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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

NIAC Project: 10 meter Sub-Orbital Large Balloon Reflector (LBR)

In Section 1 we summarize the technological approaches to the Large Balloon Reflector (LBR) that are discussed at length in our Phase I Technical report. Within each subsection we highlight how the work was advanced in Phase II. In Section 2 the work and lessons learned from the 3 and 5 meter LBR prototypes are described. In Section 3 the LBR Sensor Package stratospheric flight is described. Section 4 puts LBR in the context of on-going NASA missions.In Sections 5 and 6 the dissemination of results and plans to realize a stratospheric LBR are discussed. Instead of attempting to maintain the pointing of a large telescope at the end of a tether, we propose to deploy a telescope in the benign, protected environment within the carrier balloon. The telescope is itself a balloon, spherical in shape, metalized on one side and anchored to the top of the carrier balloon via a rotating azimuth plate (see Figure 2). The carrier balloon serves as both a stable mount and a radome for the inner balloon reflector. Light from space (or the atmosphere or ground) first passes through the ~2 mil thick polyethylene skin of the carrier balloon and then through the ~1 mil thickMylar side of the inner balloon. Together these layershave < 8% absorption at the wavelengths of interest.The incoming light then encounters the aluminized,spherical, back surface of the inner balloon and isthen focused into a receiving system. To achieve the performance of a 10 meter parabolic reflector, a 20 meter diameter inner balloon can be used with a modest size (~1 meter) spherical corrector.

Walker, Christopher↗
NASA NTRS2005

A Strategic Roadmap to Centauri

This paper discusses the connectivity between in-space propulsion and in-space fabrication/repair and is based upon a workshop presentation by Les Johnson, manager of the In-Space Propulsion (ISP) Technology Project at NASA's Marshall Space Flight Center (MSFC) in Huntsville, Ala.. Technologies under study by ISP include aerocapture, advanced solar-electric propulsion, solar-thermal propulsion, advanced chemical propulsion, tethers and solar-photon sails. These propulsion systems are all approaching technology readiness levels (TRLs) at which they can be considered for application in space-science and exploration missions. Historically, human frontiers have expanded as people have learned to live off the land in new environments and to exploit local resorces. With this expansion, frontier settlements have required development of transportation improvements to carry tools and manufactured products to and from the frontier. It is demonstrated how ISP technologies will assist in the development of the solar-system frontier. In-space fabrication and repair will both require and assist the development of ISP propulsion systems, whether humans choose to settle planetary surfaces or to exploit resources of small Solar System bodies. As was true for successful terrestrial pioneers, in-space settlement and exploitation will require sophisticated surveys of inner and outer Solar System objects. ISP technologies will contribute to the success of these surveys, as well as to the efforts to retrieve Solar System resources. In a similar fashion, the utility of ISP products will be greatly enhanced by the technologies of in-space repair and fabrication. As in-space propulsion, fabrication and repair develop, human civilization may expand well beyond the Earth. In the future, small human communities (preceded by robotic explorers) may utilize these techniques to set sail f or the nearest stars.

Johnson, Les↗
NASA NTRS2009

NASA Tech Briefs, August 2009

Topics covered include: Aligning a Receiving Antenna Array to Reduce Interference; Collecting Ground Samples for Balloon-Borne Instruments; Tethered Pyrotechnic Apparatus for Acquiring a Ground Sample; Enhanced Video-Oculography System; Joint Carrier-Phase Synchronization and LDPC Decoding; Dual-Polarization, Sideband-Separating, Balanced Receiver for 1.5 THz Modular Battery Charge Controller; Efficient Multiplexer FPGA Block Structures Based on G4FETs; VLSI Microsystem for Rapid Bioinformatic Pattern Recognition; Low-Noise Amplifier for 100 to 180 GHz; Improved Fabrication of Ceramic Matrix Composite/Foam Core Integrated Structures; Inert Welding/Brazing Gas Filters and Dryers; Fabricating Copper Nanotubes by Electrodeposition; Reducing Aerodynamic Drag on Empty Open Cargo Vehicles; Rotary Percussive Auto-Gopher for Deep Drilling and Sampling; More About Reconfigurable Exploratory Robotic Vehicles; Thermostatic Valves Containing Silicone-Oil Actuators; Improving Heat Flux Performance of Flat Surface in Spray-Cooling Systems; Treating Fibrous Insulation to Reduce Thermal Conductivity; Silica-Aerogel Composites Opacified with La(sub0.7)Sr(sub0.3)MnO3; Cyclic Oxidation Behavior of CuCrAl Cold-Sprayed Coatings for Reusable Launch Vehicles; Ceramic Fiber Structures for Cryogenic Load-Bearing Applications; Elastomer Reinforced with Carbon Nanotubes; Biologically Inspired Purification and Dispersion of SWCNTs; A Technique for Adjusting Eigenfrequencies of WGM Resonators; Low-Pressure, Field-Ionizing Mass Spectrometer; Modifying Operating Cycles to Increase Stability in a LITS; Chamber for Simulating Martian and Terrestrial Environments; Algorithm for Detecting a Bright Spot in an Image; Extreme Programming: Maestro Style; Adaptive Behavior for Mobile Robots; Protocol for Communication Networking for Formation Flying; Planning Complex Sequences Using Compressed Representations; and Self-Supervised Learning of Terrain Traversability from Proprioceptive Sensors.

Source record↗
DOE OSTI2024

NSA Site Science: Use of ARM Observations from Northern Alaska to Evaluate and Improve Prediction Capabilities

The Arctic is warming at a rate nearly double that of the rest of the planet, leading to profound changes in atmospheric, oceanic, and ice processes. The U.S. Department of Energy's (DOE) Atmospheric Radiation Measurement (ARM) user facility has played a significant role in Arctic research, operating observatories in Alaska's North Slope for over 25 years. These observatories provide a rich, and wide-reaching dataset that offers insight into atmospheric processes in northern Alaska. This report details the results of a nine-year research project (2015–2024) supported by the DOE Atmospheric Systems Research (ASR) program, that leverages data from ARM’s deployment of observing facilities at Utqiaġvik (known as the North Slope of Alaska, or NSA, site) and Oliktok Point, Alaska. The project was conducted in two phases: - Phase 1 (2015–2019): Focused on understanding key atmospheric processes at Oliktok Point, including cloud formation, high-latitude precipitation, aerosol-cloud interactions, and cloud properties. - Phase 2 (2019–2024): Extended the research to the broader North Slope region, using data from both Oliktok Point and Utqiaġvik. Topics explored included surface energy budgets, atmospheric stability, ice nucleation processes, and microphysics in Arctic clouds. The project resulted in numerous research products, including 50 peer-reviewed publications and dissertations, 169 presentations, and 10 data products. These products cover a variety of topics, including: - Cloud Macro- and Microphysical Properties: Arctic clouds play a crucial role in energy transfer, and accurate representation in models is critical. The study explored cloud transitions, ice crystal shapes, and dual-wavelength radar data to understand ice crystal habits and size distributions. - Aerosol Properties and Processes: The team examined aerosol sources in the Arctic, including industrial emissions and natural sources. Observations showed significant spatial gradients in aerosol concentrations due to human activities and wildfire smoke. The influence of aerosols on cloud formation and the surface energy budget was also assessed. - Aerosol-Cloud Interactions: Research revealed that aerosols might suppress cloud ice production, affecting cloud radiative forcing and precipitation. The impact of local industrial emissions on cloud properties was also investigated. - Contextualizing the North Slope of Alaska in the context of the broader Arctic: To understand broader trends, the project evaluated large-scale circulation patterns and the influence of weather systems on the Arctic. Studies indicated that large-scale processes play a significant role in temperature patterns and the timing of snowmelt. - Advancing ARM Observational and Modeling Capabilities: The project developed new radar data products and advanced measurement techniques, including clutter mitigation and drizzle detection. Uncrewed aerial systems (UAS) and tethered balloon systems (TBS) were deployed to gather detailed atmospheric data. Additionally, the project supported 10 early career scientists, providing training and mentorship to undergraduate interns, graduate students, postdoctoral researchers, and early career researchers. These efforts contributed to the advancement of ARM research capabilities and fostered a new generation of scientists skilled in Arctic atmospheric research. Ultimately, this ASR-supported project has provided valuable insights into Arctic atmospheric processes and their broader climate implications. Recommendations for future work include continuing support for long-term observing at Arctic locations to foster additional research, further exploration of aerosol-cloud interactions and the potential impacts of enhanced industrialization of the Arctic, and expanded use of uncrewed systems to gather data in this remote and harsh environment. Additionally, the data products developed by this work, and the data products developed through the ARM infrastructure, leave a treasure-trove of additional information that should be explored for many years to come to gain additional insight into physical processes in the Arctic atmosphere that drive the rapid changes occurring in at high latitudes and their global impact.

58 GEOSCIENCES↗
NASA NTRS2007

Crew/Robot Coordinated Planetary EVA Operations at a Lunar Base Analog Site

Under the direction of NASA's Exploration Technology Development Program, robots and space suited subjects from several NASA centers recently completed a very successful demonstration of coordinated activities indicative of base camp operations on the lunar surface. For these activities, NASA chose a site near Meteor Crater, Arizona close to where Apollo Astronauts previously trained. The main scenario demonstrated crew returning from a planetary EVA (extra-vehicular activity) to a temporary base camp and entering a pressurized rover compartment while robots performed tasks in preparation for the next EVA. Scenario tasks included: rover operations under direct human control and autonomous modes, crew ingress and egress activities, autonomous robotic payload removal and stowage operations under both local control and remote control from Houston, and autonomous robotic navigation and inspection. In addition to the main scenario, participants had an opportunity to explore additional robotic operations: hill climbing, maneuvering heaving loads, gathering geo-logical samples, drilling, and tether operations. In this analog environment, the suited subjects and robots experienced high levels of dust, rough terrain, and harsh lighting.

Diftler, M. A.↗
DOE OSTI2020

Poison or Promoter? Investigating the Dual-Role of Carbon Monoxide in Pincer-Iridium-Based Alkane Dehydrogenation Systems via Operando Diffuse Reflectance Infrared Fourier Transform Spectroscopy

Pincer-ligated iridium complexes of the form [( R 4 PCP)IrL] ( R 4 PCP = κ 3 -C 6 H 3 -2,6-(XPR 2 ) 2 ; X = CH 2 , O; R = tBu, iPr) have previously been shown competent for acceptorless alkane dehydrogenation when supported on silica. It was observed by postcatalysis solid-state NMR that silica-tethered [(≡SiO- tBu 4 POCOP)Ir(C 2 H 4 )] (3-C 2 H 4 ) was converted fully to [(≡SiO- tBu 4 POCOP)Ir(CO)] (3-CO) at 300 °C. In this work, the characterization of species under dehydrogenation reaction conditions far from equilibrium between butane and butenes (approach to equilibrium Q/K eq = 0.3 at 300 °C) is performed with operando Diffuse Reflectance Infrared Fourier–Transform Spectroscopy (DRIFTS) to show the kinetics of species conversion from 3-C 2 H 4 to 3-CO. It is further found that [(≡SiO- tBu 4 POCOP)IrHCl] (3-HCl), a species considered to be a precatalyst for alkane dehydrogenation, is also fully converted to 3-CO. Here, a mechanism of decomposition is proposed that implicates surface silanol groups, while carbon monoxide acts as a “stabilizer” for the catalyst by promoting their reductive elimination and maintaining the complex in the I oxidation state.

02 PETROLEUM↗
DOE OSTI2024

Topological Considerations in Electrolyte Additives for Passivating Silicon Anodes with Hybrid Solid–Electrolyte Interphases

Unlike most anodes used in high energy density batteries, lithiated Si does not form long-lasting passivating solid-electrolyte interphases (SEI) during formation or on charge due to SEI delamination, reconstruction, or dissolution. As a result, electrolyte degradation is continuous and results in a permanent loss of the Li inventory, shortening the useful life of the battery. Here, in this study, we show that perfluoroether electrolyte additives featuring either sulfonyl fluorides or trifluorovinyl ethers, when introduced in prescribed amounts to locally superconcentrated electrolytes, exhibit preferential reactivity at Si during formation due to their higher reduction potential than salts and solvents, creating a hybrid SEI that is simultaneously enriched with LiF and organics tethered to the reactive functionality. While both reactive motifs are effective in creating a hybrid SEI, perfluoroether additives bearing sulfonyl fluorides show more substantial integration. More important, however, is the combined influence of additive topology on anchoring efficacy and tether flexibility between anchoring sites on SEI resiliency. Top-performing Si|LFP cells featuring ditopic additive-enriched SEI improve capacity retention by as much as 45% over 100 cycles when compared to additive-free cells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

The regulation of the cell wall by glycosylphosphatidylinositol-anchored proteins in Arabidopsis

A polysaccharides-based cell wall covers the plant cell, shaping it and protecting it from the harsh environment. Cellulose microfibrils constitute the cell wall backbone and are embedded in a matrix of pectic and hemicellulosic polysaccharides and glycoproteins. Various environmental and developmental cues can regulate the plant cell wall, and diverse glycosylphosphatidylinositol (GPI)-anchored proteins participate in these regulations. GPI is a common lipid modification on eukaryotic proteins, which covalently tethers the proteins to the membrane lipid bilayer. Catalyzed by a series of enzymic complexes, protein precursors are post-translationally modified at their hydrophobic carboxyl-terminus in the endomembrane system and anchored to the lipid bilayer through an oligosaccharidic GPI modification. Ultimately, mature proteins reach the plasma membrane via the secretory pathway facing toward the apoplast and cell wall in plants. In Arabidopsis, more than three hundred GPI-anchored proteins (GPI-APs) have been predicted, and many are reported to be involved in diverse regulations of the cell wall. In this review, we summarize GPI-APs involved in cell wall regulation. GPI-APs are proposed to act as structural components of the cell wall, organize cellulose microfibrils at the cell surface, and during cell wall integrity signaling transduction. Besides regulating protein trafficking, the GPI modification is potentially governed by a GPI shedding system that cleaves and releases the GPI-anchored proteins from the plasma membrane into the cell wall.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1992

Spacecraft-plasma interaction codes: NASCAP/GEO, NASCAP/LEO, POLAR, DynaPAC, and EPSAT

Development of a computer code to simulate interactions between the surfaces of a geometrically complex spacecraft and the space plasma environment involves: (1) defining the relevant physical phenomena and formulating them in appropriate levels of approximation; (2) defining a representation for the 3-D space external to the spacecraft and a means for defining the spacecraft surface geometry and embedding it in the surrounding space; (3) packaging the code so that it is easy and practical to use, interpret, and present the results; and (4) validating the code by continual comparison with theoretical models, ground test data, and spaceflight experiments. The physical content, geometrical capabilities, and application of five S-CUBED developed spacecraft plasma interaction codes are discussed. The NASA Charging Analyzer Program/geosynchronous earth orbit (NASCAP/GEO) is used to illustrate the role of electrostatic barrier formation in daylight spacecraft charging. NASCAP/low Earth orbit (LEO) applications to the CHARGE-2 and Space Power Experiment Aboard Rockets (SPEAR)-1 rocket payloads are shown. DynaPAC application to the SPEAR-2 rocket payloads is described. Environment Power System Analysis Tool (EPSAT) is illustrated by application to Tethered Satellite System 1 (TSS-1), SPEAR-3, and Sundance. A detailed description and application of the Potentials of Large Objects in the Auroral Region (POLAR) Code are presented.

Mandell, M. J.↗
DOE OSTI2025

High-Density, Low-Hysteresis Storage Using Hydrated Salts in Surface-Functionalized Hydrogels (Final Technical Report)

Nearly 70 years ago, Glauber’s salt was identified as a leading phase change material (PCM) in terms of its heat storage density (~2x paraffin), thermal conductivity (~1W/m·K), safety, availability and cost (~$\$$100/ton). However, the complex issues of supercooling and incongruent melting due to phase separation have prevented realization of the promise. The addition of thickeners and nucleating agents such as borax solve these issues but only over few cycles. This work aims to (a) resolve long-standing challenges with Glauber’s salt as a thermal storage material through a unique materials approach, (b) to characterize the new material’s properties that are relevant to performance and (c) to explore its incorporation into commercial water heaters. The materials concept involves encapsulating the salt in custom-designed, large-mesh hydrogels that enable breakthrough advances. Specifically, (1) the choice of mesh size and polymer chemistry control diffusion of salt/water and help to eliminate phase segregation. With the hydrogel itself occupying <10% volume, there is little loss in storage density compared to another encapsulation. (2) Specific nucleation centers that covalently tether to the hydrogel trigger heterogeneous nucleation, eliminating supercooling-associated hysteresis losses. The fact that they are spatially tethered, prevents the loss in performance over multiple freeze/thaw cycles (>100). We report extensive characterization of the hydrogel complex in terms of its storage density, freezing/melting temperature, cycling losses, rheological properties, aging and thermal conductivity. The novel material developed in this work is a significant advancement over the state-of-art. Finally, we investigate its potential as a thermal storage material for commercial/residential water heating and identify scenarios in which its deployment is advantageous.

25 ENERGY STORAGE↗
DOE OSTI2019

Engineering uranyl-chelating peptides from NikR for electrochemical peptide-based sensing applications

We have, for the first time, designed three uranyl-chelating peptides by modeling after the uranyl binding pocket found in a mutated Ni(II)-dependent transcriptional repressor (NikR). All three thiolated and methylene blue (MB)-modified peptides, NikR-5, NikR-11, and NikR-15, contain the five core amino acids responsible for target recognition, but the two longer peptides have either one or two additional glycine residues in between the five amino acids. These three peptide probes were then used in the fabrication of electrochemical peptide-based (E-PB) uranyl ion (U(VI)) sensors, with the goal of elucidating the effects of the added glycine residues and probe flexibility on target recognition. The sensing mechanism is similar to other “signal-off” E-PB sensors, in which binding of the target rigidifies the probe, resulting in a decrease in the redox signal from the tethered MB label. Although all three sensors responded to U(VI), the NikR-15 sensor's behavior was irreproducible and thus precluded from the rest of the study. The NikR-11 sensor showed the largest response to U(VI), whereas the NikR-5 sensor showed higher specificity for U(VI). The limit of detection was 50 nM for both sensors, which is well below the U.S. Environmental Protection Agency maximum contaminant level for uranium. Both sensors were further tested and proven functional in a 50% synthetic aquifer sample. Overall, the NikR-11 sensor, fabricated with the 11-amino acid probe, is deemed the optimal design. Incorporating glycine residues is a strategic way to lengthen the peptide slightly to improve target binding. This simple yet versatile approach to recreating binding pockets on electrode surfaces can potentially be employed in the design of other E-PB and surface-based metal ion sensors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2015

Propulsion Technology Assessment: Science & Enabling Technologies to Explore the Interstellar Medium

As part of a larger effort led by the Keck Institute for Space Studies at the California Institute of Technology, the Advanced Concepts Office at NASA's George C. Marshall Space Flight Center conducted a study to assess what low-thrust advanced propulsion system candidates, existing and near term, could deliver a small, Voyager-like satellite to our solar system's heliopause, approximately 100 AU from the center of the sun, within 10 years and within a 2025 to 2035 launch window. The advanced propulsion system trade study consisted of three candidates, including a Magnetically Shielded Miniature (MaSMi) Hall thruster, a solar sail and an electric sail. Two aerial densities, and thus characteristic accelerations, 0.426 mm/s2 and 0.664 mm/s2, were analyzed for the solar sail option in order understand the impact of near and long term development of this technology. Similarly, two characteristic accelerations, 1 mm/s2 and 2 mm/s2, were also analyzed for the electric sail option in addition to tether quantities of 10 and 20, respectively, and individual tether length of 20 km. A second analysis was conducted to determine what existing solid rocket motor kick stage(s) would be required to provide additional thrust at various points in the trajectory, assuming an earth departure characteristic energy capability provided by a Space Launch System (SLS) Block 1B vehicle architecture carrying an 8.4 meter payload fairing. Two trajectory profiles were considered, including an escape trajectory using a Jupiter gravity assist (E-Ju), and an escape trajectory first performing a Jupiter gravity assist followed by an Oberth maneuver around the sun and an optional Saturn gravity assist (E-Ju-Su-Sa). The Oberth maneuver would need to be performed very close to the sun, wherein this study assumed a perihelion distance of approximately 11 solar radii, or 0.05 AU, away from the surface. The heat shield technology required to perform this type of ambitious maneuver was assumed to be similar to that of NASA's Solar Probe Plus mission, which is slated to launch in July 2018. With respect to a SLS Block 1B earth departure characteristic energy capability of 100 sq km/s2 for the E-Ju trajectory option, results indicated that compared to having no advanced propulsion system onboard, both the MaSMi Hall thruster and solar sail options subtract approximately 8 to 10 years from the total trip time while the electric sail outperforms all options by subtracting up to 20 years. With respect to an average kick stage velocity capability of 2.5 to 3.5 km/s at perihelion, the most sensitive segment of the E-Ju-Su-Sa trajectory option, results indicated that both the MaSMi Hall thrust and solar sail options only subtract 1 to 3 years from the total trip time whereas the electric sail again outperforms all other options by subtracting up to 5 years. In other words, if the Technology Readiness Level of an electric sail could be increased in time, this propulsion technology could not only enable a satellite to reach 100 AU in 10 years but it could potentially do so even faster. Completing such an ambitious mission in that short of a timespan would be very attractive to many as it would be well within the average career span of any of those involved.

Hopkins, Randall C.↗
NASA NTRS2016

Propulsion Technology Assessment: Science and Enabling Technologies to Explore the Interstellar Medium

As part of a larger effort led by the Keck Institute for Space Studies at the California Institute of Technology, the Advanced Concepts Office at NASA’s George C. Marshall Space Flight Center conducted a study to assess what low-thrust advanced propulsion system candidates, existing and near term, could deliver a small, Voyager-like satellite to our solar system’s heliopause, approximately 100 AU from the center of the sun, within 10 years and within a 2025 to 2035 launch window. The advanced propulsion system trade study consisted of three candidates, including a Magnetically Shielded Miniature (MaSMi) Hall thruster, a solar sail and an electric sail. Two aerial densities, and thus characteristic accelerations, 0.426 mm/s(exp 2) and 0.664 mm/s(exp 2), were analyzed for the solar sail option in order understand the impact of near and long term development of this technology. Similarly, two characteristic accelerations, 1 mm/s(exp 2) and 2 mm/s(exp 2), were also analyzed for the electric sail option in addition to tether quantities of 10 and 20, respectively, and individual tether length of 20 km. A second analysis was conducted to determine what existing solid rocket motor kick stage(s) would be required to provide additional thrust at various points in the trajectory, assuming an earth departure characteristic energy capability provided by a Space Launch System (SLS) Block 1B vehicle architecture carrying an 8.4 meter payload fairing. Two trajectory profiles were considered, including an escape trajectory using a Jupiter gravity assist (E-Ju), and an escape trajectory first performing a Jupiter gravity assist followed by an Oberth maneuver around the sun and an optional Saturn gravity assist (E-Ju-Su-Sa). The Oberth maneuver would need to be performed very close to the sun, wherein this study assumed a perihelion distance of approximately 11 solar radii, or 0.05 AU, away from the surface. The heat shield technology required to perform this type of ambitious maneuver was assumed to be similar to that of NASA’s Solar Probe Plus mission, which is slated to launch in July 2018. With respect to a SLS Block 1B earth departure characteristic energy capability of 100 km(exp 2)/s(exp 2) for the E-Ju trajectory option, results indicated that compared to having no advanced propulsion system onboard, both the MaSMi Hall thruster and solar sail options subtract approximately 8 to 10 years from the total trip time while the electric sail outperforms all options by subtracting up to 20 years. With respect to an average kick stage velocity capability of 2.5 to 3.5 km/s at perihelion, the most sensitive segment of the E-Ju-Su-Sa trajectory option, results indicated that both the MaSMi Hall thrust and solar sail options only subtract 1 to 3 years from the total trip time whereas the electric sail again outperforms all other options by subtracting up to 5 years. In other words, if the Technology Readiness Level of an electric sail could be increased in time, this propulsion technology could not only enable a satellite to reach 100 AU in 10 years but it could potentially do so even faster. Completing such an ambitious mission in that short of a timespan would be very attractive to many as it would be well within the average career span of any of those involved.

Hopkins, Randall C.↗
NASA NTRS2016

Propulsion Technology Assessment: Science and Enabling Technologies to Explore the Interstellar Medium

Led by the Keck Institute for Space Studies at the California Institute of Technology, the Advanced Concepts Office at NASA's George C. Marshall Space Flight Center conducted a study to assess what low-thrust advanced propulsion system candidates, existing and near term, could deliver a small, Voyager-like satellite to our solar system's heliopause, approximately 100 AU from the center of the sun, within 10 years and within a 2025-2035 launch window. The advanced propulsion system trade study consisted of three candidates, including a Magnetically Shielded Miniature (MaSMi) Hall thruster, a solar sail and an electric sail. Two aerial densities, and thus characteristic accelerations, 0.426 mm/sq s and 0.664 mm/sq s were analyzed for the solar sail option in order understand the impact of near and long term development of this technology. Similarly, two characteristic accelerations, 1 mm/s2 and 2 mm/sq s, were also analyzed for the electric sail option in addition to tether quantities of 10 and 20, respectively, and individual tether length of 20 km. A second analysis was conducted to determine what existing solid rocket motor kick stage(s) would be required to provide additional thrust at various points in the trajectory, assuming an earth departure characteristic energy capability provided by a Space Launch System (SLS) Block 1B vehicle architecture carrying an 8.4 meter payload fairing. Two trajectory profiles were considered, including an escape trajectory using a Jupiter gravity assist (E-Ju), and an escape trajectory first performing a Jupiter gravity assist followed by an Oberth maneuver around the sun and an optional Saturn gravity assist (E-Ju-Su-Sa). The Oberth maneuver would need to be performed very close to the sun, wherein this study assumed a perihelion distance of approximately 11 solar radii, or 0.05 AU, away from the surface. The heat shield technology required to perform this type of ambitious maneuver was assumed to be similar to that of NASA's Solar Probe Plus mission, which is slated to launch in July 2018. With respect to a SLS Block 1B earth departure characteristic energy capability of 100 km2/sq s for the E-Ju trajectory option, results indicated that compared to having no advanced propulsion system onboard, both the MaSMi Hall thruster and solar sail options subtract approximately 8 to 10 years from the total trip time while the electric sail outperforms all options by subtracting up to 20 years. With respect to an average kick stage velocity capability of 2.5 to 3.5 km/s at perihelion, the most sensitive segment of the E-Ju-Su-Sa trajectory option, results indicated that both the MaSMi Hall thrust and solar sail options only subtract 1 to 3 years from the total trip time whereas the electric sail again outperforms all other options by subtracting up to 5 years. In other words, if the Technology Readiness Level of an electric sail could be increased in time, this propulsion technology could not only enable a satellite to reach 100 AU in 10 years but it could potentially do so even faster. Completing such an ambitious mission in that short of a timespan would be very attractive to many as it would be well within the average career span of any of those involved.

Hopkins, Randall C.↗
DOE OSTI2023

Cell Free and Immobilization Technologies (CFIT)

Today, several key factors negatively impact the production of fuels and chemicals from renewable sources. Common hindrances in the biological production of biochemicals are: (1) end-product or intermediate toxicity to the microbial biocatalyst, (2) the diversion of carbon to biomass formation, and (3) co-production of undesired byproducts. A particularly attractive alternative is to eliminate the biocatalyst entirely and instead operate the desired metabolic pathways in isolation, thus circumventing the roadblocks of biological toxicity, lower yields, and lack of specificity. However, cell-free enzyme systems still suffer from low productivities owing in part to the effects of free diffusion of intermediates, lack of long term enzyme stability, cofactor cost or inefficient recycling rates, and finally, the cost of enzyme production/purification. This project represents a new effort to propose innovative and cost competitive routes to producing biochemicals from a variety of feedstocks using cell free approaches. These routes will help reduce the current risk and cost associated with classical cell free production. Cell free technologies show promise for application to the production of toxic/inhibitory products or products difficult to separate from microbial growth media and can help reduce the production barriers in multiple areas of biological conversion of feedstocks to biochemicals. More specifically, we are developing new technologies and routes that could be used to produce high value biochemicals such as 2,3 BDO and terpenes (among many others) from biomass derived C5/C6 sugars or lignin but also from waste byproducts such as glycerol. This project will lead to significant innovation and also lead to new concepts and rational design of pathways and enzymes. Within this project, we will develop new metabolic enzyme cascades that will represent natural or artificial combinations of enzymes to produce the desired biochemicals from a variety of feedstocks. We are also developing basic design principals for constructing synthetic metabolons, using fusion proteins and synthetic protein scaffolds, to promote substrate channeling and stability while conserving peak activity. Additionally, our efforts include a techno economic analysis (TEA) of cell free approaches to provide the sensitivities of the process to enzyme loading, activity, pH, reactor volumes, cofactor recycling rates. Finally, we are focusing on further increasing stability, operating lifetime and efficiency of the pathway enzymes by immobilization on support surfaces. We are also focus on immobilizing pathway enzymes or combinations of enzymes on several different conducting polymers and evaluate the effect on stability and operating lifetime. As more combinations become available we will conduct a more systematic study of the means of immobilizing these enzymes. This preliminary work will enable the in-depth study of cofactor recycling at these interfaces using mediators for electron transfer. Taken together, these approaches will enable process intensification, continuous operation, lower capital and separations costs and end-product flexibility, and thus has the potential to contribute significantly to BETO's goals of cost competitive biofuels and bioproducts. To date we have demonstrated 1) the conversion of pyruvate to 2,3 BDO (4 enzymes with cofactor recycling, no additional cofactors needed) at >100g/L (>3g/L/h) using our enzyme tethering approach, 2) Generated mutants of a key redox enzyme with >180- fold improvement in NADH utilization over WT to >85% of NADPH utilization. 3) Produced mevalonate at >10g/L from glucose, limonene at >10g/L from mevalonate and more than >5g/L from glucose with crude enzyme preparations and complete cofactor recycling. 4) successfully generated fully active cross-linked aggregates (CLEAs) of NOX, a cofactor-regenerating water-forming oxidase that is key to our process with increased stability 5) Engineered and identified enzymes able to use the biomimetic cofactor NMN and synthesized new synthetic cofactors.

biocatalysis↗
DOE OSTI2020

Compiled TBS data from Oliktok Point from ICARUS, AVPOP, and POPEYE

The dataset encompasses QA/QC TBS data, including TBS altitude, atmospheric pressure, dew point, POPs number concentrations and mean aerosol size, relative humidity, temperature, equivalent potential temperature, equivalent temperature, and date and time. These data are provided per day for at least one TBS flight. Supporting data from the AMF3 aligned with the timestamps of the TBS data include cloud base distance from TBS, if the time corresponds to cloud base transit of the TBS, surface-based pressure, surface-based precipitation rate, surface-based UHSAS data, ceilometer cloud base height, KAZR cloud top height, and MWR liquid water content. Both POPS and UHSAS aerosol number concentrations are provided as: (1) absolute (i.e. concentrations for each instrument's total size range) and (2) the overlapping size range (i.e. the same size bins for both instruments).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Dynamic Mixing Behaviors of Ionically Tethered Polymer Canopy of Nanoscale Hybrid Materials in Fluids of Varying Physical and Chemical Properties

An emerging area of sustainable energy and environmental research is focused on the development of novel electrolytes that can increase the solubility of target species and improve subsequent reaction performance. Electrolytes with chemical and structural tunability have allowed for significant advancements in flow batteries and CO 2 conversion integrated with CO 2 capture. Liquid-like nanoparticle organic hybrid materials (NOHMs) are nanoscale fluids that are composed of inorganic nanocores and an ionically tethered polymeric canopy. NOHMs have been shown to exhibit enhanced conductivity making them promising for electrolyte applications, though they are often challenged by high viscosity in the neat state. In this study, a series of binary mixtures of NOHM-I-HPE with five different secondary fluids, water, chloroform, toluene, acetonitrile, and ethyl acetate, were prepared to reduce the fluid viscosity and investigate the effects of secondary fluid properties (e.g., hydrogen bonding ability, polarity, and molar volume) on their transport behaviors, including viscosity and diffusivity. We report our results revealed that the molecular ratio of secondary fluid to the ether groups of Jeffamine M2070 ($λ_{\text{SF}}$) was able to describe the effect that secondary fluid has on transport properties. Our findings also suggest that in solution, the Jeffamine M2070 molecules exist in different nanoscale environments, where some are more strongly associated with the nanoparticle surface than others, and the conformation of the polymer canopy was dependent on the secondary fluid. This understanding of the polymer conformation in NOHMs can allow for the better design of an electrolyte capable of capturing and releasing small gaseous or ionic species.

25 ENERGY STORAGE↗
DOE OSTI2020

Charge regulation mechanism in end-tethered weak polyampholytes

Weak polyampholytes, containing oppositely charged dissociable groups, are expected to be responsive to changes in ionic conditions. Here, we determine structural and thermodynamic properties, including the charged groups’ degrees of dissociation, of end-tethered weak polyampholyte layers as a function of salt concentration, pH, and the solvent quality. For diblock weak polyampholytes grafted by their acidic blocks, we find that the acidic monomers increase their charge while the basic monomers decrease their charge with decreasing salt concentration for pH values less than the pK a value of both monomers and vice versa when the pH > pK a . This complex charge regulation occurs because the electrostatic attraction between oppositely charged blocks is stronger than the repulsion between monomers with the same charge in both good and poor solvents when the screening by salt ions is weak. This is shown by the retraction of the top block into the bottom layer. In the case of poor solvent conditions to the basic block (the top block), we find lateral segregation of basic monomers into micelles, forming a two-dimensional hexagonal pattern on the surface at intermediate and high pH values for monovalent salt concentrations from 0.01 to 0.1 M. When the solvent is poor to both blocks, we find lateral segregation of the grafted acidic block into lamellae with longitudinal undulations of low and high acidic monomer density. By exploiting weak block polyampholytes, our work expands the parameter space for creating responsive surfaces stable over a wide range of pH and salt concentration.

36 MATERIALS SCIENCE↗