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At least 271 records · Page 15

Profiling of Atmospheric Water Vapor with MIR and LASE

This paper presents the first and the only simultaneous measurements of water vapor by MIR (Millimeter-wave Imaging Radiometer) and LASE (Lidar Atmospheric Sounding Experiment) on board the same ER-2 aircraft. Water vapor is one of the most important constituents in the Earth's atmosphere, as its spatial and temporal variations affect a wide spectrum of meteorological phenomena ranging from the formation of clouds to the development of severe storms. Its concentration, as measured in terms of relative humidity, determines the extinction coefficient of atmospheric aerosol particles and therefore visibility. These considerations point to the need for effective and frequent measurements of the atmospheric water vapor. The MIR and LASE instruments provide measurements of water vapor profiles with two markedly different techniques. LASE can give water vapor profiles with excellent vertical resolution under clear condition, while MIR can retrieve water vapor profiles with a crude vertical resolution even under a moderate cloud cover. Additionally, millimeter-wave measurements are relatively simple and provide better spatial coverage.

Wang, J. R.↗

Microparticle cloud imaging and tracking for data-driven plasma science

Oceans of image and particle track data encountered in plasma interactions with microparticle clouds motivate development and applications of machine-learning (ML) algorithms. A local-constant-velocity tracker, a Kohonen neural network or self-organizing map, the feature tracking kit, and U-Net are described and compared with each other for microparticle cloud datasets generated from exploding wires, dusty plasmas, and atmospheric plasmas. Particle density and the signal-to-noise ratio have been identified as two important factors that affect the tracking accuracy. Fast Fourier transform is used to reveal how U-Net, a deep convolutional neural network developed for non-plasma applications, achieves the improvements for noisy scenes. Viscous effects are revealed in the ballistic motions of the particles from the exploding wires and atmospheric plasmas. Subdiffusion of microparticles satisfying Δr 2 ∝t k (k=0.84±0.02) is obtained from the dusty plasma datasets. Microparticle cloud imaging and tracking, when enhanced with data and ML models, present new possibilities for plasma physics.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ignition of a Combustible Atmosphere by Incandescent Carbon Wear Particles

A study was made to determine whether carbon wear particles from carbon elements in sliding contact with a metal surface were sufficiently hot to cause ignition of a combustible atmosphere. In some machinery, electric potential differences and currents may appear at the carbon-metal interface. For this reason the effect of these voltages and currents on the ability of carbon wear particles to cause ignition was evaluated. The test specimens used in the investigation were carbon vanes taken from a fuel pump and flat 21-inch-diameter 2 metal disks (440-C stainless steel) representing the pump housing. During each experiment a vane was loaded against a disk with a 0.5-pound force, and the disk was rotated to give a surface speed of 3140 feet per minute. The chamber of the apparatus that housed the vane and the disk was filled with a combustible mixture of air and propane. Various voltages and amperages were applied across the vane-disk interface. Experiments were conducted at temperatures of 75, 350, 400, and 450 F. Fires were produced by incandescent carbon wear particles obtained at conditions of electric potential as low as 106 volts and 0.3 ampere at 400 F. Ignitions were obtained only with carbon wear particles produced with an electric potential across the carbon-vane-disk interface. No ignitions were obtained with carbon wear particles produced in the absence of this potential; also, the potential difference produced no ignitions in the absence of carbon wear particles. A film supplement showing ignition by incandescent wear particles is available.

Buckley, Donald H.↗

The theory of charged particle temperatures in the upper atmosphere.

The thermal structure of the earth's upper atmosphere is examined in detail, with emphasis on the physical processes that govern the behavior of charged-particle temperatures. The characteristic features of and competition between the heating, cooling, and thermal conduction processes that govern electron and ion temperatures in the mid-latitude and auroral ionospheric regions are theoretically analyzed, and appropriate comparisons are made with experimental data. The proposed elaborate theory is considered qualitatively successful in accounting for the thermal structure of the ionosphere, and points requiring quantitative verification are delineated.

Schunk, R. W.↗

An Electrostatic Precipitator System for the Martian Environment

Human exploration missions to Mars will require the development of technologies for the utilization of the planet's own resources for the production of commodities. However, the Martian atmosphere contains large amounts of dust. The extraction of commodities from this atmosphere requires prior removal of this dust. We report on our development of an electrostatic precipitator able to collect Martian simulated dust particles in atmospheric conditions approaching those of Mars. Extensive experiments with an initial prototype in a simulated Martian atmosphere showed efficiencies of 99%. The design of a second prototype with aerosolized Martian simulated dust in a flow-through is described. Keywords: Space applications, electrostatic precipitator, particle control, particle charging

Calle, C. I.↗

Correlation of Upper-Atmospheric 7-Be with Solar Energetic Particle Events

A surprisingly large concentration of radioactive 7-Be was observed in the upper atmosphere at altitudes above 320 km on the LDEF satellite that was recovered in January 1990. We report on follow-up experiments on Russian spacecraft at altitudes of 167 to 370 km during the period of 1996 to 1999, specifically designed to measure 7-Be concentrations in low earth orbit. Our data show a significant correlation between the 7-Be concentration and the solar energetic proton fluence at Earth, but not with the overall solar activity. During periods of low solar proton fluence, the concentration is correlated with the galactic cosmic ray fluence. This indicates that spallation of atmospheric N by both solar energetic particles and cosmic rays is the primary source of 7-Be in the ionosphere.

Phillips, G. W.↗

Photochemical reactions on aerosols at West Antarctica: A molecular case-study of nitrate formation among sea salt aerosols

Environmental implications of climate change are complex and exhibit regional variations both within and between the polar regions. The increase of solar UV radiation flux over Antarctica due to stratospheric ozone depletion creates the optimal conditions for photochemical reactions on the snow. Modeling, laboratory, and indirect field studies suggest that snowpack process release gases to the atmosphere that can react on sea salt particles in remote regions such as Antarctica, modifying aerosol composition and physical properties of aerosols. Here, we present evidence of photochemical processing in West Antarctica aerosols using microscopic and chemical speciation of individual atmospheric particles. Individual aerosol particles collected at the Brazilian module Criosfera 1 were analyzed by scanning transmission X-ray microscopy with near edge X-ray absorption fine structure spectroscopy (STXM/NEXAFS) combined with computer controlled scanning electron microscopy (CCSEM) with energy-dispersive X-ray (EDX) microanalysis. The displacement of chlorine relative to sodium was observed over most of the sea salt particles. Particles with a chemical composition consistent with NaCl-NO3 contributed up to 30% of atmospheric particles investigated. Overall, this study provides evidence that the snowpack and particulate nitrate photolysis should be considered in dynamic partition equilibrium in the troposphere. Finally, these findings may assist in reducing modeling uncertainties and present new insights into the aerosol chemical composition in the polar environment.

54 ENVIRONMENTAL SCIENCES↗

Effect of inorganic-to-organic mass ratio on the heterogeneous OH reaction rates of erythritol: implications for atmospheric chemical stability of 2-methyltetrols

The 2-methyltetrols have been widely chosen as chemical tracers for isoprene-derived secondary organic aerosols. While they are often assumed to be relatively unreactive, a laboratory study reported that pure erythritol particles (an analog of 2-methyltetrols) can be heterogeneously oxidized by gas-phase OH radicals at a significant rate. This might question the efficacy of these compounds as tracers in aerosol source-apportionment studies. Additional uncertainty could arise as organic compounds and inorganic salts often coexist in atmospheric particles. To gain more insights into the chemical stability of 2-methyltetrols in atmospheric particles, this study investigates the heterogeneous OH oxidation of pure erythritol particles and particles containing erythritol and ammonium sulfate (AS) at different dry inorganic-to-organic mass ratios (IOR) in an aerosol flow tube reactor at a high relative humidity of 85 %. The same reaction products are formed upon heterogenous OH oxidation of erythritol and erythritol–AS particles, suggesting that the reaction pathways are not strongly affected by the presence and amount of AS. On the other hand, the effective OH uptake coefficient, $γ_{eff}$, is found to decrease by about a factor of ~20 from 0.45±0.025 to 0.02±0.001 when the relative abundance of AS increases and the IOR increases from 0.0 to 5.0. One likely explanation is the presence of dissolved ions slows down the reaction rates by decreasing the surface concentration of erythritol and reducing the frequency of collision between erythritol and gas-phase OH radicals at the particle surface. Hence, the heterogeneous OH reactivity of erythritol and likely 2-methyltetrols in atmospheric particles would be slower than previously thought when the salts are present. Given 2-methyltetrols often coexist with a significant amount of AS in many environments, where ambient IOR can vary from ~1.89 to ~250, our kinetic data would suggest that 2-methyltetrols in atmospheric particles are likely chemically stable against heterogeneous OH oxidation under humid conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Atmospheric correlation time measurements using coherent CO2 lidar

A pulsed TEA-CO2 lidar with coherent detection was used to measure the correlation time of backscatter from an ensemble of atmospheric aerosol particles which are illuminated by the pulsed radiation. The correlation time of the backscatter return signal is important in studies of atmospheric turbulence and its effects on optical propagation and backscatter. If the temporal coherence of the pulse is large enough, then the temporal coherence of the return signal is dominated by the turbulence and shear for a variety of interesting atmospheric conditions. Various techniques for correlation time measurement are discussed and evaluated.

Ancellet, G. M.↗

Direct EPP Affects on the Middle Atmosphere

Energetic precipitating particles (EPPs) can cause significant direct constituent changes in the mesosphere and stratosphere (middle atmosphere) during certain periods. Both protons and electrons can influence the polar middle atmosphere through ionization and dissociation processes. EPPs can enhance HOx (H, OH, HO2) through the formation of positive ions followed by complex ion chemistry and NOx (N, NO, NO2) through the dissociation of molecular nitrogen. The HOx increases result in direct ozone destruction in the mesosphere and upper stratosphere via several catalytic loss cycles. Such middle atmospheric HOx-caused ozone loss is rather short-lived due to the relatively short lifetime (hours) of the HOx constituents. The NOx family has a considerably longer lifetime than the HOx family and can also lead to catalytic ozone destruction. EPP-caused enhancements of the NOx family can affect ozone directly, if produced in the stratosphere. Ozone decreases from the EPPs lead to a reduction in atmospheric heating and, subsequent atmospheric cooling. Conversely, EPPs can cause direct atmospheric heating through Joule heating. Measured HOx constituents OH and HO2 showed increases due to solar protons. Observed NOx constituents NO and NO2 were enhanced due to both solar protons and precipitating electrons. Other hydrogen- and nitrogen-ocntaining constituents were also measured to be directly influenced by EPPs, including N2O, HNO3, HO2NO2, N2OS, H2O2, ClONO2, HCl, and HOCl. Observed constituents ClO and CO were directly affected by EPPs as well. Many measurements indicated significant direct ozone decreases. A significant number of satellites housed instruments, which observed direct EPP-caused atmospheric effects, including Nimbus 4 (BUV), Nimbus 7 (SBUV), several NOAA platforms (SBUV/2), SME, UARS (HALOE, CLAES), SCISAT-1 (ACE-FTS), Odin (OSIRIS), Envisat-l (GOMOS, MIPAS, SCIAMACHY), and Aura (MLS). Measurements by rockets and ground-based radar also indicated EPP direct impacts. Atmospheric models have been used with some success in predicting the direct EPP impacts on the mesosphere and stratosphere. A review of the observed direct effects of EPP on the middle atmosphere will be given in this presentation.

Jackman, Charles H.↗

Shortwave absorption by wildfire smoke dominated by dark brown carbon

Abstract Wildfires emit large amounts of black carbon and light-absorbing organic carbon, known as brown carbon, into the atmosphere. These particles perturb Earth’s radiation budget through absorption of incoming shortwave radiation. It is generally thought that brown carbon loses its absorptivity after emission in the atmosphere due to sunlight-driven photochemical bleaching. Consequently, the atmospheric warming effect exerted by brown carbon remains highly variable and poorly represented in climate models compared with that of the relatively nonreactive black carbon. Given that wildfires are predicted to increase globally in the coming decades, it is increasingly important to quantify these radiative impacts. Here we present measurements of ensemble-scale and particle-scale shortwave absorption in smoke plumes from wildfires in the western United States. We find that a type of dark brown carbon contributes three-quarters of the short visible light absorption and half of the long visible light absorption. This strongly absorbing organic aerosol species is water insoluble, resists daytime photobleaching and increases in absorptivity with night-time atmospheric processing. Our findings suggest that parameterizations of brown carbon in climate models need to be revised to improve the estimation of smoke aerosol radiative forcing and associated warming.

54 ENVIRONMENTAL SCIENCES↗

Topical Issue on Optical Particle Characterization and Remote Sensing of the Atmosphere: Part I

Increasing our understanding of the Earth-atmosphere system has been a scientific and political priority for the last few decades. This system not only touches on environmental science, but it has applicability to our broader understanding of planetary atmospheres in general. While this issue focuses primarily on electromagnetics, other fundamental fields of science, including fluid and thermodynamics play major roles. In recent years, significant research efforts have led to advances in the fields of radiative transfer and electromagnetic scattering from irregularly shaped particles. Recently, several workshops and small conferences have taken place to promote the fusion of these efforts. Late in 2013, for instance, two such meetings took place. The Optical Characterization of Atmospheric Aerosols (OCAA) meeting took place in Smolenice, Slovakia to promote a better understanding of microphysical properties of aerosol particles, and the characterization of such atmospheric particles using optical techniques. A complementary conference was organized in Nagoya, Japan, the 3rd International Symposium on Atmospheric Light Scattering and Remote Sensing (ISALSaRS), whose goal is to fuse the advances achieved in particle characterization with remote-sensing techniques. While the focus of these meetings is slightly different, they represent the same aspects of this rapidly growing field. This Topical Issue is the first of two parts. Within this issue we analyze different aspects of the problem of atmospheric characterization and present a broad overview of the topical area. Research includes theory and experiment, ranging from fundamental microphysical properties of individual aerosol particles to broad characterizations of atmospheric properties. Since this is an active field, we also have encouraged the submission of ideas for new methodologies that may represent the future of the field.

aerosols↗

Atmospheric pion, kaon, and muon fluxes for sub-orbital experiments

Cosmic rays interacting with the Earth's atmosphere generate extensive air showers, which produce Cherenkov, fluorescence and radio emissions. These emissions are key signatures for detection by ground-based, sub-orbital, and satellite-based telescopes aiming to study high energy cosmic ray and neutrino events. However, detectors operating at ground and balloon altitudes are also exposed to a background of atmospheric charged particles, primarily pions, kaons, and muons, that can mimic or obscure the signals from astrophysical sources. In this work, we use coupled cascade equations to calculate the atmospheric pion, kaon and muon fluxes reaching detectors at various altitudes. Our analysis focuses on energies above 10 GeV, where the influence of the Earth's magnetic field on particle trajectories is minimal. We provide angular and energy-resolved flux estimates and discuss their relevance as background for extensive air shower detection. Furthermore, our results are potentially relevant for interpreting data from current and future balloon-borne experiments such as EUSO-SPB2 and for refining trigger and veto strategies in Cherenkov and fluorescence telescopes.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A balloon measurement of the cosmic ray element abundances

The experiment described was flown from Thompson, Canada in August, 1973 to measure the cosmic ray element abundances in the atmosphere. All particles used in the analysis, including approximately 25,000 oxygen and 1600 iron nuclei, had sufficient energy at the top of the atmosphere to trigger the Cerenkov counter. Nuclei between beryllium and nickel were identified, using two plastic scintillators and an acrylic plastic Cerenkov counter. The relative composition and fluxes are determined. Agreement with earlier measurements in the atmosphere is within 5%; however, larger differences appear in composition extrapolated to the top of the atmosphere. In particular, the nitrogen abundance is almost 20% higher and the iron abundance is 20% lower than the generally accepted values.

Ormes, J. F.↗

Chapter 7: Sun Photometers

Sun photometry is an extended technique for monitoring the atmospheric composition and support satellite product validation. By measuring the direct solar irradiance, the amount and characteristics of the atmospheric aerosol particles, precipitable water vapor column, and ozone columns can be derived. Global operational networks such as the Aerosol Robotic Network (AERONET), Global Atmosphere Watch-Precision Filter Radiometer Network (GAW-PFR), Maritime Aerosol Network (MAN), or the Brewer spectrophotometer networks constitute sustained efforts for long-term monitoring of the atmosphere, with invaluable data production using cost-effective and relatively simple instrumentation. The data quality relies on the standardization of these networks, with special emphasis on the calibration as the key element in Sun photometry.

Sun photometry↗

Parameterization of Shortwave Cloud Optical Properties for a Mixture of Ice Particle Habits for use in Atmospheric Models

Based on the single-scattering optical properties pre-computed with an improved geometric optics method, the bulk absorption coefficient, single-scattering albedo, and asymmetry factor of ice particles have been parameterized as a function of the effective particle size of a mixture of ice habits, the ice water amount, and spectral band. The parameterization has been applied to computing fluxes for sample clouds with various particle size distributions and assumed mixtures of particle habits. It is found that flux calculations are not overly sensitive to the assumed particle habits if the definition of the effective particle size is consistent with the particle habits that the parameterization is based. Otherwise, the error in the flux calculations could reach a magnitude unacceptable for climate studies. Different from many previous studies, the parameterization requires only an effective particle size representing all ice habits in a cloud layer, but not the effective size of individual ice habits.

Chou, Ming-Dah↗

Abrasion

Particle erosion of spacecraft surface is considered in aerospace vehicle and associated facility designs. When the speed of the spacecraft with relation to atmospheric suspended particles is high, erosion occurs even when the particles have a hardness less than the exposed surface. Surface impact damage parameters are developed for sand, dust, raindrops, snow, and hail particles at earth surface and at altitude.

Glenn E Daniels↗

The Global Backscatter Experiment Airborne Pulsed Lidar Measurements

The Global Backscatter Experiment (GLOBE) was intended to provide data on prevailing values of atmospheric backscatter cross section. The primary intent was predicting the performance of space-borne lidar systems. A second and related goal was to understand the source and characteristics of atmospheric aerosol particles. In this paper the authors give a summary of measurement results with emphasis on the magnitude, structure, characteristics and variability of the observed atmospheric aerosol and cloud scattering. The GLOBE pulsed lidar measurements provide an extensive data set on the magnitude and variability of aerosol and cloud backscatter of the atmosphere. The data defines atmospheric aerosol scattering characteristics and should prove to be an important resource for determination of the performance and design of laser remote sensing instruments.

Spinhirne, James D.↗