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At least 271 records · Page 15

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NASA NTRS2015

Thermionic Properties of Carbon Based Nanomaterials Produced by Microhollow Cathode PECVD

Thermionic emission is the process in which materials at sufficiently high temperature spontaneously emit electrons. This process occurs when electrons in a material gain sufficient thermal energy from heating to overcome the material's potential barrier, referred to as the work function. For most bulk materials very high temperatures (greater than 1500 K) are needed to produce appreciable emission. Carbon‐based nanomaterials have shown significant promise as emission materials because of their low work functions, nanoscale geometry, and negative electron affinity. One method of producing these materials is through the process known as microhollow cathode PECVD. In a microhollow cathode plasma, high energy electrons oscillate at very high energies through the Pendel effect. These high energy electrons create numerous radical species and the technique has been shown to be an effective method of growing carbon based nanomaterials. In this work, we explore the thermionic emission properties of carbon based nanomaterials produced by microhollow cathode PECVD under a variety of synthesis conditions. Initial studies demonstrate measureable current at low temperatures (approximately 800 K) and work functions (approximately 3.3 eV) for these materials.

Haase, John R.↗

NASA NTRS2008

Assessments of Hollow Cathode Wear in the Xenon Ion Propulsion System (XIPs(c)) by Numerical Analyses and Wear Tests

The standard approach presently followed by NASA to qualify electric propulsion for the required mission throughput has been based largely on life tests, which can be costly and time consuming. Revised electric propulsion lifequalification approaches are being formulated that combine analytical and/or computational methods with (shorter-duration) wear tests. As a model case, a wear test is being performed at JPL to assess the lifetime of the discharge hollow cathode in the Xenon Ion Propulsion System (XIPS(c)), a 25-cm ion engine developed by L-3 Communications Electron Technologies, Inc. for commercial applications. Wear and plasma data accumulated throughout this life-assessment program are being used to validate the existing 2-D hollow cathode code OrCa2D. We find that the OrCa2D steady-state solution predicts very well the time-averaged plasma data and the keeper voltage after 5500 hrs of operation in high-power mode. When the wave motion that occurs naturally in these devices is accounted for, based on an estimate of the maximum wave amplitude, the molybdenum-keeper erosion profile observed in the XIPS(c) discharge cathode is also reproduced within a factor of two of the observation. When the same model is applied to predict the erosion of a tantalum keeper we find that erosion is reduced by more than two orders of magnitude compared to the molybdenum keeper due the significantly lower sputtering yield of tantalum. A tantalum keeper would therefore allow keeper lifetimes that greatly exceed the present requirements for deep-space robotic missions considered by NASA. Moreover, such large reduction of the erosion renders the largest uncertainties in the models, which are associated with the wave amplitude estimates and the electron transport model, negligible.

plasma simulations↗

NASA NTRS2015

High-Capacity, High-Voltage Composite Oxide Cathode Materials

This SBIR project integrates theoretical and experimental work to enable a new generation of high-capacity, high-voltage cathode materials that will lead to high-performance, robust energy storage systems. At low operating temperatures, commercially available electrode materials for lithium-ion (Li-ion) batteries do not meet energy and power requirements for NASA's planned exploration activities. NEI Corporation, in partnership with the University of California, San Diego, has developed layered composite cathode materials that increase power and energy densities at temperatures as low as 0 degC and considerably reduce the overall volume and weight of battery packs. In Phase I of the project, through innovations in the structure and morphology of composite electrode particles, the partners successfully demonstrated an energy density exceeding 1,000 Wh/kg at 4 V at room temperature. In Phase II, the team enhanced the kinetics of Li-ion transport and electronic conductivity at 0 degC. An important feature of the composite cathode is that it has at least two components that are structurally integrated. The layered material is electrochemically inactive; however, upon structural integration with a spinel material, the layered material can be electrochemically activated and deliver a large amount of energy with stable cycling.

Hagh, Nader M.↗

NASA NTRS2014

Investigation of Energetic Ions in a 100-A Hollow Cathode

The role of ion acoustic turbulence in the formation of high-energy ion tails in the plume of a 100-A LaB6 hollow cathode is experimentally and theoretically examined. At fixed flow rate and varying discharge current, single-point measurements of fluctuation intensity in the cathode plume are taken and compared to ion energy measurements. It is shown that for high discharge current the formation of energetic ions is correlated with the amplitude of the ion acoustic turbulence. Two-dimensional maps of background plasma parameters and wave turbulence are made at the highest discharge current investigated, 140 A. A simple, one-dimensional quasilinear model for the interaction of the ion energy distribution with the ion acoustic turbulence is employed, and it is shown that the energy in the measured wave turbulence is sufficiently large to explain the formation of ion tails in the cathode plume. Mitigation techniques for minimizing the amplitude of the turbulence are discussed.

ion acoustic turbulence↗

NASA NTRS2016

Wear Test Demonstration of a Technique to Mitigate Keeper Erosion in a High-Current LaB6 Hollow Cathode

The results of a wear test on a 100-A LaB6 hollow cathode are presented as verification of a technique to mitigate keeper erosion caused by sputtering from anomalously high-energy ions. The ions responsible for this erosion have been theorized to result from the onset ion acoustic turbulence in the plume of the cathode. The proposed technique to minimize the erosion relies on identifying operating conditions where the energy of the ion acoustic turbulence is low. 100 hour wear tests are conducted on a high-current hollow cathode with a molybdenum keeper at three operating conditions: two with low turbulence levels and one with high turbulence levels. It is demonstrated that the keeper exhibits low levels erosion (at a peak erosion rate of around 0.035 um/hour) that can be explained by classical mechanisms at the low turbulence states, and anomalously high sputtering (at a peak erosion rate of.07 um/hour) at the high erosion state.

Ho, Amanda K.↗

NASA NTRS2019

Qualification of the Flight Heaters for the NEXT-C Hollow Cathodes

After successful validation of the design, swaged cathode heaters have been delivered by the NASA Glenn Research Center to Aerojet Rocketdyne for the fabrication of the NEXT-C ion thruster. NASA Glenn Research Center re-established and validated process controls as well as completed cyclic life testing of development heaters. Following an extensive requalification program, fabrication of a flight batch of heaters was executed using the qualified process controls. Of the 28 heaters fabricated in this flight batch, a set of six heaters were acceptance and cyclic tested to verify conformance with operational requirements. Upon completion of 200 percent of the NEXT-C cyclic requirement, the heater batch was certified by NASA for use in the flight hollow cathodes. Nine heaters from the batch of 28 were provided to Aerojet Rocketdyne in early 2018 for cathode fabrication. This paper summarizes the acceptance and cyclic life testing of the flight heaters and preliminary findings of post-test analyses.

Arthur, Neil↗

NASA NTRS2019

Qualification of the Flight Heaters for the NEXT-C Hollow Cathodes

After successful validation of the design, swaged cathode heaters have been delivered by the NASA Glenn Research Center to Aerojet Rocketdyne for the fabrication of the NEXT-C ion thruster . NASA Glenn Research Center re-established and validated process controls as well as completed cyclic life testing of development heaters. Following an extensive requalification program, fabrication of a flight batch of heaters was executed using the qualified process controls. Of the 28 heaters fabricated in this flight batch, a set of six heaters were acceptance and cyclic tested to verify conformance with operational requirements. Upon completion of 200 percent of the NEXT-C cyclic requirement, the heater batch was certified by NASA for use in the flight hollow cathodes. Nine heaters from the batch of 28 were provided to Aerojet Rocketdyne in early 2018 for cathode fabrication. This paper summarizes the acceptance and cyclic life testing of the flight heaters and preliminary findings of post-test analyses.

Arthur, Neil↗

NASA NTRS2020

QualifiCation of the Flight Heaters for the NEXT-C Hollow Cathodes

After successful validation of the design, swaged cathode heaters have been delivered by the NASA Glenn Research Center to Aerojet Rocketdyne for the fabrication of the NEXT-C ion thruster . NASA Glenn Research Center re-established and validated process controls as well as completed cyclic life testing of development heaters. Following an extensive requalification program, fabrication of a flight batch of heaters was executed using the qualified process controls. Of the 28 heaters fabricated in this flight batch, a set of six heaters were acceptance and cyclic tested to verify conformance with operational requirements. Upon completion of 200 percent of the NEXT-C cyclic requirement, the heater batch was certified by NASA for use in the flight hollow cathodes. Nine heaters from the batch of 28 were provided to Aerojet Rocketdyne in early 2018 for cathode fabrication. This paper summarizes the acceptance and cyclic life testing of the flight heaters and preliminary findings of post-test analyses.

Arthur, Neil↗

NASA NTRS2021

A Nanoscale Vacuum Field Emission Gated Diode with an Umbrella Cathode

A nanoscale field emission vacuum channel gated diode structure is proposed and a tungsten cathode with an umbrella-like geometry and sharp vertical edge is fabricated. The edge of the suspended cathode becomes the field emission surface. Unlike in the traditional transistor with the gate typically located between the source and the drain, the bottom silicon plate becomes the gate here and the anode terminal is located between the umbrella cathode and the gate. The fabricated devices show excellent diode characteristics and the gated diode structure is attractive for extremely low gate leakage.

Vacuum field emission diode↗

NASA NTRS1966

Liquid-metal cathode research.

Design of gravity-independent force-fed liquid-metal cathode providing unlimited cathode life in gas discharge devices and mercury electron-bombardment thrustors

GAS DISCHARGE↗

NASA NTRS2000

Field Emitter Cathodes and Electric Propulsion Systems

Replacing hollow and filament cathodes with field emitter (FE) cathodes could significantly improve the scalability, power, and performance of some meso- and microscale Electric Propulsion (EP) systems. This article discusses the motivation and challenges of integrating of FE and Electric Propulsion systems.

field emitters cathodes Electric Propulsion↗

NASA NTRS2000

Electric Propulsion Applications for Field Emitter Cathodes

Field emitters cathodes electric propulsion↗

NASA NTRS2006

Production of High Energy Ions Near an Ion Thruster Discharge Hollow Cathode

Several researchers have measured ions leaving ion thruster discharge chambers with energies far greater than measured discharge chamber potentials. Presented in this paper is a new mechanism for the generation of high energy ions and a comparison with measured ion spectra. The source of high energy ions has been a puzzle because they not only have energies in excess of measured steady state potentials, but as reported by Goebel et. al. [1], their flux is independent of the amplitude of time dependent plasma fluctuations. The mechanism relies on the charge exchange neutralization of xenon ions accelerated radially into the potential trough in front of the discharge cathode. Previous researchers [2] have identified the importance of charge exchange in this region as a mechanism for protecting discharge cathode surfaces from ion bombardment. This paper is the first to identify how charge exchange in this region can lead to ion energy enhancement.

ion propulsion↗

NASA NTRS2009

Results of a XIPS(copyrighted) 25-cm Thruster Discharge Cathode Wear Test

The Xenon Ion Propulsion System (XIPS(c)) 25-cm thruster produced by L-3 Communications Electron Technologies, Inc. offers a number of potential benefits for planetary missions, including high efficiency and high Isp over a large power throttling range and availability from an active product line. The thruster is qualified for use on commercial communications satellites, which have requirements differing from those for typical planetary missions. In particular, deep space missions require longer service life over a broad range of throttling conditions. A XIPS (c) discharge cathode assembly was subjected to a long duration test to extend operating experience at the maximum power point and at throttled conditions unique to planetary mission applications. A total of 16079 hours were accumulated at conditions corresponding to the full power engine operating point at 4.2 kWe, an intermediate power point at 2.76 kWe and the minimum power point at 0.49 kWe. Minor performance losses and cathode keeper erosion were observed at the full power point, but there were no changes in performance and negligible erosion at the intermediate and minimum power points.

cathode↗

NASA NTRS2008

Ongoing Wear Test of a XIPS(c) 25-Centimeter Thruster Discharge Cathode

The Xenon Ion Propulsion System (XIPS(c)) 25-cm thruster produced by L-3 Communications Electron Technologies, Inc. offers a number of potential benefits for planetary missions, including high efficiency and high Isp over a large power throttling range and availability from an active product line. The thruster is qualified for use on commercial communications satellites, which have requirements differing from those for typical planetary missions. In particular, deep space missions require longer service life over a broad range of throttling conditions. A XIPS(c) discharge cathode assembly is currently undergoing a long duration test to extend operating experience at the maximum power point and at throttled conditions unique to planetary mission applications. A total of 11080 hours have been accumulated at conditions corresponding to the full power engine operating point at 4.2 kWe and an intermediate power point at 2.76 kWe. Minor performance losses and cathode keeper erosion were observed at the full power point, but there were no changes in performance and negligible erosion at the intermediate power point.

Hollow cathodes↗

NASA NTRS2015

Study of Stable Cathodes and Electrolytes for High Specific Density Lithium-Air Battery

Future NASA missions require high specific energy battery technologies, greater than 400 Wh/kg. Current NASA missions are using "state-of-the-art" (SOA) Li-ion batteries (LIB), which consist of a metal oxide cathode, a graphite anode and an organic electrolyte. NASA Glenn Research Center is currently studying the physical and electrochemical properties of the anode-electrolyte interface for ionic liquid based Li-air batteries. The voltage-time profiles for Pyr13FSI and Pyr14TFSI ionic liquids electrolytes studies on symmetric cells show low over-potentials and no dendritic lithium morphology. Cyclic voltammetry measurements indicate that these ionic liquids have a wide electrochemical window. As a continuation of this work, sp2 carbon cathode and these low flammability electrolytes were paired and the physical and electrochemical properties were studied in a Li-air battery system under an oxygen environment.

cathodes↗

NASA NTRS2017

Characterization of the NEXT Hollow Cathode Inserts After Long-Duration Testing

Hollow dispenser cathode inserts are a critical element of electric propulsion systems, and should therefore be well understood during long term operation to ensure reliable system performance. This work destructively investigated cathode inserts from the NEXT long-duration test which demonstrated 51,184 hours of high-voltage operation, 918 kg of propellant throughput, and 35.5 MN-s of total impulse. The characterization methods used include scanning electron microscopy with energy dispersive spectroscopy and X-ray diffraction. Microscopy analysis has been performed on fractured surfaces, emission surfaces, and metallographically polished cross-sections of post-test inserts and unused inserts. Impregnate distribution, etch region thickness, impregnate chemical content, emission surface topography, and emission surface phase identification are the primary factors investigated.

life (durability)↗

NASA NTRSDate not supplied

Emitter Surface Temperature Measurements of a 25-A Class Hollow Cathode

The axial emitter surface temperature profile is experimentally characterized for a 25-A class hollow cathode operating across a range of operating conditions. Profiles were measured using aratio pyrometry diagnostic featuring a fiber optic inserted into the emitter region using a fast motion stage. Emitter temperature is found to increase with increasing discharge current, decreasing flow rate, and increasing magnetic field strength. Across a range of 10 –29 A, the maximum emitter temperature increased 176 ºC, an order of magnitude more than the changes measured for flow rate or magnetic fields strength. Profiles were generally self-similar across all operating conditions, and the difference between maximum and minimum emitter temperature never surpassed 10%, indicating that this cathode design results in satisfactory emitter utilization across its operating envelope

space propulsion↗