Shockley-Queisser analysis of the temperature-efficiency correlation of solar cells in the presence of non-radiative heat transfer
An empirical negative T cell − η correlation has been widely applied, without careful justifications, to evaluate the efficiency ( η ) increase of solar cells due to their temperature ( T cell ) decrease. Here, a framework is introduced to simultaneously compute T cell and η . This model confirms the negative T cell − η correlation if the above-bandgap absorptivity ( α I ) is not suppressed in the optimization of the sub-bandgap reflectivity ( ρ II ) or the infrared emissivity, otherwise it may suggest a positive correlation. It further gives a guideline to enhance η of silicon cells under typical conditions: every 1% increase of α I is equivalent to a 57% increase of ρ II .