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At least 271 records · Page 15

Infrared spectroscopic measurements of the ethane (C2H6) total column abundance above Mauna Loa, Hawaii -- seasonal variations

About 200 i.r. solar spectra recorded at 0.01/cm resolution on 71 days between November 1991 and July 1993 at the Network for the Detection of Stratospheric Change (NDSC) station at Mauna Loa, Hawaii (latitude 19.53 deg N, longitude 155.58 deg W, elevation 3.459 km) have been analyzed with a nonlinear least-squares spectral fitting technique to study temporal variations in the total column of atmospheric ethane (C2H6) above the site. The results were derived from the analysis of the unresolved nu(sub 7) band (P)Q(sub 3) subbranch at 2976.8/cm. A distinct seasonal cycle is observed with a factor of 2 variation, a maximum total column of 1.16 x 10(exp 16) mol/sq cm at the end of winter, and a minimum total column of 0.53 x 10(exp 16) mol/sq cm at the end of summer. Our measurements are compared with previous observations and model predictions.

Rinsland, C. P.↗

Determination of the major groups of phytoplankton pigments from the absorption spectra of total particulate matter

The contributions of detrital particles and phytoplankton to total light absorption are retrieved by nonlinear regression on the absorption spectra of total particles from various oceanic regions. The model used explains more than 96% of the variance in the observed particle absorption spectra. The resulting absorption spectra of phytoplankton are then decomposed into several Gaussian bands reflecting absorption by phytoplankton pigments. Such a decomposition, combined with high-performance liquid chromatography data on phytoplankton pigment concentrations, allows the computation of specific absorption coefficients for chlorophylls a, b, and c and carotenoids. The spectral values of these in vivo absorption coefficients are then discussed, considering the effects of secondary pigments which were not measured quantitatively. We show that these coefficients can be used to reconstruct the absorption spectra of phytoplankton at various locations and depths. Discrepancies that do occur at some stations are explained in terms of particle size effect. These coefficients can be used to determine the concentrations of phytoplankton pigments in the water, given the absorption spectrum of total particles.

Hoepffner, Nicolas↗

Total Solar Eclipse of 1999 August 11

On 1999 August 11, a total eclipse of the Sun will be visible from within a narrow corridor which traverses the Eastern Hemisphere. The path of the Moon's umbral shadow begins in the Atlantic and crosses central Europe, the Middle East, and India, where it ends at sunset in the Bay of Bengal. A partial eclipse will be seen within the much broader path of the Moon's penumbral shadow, which includes northeastern North America, all of Europe, northern Africa, and the western half of Asia. Detailed predictions for this event are presented and include besselian elements, geographic coordinates of the path of totality, physical ephemeris of the umbra, topocentric limb profile corrections, local circumstances for approximately 1400 cities, maps of the eclipse path, weather prospects, the lunar limb profile, and the sky during totality. Tips and suggestions are also given on how to safely view and photograph the eclipse.

Espenak, Fred↗

Infrared Spectroscopic Measurements of the Ethane (C2H6) Total Column Abundance Above Mauna Loa, Hawaii: Seasonal Variations

About 200 i.r. solar spectra recorded at 0.01/ cm resolution on 71 days between November 1991 and July 1993 at the Network for the Detection of Stratospheric Change (NDSC) station at Mauna Loa, Hawaii (latitude 19.53 deg N, longitude 155.58 deg W, elevation 3.459 km) have been analyzed with a nonlinear least-squares spectral fitting technique to study temporal variations in the total column of atmospheric ethane (C2H6) above the site. The results were derived from the analysis of the unresolved nu(sub 7) band (sup P)Q(sub 3) subbranch at 2976.8/cm. A distinct seasonal cycle is observed with a factor of 2 variation, a maximum total column of 1.1 6 x 10(exp 16) mol /sq cm at the end of winter, and a minimum total column of 0.53 x 10(exp 16) mol/sq cm at the end of summer. Our measurements are compared with previous observations and model predictions.

Rinsland, C. P.↗

Total Lightning Activity Associated with Tornadic Storms

Severe storms often have high flash rates (in excess of one flash per second) and are dominated by intracloud lightning activity. In addition to the extraordinary flash rates, there is a second distinguishing lightning characteristic of severe storms that seems to be important. When the total lightning history is examined, one finds sudden increases in the lightning rate, which we refer to as lightning "jumps," that precede the occurrence of severe weather by ten or more minutes. These jumps are typically 30-60 flashes/min, and are easily identified as anomalously large derivatives in the flash rate. This relationship is associated with updraft intensification and updraft strength is an important factor in storm severity (through the accumulation of condensate aloft and the stretching of vorticity). In several cases, evidence for diminishment of midlevel rotation and the descent of angular momentum from aloft is present prior to the appearance of the surface tornado. Based on our experience with severe and tornadic storms in Central Florida, we believe the total lightning may augment the more traditional use of NEXRAD radars and storm spotters. However, a more rigorous relation of these jumps to storm kinematics is needed if we are to apply total lightning in a decision tree that leads to improved warning lead times and decreased false alarm rates.

Goodman, Steven J.↗

Total Solar Eclipse of 2001 June 21

On 2001 June 21, a total eclipse of the Sun will be visible from within a narrow corridor which traverses the Southern Hemisphere. The path of the Moon's umbral shadow begins in the South Atlantic, crosses southern Africa and Madagascar, and ends at sunset in the Indian Ocean. A partial eclipse will be seen within the much broader path of the Moon's penumbral shadow, which includes eastern South America and the southern two thirds of Africa. Detailed predictions for this event are presented and include besselian elements, geographic coordinates of the path of totality, physical ephemeris of the umbra, topocentric limb profile corrections, local circumstances for approximately 350 cities, maps of the eclipse path, weather prospects, the lunar limb profile and the sky during totality. Tips and suggestions are also given on how to safely view and photograph the eclipse.

Espenak, Fred↗

Tropospheric Ozone Pollution from Space: New Views from the TOMS (Total Ozone Mapping Spectrometer) Instrument

New products from the TOMS (Total Ozone Mapping Spectrometer) >satellite instrument can resolve pollution events in tropical and mid-latitudes, Over the past several years, we have developed tropospheric ozone data sets by two methods. The modified-residual technique [Hudson and Thompson, 1998; Thompson and Hudson, 1999] uses v. 7 TOMS total ozone and is applicable to tropical regimes in which the wave-one pattern in total ozone is observed. The TOMSdirect method [Hudson et at., 2000] represents a new algorithm that uses TOMS radiances to extract tropospheric ozone in regions of constant stratospheric ozone and tropospheric ozone displaying high mixing ratios and variability characteristic of pollution, Absorbing aerosols (dust and smoke; Herman et at., 1997 Hsu et al., 1999), a standard TOMS product, provide transport and/or source marker information to interpret tropospheric ozone. For the Nimbus 7/TOMS observing period (1979-1992), modified-residual TTO (tropical tropospheric ozone) appears as two maps/month at I-degree latitude 2-degree longitude resolution at a homepage and digital data are available (20S to 20N) by ftp at http://metosrv2. umd.edu/~tropo/ 14y_data.d. Preliminary modified-residual TTO data from the operational Earth-Probe/TOMS (1996- present) are posted in near-real-time at the same website. Analyses with the new tropospheric ozone and aerosol data are illustrated by the following (I)Signals in tropical tropospheric ozone column and smoke amount during ENSO (El Nino-Southern Oscillation) events, e.g. 1982-1983 and the intense ENSO induced biomass fires of 1997-1998 over the Indonesian region [Thompson et a[, 2000a, Thompson and Hudson, 1999]. (2) Trends in tropospheric ozone and smoke aerosols in various tropical regions (Atlantic, Pacific, Africa, Brazil). No significant trends were found for ozone from1980-1990 [Thompson and Hudson, 19991 although smoke aerosols increased during the period [Hsu et al.,1999]. (3) Temporal and spatial offsets ("paradoxes") in tropical tropospheric ozone and smoke aerosol in regions of greatest tropical biomass burning [Thompson et at., 1996;2000b]. (4) Trans-boundary pollution tracking. With an air parcel (trajectory) model, smoke aerosol and ozone and dust plumes can be tracked across oceans (e.g., Asia to North America; North America to Europe) and national boundaries, e.g. Indonesia to Singapore and Malaysia during the 1997 ENSO fires.

Thompson, Anne M.↗

Tropospheric Ozone Pollution Transport Traced from the TOMS (Total Ozone Mapping Spectrometer) Instrument During the Nashville-1999 Campaign

Over the past several years, we have developed two new tropospheric ozone retrievals from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument that are of sufficient resolution to follow pollution episodes. The modified-residual technique [Hudson and Thompson, 1998; Thompson and Hudson, 1999] uses v. 7 TOMS total ozone and is applicable to tropical regimes in which the wave-one pattern in total ozone is observed. The TOMS-direct method [("TDOT" = TOMS Direct Ozone in the Troposphere; Frolov et al., 2000] represents a new algorithm that uses TOMS radiances directly (i.e., not previously processed for TOMS ozone) to extract tropospheric ozone in regions of constant stratospheric ozone and tropospheric ozone displaying high mixing ratios and variability characteristic of pollution. These events tend to occur in certain meteorological regimes. For example, mid-latitude pollution usually occurs on the backside of subtropical fronts, as low pv, usually moist air intrudes to the extra-tropics. July 1999 was a month characterized by robust pollution in the eastern US, with high ozone, as detected by TOMS, originating over south central states and moving up the Atlantic seaboard. This corresponds to 50-80 DU in tropospheric ozone column depth. In most cases, further transport occurred to the North Atlantic, with ozone plumes traveling to western Europe in 4-5 days. Examples of high ozone and transit across boundaries within the US, as well as US->Europe, give a regional context for model results and field measurements taken in the SE US during the Nashville-1999 campaign period. Validation of the TDOT maps is made with ozonesondes taken during that time. TDOT maps also show ozone pollution from Asia traveling to the western US in July 1999.

Thompson, Anne M.↗

Total Solar Eclipse of 2002 December 04

On 2002 December 04, a total eclipse of the Sun will be visible from within a narrow corridor which traverses the Southern Hemisphere. The path of the Moon's umbral shadow begins in the South Atlantic, crosses southern Africa and the Indian Ocean, and ends at sunset in southern Australia. A partial eclipse will be seen within the much broader path of the Moon's penumbral shadow, which includes the southern two thirds of Africa, Antarctica, Indian Ocean and Australia. Detailed predictions for this event are presented and include besselian elements, geographic coordinates of the path of totality, physical ephemeris of the umbra, topocentric limb profile corrections, local circumstances for approximately 400 cities, maps of the eclipse path, weather prospects, the lunar limb profile and the sky during totality. Information on safe eclipse viewing and eclipse photography is included.

Espenak, Fred↗

CCKT Calculation of e-H Total Cross Sections

We are in the process of carrying out calculations of e-H total cross sections using the 'complex-correlation Kohn-T' (CCKT) method. In a later paper, we described the methodology more completely, but confined calculations to the elastic scattering region, with definitive, precision results for S-wave phase shifts. Here we extend the calculations to the (low) continuum (1 much less than k(exp 2) much less than 3) using a Green's function formulation. This avoids having to solve integro-differential equations; rather we evaluate indefinite integrals involving appropriate Green's functions and the (complex) optical potential to find the scattering function u(r). From the asymptotic form of u(r) we extract a T(sub L) which is a complex number. From T(sub L), elastic sigma(sub L)(elastic) = 4pi(2L+1)((absolute value of T(sub L))(exp 2)), and total sigma (sub L)(total) = 4pi/k(2L+1)Im(T(sub L)) cross sections follow.

Bhatia, Aaron K.↗

A Comparison of TOMS Version 8 Total Column Ozone Data with Data from Groundstations

The Nimbus-7 and Earth Probe Total Ozone Mapping Spectrometer (TOMS) data have been reprocessed with a new retrieval algorithm, (Version 8) and an updated calibration procedure. These data have been systematically compared to total ozone data from Brewer and Dobson spectrophotometers for 73 individual ground stations. The comparisons were made as a function of latitude, solar zenith angle, reflectivity and total ozone. Results show that the accuracy of the TOMS retrieval'is much improved when aerosols are present in the atmosphere, when snow/ice and sea glint are present, and when ozone in the northern hemisphere is extremely low. TOMS overpass data are derived from the single TOMS best match measurement, almost always located within one degree of the ground station and usually made within an hour of local noon. The version 8 Earth Probe TOMS ozone values have decreased by an average of about 1% due to a much better understanding of the calibration of the instrument. The remaining differences between TOMS and ground stations suggest that there are still small errors in the TOMS retrievals. But if TOMS is used as a transfer standard to compare ground stations, the large station-to-station differences suggest the possibility of significant instrument errors at some ground stations.

Labow, G. J.↗

Retrieval of Total Ozone Amounts from Zenith-Sky Intensities in the Ultraviolet Region

A new method to determine the total ozone column from zenith-sky intensities in the ultraviolet region has been developed for the Shuttle Solar Backscatter Ultraviolet Spectrometer (SSBUV) operating at the NASA Goddard Space Flight Center. The total ozone column amounts are derived by comparing the ratio of measured intensities from three wavelengths with the equivalent ratios calculated by a radiative transfer model. The differences between the retrieved ozone column amounts and the collocated Brewer double monochromator are within 2% for the measurement period beginning in April 2001. The methodology, as well as the influences of the ozone profiles, aerosols, surface albedo, and the solar zenith angle on the retrieved total ozone amounts will be presented.

Bojkov, B. R.↗

The LATEST Project: Operational Assessment of Total Lightning Data in the U.S.

A government, university, and industry alliance has joined forces to transition total lightning observations from ground-based research networks and NASA satellites (LIS/TRMM) to improve the short range prediction of severe weather. This interest builds on the desire of the U.S Weather Research Program to foster a national Nowcasting Test Bed, with this specific transition activity initiated through the NASA short-term Prediction Research and Transition (SPoRT) Center in Huntsville, AL. A kick-off national workshop sponsored by the SPoRT Center was held in Huntsville April 1-2 to identify the common goals and objectives of the research and operational community, and to assign roles and responsibilities within the alliance. The workshop agenda, presentations, and summary are available at the SPoRT Center Web site ( h h under the "Meetings" tab. The next national workshop is planned for 2005 in Dallas, TX. The NASA North Alabama regional Lightning Mapping Array &MA) has been operational in the Huntsville area for 3 years, and has continuously sampled a variety of severe weather systems during that period. A gridded version of the LMA total lightning data is currently being supplied to National Weather Service offices in Huntsville, Nashville and Birmingham through the NWS AWES decision support system, for the purposes of assessing the utility of the data in the nowcasting of severe weather such as tornadoes, damaging straight line winds, flash flooding and other weather hazards (lightning induced forest fires, microbursts). While the raw LMA data have been useful to NWS forecasters, even greater utility would be realized if higher-order data products could be supplied through AWIPS along with the gridded data over a larger domain. In 2003-2004 additional LMA systems have been deployed across the southern US. from Florida to New Mexico, providing an opportunity for more than 20 NWS forecast offices to evaluate the incremental value of total lightning data in the warning decision making process.

Goodman, Steven↗

Total Water Measurements Using In Situ UV Fragment Fluorescence Spectroscopy in Support of CRYSTAL-FACE

Given both the powerful diagnostic importance of the condensed phases of water for dynamics and the impact of phase changes in water on the radiation field, the accurate, in situ observation of total water is of central importance to CRYSTAL-FACE. This is clear both from the defined scientific objectives of the NRA and from developments in the coupled fields of stratosphere/troposphere exchange, cirrus cloud formation/removal and mechanisms for the distribution of water vapor in the middle/upper troposphere. Accordingly, we were funded under NASA Grant NAG5-115487 to perform the following tasks for the CRYSTAL-FACE mission that took place in Key West, Florida, during July 2001: 1) Prepare the Total Water instrument for integration into the WB57F and test flights scheduled for Spring 2002. 2) Calibrate and prepare the Total Water instrument for the Summer 2002 CRYSTAL-FACE science flights based in Jacksonville, Florida. 3) Provide both science and engineering support for the above-mentioned efforts. 4) Analyze and interpret the CRYSTAL-FACE data in collaboration with the other mission scientists. 5) Attend the proposed science workshop in Spring 2003. 6) Publish the data and analysis in peer-reviewed journals.

Anderson, James G.↗

Improvements to the Total Temperature Calibration of the NASA Glenn Icing Research Tunnel

The ability to accurately set repeatable total temperature conditions is critical for collecting quality icing condition data, particularly near freezing conditions. As part of efforts to continually improve data quality in the NASA Glenn Icing Research Tunnel (IRT), new facility instrumentation and new calibration hardware for total temperature measurement were installed and new operational techniques were developed and implemented. This paper focuses on the improvements made in the calibration of total temperature in the IRT.

Arrington, E. Allen↗

Electron-impact total ionization cross sections of DNA sugar-phosphate backbone and an additivity principle

The improved binary-encounter dipole (iBED) model [W.M. Huo, Phys. Rev. A64, 042719-1 (2001)l is used to study the total ionization cross sections of the DNA sugar-phosphate backbone by electron impact. Calculations using neutral fragments found that the total ionization cross sections of C3' - and C5', -deoxyribose-phospate, two conformers of the sugar-phosphate backbone, are close to each other. Furthermore, the sum of the ionization cross sections of the separate deoxyribose and phosphate fragments is in close agreement with the C3' - and C5" -deoxyribose-phospate cross sections, differing by less than 10%. The result implies that certain properties of the-DNA, like the total singly ionization cross section, are localized properties and a building-up or additivity principle may apply. This allows us to obtain accurate properties of larger molecular systems built up from the results of smaller subsystem fragments. Calculations are underway using a negatively charged sugar-phosphate backbone with a metal counter-ion.

Huo, Winifred M.↗

Total Solar Eclipse of 2006 March 29

On 2006 March 29, a total eclipse of the Sun will be visible from within a narrow corridor which traverses half the Earth. The path of the Moon's umbral shadow begins in Brazil and extends across the Atlantic, northern Africa, and central Asia where it ends at sunset in western Mongolia. A partial eclipse will be seen within the much broader path of the Moon's penumbral shadow, which includes the northern two thirds of Africa, Europe, and central Asia.Detailed predictions for this event are presented and include besselian elements, geographic coordinates of the path of totality, physical ephemeris of the umbra, topocentric limb profile corrections, local circumstances for approximately 350 cities, maps of the eclipse path, weather prospects, the lunar limb profile, and the sky during totality. Information on safe eclipse viewing and eclipse photography is included.

Espenak, F.↗

Total Solar Eclipse of 2008 August 01

On 2008 August 01, a total eclipse of the Sun is visible from within a narrow corridor that traverses half the Earth. The path of the Moon's umbral shadow begins in northern Canada and extends across Greenland, the Arctic, central Russia, Mongolia, and China. A partial eclipse is seen within the much broader path of the Moon's penumbral shadow, which includes northeastern North America, most of Europe and Asia. Detailed predictions for this event are presented and include besselian elements, geographic coordinates of the path of totality, physical ephemeris of the umbra, topocentric limb profile corrections, local circumstances for 308 cities, maps of the eclipse path, weather prospects, the lunar limb profile and the sky during totality. Information on safe eclipse viewing and eclipse photography is included.

Espenak, F.↗