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Results for “Rigidity function”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

New Mathematical Functions for Vacuum System Analysis

A new bivariate function has been found that provides solutions of integrals having the form u (sup minus eta) e (sup u) du which arise when developing predictions for the behavior of pressure within a rigid volume under high vacuum conditions in the presence of venting as well as sources characterized by power law transient decay over the range [0,1] for eta and for u greater than or equal to 0. A few properties of the new function are explored in this work. For instance the eta equals 1/2 case reproduces the Dawson function. In addition, a slight variation of the solution technique reproduces the exponential integral for eta equals 1. The technique used to generate these functions leads to an approach for solving a more general class of nonlinear ordinary differential equations, with the potential for identifying other new functions that solve other integrals.

Dawson Function↗
NASA NTRS1993

Effective elastic thickness of the Venusian lithosphere with lateral viscosity variations in the mantle

Both the Earth and Venus have a convecting mantle at the top of which is a relatively strong, mechanical boundary layer. The surface topography and gravity signals which result from the convection within the viscous mantle are modified by the elastic properties of this lithospheric boundary layer. In particular the ability of the lithosphere to support loads and transmit stresses from below is a function of the wavelength of the load--the lithosphere is strong to loading at shorter wavelengths. As a consequence it is usual to expect that long wavelength topography cannot be supported by the mechanical strength of the lithosphere and must be compensated--isostatically or dynamically--within the uppermost mantle or the crust. The flexural rigidity of the lithosphere can therefore be determined by estimating the greatest wavelength at which uncompensated surface topography can be supported, usually by measuring the admittance as a function of wavelength. In fact this procedure for determining the elastic thickness relies upon being able to distinguish topography with underlying support from that supported by the brittle lithosphere on the basis of their each having a characteristic value of the admittance. However, in the presence of lateral viscosity variations in the mantle, it is possible for topography to be generated which is NOT compensated by density anomalies in the underlying mantle at the same wavelength. Although this effect is not likely to be important for the Earth, on Venus, where the high surface temperatures would be expected to give a weaker lithosphere, lateral viscosity variations in the mantle can give a misleadingly large apparent elastic thickness for the lithosphere.

Moresi, Louis↗
DOE OSTI2020

Carotenoids promote lateral packing and condensation of lipid membranes

Carotenoids are pigment molecules that protect biomembranes against degradation and may be involved in the formation of functional bacterial membrane microdomains. Little is known on whether different types of carotenoids have different effects on the membrane or if there is any concentration dependence of these effects. Here, we present results from molecular dynamics simulations of phospholipid bilayers containing different amounts of either β-carotene or zeaxanthin. Both β-carotene and zeaxanthin show the ability to laterally condense the membrane lipids and reduce their inter-leaflet interactions. With increasing concentrations, both carotenoids increase the bilayer thickness and rigidity. The results reveal that carotenoids have similar effects to cholesterol on regulating the behavior of fluid-phase membranes, suggesting that they could function as sterol substitutes and confirming their potential role in the formation of functional membrane domains.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2009

Challenges with Deploying and Integrating Environmental Control and Life Support Functions in a Lunar Architecture with High Degrees of Mobility

Visions of lunar outposts often depict a collection of fixed elements such as pressurized habitats, in and around which human inhabitants spend the large majority of their surface stay time. In such an outpost, an efficient deployment of environmental control and life support equipment can be achieved by centralizing certain functions within one or a minimum number of habitable elements and relying on the exchange of gases and liquids between elements via atmosphere ventilation and plumbed interfaces. However, a rigidly fixed outpost can constrain the degree to which the total lunar landscape can be explored. The capability to enable widespread access across the landscape makes a lunar architecture with a high degree of surface mobility attractive. Such mobility presents unique challenges to the efficient deployment of environmental control and life support functions in multiple elements that may for long periods of time be operated independently. This paper describes some of those anticipated challenges.

Bagdigian, Robert M.↗
NASA NTRS1992

A convected kappa distribution model for hot ions in the Jovian magnetodisc

Hot ion angular anisotropies measured by the Low Energy Charged Particle (LECP) instrument during the Voyager 2 encounter with the Jovian dayside outer magnetosphere (60-30 RJ) have been fitted to a 2 species convected kappa distribution function using a nonlinear least squares technique. The resulting parameters are well constrained by the data. The heavy ion species was assumed to be either sulfur or oxygen of unknown charge. The light species was assumed to be protons. The bulk flow speeds deduced from the model were found, contrary to some theories, to increase with increasing radial distance from Jupiter within the radial region addressed, remaining a substantial fraction (0.6) of the rigid corotation speed. Agreement with the averaged Voyager Plasma Science results was obtained near 30 RJ. The core Maxwellian temperature of the heavy ion distribution functions (30-100 keV) increased with increasing radial distance, following the trend anticipated from the corotation pickup of heavy ions. The proton temperature (20 keV) remained nearly constant.

Kane, M.↗
NASA NTRSDate not supplied

Evaluation of Preliminary Buffet Forcing Function Development based on Wind-Tunnel Tests of Geometrically-similar Models

The current state-of-the-art for launch vehicle buffet load estimation involves wind tunnel testing of highly instrumented rigid models and data processing of experimental unsteady pressure measurements to estimate the fluctuating aerodynamic loads. The model and instrumentation requirements to accomplish this type of testing are significant. The rigid model, in particular, must be built with relatively high geometric fidelity to approximate similar aerodynamic phenomena that will occur during the full-scale vehicle flight. Due to this requirement, several iterative wind tunnel tests are often required during the design maturation of the vehicle. For preliminary buffet load estimation, however, data from previous launch vehicle wind tunnel tests of geometrically similar models can be used to provide initial buffet environment estimates before a high geometric fidelity wind tunnel test has been conducted. In this paper, two components of this preliminary buffet estimation process are described: (1) assembly of buffet forcing functions from multiple data sources and (2) scaling of these buffet forcing functions to geometrically-similar components of a target vehicle configuration. The impacts of these estimation methods on the full-vehicle buffet forcing functions, including their longitudinal distribution along the vehicle, frequency-content at individual stations, and station-to-station coherence, are investigated. Considerations for using these methods to extrapolate wind tunnel data to geometrically similar models are also discussed.

Patrick S Heaney↗
DOE OSTI2018

Thermally Rearranged Polymer Membranes Containing Tröger's Base Units Have Exceptional Performance for Air Separations

The influence of segmental chain motion on the gas separation performance of thermally rearranged (TR) polymer membranes is established for TR polybenzoxazoles featuring Tröger's base (TB) monomer subunits as exceptionally rigid sites of contortion along the polymer backbone. These polymers are accessed from solution-processable ortho-acetate functionalized polyimides, which are readily synthesized as high-molecular-weight polymers for membrane casting. We discover that thermal rearrangement leads to a small increase in d-spacing between polymer chains and a dramatic pore-network reconfiguration that increases both membrane permeability and O 2 /N 2 selectivity, enabling its performance above the 2015 upper bound.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Mechanically flexible mid-wave infrared imagers using black phosphorus ink films

The mid-wave infrared (MWIR) spectral range (λ = 3–8 μm) enables important sensing and imaging applications, including non-invasive bioimaging, night vision, and autonomous navigation. Commercial MWIR photodetectors are limited to rigid imagers based on heteroepitaxial materials. There is an emerging need for mechanically flexible MWIR imagers to broaden their functionality and practicality. Recently, photodetectors using van der Waals (vdW) black phosphorus (BP) flakes have demonstrated highly sensitive room-temperature photodetection. Additionally, vdW materials are solution-processable, facilitating scalable processing and flexible device fabrication. In this work, we present flexible MWIR imagers consisting of photodiodes fabricated on thin plastic substrates using BP ink films. We demonstrate mechanically robust responsivity up to 2.5-mm bending radii and after 5000 bending cycles. Leveraging this flexibility, we achieve full-azimuthal imaging, detecting directional light sources with precision. These results establish a scalable approach for large-area, conformable MWIR imaging and pave the way for integration with flexible electronics.

Wijaya, Theodorus Jonathan↗
DOE OSTI2018

The structures of penicillin-binding protein 4 (PBP4) and PBP5 from Enterococci provide structural insights into β-lactam resistance

The final steps of cell-wall biosynthesis in bacteria are carried out by penicillin-binding proteins (PBPs), whose transpeptidase domains form the cross-links in peptidoglycan chains that define the bacterial cell wall. These enzymes are the targets of β-lactam antibiotics, as their inhibition reduces the structural integrity of the cell wall. Bacterial resistance to antibiotics is a rapidly growing concern; however, the structural underpinnings of PBP-derived antibiotic resistance are poorly understood. PBP4 and PBP5 are low-affinity, class B transpeptidases that confer antibiotic resistance to Enterococcus faecalis and Enterococcus faecium, respectively. We report the crystal structures of PBP4 (1.8 Å) and PBP5 (2.7 Å) in their apo and acyl-enzyme complexes with the β-lactams benzylpenicillin, imipenem, and ceftaroline. We found that, although these three β-lactams adopt geometries similar to those observed in other class B PBP structures, there are small, but significant, differences that likely decrease antibiotic efficacy. Further, we also discovered that the N-terminal domain extensions in this class of PBPs undergo large rigid-body rotations without impacting the structure of the catalytic transpeptidase domain. Together, our findings are defining the subtle functional and structural differences in the Enterococcus PBPs that allow them to support transpeptidase activity while also conferring bacterial resistance to antibiotics that function as substrate mimics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1981

Observations of the ionization states of energetic particles accelerated in solar flares

Results of a survey of ten solar flare particle events, in which the ionization states and spectra of 0.3 to 2.4 MeV/nuc He, C, O and Fe were measured, are reported. He+ was present in all events (He+/He++ approximately 0.1 to 0.25), and the mean ionization states of C, O and Fe are high. The distribution functions of He+, He++ and heavier elements are well represented by simple exponentials of the particle speed times its rigidity to a power n, where n is between O and 1, and equal e-folding values. Results are consistent with a model whereby ions are accelerated in the corona by multi-dimensional shocks out of a population taken from both hot and cold coronal regions.

Gloeckler, G.↗
NASA NTRS1981

Simulation of large motions of nonuniform beams in orbit. I - The cantilever beam

An algorithm is developed for producing numerical simulations of large motions of a nonuniform cantilever beam in orbit. Special emphasis is given to the effective formulation of equations of motion and to the use of the finite element method to construct modal functions. Finite element methods are used to generate modal functions in such a way as to permit a particularly harmonious relationship to be established between the disciplines of rigid body dynamics and structural analysis. Sufficient information is provided to enable a reader to create, with relatively little effort, his own simulation program; simulation results are reported, both to provide check cases for other investigators and to illustrate certain important facets of the behavior of flexible spacecraft.

Levinson, D. A.↗
NASA NTRS1983

The NASTRAN user's manual

All information directly associated with problem solving using the NASTRAN program is presented. This structural analysis program uses the finite element approach to structural modeling wherein the distributed finite properties of a structure are represented by a finite element of structural elements which are interconnected at a finite number of grid points, to which loads are applied and for which displacements are calculated. Procedures are described for defining and loading a structural model. Functional references for every card used for structural modeling, the NASTRAN data deck and control cards, problem solution sequences (rigid formats), using the plotting capability, writing a direct matrix abstraction program, and diagnostic messages are explained. A dictionary of mnemonics, acronyms, phrases, and other commonly used NASTRAN terms is included.

Source record↗
NASA NTRS1995

Pressure correlations at a fluid/structure interface

The structure of pressure-pressure correlations at the interface of an incompressible steady-state turbulent flow with a rigid boundary was investigated. For the sake of completeness, the absolute value of the correlation between two random varying functions is herein defined as a number greater than or equal to zero and less than or equal to unity which is a measure of that fraction of one of the functions that 'follows' the second function (or vice versa). It was found that the soughtafter correlations can be determined by consideration of the high Re Navier-Stokes equation, but that the complexity of boundary layer turbulence, in particular the inhomogeneity perpendicular to the boundary and the anisotropy due to convective flow gradients, makes the structure of said correlations extremely difficult to assess. One of the earlier researchers in this field described the quantity under present consideration as 'a quantity which is beyond assessment.' Nonetheless, it was found that under some rather simplifying assumptions the determination of the required structure necessitates the formulation of the related structure of second order two-point correlations of turbulent velocity gradients, as well as third order two-point correlations of velocity gradients. The presence of these latter gradients is due to the nonlinearity in the turbulence ('turbulence self-interaction'). Both of these correlations are scaled, although not similarly, by factors dependent upon the magnitude of the convective flow, which can be modeled using a log law approximation. Fourth order correlations, although present, can be ignored, since they constitute 'higher order terms.' In a slightly more complex situation, it was found that convective flow gradients also have to be incorporated. At the moment, no definitive algebraic information peculiar to pressure-pressure correlations is available in the most highly idealized cases.

Trevino, George↗
DOE OSTI2018

The helix-to-sheet transition of an HIV-1 fusion peptide derivative changes the mechanical properties of lipid bilayer membranes

Here, a short sequence on the gp41 envelope protein of HIV-1 is integral to infection by the virus. Without this sequence, termed the fusion peptide (FP), the virus is far less effective at fusing with the cellular membrane. One of the interesting features of the isolated FP is that it transitions between an α-helical conformation and a β-sheet conformation in lipid bilayer membranes as a function of lipid composition and concentration, and the transition correlates with fusion. To better understand how the conformations of the FP impact lipid bilayer membranes, a variant of the FP that does not strongly promote fusion, termed gp41rk, was studied. Circular dichroism spectroscopy, dynamic light scattering, small-angle neutron scattering (SANS) and neutron spin echo spectroscopy (NSE) were used to relate the conformation of gp41rk to the structure and mechanical properties of lipid bilayer membrane vesicles composed of a 7:3 molar ratio mixture of 1,2-dimyristoyl- sn -glycero-3-phosphocholine and 1,2-dimyristoyl- sn -glycero-3-phospho-(1'-rac-glycerol). At a peptide-to-lipid ratio (P/L) of 1/200, it adopts an α-helical conformation, while gp41rk is a β-sheet at a P/L of 1/50 in the unilamellar vesicles. SANS reveals that the lipid bilayer membrane becomes thicker when gp41rk adopts a β-sheet conformation, which indicates that the high-concentration state of the peptide increases the order of the lipid acyl chains. At the same time, NSE demonstrates that the bilayer becomes more rigid, demonstrating that the β-sheet conformation, which correlates with fusion for the native FP sequence, stiffens the bilayer. The results have implications for the function of the FP.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2022

Robust chain aggregation of low-entropy rigid ladder polymers in solution

Conjugated polymers have been widely investigated where ladder-type conjugated polymers receive more attention due to their rigid backbones and extraordinary properties. However, the understanding of how the rigid conformation of ladder polymers translates to material properties is still limited. Here, we systematically investigated the solution aggregation properties of a carbazole-derived conjugated ladder polymer (LP) and its analogous non-ladder control polymer (CP) via light scattering, neutron scattering, and UV-vis absorption spectroscopy characterization techniques, revealing a highly robust, temperature-insensitive aggregation behavior of the LP. The experimental findings were further validated by computational molecular dynamics simulations. Here we found that the peak positions and intensities of the UV spectra of the LP remained constant between 20 °C and 120 °C in chlorobenzene solution. The polymer also showed a stable hydrodynamic radius measured by dynamic light scattering from 20 °C to 70 °C in the chlorobenzene solution. Using small-angle neutron scattering, no Guinier region was reached in the measured q range down to 0.008 Å –1 , even at elevated temperature. In contrast, the non-ladder control polymer CP was fully soluble in the chlorobenzene solvent without the observation of any notable aggregates. The Brownian dynamics simulation showed that during polymer aggregation, the entropy change of the LP was significantly less negative than that of the non-ladder control polymer. These findings revealed the low entropy nature of rigid conjugated ladder polymers and the low entropy penalty for their aggregation, which is promising for highly robust intermolecular interactions at high temperatures. Such a unique thermodynamic feature of rigid ladder polymers can be leveraged in the design and application of next-generation electronic and optoelectronic devices that function under unconventional high temperature conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Quantum magnetism of iron-based ladders: Blocks, spirals, and spin flux

Motivated by increasing experimental evidence of exotic magnetism in low-dimensional iron-based materials, we present a comprehensive theoretical analysis of magnetic states of the multiorbital Hubbard ladder in the orbital-selective Mott phase (OSMP). Here, the model we used is relevant for iron-based compounds of the AFe 2 X 3 family (where A=Cs, Rb, Ba, K are alkali metals and X=S, Se are chalcogenides). To reduce computational effort, and obtain almost exact numerical results in the ladder geometry, we utilize a low-energy description of the Hubbard model in the OSMP—the generalized Kondo-Heisenberg Hamiltonian. Our main result is the doping vs interaction magnetic phase diagram. We reproduce the experimental findings on the AFe 2 X 3 materials, especially the exotic block magnetism of BaFe 2 Se 3 (antiferromagnetically coupled 2×2 ferromagnetic islands of the ↑↑↓↓ form). As in recent studies of the chain geometry, we also unveil block magnetism beyond the 2×2 pattern (with block sizes varying as a function of the electron doping) and also an interaction-induced frustrated block-spiral state (a spiral order of rigidly rotating ferromagnetic islands). Moreover, we predict new phases beyond the one-dimensional system: a robust regime of phase separation close to half filling, incommensurate antiferromagnetism for weak interaction, and a quantum spin-flux phase of staggered plaquette spin currents at intermediate doping. Finally, exploiting the bonding/antibonding band occupations, we provide an intuitive physical picture giving insight into the structure of the phase diagram.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

RMCProfile7 : reverse Monte Carlo for multiphase systems

This work introduces a completely rewritten version of the programRMCProfile(version 7), big-box, reverse Monte Carlo modelling software for analysis of total scattering data. The major new feature ofRMCProfile7is the ability to refine multiple phases simultaneously, which is relevant for many current research areas such as energy materials, catalysis and engineering. Other new features include improved support for molecular potentials and rigid-body refinements, as well as multiple different data sets. An empirical resolution correction and calculation of the pair distribution function as a back-Fourier transform are now also available.RMCProfile7is freely available for download at https://rmcprofile.ornl.gov/.

Chemistry↗