The theory of the absorption of flame radiation by molecular bands.
Atmospheric absorption of flame radiation of discrete lines and extension for overlapping lines compared with black body source
RADIATION EMISSION↗
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Spectral properties of mixtures of montmorillonite and dark grains - Implications for remote sensing minerals containing chemically and physically adsorbed water
The spectral properties from 0.4 to 3 microns of montmorillonite plus dark carbon grains (called opaques) of various sizes are studied as a function of the weight fraction of opaques present. The reflectance level and band depths of the 1.4-, 1.9-, 2.2-, and 2.8-micron water and/or OH absorption features are analyzed using derived empirical relationships and scattering theory. It is found that the absorption band depths and reflectance level are a very nonlinear function of the weight fraction of opaques present but can be predicted in many cases by simple scattering theory. The 2.8-micron bound water fundamental band is the most difficult absorption feature to suppress. The overtone absorptions are suppressed a greater amount than the fundamental but are still apparent even when 10-20 wt pct opaques are present. The relationships observed and the simple scattering theory presented show that quantitative compositional remote sensing studies are feasible for surfaces containing complex mineral mixtures.
Clark, R. N.↗
3 nu sub 3 band of C-12H4 at 1.1 micron.
The 3 nu sub 3 absorption band of C-12H4 has been measured using a high-resolution vacuum infrared spectrometer. A technique is described which allows an extension of the use of the absorption standards available at 4.7 microns to the photomultiplier region of the spectrum. The new measurements indicate a shift of about 0.18 per cm from the most recently published measurements of this band.
Pugh, L. A.↗
Low-energy electron effects on tensile modulus and infrared transmission properties of a polypyromellitimide film
Infrared (IR) spectroscopy and tensile modulus testing were used to evaluate the importance of experimental procedure on changes in properties of pyromellitic dianhydride-p,p prime-oxydianiline film exposed to electron radiation. The radiation exposures were accelerated, approximate equivalents to the total dose expected for a 30 year mission in geosynchronous Earth orbit. The change in the tensile modulus depends more on the dose rate and the time interval between exposure and testing than on total dose. The IR data vary with both total dose and dose rate. A threshold dose rate exists below which reversible radiation effects on the IR spectra occur. Above the threshold dose rate, irreversible effects occur with the appearance of a new band. Post-irradiation and in situ IR absorption bands are significantly different. It is suggested that the electron radiation induced metastable, excites molecular states.
Ferl, J. E.↗
Detection of a CH4 atmosphere on Pluto
A ratio spectrum of Pluto shows methane absorption bands at 6200, 7200, 7900, 8400, 8600, 8900, and 10,000 A. The heavy saturation of the 8900 band as compared to the other bands indicates a gaseous origin for the observed absorptions. A total methane abundance of 80 + or - 20 m-am is derived, and an upper limit to the total pressure of approximately .05 atm is set. The methane atmosphere would be stable if the mass of Pluto is increased 50% over its present value and its radius is 1400 km. A heavier gas mixed with the methane atmosphere would also aid its stability.
Fink, U.↗
Evaluation of radiometric and geometric characteristics of LANDSAT-D imaging system
With vegetation masked and noise sources eliminated or minimized, different carbonate facies could be discriminated in a south Florida scene. Laboratory spectra of grab samples indicate that a 20% change in depth of the carbonate absorption band was detected despite the effects of atmospheric absorption. Both bright and dark hydrothermally altered volcanic rocks can be discriminated from their unaltered equivalents. A previously unrecognized altered area was identified on the basis of the TM images. The ability to map desert varnish in semi-arid terrains has economic significance as it defines areas that are less susceptible desert erosional process and suitable for construction development.
Salisbury, J. W.↗
Determination of total column water vapor in the atmosphere at high spatial resolution from AVIRIS data using spectral curve fitting and band ratioing techniques
Techniques are developed for quantitative retrievals of high spatial resolution column atmospheric water vapor that is largely contained in the lower portion of the troposphere. One method consists of curve fitting observed spectra with simulated spectra in the 1.14 microns or the 0.94 micron water vapor band absorption region. The other method is a simple band ratioing technique, which requires less computer time than the curve fitting method. The advantage of the technique over humidity sounding by IR emission measurements is that the retrieved column water vapor amounts over land surfaces have significantly higher precision.
Gao, Bo-Cai↗
Evaluation of the sensitivity of reflectance ratios to mafic minerals in the lunar regolith
The 950/560-nm spectral ratio has been traditionally used as a qualitative indicator or lunar soil maturity because the 950-nm band falls within the major Fe(2+) mineral absorption bands near 1-micron characteristic of relatively immature crystalline surfaces. Since there are several other processes unrelated to maturation that may affect this ratio value, the 950/730-nm ratio has been evaluated as a potentially better measure of the relative 1-micron band strength. It is found that the 950/730-nm ratio appears to be much more sensitive to the 1-micron band depth, but it is believed that other unknown variables preclude using these single ratios to provide meaningful quantitative results at this time.
Larson, Stephen M.↗
Spectroscopy of D-type asteroids
We have performed a spectroscopic survey of 19 D-type asteroids. Comparison with previous photometry shows excellent agreement. Although the majority have similar colors to cometary nuclei, no cometary emission bands were present in any of the spectra. Absorption bands sporadically appearing were apparently due to stellar objects, and no features inherent to the asteroids were observed.
Fitzsimmons, Alan↗
Infrared and Reflected Solar Radiation Measurements from the TIROS 2 Meteorological Satellite
TIROS II contains instrumentation for measuring infrared and reflected solar radiation from the earth and its atmosphere. A medium resolution scanning radiometer and a low resolution non-scanning radiometer are employed. The satellite's spin provides the scan line of the medium resolution radiometer which is then advanced by the orbital motion. The spatial resolution is about 40 miles square when the earth directly beneath the satellite is viewed. The five channels employ bolometer detectors and filters to limit the spectral responses to five bands: 6 to 6.5 microns, 8 to 12 microns, 0.2 to 6 microns, 8 to 30 microns, and 0.55 to 0.75 microns. These five bands study, respectively: radiation in the water vapor absorption band; day and nighttime cloud cover; albedo; thermal radiation; and visual maps for comparison with satellite vidicon pictures. The low resolution non-scanning radiometer measures the earth's black-body temperature and albedo. Its field when viewing directly below is a circle of 450 miles diameter, covering part of each frame from the wide-field television camera. This radiometer consists of two thermistors, each in the apex of a reflective cone which provides optical gain. One thermistor is black and responds to both thermal and reflected solar radiation. The second responds to thermal but reflects solar radiation. The design, calibration, performance, and data reduction for both systems are discussed herein.
Bandeen, W. R.↗
Impact of Cirrus Crystal Shape on Solar Spectral Irradiance: A Case Study for Subtropical Cirrus
Profiles of in situ measurements of ice crystal size distribution of subtropical cirrus were used to calculate solar spectral irradiances above and below the clouds. Spheres and nonspherical ice crystal habits (columns, hollows, plates, bullets, and aggregates) were assumed in the calculations. The simulation results were compared to irradiance measurements from the NASA Solar Spectral Flux Radiometer. The microphysical and radiation data were collected by three aircraft during CRYSTAL-FACE. Two cirrus cases (optical thickness of about 1 and 7) from two mission dates (26 and 23 July 2002) were investigated in detail. The measured downwelling and upwelling irradiance spectra above the cirrus could mostly be reproduced by the radiation model to within +/- 5-10% for most ice crystal habits. Below the cirrus the simulations disagreed with the measured irradiances due to surface albedo variability along the flight track, and nonoptimal colocation between the microphysical and irradiance measurements. The impact of shape characteristics of the crystals was important for the reflected irradiances above the optically thin cirrus, especially for small solar zenith angles, because in this case single-scattering dominated the solar radiation field. For the cirrus of moderate optical thickness the enhanced multiple scattering tended to diminish particular shape features caused by nonspherical single-scattering. Within the ice absorption bands the shape-related differences in the absorption characteristics of the individual nonspherical ice crystals were amplified if multiple scattering prevailed. Furthermore, it was found that below the cloud the shape sensitivity of the downwelling irradiance spectra is larger compared to the nonsphericity effects on reflected irradiances above the cirrus. Finally, it was shown that the calculated cirrus solar radiative forcing could vary by as much as 26% depending on the ice crystal habit.
Wendisch, Manfred↗
The Diffuse Interstellar Bands: Solving a Century Old Problem
The Diffuse Interstellar Bands (DIBs) are a set of apporoximately 500 absorption bands that are seen in the spectra of reddened stars (i.e., stars obscured by the presence of interstellar clouds in their line of sight). The first DIBs were detected in the visible over a century ago. Diffuse Interstellar Bands are now detected from the near ultraviolet to the near infrared in the spectra of reddened stars spanning a variety of interstellar environments in our local, and in other galaxies. Although DIB carriers are a significant part of the interstellar chemical inventory as they account for a noticeable fraction of the interstellar extinction, the nature of their carriers is still unknown over a century after the detection of the first bands. DIB carriers are stable and ubiquitous in a broad variety of interstellar environments and play a unique role in interstellar physics and chemistry. It has long been realized that the solving of the DIB problem requires a strong synergy between astronomical observations, laboratory astrophysics and astrochemistry, quantum chemistry calculations and astrophysical modeling of line-of-sights. In this review, we'll present and discuss the current state of this perplexing problem. We'll review the progress and the failures that have been encountered in the long quest for the identification of the carriers of these ubiquitous interstellar bands.
Molecules in Space↗
New heterojunction LWIR detector options
Researchers investigate the heterojunction internal photoemission (HIP) approach that potentially offers long wavelength infrared (LWIR) photovoltaic detector performance (single pixel) that is competitive with the best of other approaches being considered. Most significantly, this approach offers a relatively simple device technology that promises producible and uniform FPA's. Researchers emphasize an exciting process based on intervalence band absorption. They investigate both III-V and Si-based heterojunctions grown by molecular beam epitaxy (MBE) in which the barrier can be tailored to the desired cutoff wavelength. In addition, MBE allows one to optimize the device structure with precise control of doping profiles and layer thicknesses, and perform band structure engineering by control of composition and heterojunction strain. Researchers also consider free carrier absorption in heterojunctions. Acceptable absorption coefficients can be achieved in very heavily n(exp +) doped semiconductor layers (approx. equals 10(exp 20)cm(exp -3). However, in this case the appreciable filling of conduction band states leads to a Schottky-like photoresponse with a gradual (quadratic) turn-on above threshold. A more satisfactory approach would be to use p(exp +) doping so that with the higher density of states in the heavy hole valence band there would be a narrow band of occupied states. This gives the desirable effect of a more rapid (linear) turn-on above threshold. Unfortunately, the higher hole effective mass also reduces (inversely) the free carrier absorption. For this and other reasons, the intervalence band absorption process looks much more promising.
Maserjian, Joseph↗
Atmospheric pressure and temperature profiling using near IR differential absorption lidar
The present investigation is concerned with differential absorption lidar techniques for remotely measuring the atmospheric temperature and pressure profile, surface pressure, and cloud top pressure-height. The procedure used in determining the pressure is based on the conduction of high-resolution measurements of absorption in the wings of lines in the oxygen A band. Absorption with respect to these areas is highly pressure sensitive in connection with the mechanism of collisional line broadening. The method of temperature measurement utilizes a determination of the absorption at the center of a selected line in the oxygen A band which originates from a quantum state with high ground state energy.
Korb, C. L.↗
Influence of temperature on the spectrum of water.
Measurement of the normal-incidence spectral reflectance of water at 5, 27, and 70 C in the spectral region between 5000 and 350 per cm. From the measured values of spectral reflectance the optical constants n sub r and n sub i are determined by Kramers-Kronig methods. The band strengths and bandwidths have been determined for the absorption bands near 3400, 1640, and 600 per cm at each temperature. A similar study of deuterium oxide at 27 C has been conducted for purposes of comparison.
Hale, G. M.↗
Ultraviolet reflectivity and geometrical albedo of Titan
Titan's geometrical albedo of 0.094 plus or minus 0.012 was measured at 4255 A with a 50-A bandpass. From this and the spectral measurements, the geometrical albedo was derived as a function of wavelength. It is found that the wavelength dependences of Titan's UV spectrum and of the spectrum of Saturn's Rings are remarkably similar. No trace of any absorption bands is apparent. These results imply that UV gaseous absorption and Rayleigh scattering play a strongly subdued role in Titan's atmosphere. Any homogeneous atmospheric model implies that the absorber responsible for Titan's UV spectral albedo varies strongly with wavelength. On the other hand, it is found that the UV observations can be satisfied by an absorber having a relatively weak dependence upon wavelength if an inhomogeneous atmospheric model is employed. In particular, a fine dust, which absorbs as the reciprocal of the wavelength, can explain the UV observations, provided that it is preferentially distributed high up in Titan's atmosphere where the optical depth from Rayleigh scattering is low.
Barker, E. S.↗
Verification of small-scale water vapor features in VAS imagery using high resolution MAMS imagery
The Multispectral Atmospheric Mapping Sensor (MAMS), a modification of NASA's Airborne Thematic Mapper, is described, and radiances from the MAMS and the VISSR Atmospheric Sounder (VAS) are compared which were collected simultaneously on May 18, 1985. Thermal emission from the earth atmosphere system in eight visible and three infrared spectral bands (12.3, 11.2 and 6.5 microns) are measured by the MAMS at up to 50 m horizontal resolution, and the infrared bands are similar to three of the VAS infrared bands. Similar radiometric performance was found for the two systems, though the MAMS showed somewhat less attenuation from water vapor than VAS because its spectral bands are shifted to shorter wavelengths away from the absorption band center.
Menzel, Paul W.↗
X-Ray and Infrared Observations of Embedded Young Stars in NGC 2264
Images of the NGC 2264 star-forming region, which we have acquired with the XMM-Newton spacecraft, reveal strong X-ray emission from three deeply embedded (Av > 10 mag) young stellar objects in the vicinity of Allen's infrared source (AFGL 989 = IRS 1) and Castelaz & Grasdalen s infrared source (RNO-EW = IRS 2). Thermal plasma models for the brightest source in X-rays, located 11 southwest of Allen's star, yield a quasi-steady luminosity of Lx = 10 ergs s-1 and an extraordinarily high X-ray temperature of 100 MK. The high temperature is consistent with the presence of emission lines of Fe xxv and Fe xxvi at photon energies of 6.7 and 6.9 keV, respectively. An even higher temperature of nearly 140 MK was observed during the rise phase of a powerful impulsive X-ray flare of another young star in the IRS 2 region. Moderate-resolution near-infrared (1-4 um) spectra of the embedded objects, obtained at the NASA Infrared Telescope Facility, exhibit deep water ice absorption bands, as well as a variety of emission and absorption features of H I, CO, and both neutral and ionized metals.
Simon, Theordore↗