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At least 271 records · Page 15

Ice crystal growth in water vapor at high saturation

A simple technique is presented for estimating the energy of formation of monolayer icelike clusters at ice-vapor interfaces. Under the assumptions that the ice surfaces are smooth and sparsely covered with monomers, dimers, etc., in near equilibrium with the vapor, and that the bond energies and configurational entropy dominate the energy of formation, it is found that the basal surfaces prefer triangular embryos with an orientation which reverses from layer to layer, whereas the most stable clusters on the prism surfaces are rectangular in configuration. The preferred prism clusters are determined to have a significantly lower critical energy of formation than the basal clusters due to differences in both corner free energy and configurational entropy. This phenomenon provides a mechanism for strongly anisotropic crystal growth at high saturations.

Bartley, D. L.↗

Formation of fatty acids in photochemical conversions of saturated hydrocarbons

Abiogenic synthesis of fatty acids was studied in photochemical conversions of saturated hydrocarbons. It was shown that, in a hydrocarbon water CaCO3 suspension, the action of 254 nm UV rays caused the formation of fatty acids with a maximum number of carbon atoms in the chain not exceeding that in the initial hydrocarbon. Synthesis of acetic, propionic, butyric, valeric, caproic, enanthic and caprylic (in the case of octane) acids occurs in heptane water CaCO3 and octane water CaCO3 systems.

Telegina, T. A.↗

A saturation model of the atmosphere of Uranus

A model of the atmospheric structure of Uranus is presented which differs from previous types of models in two important respects: (1) the CH4/H2 ratio is sufficiently large that CH4 is saturated to large depths in the Uranian atmosphere and (2) the internal energy flux is small compared with that due to solar heating. Because of the small internal flux, the thermal flux decreases rapidly with depth and the atmosphere is radiative to large optical depths. A CH4 droplet cloud forms where the atmosphere finally becomes convective due to the internal flux. The model is shown to be in reasonable agreement with published observations of the H2 quadrupole 3-0 and 4-0 bands, the visible (4000-6000 A) CH4 bands, and the infrared emission spectrum.

Danielson, R. E.↗

Rise-time control in saturated amplifiers

Inductor in transistor emitter circuit controls output rise time of saturated amplifier thereby reducing radiated noise and distortion in subsequent circuits. Device also improves current balancing in push/pull transformer circuits. Resulting circuits are self compensating for temperature.

Theall, C. E.↗

Crystallization kinetics in a multiply saturated basalt magma - An experimental study of Luna 24 ferrobasalt

The paper deals with the effects of kinetics on mineral/melt partitioning and on fractional crystallization for a Luna-24 ferrobasalt. The composition is nearly multiply saturated under lunar surface conditions, making it possible to study the response of several mineral phases to kinetic factors during cooling. The differential suppression of the temperature of appearance of olivine, clinopyroxene, and plagioclase causes changes in the liquid line of descent. The course of liquid line of descent is mapped as a function of the cooling rate, and the partitioning of elements between pyroxene/liquid and olivine/liquid is examined.

Grove, T. L.↗

A thermochemical calculation of the pyroxene saturation surface in the system diopside-albite-anorthite

The pyroxene saturation surface in the system diopside-albite-anorthite may be calculated to + or - 10 C from thermochemical data over most of its composition range. The thermochemical data used are the experimentally determined enthalpies of mixing of the ternary liquids and the enthalpy of fusion of diopside. These are combined with a mixing model for the configurational entropy in the melt and the activity of CaMgSi2O6 in the clinopyroxene, which is less than unity due to departures from CaMgSi2O6 stoichiometry. The two-lattice melt model appears to work satisfactorily throughout the pyroxene primary phase field but probably needs modification at more anorthite-rich compositions.

Hon, R.↗

Saturation and energy-conversion efficiency of auroral kilometric radiation

A quasi-linear theory is used to study the saturation level of the auroral kilometric radiation. The investigation is based on the assumption that the emission is due to a cyclotron maser instability as suggested by Wu and Lee and Lee et al. The thermodynamic bound on the radiation energy is also estimated separately. The energy-conversion efficiency of the radiation process is discussed. The results are consistent with observations.

Wu, C. S.↗

Chaotic /strange/ and periodic behavior in instability saturation by the oscillating two-stream instability

The nonlinear Schroedinger equation with linear growth and damping is truncated to three waves. The resulting system of nonlinear ordinary differential equations describes the excitation of linearly damped waves by the oscillating two-stream instability driven by a linearly unstable pump wave. This system represents a simple model for the nonlinear saturation of a linearly unstable wave. The model is examined analytically and numerically as a function of the dimensionless parameters of the system. It is found that the model can exhibit a wealth of characteristic dynamical behavior including stationary equilibria, Hopf bifurcations to periodic orbits, period doubling bifurcations, chaotic solutions characteristic of a strange attractor, tangent bifurcations from chaotic to periodic solutions, transient chaos, and hysteresis. Many of these features are shown to be explainable on the basis of one-dimensional maps. In the case of chaotic solutions, evidence for the presence of a strange attractor is provided by demonstrating Cantor set-like structure (i.e., scale invariance) in the surface of section.

Russell, D. A.↗

Nonlinear saturation spectra of electric fields and density fluctuations in drift wave turbulence

The detection of drift waves in the nonlinear evolution of a space plasma process driven at long wavelengths is considered, adducing measurements of the electric field and density fluctuation power spectra as evidence. Since the driving mechanism is clearly at long wavelengths, the detection of drift waves suggests that they may play an important role in the transfer of wave energy from long to short wavelengths in a low beta plasma. The saturated spectral density is compared with theoretical results in order to estimate the anomalous diffusion rate. The observed spectral form and amplitude is in excellent agreement with drift wave predictions.

Kelley, M. C.↗

High-intensity sound in air saturated fibrous bulk porous materials

The interaction high-intensity sound with bulk porous materials in porous materials including Kevlar 29 is reported. The nonlinear behavior of the materials was described by dc flow resistivity tests. Then acoustic propagation and reflection were measured and small signal broadband measurements of phase speed and attenuation were carried out. High-intensity tests were made with 1, 2, and 3 kHz tone bursts to measure harmonic generation and extra attenuation of the fundamental. Small signal standing wave tests measured impedence between 0.1 and 3.5 kHz. High level tests with single cycle tone bursts at 1 to 4 kHz show that impedance increases with intensity. A theoretical analysis is presented for high-porosity, rigid-frame, isothermal materials. One dimensional equations of motion are derived and solved by perturbation. The experiments show that there is excess attenuation of the fundamental component and in some cases a close approach to saturation. A separate theoretical model, developed to explain the excess attenuation, yields predictions that are in good agreement with the measurements. Impedance and attenuation at high intensities are modeled.

Kuntz, H. L., II↗

Hue-saturation-intensity split-spectrum processing of Seasat radar imagery

Characteristics of terrain features in orbital radar imagery are investigated on the basis of radar physics and the human visual system. Signal scattering, the dominant factor in radar imagery, is caused by look angle and relief displacement. Power spectra characteristics are explored, noting that surface scattering dominates the low frequencies and slope significantly affects the high frequency tone variations. The maximum human visual response has been identified for achromatic scenes as 7 cycles per degree, whereas in radar imagery the low frequency half-power point occurs near 2.5 cycles/deg. Image feature size at a scale of 1:500,000 has been calculated for the maximum human response at 1.25 km. A hue-saturation-intensity transformation is presented for displaying two or three data sets on the same image and is demonstrated for Seasat SAR imagery. The transformation is shown to restore low spatial frequencies to the SAR imagery in order to identify terrain features which would otherwise not be visually discernible.

Daily, M.↗

Saturated laser fluorescence in turbulent sooting flames at high pressure

The primary objective was to develop a quantitative, single pulse, laser-saturated fluorescence (LSF) technique for measurement of radical species concentrations in practical flames. The species of immediate interest was the hydroxyl radical. Measurements were made in both turbulent premixed diffusion flames at pressures between 1 and 20 atm. Interferences from Mie scattering were assessed by doping with particles or by controlling soot loading through variation of equivalence ratio and fuel type. The efficacy of the LSF method at high pressure was addressed by comparing fluorescence and adsorption measurements in a premixed, laminar flat flame at 1-20 atm. Signal-averaging over many laser shots is sufficient to determine the local concentration of radical species in laminar flames. However, for turbulent flames, single pulse measurements are more appropriate since a statistically significant number of laser pulses is needed to determine the probability function (PDF). PDFs can be analyzed to give true average properties and true local kinetics in turbulent, chemically reactive flows.

King, G. B.↗

Does saturation cratering exist in the solar system?

A number of researchers have concluded that saturation equilibrium cratering exists nowhere in the solar system, and therefore that diameter distributions in even the most heavily cratered provinces reveal initial production functions related to impacting bodies. Based on this premise, different populations of impactors are identified in different epochs and regions of the solar system. These hypotheses are clearly crucial to interpreting planetary history and need further independent examination. The production function in the outer solar system may differ from that in the inner solar system, but it is also possible that viscous relaxation of ice craters or immediate flooding of craters that penetrate through an ice lithosphere into watery substrate may explain the greater deficiency of large craters on icy moons. This problem is controversial and needs more study.

Hartmann, W. K.↗

An investigation of chemically-induced improvement in saturation moisture characteristics of epoxies

MY-720/DDS epoxy samples were treated with three selected chemical compounds to render the active H-sites inactive for moisture absorption. Treating the epoxy castings with acetyl chloride and dichlorodimethyl silane leads only to surface changes indicating that these molecules are too large to penetrate the epoxy castings. Boron trifluoride, on the other hand, does penetrate the epoxy chain as is indicated by the formation of green domains in the interior of the castings. However, the process of saturating the specimens with moisture appears to leach out the chemical additives--thereby nullifying their possible ameliorative effects.

Singh, J. J.↗

Single-pulse, laser-saturated fluorescence measurements of OH in turbulent nonpremixed flames

A single-pulse, laser-saturated fluorescence technique has been developed for absolute OH concentration measurements with a temporal resolution of 2 nsec, a spatial resolution of less than 0.1 cu mm, and an estimated accuracy of + or - 30 percent. It has been applied in laminar, transitional, and turbulent hydrogen-air diffusion flames, providing the first reported quantitative measurements of average values, rms fluctuations, and probability-density functions of OH-radical concentration in nonpremixed flames.

Lucht, R. P.↗

The core-saturation method with partial redistribution

The core-saturation technique for calculating the radiation field in spectral lines (Rybicki, 1971) is extended to cases where partial redistribution is important. The frequency space is discretized and a general vector equation relating the source function S to the mean intensities is derived. The components of S are then used in a lambda iteration to determine the specific intensities. Numerical tests show that the efficiency and accuracy of this method are maintained.

Stenholm, L. G.↗

On the linear approximation of gravity wave saturation in the mesosphere

Lindzen's model of gravity wave breaking is shown to be inconsistent with the process of convective adjustment and associated turbulent outbreak. The K-theory turbulent diffusion model used by Lindzen implies a spatially uniform turbulent field which is not in agreement with the fact that gravity wave saturation and the associated convection produce turbulence only in restricted zones. The Lindzen model may be corrected to some extent by taking the turbulent Prandtl number for a diffusion acting on the wave itself to be very large. The eddy diffusion coefficients computed by Lindzen then become a factor of 2 larger and eddy transports of heat and constituents by wave fields vanish to first order.

Chao, W. C.↗