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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Organic non-aqueous cation-based redox flow batteries

The present invention provides a non-aqueous redox flow battery comprising a negative electrode immersed in a non-aqueous liquid negative electrolyte, a positive electrode immersed in a non-aqueous liquid positive electrolyte, and a cation-permeable separator (e.g., a porous membrane, film, sheet, or panel) between the negative electrolyte from the positive electrolyte. During charging and discharging, the electrolytes are circulated over their respective electrodes. The electrolytes each comprise an electrolyte salt (e.g., a lithium or sodium salt), a transition-metal free redox reactant, and optionally an electrochemically stable organic solvent. Each redox reactant is selected from an organic compound comprising a conjugated unsaturated moiety, a boron cluster compound, and a combination thereof. The organic redox reactant of the positive electrolyte is selected to have a higher redox potential than the redox reactant of the negative electrolyte.

25 ENERGY STORAGE↗
DOE OSTI2018

Organic non-aqueous cation-based redox flow batteries

The present invention provides a non-aqueous redox flow battery comprising a negative electrode immersed in a non-aqueous liquid negative electrolyte, a positive electrode immersed in a non-aqueous liquid positive electrolyte, and a cation-permeable separator (e.g., a porous membrane, film, sheet, or panel) between the negative electrolyte from the positive electrolyte. During charging and discharging, the electrolytes are circulated over their respective electrodes. The electrolytes each comprise an electrolyte salt (e.g., a lithium or sodium salt), a transition-metal free redox reactant, and optionally an electrochemically stable organic solvent. Each redox reactant is selected from an organic compound comprising a conjugated unsaturated moiety, a boron cluster compound, and a combination thereof. The organic redox reactant of the positive electrolyte comprises a tetrafluorohydroquinone ether compound or a tetrafluorocatechol ether compound.

25 ENERGY STORAGE↗
DOE OSTI2019

Aqueous pyridinium cation-based redox flow batteries

The present invention provides an aqueous redox flow battery comprising a negative electrode immersed in an aqueous liquid negative electrolyte, a positive electrode immersed in an aqueous liquid positive electrolyte, and a cation-permeable separator (e.g., a porous membrane, film, sheet, or panel) between the negative electrolyte from the positive electrolyte. During charging and discharging, the electrolytes are circulated over their respective electrodes. The electrolytes each comprise an electrolyte salt (e.g., a lithium or sodium salt), a redox reactant. The negative redox reactant comprises a pyridinium compound of Formula (I) as described in the specification.

25 ENERGY STORAGE↗
DOE OSTI2019

Organic non-aqueous cation-based redox flow batteries

The present invention provides a non-aqueous redox flow battery comprising a negative electrode immersed in a non-aqueous liquid negative electrolyte, a positive electrode immersed in a non-aqueous liquid positive electrolyte, and a cation-permeable separator (e.g., a porous membrane, film, sheet, or panel) between the negative electrolyte from the positive electrolyte. During charging and discharging, the electrolytes are circulated over their respective electrodes. The electrolytes each comprise an electrolyte salt (e.g., a lithium or sodium salt), a transition-metal free redox reactant, and optionally an electrochemically stable organic solvent. The redox reactant of the positive electrolyte is a dialkoxybenzene compound, and the redox reactant of the negative electrolyte is a viologen compound or a dipyridyl ketone.

Zhang, Lu↗
DOE OSTI2020

Conjugate Heat Transfer Analysis of the Supercritical CO2 Based Counter Flow Compact 3D Heat Exchangers

Compact heat exchangers using supercritical fluids such as CO2 are preferred due to their high heat transfer capacity and smaller footprint. Three-dimensional conjugate forced convection heat transfer analysis was performed on several shell-and-tube counter-flow microchannel heat exchangers. Numerical simulations were conducted to test effect of change in mass flow rate, hydraulic diameter and various cross sections on the heat transfer. Increasing mass flow rate improved heat transfer up to a maximum value and then decreased downstream with increasing turbulence. Maximum heat transfer was obtained for the micro channel with the smallest hydraulic diameter. Amongst the cross sections analyzed (circular, square, circular with radial ribs, and square with radial ribs), the most uniform distribution of temperature and maximum heat transfer were obtained for circular cross section with radial ribs. An optimally efficient operation of such a heat exchanger can be attained by considering these factors during multi-objective constrained optimization of geometric parameters and requirements for additive manufacturing of such compact heat exchangers.

Chitale, Janhavi↗
NASA NTRS1972

Basic flow characteristics of a linear aerospike nozzle segment.

The separated base flow region within a linear aerospike nozzle segment is investigated experimentally in an ejector-diffuser system. The nozzle-diffuser system and base pressure characteristics are described over the pressure ratio range from the 'open wake' to the 'closed wake' operation. Schlieren photographs and static pressure distributions along the test section centerline and top contour describe the transition from 'open wake' to 'closed wake' flow fields. Base pressure and static pressure distributions are utilized to present the effects of a ramp diffuser. The effects of base bleed on the base pressure ratio and structure of the nozzle flow field are also presented.

Mueller, T. J.↗
NASA NTRS2009

Microfluidic Mixing Technology for a Universal Health Sensor

A highly efficient means of microfluidic mixing has been created for use with the rHEALTH sensor an elliptical mixer and passive curvilinear mixing patterns. The rHEALTH sensor provides rapid, handheld, complete blood count, cell differential counts, electrolyte measurements, and other lab tests based on a reusable, flow-based microfluidic platform. These geometries allow for cleaning in a reusable manner, and also allow for complete mixing of fluid streams. The microfluidic mixing is performed by flowing two streams of fluid into an elliptical or curvilinear design that allows the combination of the flows into one channel. The mixing is accomplished by either chaotic advection around micro - fluidic loops. All components of the microfluidic chip are flow-through, meaning that cleaning solution can be introduced into the chip to flush out cells, plasma proteins, and dye. Tests were performed on multiple chip geometries to show that cleaning is efficient in any flowthrough design. The conclusion from these experiments is that the chip can indeed be flushed out with microliter volumes of solution and biological samples are cleaned readily from the chip with minimal effort. The technology can be applied in real-time health monitoring at patient s bedside or in a doctor s office, and real-time clinical intervention in acute situations. It also can be used for daily measurement of hematocrit for patients on anticoagulant drugs, or to detect acute myocardial damage outside a hospital.

Chan, Eugene Y.↗
NASA NTRSDate not supplied

rHealth One Demonstration Aboard ISS: A Microfluidic Bioanalyzer Based on Sheath/Hydrodynamic Focusing Flow Cytometry

The Exploration Medical Capability (ExMC) element aims to provide astronauts with the means for their own health monitoring, diagnosis, and treatment during exploration missions. As space flight ventures further from earth, the need for autonomous medical care increases under greater constraints on size, mass, and resources. One pillar for diagnosis that crew would be separated from is laboratory analysis. Even now on ISS, blood samples must be collected and returned to earth for testing. In response, ExMC is assessing how assays for hematology, bone health, radiation exposure etc. could be addressed through commercial-off-the-shelf (COTS) and Small Business Innovation Research (SBIR) funded bioanalyzers that are miniaturizing lab technology. Since missions will reach distances where there are no timely replacements, validation on the International Space Station (ISS) is a necessary part of that assessment. In partnership with NASA Johnson Space Center (JSC) Immunology Lab and the Research Operations and Integration (ROI) element, ExMC conducted a technology demonstration on ISS of the rHEALTH ONE, a flow cytometry based bioanalyzer, to assess future devices based on this design. In flow cytometry, there are predominantly three ways to focus the cells (or particles) into a single file stream: hydrodynamic focusing, microcapillary, and acoustic focusing. The rHEALTH ONE utilizes the commercial standard, sheath-based hydrodynamic focusing. rHEALTH itself represents both a company and a suite of medical tools NASA has funded through SBIR grants towards the development of a promising diagnosis instrument for exploration missions. rHEALTH ONE is the interim version of the technology, functional as a benchtop analyzer and test bed for the next generation of rHEALTH in development. Several modifications were made to the rHEALTH ONE analyzer for operation in microgravity. For function, fluid management was key. A sheath-based analyzer uses sheath fluid to flow the sample, cleaning fluid to prevent biological contamination, and a reservoir to collect the liquid waste. The rHEALTH ONE analyzer uses bottles dependent on gravity to separate the air and liquid pathways and keep the liquids contained. It uses only 1 psig of air pressure to directly push the liquid through the device, requiring little-to-no resistance at inlet and outlet. A microtubing assembly with self-sealing luer connectors was designed – featuring 0.014 mm thick durable medical balloons to hold water inside the supply bottles – to create safe containment and easy access for the crew while maintaining the analyzer’s function. For safety, copper tape was added to the interior of the plastic housing to reduce electromagnetic interference, fluid and electrical connections were secured against vibration and leaks, and gaps were further sealed to ensure containment of the optical block and lasers. Water as the sheath and cleaning fluid and TOX 0 samples were used to reduce the biohazard risk to the crew. In May 2022, European Space Agency astronaut Samantha Cristoforetti demonstrated the rHEALTH ONE aboard ISS for its sample loading, flow cytometry, and data collection capability in microgravity. The JSC Immunology Lab provided flow cytometry expertise, designed the sample test protocol, and manufactured and benchmarked the flight samples on a ‘gold-standard’ flow cytometer. The analyzer was primed with water, purged of air, and four calibration solutions of polystyrene microparticles were tested to characterize its performance. Tightly controlled procedures and excellent execution prevented air bubble interference during air/water separation, fluid transfer, sample mixing and loading. Data showed a slight increase in signal noise on 3 of 5 channels and an anomaly of fluorophores migrating in one sample (confirmed by JSC post-flight). Flight results correctly detected the change in sample, matched the analyzer’s ground performance, and were consistent with the gold-standard’s ground results. Although areas were noted for improvement, these outcomes signified complete mission success.

R. S. Miller↗
NASA NTRS1951

Investigation at Mach Number 1.91 of Side and Base Pressure Distributions over Conical Boattails Without and with Jet Flow Issuing from Base

Experimental side and bade pressure distributions over a series of conical boattails without and with jet flow from the base are presented at a Mach number of 1.91. For the case of no jet flow the methods of characteristics and linearized theory are shown to overpredict the side pressure drag. A semi-empirical theory is presented to predict the effect of boattail angle on base pressure. With the boattail extending to a sharp edge at the nozzle exit, the over-pressure jet is shown to decrease the side pressure drag. Presence of an annular base may eliminate the effect of the jet on the side pressure drag, but the jet effect on the base pressure drag may greatly increase or decrease the total boattail drag.

FLOW, JET MIXING↗
DOE OSTI2024

MENT-Flow: maximum-entropy phase space tomography using normalizing flows

Generative models can be trained to reproduce low-dimensional projections of high-dimensional phase space distributions. Normalizing flows are generative models that parameterize invertible transformations, allowing exact probability density evaluation and sampling. Consequently, flows are unbiased entropy estimators and could be used to solve the high-dimensional maximum-entropy tomography (MENT) problem. In this work, we evaluate a flow-based MENT solver (MENT-Flow) against exact maximum-entropy solutions and Minerbo's iterative MENT algorithm in two dimensions.

Hoover, Austin↗
NASA NTRS1985

AOTV bluff body flow - Relaxation algorithm

Preliminary investigations have led to the consideration of two classes of energy efficient aeroassisted orbital transfer vehicle (AOTV) concepts, with high and low L/D. The AOTV represent reentry space vehicles which are to fly hypersonically in the continuum upper reaches of the atmosphere. Problems arise in connection with convective and nonequilibrium radiative heating. As the possibilities for obtaining needed information by experimentation are limited, reliance must be placed on computational techniques to simulate testing of design concepts. A new relaxation algorithm for the compressible Navier-Stokes equations has been developed in the context of recent work with a conservative flux difference eigenvector split implicit upwind scheme CSCM (conservative supracharacteristics method). Attention is given to the CSCM implicit method, and early results for axisymmetric bluff body flow including complete forebody and base flow for a free flight range model drag brake AOTV.

Lombard, C. K.↗
NASA NTRS2023

Analysis of Strategic Conflict Management Approaches as Applied to Simulated UAM Operations

This report presents the results of a comparison analysis of candidate Strategic Conflict Management (SCM) strategies as applied to Urban Air Mobility (UAM) operations. The SCM strategies investigated included: no SCM, resource scheduling (RS), resource flow rates (FR), area-based flow rates (AR), and conflict detection and resolution (CR). The study evaluated each strategy against the same 3 levels of flight demand in a representative airspace construct for the Dallas/Fort Worth region. The study also accounted for different levels of uncertainty in operational planning and equivalent levels of trajectory following error. In the analysis, we compared the SCM strategies’ effectiveness in reducing the need for the tactical conflict management layer to act and looked at the metrics of unmitigated losses-of-separation (LOS), flight delays imposed by strategic planning, and throughput of the overall airspace. The study results indicated that the CR strategy was the most effective at reducing LOS and percentage of flights with LOS, even in the presence of trajectory error when uncertainty is accounted for in planning. Thus, if the objective is to reduce the number of actions that the tactical conflict management layer will have to take, in terms of conflicts that may need to be resolved, CR is the strategy to use. The FR strategy was found to be the worst at reducing LOS and percentage of flights with LOS. Thus, it is not very effective at reducing the actions required by a tactical conflict management layer. In the airspace tested, the demand was high enough to produce unacceptable levels of flight delay and reductions of throughput when the SCM strategies were implemented. This was especially evident at the higher levels of trajectory uncertainty and error. The need to account for expected levels of uncertainty becomes more and more important as the demand level increases and as the level of trajectory error increases. This is because the likelihood of flights with LOS increases as the density of operations increases and as the level of trajectory error increases. Accounting for uncertainty in the SCM strategies improves the strategy effectiveness with respect to LOS but increases delays and reduces throughput. Thus, there is a tradeoff between scalability and allowable levels of uncertainty. That is, we can implement an air traffic management construct that allows high levels of uncertainty, but we can expect that same system to have limits on scalability that may be evident even at small demand levels, such as those used in this study. Therefore, the results in this study indicate that an air traffic system should attempt to implement mechanisms appropriate for reducing uncertainty where possible in order to increase the chances for scalability. And this increased level of predictability of operations needs to be balanced with mechanisms for ensuring flexibility when operational conditions and plans need to change, even though those types of changes should be the exception rather than the rule under normal conditions. The study also introduced a trade space that could serve as a mechanism for selecting the appropriate SCM strategy in a trade-off between uncertainty and error, mean flight delay, and the LOS metrics (which this study equates to the potential for tactical conflict management actions). The optimal solution for a given airspace, demand level, and other factors, could likely be a combination of SCM strategies, although this study only compared the use of a single SCM strategy at a time. The CR strategy appeared to have the best opportunity for scalability by limiting the number of potential tactical actions to nearly zero.

Strategic Conflict Management↗