiency than would otherwise be possible. A description of the prior art is prerequisite to a meaningful description of the present refinements. The hydrogen-generating apparatus in question is one of two versions of what was called the "advanced hydrogen generator" in "Fuel-Cell Power Systems Incorporating Mg-Based H2 Generators" (NPO-43554), NASA Tech Briefs, Vol. 33, No. 1 (January 2009), page 52. To recapitulate: The apparatus would include a reactor vessel that would be initially charged with magnesium hydride. The apparatus would exploit two reactions: The endothermic decomposition reaction MgH2-->Mg + H2, which occurs at a temperature greater than or equal to 300 C, and The exothermic oxidation reaction MgH2 + H2O MgO + 2H2, which occurs at a temperature greater than or equal to 330 C.

Kindler, Andrew↗

A Mechanistic Reliability Assessment of RVACS and Metal Fuel Inherent Reactivity Feedbacks

GE Hitachi Nuclear Energy (GEH) and Argonne National Laboratory (Argonne) participated in a two year collaboration to modernize and update the probabilistic risk assessment (PRA) for the PRISM sodium fast reactor. At a high level, the primary outcome of the project was the development of a next-generation PRA that is intended to enable risk-informed prioritization of safety- and reliability-focused research and development. A central Argonne task during this project was a reliability assessment of passive safety systems, which included the Reactor Vessel Auxiliary Cooling System (RVACS) and the inherent reactivity feedbacks of the metal fuel core. Both systems were examined utilizing a methodology derived from the Reliability Method for Passive Safety Functions (RMPS), with an emphasis on developing success criteria based on mechanistic system modeling while also maintaining consistency with the Fuel Damage Categories (FDCs) of the mechanistic source term assessment. This paper provides an overview of the reliability analyses of both systems, including highlights of the FMEAs, the construction of best-estimate models, uncertain parameter screening and propagation, and the quantification of system failure probability. In particular, special focus is given to the methodologies to perform the analysis of uncertainty propagation and the determination of the likelihood of violating FDC limits. Additionally, important lessons learned are also reviewed, such as optimal sampling methodologies for the discovery of low likelihood failure events and strategies for the combined treatment of aleatory and epistemic uncertainties.

Grabaskas, David↗

Investigation of the Impact of TSL Data Libraries and Geometry Variations on the MSRE Benchmark

The increasing demand for green, low-carbon energy solutions has amplified the focus on advanced nuclear reactor technologies. Among these, Molten Salt Reactors (MSRs) have been spotlighted because of their special features. Historically, Oak Ridge National Laboratory (ORNL) started the Molten Salt Reactor Experiment (MSRE) in 1956. Later, ORNL and the University of California, Berkeley (UCB) jointly developed the MSRE benchmark. This was then reviewed by the International Reactor Physics Experiment Evaluation Project (IRPhEP) committee and added to their 2019 handbook. In the current study, the benchmark model was recreated via the Serpent code. The calculated effective multiplication factor was 1.02087 ± 0.00019, which gives a deviation of about 2000 pcm compared to the benchmark/experimental result. At North Carolina State University (NCSU), recent evaluations were conducted on thermal scattering cross sections for molten salt FLiBe and 20% porous nuclear graphite, anticipated for incorporation in the ENDF/B-VIII.1 library. The influences of these thermal scattering law (TSL) data and geometry changes on the multiplication factor were examined using the ENDF/B-VII.1 and ENDF/B-VIII.0 libraries. Introducing the TSL data for FLiBe and 20% porous graphite resulted in an effective multiplication factor of +270 pcm compared to the reference value obtained with ENDF/B-VII.1 in this study. The adjustment of the reactor vessel dimensions resulted in decrease of -448 pcm in the calculated effective multiplication factor.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Relithiation process for direct regeneration of cathode materials from spent lithium-ion batteries

A method for the regeneration of cathode material from spent lithium-ion batteries is provided. The method includes dissolving a lithium precursor in a polyhydric alcohol to form a solution. Degraded cathode material containing lithium metal oxides are dispersed into the solution under mechanical stirring, forming a mixture. The mixture is heat treated within a reactor vessel or microwave oven. During this heat treatment, lithium is intercalated into the degraded cathode material. The relithiated electrode material is collected by filtration, washing with solvents, and drying. The relithiated electrode material is then ground with a lithium precursor and thermally treated at a relatively low temperature for a predetermined time period to obtain regenerated cathode material.

Belharouak, Ilias↗

Chemical and Radiological Compatibility Testing of 3D Printed Materials

To dramatically increase the adaptability, performance, and safety of processes in support of the Defense Waste Processing Facility (DWPF), Savannah River National Lab (SRNL) plans to perform chemical and radiological compatibility testing on a wide variety of 3D printed materials of interest. The 3D printing process provides numerous strategic operational benefits such as rapid prototyping of complex designs and geometry specific to the needs of the nuclear waste disposition process, as well as on-demand rapid prototyping and iteration with materials that aren’t as accessible through traditional manufacturing methods. Reaction chemistry in simulated waste batches can be matched closely to its radioactive counterpart, but glass reactor vessels have limitations. Vessel geometry can play a big factor in mixing transport limitations, process chemistry, and degradation reaction kinetics. In addition, additive manufacturing allows for much more detailed vessel design than traditional alternatives. Waste processing techniques in DWPF also encounter extreme chemical environments including high pH, strong acids, abrasive slurries, and significant irradiation. To meet these challenges, a matrix of various polymer, ceramic, and metal additive manufacturing materials have been exposed to a suite of chemical environments of interest as well as radioactive dose (such as gamma radiation from 60 Co) to properly test their durability under these conditions. Mass change has been monitored over a period of up to a week in these conditions, as well as added characterization for surface modification through Scanning Electron Microscopy/Electron Dispersive X-ray analysis (SEM/EDX). Further chemical characterization has been monitored through Fourier-Transform InfraRed Spectroscopy (FTIR), with planned investigation via thermal and tensile strength degradation. While the direct product of this research is identification of material(s) that can withstand specific hazardous environments encountered by the mercury water wash tank in DWPF process simulation experiments, the reference base of materials will be used for many other nuclear processes in the pursuit of rapidly developed, cost-efficient, and highly specific devices for environmental remediation and much more.

Wilson, Nathan W. [Savannah River National Laborat↗

Mesoscale modeling of solute precipitation and radiation damage

This report summarizes the low length scale effort during FY 2014 in developing mesoscale capabilities for microstructure evolution in reactor pressure vessels. During operation, reactor pressure vessels are subject to hardening and embrittlement caused by irradiation-induced defect accumulation and irradiation-enhanced solute precipitation. Both defect production and solute precipitation start from the atomic scale, and manifest their eventual effects as degradation in engineering-scale properties. To predict the property degradation, multiscale modeling and simulation are needed to deal with the microstructure evolution, and to link the microstructure feature to material properties. In this report, the development of mesoscale capabilities for defect accumulation and solute precipitation are summarized. Atomic-scale efforts that supply information for the mesoscale capabilities are also included.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Fukushima inspection manipulator - 15485

After the March 2011 nuclear accident at Fukushima Daiichi NPP it was discovered that there was a large leak inside the Reactor Pressure Vessel (RPV). During the efforts to cool the reactor vessel following the accident, water that was injected into the RPV was found in a lower portion of the facility indicating a leak in the Primary Containment Vessel (PCV). Later, TEPCO announced its high level decommissioning and recovery plan that included equipment locate these leaks and plug them so that the RPV and PCV could be filled with water. Over the past two years Toshiba, IHI and Kurion have been teamed together on projects to find and ultimately to seal these leaks. In the first phase, which was demonstrated in August of 2014, Kurion provided a remote manipulator arm called the Fukushima Inspection Manipulator (FIM) in conjunction with a remotely operated vehicle (ROV) which was developed by Toshiba and IHI to inspect the lower portion of the PCV in Unit 2 of Fukushima Daiichi. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Reactor moderator, pressure vessel, and heat rejection system of an open-cycle gas core nuclear rocket concept

A preliminary design study of a conceptual 6000-megawatt open-cycle gas-core nuclear rocket engine system was made. The engine has a thrust of 196,600 newtons (44,200 lb) and a specific impulse of 4400 seconds. The nuclear fuel is uranium-235 and the propellant is hydrogen. Critical fuel mass was calculated for several reactor configurations. Major components of the reactor (reflector, pressure vessel, and waste heat rejection system) were considered conceptually and were sized.

Taylor, M. F.↗

Density Effects on Lock Exchange Flow During a DCC

The High Temperature Test Facility (HTTF) is a scaled, electric model at Oregon State University (OSU) of the Modular High Temperature Gas Reactor (MHTGR) by General Atomics. There are a few major differences between the design and the OSU facility. In the HTTF the reactor pressure vessel and the reactor cavity are in two separate tanks connected by a crossover duct similar to the crossover duct that would be seen between the reactor core and the steam generator in the MHTGR. This feature allows for the facility to open two main break valves simulating a Double-Ended Guillotine Break (DEGB) of the cross over duct, synonymous to a crossover duct break in the MHTGR. The density gradient driven flow phenomena in the HTTF duct can then be studied further. This break would cause a depressurization of the reactor and a loss of flow. It is called the Depressurized Loss of Forced Convection Accident (D-LOFC), also known as the Depressurized Conduction Cool-Down Event for High Temperature Gas Reactors (HTGRs) because heat removal is by conduction through the core and radiation out of the vessel. The HTTF was built and scaled to maintain the highest accuracy for the DCC. Prototypical temperatures with an inlet temperature of 259 deg. C and an outlet temperature of 687 deg. C are maintained in the HTTF. The temperature profile is also maintained in the smaller volume by using a ceramic core. The HTTF uses graphite heaters because the resistive heat produced does not change significantly with temperature . In order to produce a facility of similar temperatures within the allotted budget, sacrifices had to be made in other areas. The HTTF is scaled one-fourth in diameter, one-fourth in height and one-eighth in pressure of the MHTGR. There are also a few limitations for the HTTF. While in the MHTGR, the cavity is filled with air, the HTTF uses highly pure Nitrogen and does not have the ability to simulate a full depressurization. The DCC event is traditionally comprised of multiple stages: depressurization, molecular diffusion and natural circulation. However, this traditional interpretation ignores lock exchange flow which will occur immediately following depressurization and could have significant consequences in the reactor. It was found that the traditional model underestimates the amount of air ingress by at least 660 times according to Oh and Kim in their theoretical research of air ingress. Molecular diffusion also decreases with stratification. Any model that specifies the gases are stratified has further underestimated the air ingress of the DCC event. In addition, molecular diffusion is a much slower process, allowing the reactor to shut down and cool off considerably from operating temperatures. Thus, understanding lock exchange flow, the air ingress concentrations and the time scale is critical to MHTGR research and licensing. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Passive integral isolation valve

A valve assembly includes a flange connected to a vessel penetration of a reactor pressure vessel of a nuclear reactor. A valve is disposed inside the flange or protrudes from the flange into the vessel penetration. The valve includes a valve seat and a movable valve member positioned so that pressure inside the reactor pressure vessel urges the movable valve member against the valve seat to close the valve. The valve assembly further includes a plenum having an inlet via which the plenum can be pressurized to apply pressure to the movable valve member that urges the movable valve member away from the valve seat to open the valve. The plenum may be defined in part by a surface of the movable valve member. The valve assembly preferably does not include a valve actuator.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Humboldt bay power plant decommissioning transition to civil works - 15039

Decommissioning of the Pacific Gas and Electric (PG and E) Company Humboldt Bay Power Plant (HBPP) Unit 3 nuclear facility has now, after more than three decades of SAFSTOR, completed the Plant Systems Removal Phase by removal of all radiologically significant plant systems from the buildings in June 2014. The HBPP historical design and construction, close proximity to the bay and associated tidal interactions poses unique challenges to an effective decommissioning effort as the Site transitions to a major earthwork project - designated as Civil Works. The last significant large component removal project remaining is segmentation and disposal of the reactor pressure vessel shell and this project is now integrated and executed under Civil Works with PG and E solely in an oversight role across the site beginning 2015. The value from run-up and mock-up testing of tooling to segment the HBPP reactor vessel will be discussed. Experience obtained, especially at error prone interfaces, during start-up, systemisation and operating phases for the First of a Kind (KOAK) tooling will be discussed. Implementation of the civil scope of work commenced July 2013. Its status and experience applicable to other decommissioning efforts will be provided from an owner's perspective. Implementation of the civil work scope includes development and implementation of oversight capability including policy, procedures and deployment of skilled, experienced and trained oversight staff in the field. Challenges encountered and solutions implemented during mobilization and ramp up of the civil contractor commensurate with demobilization of the self-perform staff will be covered. Partnering with the contractor to establish a good Client/Contractor relationship and tips on where to invest owner resources will be shared. Development of a solid baseline project schedule that incorporates regulatory constraints, client expectations and contract constraints and its importance to safe, compliant project execution will be shared. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Passive cooling to cold shutdown

A cooling system for a reactor module includes a reactor pressure vessel that houses primary coolant and a steam generator that lowers a temperature of the reactor pressure vessel by transferring heat from the primary coolant to a secondary coolant. The steam generator releases at least a portion of the secondary coolant as steam. Additionally, the cooling system includes a containment vessel that at least partially surrounds the reactor vessel in a containment region. The containment region is dry during normal operation of the reactor module. A controller introduces a source of water into the containment region in response to a non-emergency shut down of the reactor module. The source of water is located external to the containment vessel, and the water is introduced into the containment region after the steam generator has initially lowered the temperature of the reactor pressure vessel in response to releasing the steam.

Keller, Michael↗

Grizzly Staus Report

This report summarizes work during FY 2014 to develop capabilities to predict embrittlement of reactor pressure vessel steel, and to assess the response of embrittled reactor pressure vessels to postulated accident conditions. This work has been conducted a three length scales. At the engineering scale, 3D fracture mechanics capabilities have been developed to calculate stress intensities and fracture toughnesses, to perform a deterministic assessment of whether a crack would propagate at the location of an existing flaw. This capability has been demonstrated on several types of flaws in a generic reactor pressure vessel model. Models have been developed at the scale of fracture specimens to develop a capability to determine how irradiation affects the fracture toughness of material. Verification work has been performed on a previously-developed model to determine the sensitivity of the model to specimen geometry and size effects. The effects of irradiation on the parameters of this model has been investigated. At lower length scales, work has continued in an ongoing to understand how irradiation and thermal aging affect the microstructure and mechanical properties of reactor pressure vessel steel. Previously-developed atomistic kinetic monte carlo models have been further developed and benchmarked against experimental data. Initial work has been performed to develop models of nucleation in a phase field model. Additional modeling work has also been performed to improve the fundamental understanding of the formation mechanisms and stability of matrix defects caused.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Innovative Decommissioning Strategies for Large Components - 18535

Within decommissioning projects the dismantling of steam generators as well as of the reactor pressure vessel with its internals form important and time consuming tasks. In order to optimize these, the reactor pressure vessel will be segmented into larger pieces in-situ and the larger pieces will be further segmented in a post segmentation area in order to suit the dimensional and radiological requirements of the final waste package. A similar approach is used also for the dismantling of Steam Generators. NUKEM Technologies Engineering Services has combined the two principles 'Rip / Store / Ship' and 'In-situ segmentation' to firstly segment the steam generator in-situ and then pack and ship all resulting parts allowing decontamination within 20' container to an existing decontamination facility. The aim is to free release 90 - 95% of the material. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Improvements to Passive Heat Removal Systems in SAS4A/SASSYS-1

Safe operation of a sodium cooled fast reactor (SFR) can be significantly aided by heat removal systems that do not rely on active power, but function using passive means. Passive heat removal from such reactors can employ systems that extract heat directly from sodium coolant by utilizing heat exchangers submerged in the coolant and natural circulation of a metal fluid sodium (or sodium potassium eutectic) to heat exchangers (generally air cooled) externally located. These types of systems are generally called Direct Reactor Auxiliary Cooling Systems (DRACS). Another type of passive heat removal system particularly suitable for pool-type SFRs relies on indirect extraction of heat by utilizing air flow in an annular region surrounding the reactor guard vessel which discharges the heat via the chimney effects to the atmosphere. These systems are generally called Reactor Vessel Auxiliary Cooling Systems (RVACS).

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

A STRONGLY COUPLED REACTOR CORE ISOLATION COOLING SYSTEM MODEL FOR EXTENDED STATION BLACK-OUT ANALYSES

The reactor core isolation cooling (RCIC) system in a boiling water reactor (BWR) provides makeup cooling water to the reactor pressure vessel (RPV) when the main steam lines are isolated and the normal supply of water to the reactor vessel is lost. The RCIC system operates independently of AC power, service air, or external cooling water systems. The only required external energy source is from the battery to maintain the logic circuits to control the opening and/or closure of valves in the RCIC systems in order to control the RPV water level by shutting down the RCIC pump to avoid overfilling the RPV and flooding the steam line to the RCIC turbine. It is generally considered in almost all the existing station black-out accidents (SBO) analyses that loss of the DC power would result in overfilling the steam line and allowing liquid water to flow into the RCIC turbine, where it is assumed that the turbine would then be disabled. This behavior, however, was not observed in the Fukushima Daiichi accidents, where the Unit 2 RCIC functioned without DC power for nearly three days. Therefore, more detailed mechanistic models for RCIC system components are needed to understand the extended SBO for BWRs. As part of the effort to develop the next generation reactor system safety analysis code RELAP-7, we have developed a strongly coupled RCIC system model, which consists of a turbine model, a pump model, a check valve model, a wet well model, and their coupling models. Unlike the traditional SBO simulations where mass flow rates are typically given in the input file through time dependent functions, the real mass flow rates through the turbine and the pump loops in our model are dynamically calculated according to conservation laws and turbine/pump operation curves. A simplified SBO demonstration RELAP-7 model with this RCIC model has been successfully developed. The demonstration model includes the major components for the primary system of a BWR, as well as the safety system components such as the safety relief valve (SRV), the RCIC system, the wet well, and the dry well. The results show reasonable system behaviors while exhibiting rich dynamics such as variable flow rates through RCIC turbine and pump during the SBO transient. The model has the potential to resolve the Fukushima RCIC mystery after adding the off-design two-phase turbine operation model and other additional improvements.

RCIC↗

Thermal-hydraulic validation tests using the SMART-ITL facility with a single train passive safety injection system for the smart design

A test program was launched using a large-scale thermal-hydraulic integral effect test facility of SMART-ITL (or FESTA) to validate the performance of the SMART passive safety system. In this paper thermal-hydraulic validation tests using the SMART-ITL facility equipped with a single train of a passive safety injection system were performed and their major results were summarized. The effect of the flow distributor, break size and different types of Core Makeup Tank (CMT) and Safety Injection Tank (SIT) on the thermal-hydraulic behavior during a Small-Break Loss of Coolant Accident (SBLOCA) scenario was investigated for the SMART passive safety system development. During the SBLOCA scenario, the water layer was well stratified thermally in the core makeup tank, and the safety injection water was injected efficiently into the reactor pressure vessel from the initial period. Eventually, the reactor coolant system was cooled down properly. From the test results, it was estimated that the SMART passive safety system has sufficient cooling capability to deal with the SBLOCA scenario of SMART. The acquired data will be used to validate the safety analysis code and its related models, to evaluate the performance of SMART PSS, and to provide the base data during the application phase of the revision of standard design approval and construction licensing. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗