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At least 271 records · Page 15

Sensitivity of Maize Yield in Smallholder Systems to Climate Scenarios in Semi-Arid Regions of West Africa: Accounting for Variability in Farm Management Practices

Climate change is estimated to exacerbate existing challenges faced by smallholder farmers in Sub-Sahara Africa. However, limited studies quantify the extent of variation in climate change impact under these systems at the local scale. The Decision Support System for Agro-technological Transfer (DSSAT) was used to quantify variation in climate change impacts on maize yield under current agricultural practices in semi-arid regions of Senegal (Nioro du Rip) and Ghana (Navrongo and Tamale). Multi-benchmark climate models (Mid-Century, 2040–2069 for two Representative Concentration Pathways, RCP4.5 and RCP8.5), and multiple soil and management information from agronomic surveys were used as input for DSSAT. The average impact of climate scenarios on grain yield among farms ranged between −9% and −39% across sites. Substantial variation in climate response exists across farms in the same farming zone with relative standard deviations from 8% to 117% at Nioro du Rip, 13% to 64% in Navrongo and 9% to 37% in Tamale across climate models. Variations in fertilizer application, planting dates and soil types explained the variation in the impact among farms. This study provides insight into the complexities of the impact of climate scenarios on maize yield and the need for better representation of heterogeneous farming systems for optimized outcomes in adaptation and resilience planning in smallholder systems.

Freduah, Bright S.↗

Systems and Implementation: Integrating Unmanned Aircraft Systems into Physical Protection Systems at Fixed Sites and During Transportation

Physical protection systems, and response forces in particular, are designed to prevent an adversary from successfully completing a malevolent act against a facility or transport operations. Timely detection and assessment of any potential adversary action against a target is an essential element of materials security. The timely detection and assessment must then be followed-up by a capable and timely response that might be enhanced with the additional situational awareness provided by unmanned aircraft systems (UAS). The United States Department of Energy’s National Nuclear Security Administration Office of International Nuclear Security has been exploring capabilities provided by UAS to support response force operations within the physical protection system. UAS have the potential to provide response force commanders and operators with situational awareness in assessing adversary locations and actions as well as the locations of responders. UAS may be utilized for area searches ahead of responder pathways to identify potential threats and to provide situational awareness of areas not normally covered by cameras (such as areas outside the fence line outside at fixed facilities). In addition, UAS can provide real-time information to transportation convoy teams that pass through constantly changing public access environments. This paper will provide operational recommendations to be addressed when integrating UAS into existing physical protection systems at fixed sites and during transport. Recommendations will include aspects of the following: needs analysis; tactics and techniques to support detection and assessment as well as response force deployment; remote pilot selection, qualifications, training, and currency; UAS selection criteria; UAS laws and regulations; possible cost sharing with other facility operations; and on-scene emergency management.

Stockwell, Brandon↗

Engineering evaluation of 24 channel multispectral scanner

The results of flight tests to evaluate the performance of the 24 channel multispectral scanner are reported. The flight plan and test site are described along with the time response and channel registration. The gain and offset drift, and moire patterns are discussed. Aerial photographs of the test site are included.

Lambeck, P. F.↗

Microwave radiometer experiment of soil moisture sensing at BARC test site during summer 1981

Soil moisture was measured by truck mounted microwave radiometers at the frequencies of 1.4 GHz, 5 GHz, and 10.7 GHz. The soil textures in the two test sites were different so that the soil type effect of microwave radiometric response could be studied. Several fields in each test site were prepared with different surface roughnesses and vegetation covers. Ground truth on the soil moisture, temperature, and the biomass of the vegetation was acquired in support of the microwave radiometric measurements. Soil bulk density for each of the fields in both test sites was sampled. The soils in both sites were measured mechanically and chemically. A tabulation of the measured data is presented and the sensors and operational problems associated with the measurements are discussed.

Wang, J.↗

Analysis of short‐ and long‐term system response during gas production from a gas hydrate deposit at the UBGH2‐6 site of the Ulleung Basin in the Korean East Sea

Abstract This study is a continuation of an investigation into the feasibility of long‐term production from a marine hydrate accumulation that has the properties and conditions of the UBGH2‐6 (UBGH2, Ulleung Basin Gas Hydrates 2; 2 is the number of the scientific expedition) site at the Ulleung Basin in the Korean East Sea. The 12.7 m‐thick system is in deep water (2157 m), but at 140 m below the seafloor. It is characterized by alternating hydrate‐free clays and muds and hydrate‐rich sand layers. The layered stratigraphy and the presence of mud layers favours the use of vertical wells rather than horizontal wells for production. The analysis indicates that production from such a hydrate accumulation is technically feasible, but the gas production rates are generally low. Water production accompanying gas production from this deposit appears manageable under all the scenarios investigated in this study, however, the water‐to‐gas ratio is high. Subsidence at the ocean floor at the end of a 14 day test is quite limited. However, there is significant uncertainty in the predictions of the geomechanical system's behaviour because they are not based on measured system properties but only on estimates/assumptions from analogues. The long‐term production potential of the reservoir at the site investigated here appears challenging because of the limited effectiveness of dissociation and large water production, in addition to substantial subsidence.

Moridis, George J.↗

Role of Boreal Vegetation in Controlling Ecosystem Processes and Feedbacks to Climate

In the field, dark respiration rates are greatest in cores from more northerly locations. This is due in part to greater amounts of dwarf shrub biomass in the more northerly cores, but also to differences in soil organic matter quality. Laboratory incubations of these soils under common conditions show some evidence for greater pools of available carbon in soils from more northerly tundra sites, although the most northerly site does not fit this pattern for reasons which are unclear at this time. While field measurements of cores transplanted among different vegetation types at the same location (Toolik Lake) show relatively small differences in whole ecosystem carbon flux, laboratory incubation of these same soils shows that there are large differences in soil respiration rates under common conditions. This is presumably due to differences in organic matter quality. Microenvironmental site factors (temperature, soil moisture, degree of anaerobiosis, etc.) may be responsible for evening out these differences in the field. These site factors, which differ with slope, aspect, and drainage within a given location along the latitudinal gradient, appear to exert at least as strong a control over carbon fluxes as do macroclimatic factors among sites across the latitudinal gradient. While our field measurements indicate that, in the short term, warming will tend to increase ecosystem losses Of CO2 via respiration more than they will increase plant gross assimilation, the degree to which different topographically-defined plant communities will respond is likely to vary.

Chapin, F. S., III↗

Pantex Plant Ogallala Aquifer and Perched Groundwater Contingency Plan

The Pantex Plant Ogallala Aquifer and Perched Groundwater Contingency Plan has been developed in accordance with the requirements identified in the: • Interagency Agreement for the Pantex Superfund Site, Article 8.5 Work to be Performed, • Compliance Plan Provision of Hazardous Waste Permit No. 50284, and • Record of Decision for Groundwater, Soil, and Associated Media, Pantex Plant. A Long‐Term Monitoring System Design has been designed to monitor conditions in the perched groundwater including changes in the perched aquifer as a result of implementing the response actions. Monitoring is required for verifying the effectiveness of perched groundwater response actions (i.e., conditions in the perched aquifer are being affected as intended) and for confirming that the perched aquifer and Ogallala Aquifer characterization as defined in the Resource Conservation and Recovery Act Facility Investigation Report and the Corrective Measure Studies/Feasibility Study remains accurate. If monitoring results obtained through the monitoring network identify an unexpected condition or deviation, contingent actions will be considered and implemented as necessary to ensure continued protection of the Ogallala Aquifer and human health and the environment. Potential deviations to expected technology performance may be encountered for each of the four primary response actions that compose the selected remedy for perched groundwater; Playa 1 Pump and Treat System, Southeast Area Pump and Treat System, Southeast Area In‐Situ Bioremediation System (comprised of the Southeast In‐Situ Bioremediation System Original System, Southeast Area In‐Situ Bioremediation System Extension System, Offsite In‐Situ Bioremediation System, Perchlorate/Chromium ISB, Northeast ISB and County Road 8 ISB), and Zone 11 In‐Situ Bioremediation System. Monitoring will also be conducted to determine if there are deviations to the expected characterization, e.g., contaminants not expected as a result of the RCRA Facility Investigation characterization. Deviations to expected conditions in the Ogallala Aquifer could also be encountered if the response actions in the perched groundwater are not performing as expected, i.e., preventing contaminants from migrating to the Ogallala Aquifer. Currently, Pantex has begun investigation of detections of high explosives above groundwater protection standards in wells on the Texas Tech University property and a plume that is moving to the northeast from that area. Due to those detections, this Plan recognizes the fact that future detections in the Ogallala will be focused on first‐ time detections of analytes. After a remedy is determined, this Plan will require modification to address-deviations and contingent actions. This Plan was developed to identify the contingent actions necessary to mitigate impacts resulting from deviations to site conditions or response action performance. The Plan defines the environmental problem being addressed by the response actions, clarifies the expected conditions and objectives of the response actions, and identifies the potential deviations to the response actions (due to site conditions or technology performance) that could be encountered. The deviations were evaluated to determine the likelihood of occurrence, potential impact, and time to respond to avoid impact. The Plan also identifies the monitoring outlined in the Long‐Term Monitoring System Design Report (Consolidated Nuclear Security, 2024) and Sampling Analysis Plan (PanTeXas Deterrence, 2024) that will be used to detect the deviations. Lastly, the Plan specifies the contingent actions that could be implemented in response to the deviations. Because each response focuses on a discrete portion of the perched aquifer and contaminant plume, each response action has a different set of expected conditions, and therefore differing impacts from deviations to the site and technology expectations. As a result, the contingent actions are identified for each response action and potential deviation including specific constituents, location, and conditions. If deviations are encountered that impact the ability of the response action to meet performance objectives, the contingent actions will be focused on ensuring the response action can meet the performance objective. Contingent actions may be implemented as interim actions (ISMs/removal actions) in accordance with the Record of Decision, Interagency Agreement, and Hazardous Waste Permit‐50284, if warranted by the specific circumstances. For deviations to site characterization expected conditions, the contingent action will focus on determination of the source of the deviation, determination of the appropriate response, and evaluation of additional work to be completed. However, if the deviation to characterization impacts the performance of the response action, the contingent action will again focus on ensuring performance objectives can be met. Early source term removals and cleanup actions have been implemented to protect the Ogallala Aquifer. Because of these actions and based on modeling results, the expected conditions in the Ogallala Aquifer are that constituents of concern will not be detected above the Groundwater Protection Standards (GWPSs) nor will they reach potential points of exposure above the GWPS. The primary deviation of concern for the Ogallala is if constituents are detected in the Ogallala Aquifer near or above GWPSs. If it occurs, this change in expected conditions would require further evaluation of site and contaminant characteristics to determine an appropriate course of action. The evaluation would include additional monitoring, source identification, implementation of interim protective measures (if necessary), and delineation of extent. These evaluations are necessary to determine an appropriate response action for the Ogallala. The primary goal of the Plan is to provide for the continued protection of the Ogallala Aquifer and the health of its consumers. In recognition, this Plan presents a flexible and rational approach for making future decisions associated with confirming the change in perched and Ogallala aquifer conditions and identifying a response (technical activities, changes to response actions, regulatory oversight, and public involvement).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Dynamic Profiling of β-Coronavirus 3CL Mpro Protease Ligand-Binding Sites

β-coronavirus (CoVs) alone has been responsible for three major global outbreaks in the 21st century. The current crisis has led to an urgent requirement to develop therapeutics. Even though a number of vaccines are available, alternative strategies targeting essential viral components are required as a backup against the emergence of lethal viral variants. One such target is the main protease (Mpro) that plays an indispensable role in viral replication. The availability of over 270 Mpro X-ray structures in complex with inhibitors provides unique insights into ligand–protein interactions. Herein, we provide a comprehensive comparison of all nonredundant ligand-binding sites available for SARS-CoV2, SARS-CoV, and MERS-CoV Mpro. Extensive adaptive sampling has been used to investigate structural conservation of ligand-binding sites using Markov state models (MSMs) and compare conformational dynamics employing convolutional variational auto-encoder-based deep learning. Our results indicate that not all ligand-binding sites are dynamically conserved despite high sequence and structural conservation across β-CoV homologs. This highlights the complexity in targeting all three Mpro enzymes with a single pan inhibitor.

59 BASIC BIOLOGICAL SCIENCES↗

Lunar laser ranging data processing in a Unix/X windows environment

In cooperation with the NASA Crustal Dynamics Project initiative placing workstation computers at each of its laser ranging stations to handle data filtering and normalpointing, MLRS personnel have developed a new generation of software to provide the same services for the lunar laser ranging data type. The Unix operating system and X windows/Motif provides an environment for both batch and interactive filtering and normalpointing as well as prediction calculations. The goal is to provide a transportable and maintainable data reduction environment. This software and some sample displays are presented. that the lunar (or satellite) datacould be processed on one computer while data was taken on the other. The reduction of the data was totally interactive and in no way automated. In addition, lunar predictions were produced on-site, another first in the effort to down-size historically mainframe-based applications. Extraction of earth rotation parameters was at one time attempted on site in near-realtime. In 1988, the Crustal Dynamics Project SLR Computer Panel mandated the installation of Hewlett-Packard 9000/360 Unix workstations at each NASA-operated laser ranging station to relieve the aging controller computers of much of their data and communications handling responsibility and to provide on-site data filtering and normal pointing for a growing list of artificial satellite targets. This was seen by MLRS staff as an opportunity to provide a better lunar data processing environment as well.

Ricklefs, Randall L.↗

Exploring the role of biotic factors in regulating the spatial variability in land surface phenology across four temperate forest sites

Here, land surface phenology (LSP), the characterization of plant phenology with satellite data, is essential for understanding the effects of climate change on ecosystem functions. Considerable LSP variation is observed within local landscapes, and the role of biotic factors in regulating such variation remains underexplored. In this study, we selected four National Ecological Observatory Network terrestrial sites with minor topographic relief to investigate how biotic factors regulate intra-site LSP variability. We utilized plant functional type (PFT) maps, functional traits, and LSP data to assess the explanatory power of biotic factors for the start and end of season (SOS and EOS) variability. Our results indicate that PFTs alone explain only 0.8–23.4% of intra-site SOS and EOS variation, whereas including functional traits significantly improves explanatory power, with cross-validation correlations ranging from 0.50 to 0.85. While functional traits exhibited diverse effects on SOS and EOS across different sites, traits related to competitive ability and productivity were important for explaining both SOS and EOS variation at these sites. These findings reveal that plants exhibit diverse phenological responses to comparable environmental conditions, and functional traits significantly contribute to intra-site LSP variability, highlighting the importance of intrinsic biotic properties in regulating plant phenology.

60 APPLIED LIFE SCIENCES↗

A Virtual Collaborative Environment for Mars Surveyor Landing Site Studies

Over the past year and a half, the Center for Mars Exploration (CMEX) at NASA Ames Research Center (ARC) has been working with the Mars Surveyor Project Office at JPL to promote interactions among the planetary community and to coordinate landing site activities for the Mars Surveyor Project Office. To date, CMEX has been responsible for organizing the first two Mars Surveyor Landing Site workshops, web-archiving resulting information from these workshops, aiding in science evaluations of candidate landing sites, and serving as a liaison between the community and the Project. Most recently, CMEX has also been working with information technologists at Ames to develop a state-of-the-art collaborative web site environment to foster interaction of interested members of the planetary community with the Mars Surveyor Program and the Project Office. The web site will continue to evolve over the next several years as new tools and features are added to support the ongoing Mars Surveyor missions.

Gulick, V.C.↗

A Virtual Collaborative Environment for Mars Surveyor Landing Site Studies

Over the past year and a half, the Center for Mars Exploration (CMEX) at NASA Ames Research Center (ARC) has been working with the Mars Surveyor Project Office at JPL to promote interactions among the planetary community and to coordinate landing site activities for the Mars Surveyor Project Office. To date, CMEX has been responsible for organizing the first two Mars Surveyor Landing Site workshops, web-archiving resulting information from these workshops, aiding in science evaluations of candidate landing sites, and serving as a liaison between the community and the Project. Most recently, CMEX has also been working with information technologists at Ames to develop a state-of-the-art collaborative web site environment to foster interaction of interested members of the planetary community with the Mars Surveyor Program and the Project Office. The web site will continue to evolve over the next several years as new tools and features are added to support the ongoing Mars Surveyor missions.

Gulick, V. C.↗

Opportunities to Implement Solutions to Achieve Remedial Action Objectives in Consideration of Stakeholder Interests - 20365

A case study in the implementation of a soils excavation and removal project conducted at a Formerly Utilized Sites Remedial Action Program (FUSRAP) Maywood Superfund Site (FMSS) vicinity property; an active commercial business, in a densely populated area, with significant operational, technical and, logistical constraints that were expected to limit areas that could be remediated. The United States Army Corps of Engineers-led (USACE) team successfully navigated complex overlapping stakeholder interests to achieve a more efficient and complete removal of contaminated soils and debris while minimizing unnecessary excess costs to the Government. This paper centers on FUSRAP activities at the FMSS vicinity property located at 149-151 Maywood Avenue, Maywood, Bergen County, New Jersey. For most of its FUSRAP history, this ∼109,000 square meter (27-acre) property housed a now-demolished ∼26,000 square meter (6.5-acre) warehouse operated by Sears Logistics Services, a unit of the Sears Roebuck Company (Figure 2). Sears ended its property lease and vacated the warehouse in December 2016. Given that long history and for the purposes of this paper, the property will be referred to as the 'Sears property' or simply 'the property.' The Sears property is approximately 109,000 square meters (27-acres) and is currently zoned for commercial use. The property is bound to the north and northwest by 100 West Hunter Avenue (the Stepan Company), to the northeast by 205 Maywood Avenue, to the east by Maywood Avenue, to the south by 23 West Howcroft Road, and to the west by businesses on NJ Route 17 and the NJ Route 17 roadway. Until December 2016, the property housed a warehouse and distribution center operated by Sears Logistical Services. On-site structures were demolished by the property owner in 2017. The warehouse covered the north section of the property along the Stepan Company property line. A railroad spur from the adjacent property now known as the Maywood Interim Storage Site (MISS) ended at the northeast corner of the warehouse. Wetlands were located east of the warehouse; the rest of the property was covered with paved parking lots and grassed areas. During remediation at the property, opportunities frequently arose where the project team was able to coordinate effectively with stakeholders to sequence remediation activities to facilitate removal of otherwise inaccessible soils and identify opportunities for materials reuse when supported by residual radiological and chemical levels. Some specific opportunities include: - remediating individual truck loading dock bays to maintain tenant operations; - working along a busy highway and in a utility corridor containing a 30-inch high pressure gas main; - remediating Lodi Brook and associated wetlands requiring bypass pumping and other diversionary structures to maintain local community stormwater drainage; - protecting during remediation and supporting access to facilitate tenant/owner maintenance of critical fire protection and water supply system service lines buried in contaminated soils and necessary for safe warehouse operations; and - coordinating with stakeholders to ensure non-radiological contaminants of concern for the site (unaffiliated with FUSRAP) were addressed by the responsible party in a manner that maximized benefit to all parties while supporting an efficient overall site remediation program. Once the property was vacant and the warehouse structure and radiologically non-impacted above-grade structures were demolished, the project identified an opportunity to significantly reduce the volume of waste associated with the foundation of the former warehouse, a foundation suspected of being partially constructed in radiologically contaminated soils. The project developed and implemented supplemental radiological verification survey and sampling strategies based on radiological cross-contamination risk potential with process flow-charts and screening-level based decision points; a program that classified saw-cut sections of concrete based on observed residual surface radioactivity conditions using a combination of gamma sensitive sodium-iodide scans and beta sensitive Geiger-Muller direct measurements. The proposed approach was reviewed with stakeholders with feedback, including consideration of applicable State of New Jersey Site Remediation Program criteria and guidance before implementation. Once classified, additional sampling was performed at frequencies driven by screening. The sampling methods, stockpile sampling frequencies, criteria and, approach to data evaluation were developed in consideration of existing site cleanup standards, regional background ranges, State of New Jersey radiological remediation program guidance, and specific stakeholder input With the property remediation and survey efforts nearly completed, it is relevant to examine retrospectively the objectives, assumptions and limitations in the remedial design (i.e., what was planned) versus what was able to be accomplished through effective teaming. Benefits to other environmental remediation site programs include better understanding of how to work effectively with stakeholders to achieve win-win outcomes, and approaches to site remediation, waste minimization and materials reuse that were successful in their overall outcomes. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

MODIS Reflective Solar Band Calibration Improvements using Pseudo-Invariant Desert Targets

To provide the best science data quality, an accurate characterization of the response versus scan angle (RVS) function is critical for the MODIS reflective solar bands (RSB) on-orbit calibration. In every MODIS operational scan, the Earth’s surface, referred to here as Earth view (EV), the space view (SV) port, and the onboard calibrators are viewed via a two-sided scan mirror. The RVS is defined as the sensor’s relative response as a function the angle of incidence (AOI) to the scan mirror. Many different approaches have been developed to derive the time-dependent RVS and its look-up table (LUT) applied to MODIS Level 1B (L1B) products since calibration Collection 4. For most MODIS RSB, the on-board calibrators can reasonably track the RVS change with time. In practice, their RVS is derived using data from on-board calibrators and the EV mirror side ratio (for mirror side 2). For Terra bands 1-4, 8-10 and Aqua bands 1-4, 8-9, an enhancement has been employed in Collections 6 and 6.1 (C6/C6.1) by using Earth scene response trending from pseudo-invariant desert sites in addition to the onboard calibrators. The current C6/C6/1 RVS algorithm is focused on fitting the EV data at each AOI over time and then deriving the relative change at different AOI. The EV response trending is currently fitted with multiple segments over time. Alternatively, the EV responses can be fit first as a function of AOI before fitting temporally in order to reduce the dependence on the stability of the desert site. These pre-treatment methods on the EV data provide improvement in the derived calibration coefficients. However, evidence of insufficient calibration is still observed in the MODIS L1B reflectance data, especially in the form of differences between the mirror sides. In this paper, we review the current methodologies that utilize the EV response trends from the pseudo-invariant Libyan desert targets to supplement the gain derived from the onboard calibrators. An improvement is then proposed and investigated such that a sliding window average (SWA) is used to pre-process the raw EV data. The SWA parameters are carefully selected using trade-off studies to accurately track the Earth scene response trending in multiple cases to overcome the reflectance differences between two mirror sides. Calibration results show improvements for both Aqua and Terra MODIS RSB L1B data products. This new adjustment has been included in the recently delivered Collection 7 LUT that will be evident in the L1B products expected to be released in late 2021.

MODIS↗

Whose Gas is it anyway? Differentiating the Source of a Large Soil Vapor Plume beneath Two Adjacent Waste Sites - 20487

DOE contractor CH2M Hill Plateau Remediation Company is currently responsible for conducting groundwater contamination monitoring at several RCRA treatment, storage, and disposal units located on the Hanford Site in Richland, Washington State. The Nonradioactive Dangerous Waste Landfill treatment, storage, and disposal unit presents a distinct groundwater monitoring problem because of a large multi-contaminant soil vapor plume beneath it that is a likely source of low-level volatile organic compound groundwater contamination. Adjacent to Nonradioactive Dangerous Waste Landfill is the Solid Waste Landfill. Volatile organic compounds are inventory components of both the Nonradioactive Dangerous Waste Landfill and the Solid Waste Landfill. Therefore, it is possible that both sites could be contributing to the soil vapor plume. For regulatory purposes, it is important to differentiate which site is the primary contributor of volatile organic compounds to the plume. An approach was developed to identify the primary volatile organic compound source of the soil vapor plume beneath Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill. The site conceptual model hypothesis of vapor-phase volatile organic compound transport to the dissolved phase in groundwater was tested by a simple mathematical model of vapor/liquid equilibrium concentrations at the groundwater/air interface. Once it was shown that vapor-phase volatile organic compound transport to groundwater was a valid conceptual model for Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill, spatial and statistical methods were used to determine the primary site contributing to the majority of volatile organic compounds to the soil vapor plume. Average groundwater chloroform, tetrachloroethene, and trichloroethene concentrations from Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill monitoring network wells were plotted on maps of the facilities and immediate vicinities and compared to soil vapor sampling probe locations. Principal component analysis and mixing ratios were used to identify source contributions of each treatment, storage, and disposal unit to the plume. Results of the vapor/liquid equilibrium concentrations mathematical model showed that transport phenomena outweigh steady-state equilibria. Estimated vapor/liquid equilibrium concentrations were considerably lower than soil vapor measurements. The results indicate that dynamic vadose zone and groundwater factors such as decreased vapor concentrations with depth, vapor dilution from dispersion in the vadose zone, and advective and diffusional volatile organic compound dilution in groundwater result in groundwater volatile organic compound concentrations much less than would be measured under steady-state equilibrium conditions. Site source contribution differentiation by principal component analysis and mixing ratios was inconclusive using actual soil gas data because of the similarity in concentration values in both datasets for Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill. Similar data populations suggest mixing of the vapor contributions from both sites by dispersion through the soil matrix pore spaces. However, when groundwater volatile organic compound data were compared between the Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill monitoring networks, Solid Waste Landfill mean concentrations were higher, suggesting more vapor-phase volatile organic compound transport to groundwater at those locations. Simulated volatile organic compound soil vapor and groundwater datasets created to test the methods developed for this study show that the method can be successful in source differentiation when significantly different datasets are compared. This paper will describe a method of testing a conceptual model for vapor-phase contaminant transport to groundwater and for differentiating site sources of contaminants comprising a mixed-constituent soil vapor plume. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterizing Response Versus Scan-Angle for MODIS Reflective Solar Bands Using Deep Convective Clouds

MODIS consists of a cross-track, two-sided scan mirror, whose reflectance is not uniform but is a function of angle of incidence (AOI). This feature, known as response versusscan-angle (RVS), was characterized for all reflective solar bands of both MODIS instruments prior to launch. The RVS characteristic has changed on orbit, which must be tracked precisely over time to ensure the quality of MODIS products. The MODIS characterization support team utilizes the onboard calibrators and the earth view responses from multiple pseudo invariant desert sites to track the RVS changes at different AOIs. The drawback of using deserts is the assumption that these sites are radiometrically stable during the monitoring period. In addition, the 16-day orbit repeat cycle of MODIS allows for only a limited set of AOIs over a given desert. We propose a novel and robust approach of characterizing the MODIS RVS using tropical deep convective clouds (DCC). The method tracks the monthly DCC response at specified sets of AOIs to compute the temporal RVS changes. Initial results have shown that the Aqua-MODIS collection 6 band 1 level 1B radiances show considerable residual RVS dependencies, with long-term drifts up to 2.3 at certain AOIs.

Clouds↗

Response Versus Scan-Angle Corrections for MODIS Reflective Solar Bands Using Deep Convective Clouds

The absolute radiometric calibration of the reflective solar bands (RSBs) of Aqua- and Terra-MODIS is performed using on-board calibrators. A solar diffuser (SD) panel along with a solar diffuser stability monitor (SDSM) system, which tracks the performance of the SD over time, provides the absolute reference for calibrating the MODIS sensors. MODIS also views the moon and deep space through its space view (SV) port for lunar-based calibration and computing the zero input radiance, respectively. The MODIS instrument views the Earth's surface through a two-sided scan mirror, whose reflectance is a function of angle of incidence (AOI) and is described by response versus scan-angle (RVS). The RVS for both MODIS instruments was characterized prior to launch. MODIS also views the SD and the moon at two different assigned RVS positions. There is sufficient evidence that the RVS is changing on orbit over time and as a function of wavelength. The SD and lunar observation scans can only track the RVS variation at two RVS positions. Consequently, the MODIS Characterization Support Team (MCST) developed enhanced approaches that supplement the onboard calibrator measurements with responses from pseudo-invariant desert sites. This approach has been implemented in Level 1B (L1B) Collection 6 (C6) for selected short-wavelength bands. This paper presents an alternative approach of characterizing the mirror RVS to derive the time-dependent RVS correction factors for MODIS RSBs using tropical deep convective cloud (DCC) targets. An initial assessment of the DCC response from Aqua-MODIS band 1 C6 data indicates evidence of RVS artifacts, which are not uniform across the scans and are more prevalent in the left side Earth-view scans.

Bhatt, Rajendra↗

Response Versus Scan-Angle Corrections for MODIS Reflective Solar Bands Using Deep Convective Clouds

The absolute radiometric calibration of the reflective solar bands (RSBs) of Aqua- and Terra-MODIS is performed using on-board calibrators. A solar diffuser (SD) panel along with a solar diffuser stability monitor (SDSM) system, which tracks the performance of the SD over time, provides the absolute reference for calibrating the MODIS sensors. MODIS also views the moon and deep space through its space view (SV) port for lunar-based calibration and computing the zero input radiance, respectively. The MODIS instrument views the Earths surface through a two-sided scan mirror, whose reflectance is a function of angle of incidence (AOI) and is described by response versus scan-angle (RVS). The RVS for both MODIS instruments was characterized prior to launch. MODIS also views the SD and the moon at two different assigned RVS positions. There is sufficient evidence that the RVS is changing on orbit over time and as a function of wavelength. The SD and lunar observation scans can only track the RVS variation at two RVS positions. Consequently, the MODIS Characterization Support Team (MCST) developed enhanced approaches that supplement the onboard calibrator measurements with responses from pseudo-invariant desert sites. This approach has been implemented in Level 1B (L1B) Collection 6 (C6) for selected short-wavelength bands. This paper presents an alternative approach of characterizing the mirror RVS to derive the time-dependent RVS correction factors for MODIS RSBs using tropical deep convective cloud (DCC) targets. An initial assessment of the DCC response from Aqua-MODIS band 1 C6 data indicates evidence of RVS artifacts, which are not uniform across the scans and are more prevalent in the left side Earth-view scans.

Bhatt, Rajendra↗