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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Reduced annealing temperatures in silicon solar cells

Cells irradiated to a fluence of 5x10,000,000,000,000/square cm showed short circuit current on annealing at 200 C, with complete annealing occurring at 275 C. Cells irradiated to 100,000,000,000,000/square cm showed a reduction in annealing temperature from the usual 500 to 300 C. Annealing kinetic studies yield an activation energy of (1.5 + or - 2) eV for the low fluence, low temperature anneal. Comparison with activation energies previously obtained indicate that the presently obtained activation energy is consistent with the presence of either the divacancy or the carbon interstitial carbon substitutional pair, a result which agrees with the conclusion based on defect behavior in boron-doped silicon.

Weinberg, I.↗
NASA NTRS1972

Relationship of dislocation density of silicon to solar cell current loss at low temperature

Large decreases in short circuit current of silicon solar cells have been reported to occur as temperature is decreased below -60 C. Experimental results are presented which relate high dislocation density of the silicon bulk material of cells to the large current loss effect. Solar cells were made by the same processes from a variety of silicon materials, namely low-dislocation-density, high-dislocation-density float-zone, and Czochralski silicon. All cells were etched in a manner which revealed the dislocation density of the cell bulk silicon. It was found that every cell made from any of the various low-dislocation starting materials obtained from three suppliers still had a low-dislocation bulk after cell processing, and that all such cells belonged to category good. Cells made from float-zone materials showed high dislocation densities in their bulk and either fell into category poor, or had intermediate losses of short-circuit current at low temperature.

Mandelkorn, J.↗
NASA NTRS2010

Improved Low-Temperature Performance of Li-Ion Cells Using New Electrolytes

As part of the continuing efforts to develop advanced electrolytes to improve the performance of lithium-ion cells, especially at low temperatures, a number of electrolyte formulations have been developed that result in improved low-temperature performance (down to 60 C) of 26650 A123Systems commercial lithium-ion cells. The cell type/design, in which the new technology has been demonstrated, has found wide application in the commercial sector (i.e., these cells are currently being used in commercial portable power tools). In addition, the technology is actively being considered for hybrid electric vehicle (HEV) and electric vehicle (EV) applications. In current work, a number of low-temperature electrolytes have been developed based on advances involving lithium hexafluorophosphate-based solutions in carbonate and carbonate + ester solvent blends, which have been further optimized in the context of the technology and targeted applications. The approaches employed, which include the use of ternary mixtures of carbonates, the use of ester co-solvents [e.g., methyl butyrate (MB)], and optimized lithium salt concentrations (e.g., LiPF6), were compared with the commercial baseline electrolyte, as well as an electrolyte being actively considered for DoE HEV applications and previously developed by a commercial enterprise, namely LiPF6 in ethylene carbonate (EC) + ethyl methyl carbonate (EMC)(30:70%).

Smart, Marshall C.↗
NASA NTRS1991

Phase equilibrium modeling for high temperature metallization on GaAs solar cells

Recent trends in performance specifications and functional requirements have brought about the need for high temperature metallization technology to be developed for survivable DOD space systems and to enhance solar cell reliability. The temperature constitution phase diagrams of selected binary and ternary systems were reviewed to determine the temperature and type of phase transformation present in the alloy systems. Of paramount interest are the liquid-solid and solid-solid transformations. Data are being utilized to aid in the selection of electrical contact materials to gallium arsenide solar cells. Published data on the phase diagrams for binary systems is readily available. However, information for ternary systems is limited. A computer model is being developed which will enable the phase equilibrium predictions for ternary systems where experimental data is lacking.

Chung, M. A.↗
NASA NTRS1991

Lithium Cells Accept Hundreds Of Recharges

New mixed-solvent electrolyte increases number of times room-temperature lithium cell discharged and recharged. Conductivity 70 percent higher. Useful in such other room-temperature rechargeable lithium cells as lithium/niobium triselenide and lithium molybdenum disulfide systems.

Shen, David H.↗
NASA NTRS2015

Electrode Design for Low Temperature Direct-Hydrocarbon Solid Oxide Fuel Cells

In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

Chen, Fanglin↗
NASA NTRS1987

High temperature solid oxide regenerative fuel cell for solar photovoltaic energy storage

A hydrogen-oxygen regenerative fuel cell (RFC) energy storage system based on high temperature solid oxide fuel cell (SOFC) technology is described. The reactants are stored as gases in lightweight insulated pressure vessels. The product water is stored as a liquid in saturated equilibrium with the fuel gas. The system functions as a secondary battery and is applicable to darkside energy storage for solar photovoltaics.

Bents, David J.↗
NASA NTRS1972

Maximum power transfer from a solar-cell array by sensing array temperature

A technique is described in which a spacecraft solar-cell array is caused to operate at or near maximum power output over a wide range of environmental conditions. The output of an array temperature sensor is used to vary the duty cycle of a pulse-width-modulated impedance regulator so that the array operates at the voltage of maximum power. A resistance-type temperature sensor was found to be applicable for most spacecraft missions. However, a solar cell used as a temperature sensor has the advantage of negligible transient errors on lightweight arrays for orbiting spacecraft.

Sussman, M.↗
NASA NTRS1996

Testing Thermophotovoltaic Cells With Black-Body Radiation

Method of testing thermophotovoltaic (TPV) cells involves maintaining cells at various temperatures while exposing cells to black-body radiation at various intensities from black-body sources at various other temperatures. Provides for simulation and evaluation of performance under variety of operating conditions and could become standard testing method for government and industry.

Lin, James J.↗
NASA NTRS1984

Charge Control Investigation of Rechargeable Lithium Cells

An ambient temperature rechargeable Li-TiS2 cell was cycled under conditions which simulate aerospace applications. A novel charge/discharge state-of-charge control scheme was used, together with tapered current charging, to overcome deleterious effects associated with end-of-charge and end-of-discharge voltages. The study indicates that Li-TiS2 cells hold promise for eventual synchronous satellite-type applications. Problem areas associated with performance degradation and reconditioning effects are identified.

Otzinger, B.↗
NASA NTRS1985

High-Temperature, High-Pressure Optical Cells

Optical cell constructed for measurement of thermal diffusivity of HgCdTe semiconductor by laser pulses. Container allows radiation from laser to enter one side of alloy sample, while allowing lower-energy infrared radiation to leave opposite side of sample so temperature rise read by sensor. Composed entirely of fused silica, cell includes two optical windows joined by tube. Cell withstands 1,000 degrees C cell-operating temperature and contains molten alloy at its 100-atmosphere vapor pressure. Finally, allows alloy to solidify without bursting even though alloy expands on cooling.

Harris, R. P.↗
NASA NTRS2020

Thermodynamic Measurements Using the Knudsen Cell Technique

The Knudsen cell technique has been used for over a century and is a valuable tool for measurement of vapor pressures and thermodynamic properties. It is based on a small enclosure (~1 cm long x 1 cm diameter) in which a condensed phase/vapor equilibria can be established. A small (<1 mm) orifice on the cell allows sampling of the vapor via a variety of techniques including weight loss, torsion effusion, target collection, and mass spectrometry. Many excellent measurements based on these methods have been reported. However in order to obtain reliable measurements, a variety of factors must be considered. They include proper cell material selection, accurate and uniform temperature control and measurement, and proper sampling of the vapor. Each of these factors are discussed in detail in this chapter. Typically these studies are conducted at high temperatures and it is a challenge to select an inert container material. Recommended materials are discussed and in some cases the container may be used as part of the system under study. Temperature control and measurement is perhaps the most important issue. In most systems, the furnace must be compact yet there can be no temperature gradient in the cell. Temperatures are measured with either a thermocouple or pyrometer and the relative advantages of each are discussed. Sampling method considerations depend on the particular technique. It is essential that all of the vapor or a representative portion of the vapor be sampled. The distribution of the effusate from a Knudsen cell is discussed and sampling positions discussed. Mass spectrometry is often used to study the effusing vapor and the relations between ion current and vapor pressure are discussed.

mass spectrometry↗
NASA NTRS2007

Fluorinated Ester Co-Solvents for Low-Temperature Li-Ion Cells

This viewgraph presentation reviews the development of co-solvents for Li-ion cells. The future planned NASA Missions to explore Mars, the Moon, and the outer planets require rechargeable batteries that can operate at low temperatures. The applications for these batteries include landers, rovers and penetraters. This presentation reviews the work on optimizing the ester-based electrolyte formulations, with the intent of providing the best performance at temperatures ranging from -60 to +60 C.

low temperature batteries↗
NASA NTRS1971

Simulated space environment tests on cadmium sulfide solar cells

Cadmium sulfide (Cu2s - CdS) solar cells were tested under simulated space environmental conditions. Some cells were thermally cycled with illumination from a Xenon-arc solar simulator. A cycle was one hour of illumination followed immediately with one-half hour of darkness. In the light, the cells reached an equilibrium temperature of 60 C (333 K) and in the dark the cell temperature dropped to -120 C (153 K). Other cells were constantly illuminated with a Xenon-arc solar simulator. The equilibrium temperature of these cells was 55 C (328 K). The black vacuum chamber walls were cooled with liquid nitrogen to simulate a space heat sink. Chamber pressure was maintained at 0.000001 torr or less. Almost all of the solar cells tested degraded in power when exposed to a simulated space environment of either thermal cycling or constant illumination. The cells tested the longest were exposed to 10.050 thermal cycles.

Clarke, D. R.↗
NASA NTRS1987

Raman spectroscopic investigations of Hg-Cd-Te melts

Raman scattering measurements are reported for a series of Hg sub1-xCd subxTe (with x less than or =0.2) materials from 295 K (room temperature) to 1126K (up to and above their liquidus temperatures), and for Hg sub1-xCd subxTe (x=0.3) at 285K. The samples were contained in high-temperature optically-flat fused silica cell. Variable temperature measurements were effected in a three-zone, high-temperature furnace equipped with optical windows, and monitored externally by three independently programmable temperature controllers. All studies were made in the backscattering geometry using the 5145 A line of an Ar+ ion laser, with incident power less than 250 mW, as the excitiation source. An intensity enhancement is observed for a mode in each of the compositions studied. The frequency of this mode varies with composition, 142/cm for HgTe, and 128/cm for both the Hg sub1-xCd subxTe (x=0.053 and 0.204) samples. In addition, a shift to lower frequency as a function of temperature is observed in all samples. This shift is most prominent for the x=0.053 sample. The temperature dependence of these modes as the liquidus temperatures are achieved and surpassed for these samples is presented as being associated with a structural transition in the Hg-rich compositions of the Hg sub1-xCd subxTe series. To our knowledge, this is the first reported study of Raman scattering by phonons in the melts of these materials.

Morrobel-Sosa, Anny↗
NASA NTRS1992

Indium phosphide solar cells for laser power beaming applications

Lasers can be used to transmit power to photovoltaic cells. Solar cell efficiencies are enhanced significantly under monochromatic light, and therefore a laser beam of proper wavelength could be a very effective source of illumination for a solar array operating at very high efficiencies. This work reviews the modeling studies made on indium phosphide solar cells for such an application. These cells are known to be very radiation resistant and have a potential for high efficiency. Effects of cell series resistance, laser intensity, and temperature on cell performance have been discussed.

Jain, Raj K.↗
NASA NTRS2012

Restoration and Reexamination of Apollo Lunar Dust Detector Data from Original Telemetry Files

We are recovering the original telemetry (Figure I) from the Apollo Dust, Thermal, Radiation Environment Monitor (DTREM) experiment, more commonly known as the Dust Detector, and producing full time resolution (54 second) data sets for release through the Planetary Data System (PDS). The primary objective of the experiment was to evaluate the effect of dust deposition, temperature, and radiation damage on solar cells on the lunar surface. The monitor was a small box consisting of three solar cells and thermistors mounted on the ALSEP (Apollo Lunar Surface Experiments Package) central station. The Dust Detector was carried on Apollo's 11, 12, 14 and 15. The Apollo 11 DTREM was powered by solar cells and only operated for a few months as planned. The Apollo 12, 14, and 15 detectors operated for 5 to 7 years, returning data every 54 seconds, consisting of voltage outputs from the three solar cells and temperatures measured by the three thermistors. The telemetry was received at ground stations and held on the Apollo Housekeeping (known as "Word 33") tapes. made available to the National Space Science Data Center (NSSDC) by Yosio Nakamura (University of Texas Institute for Geophysics). We have converted selected parts of the telemetry into uncalibrated and calibrated output voltages and temperatures.

McBride, M. J.↗