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At least 271 records · Page 15

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DOE OSTI2020

Dicarboxylic acid emissions from a GDI engine equipped with a catalytic gasoline particulate filter

Dicarboxylic acids play an important role in atmospheric chemistry, yet their emissions from primary sources, such as internal combustion engines, has not been extensively studied. In this paper, KOH impregnated quartz filters were loaded with exhaust gases from a gasoline direct injection (GDI) engine equipped with a catalytic gasoline particulate filter (GPF). All filters were analyzed for carboxylic and dicarboxylic acids using a derivatized gas chromatography-mass spectroscopy method. Exhaust gas was sampled from pre-GPF and post-GPF locations to determine the performance of the GPF regarding acid conversion. Lean and stoichiometric engine modes were considered with non-oxygenated gasoline and 10% splash blended ethanol in gasoline (E10) to examine the impact of stoichiometry and fuel type. Acid emissions represented as much as 0.51% of total unburned hydrocarbon emissions for total monocarboxylic acids and as much as 0.40% for total dicarboxylic acids. Individual acid concentrations were as high as 38 mg/kg-fuel for monocarboxylic acids and as high as 29 mg/kg-fuel for dicarboxylic acids. Overall, the study found that fuel oxygenates had mixed impact on the acid emissions. Engine-out monocarboxylic acids were reduced when using the E10 fuel by approximately 30–45% for the stoichiometric condition and increased marginally for the lean condition. Dicarboxylic acid emissions were generally insensitive to ethanol content. However, the engine condition significantly affected the acid emissions. Lean operation produced a factor of two to an order of magnitude higher emissions rates of both monocarboxylic and dicarboxylic acids than the stoichiometric condition. The catalytic GPF eliminated between 80 and 92% of the acids emitted from the engine, allowing some acids to be emitted into the environment.

42 ENGINEERING↗

NASA NTRS1992

Factor analysis as a tool for spectral line component separation 21cm emission in the direction of L1780

The spectra of the 21cm HI radiation from the direction of L1780, a small high-galactic latitude dark/molecular cloud, were analyzed by multivariate methods. Factor analysis was performed on HI (21cm) spectra in order to separate the different components responsible for the spectral features. The rotated, orthogonal factors explain the spectra as a sum of radiation from the background (an extended HI emission layer), and from the L1780 dark cloud. The coefficients of the cloud-indicator factors were used to locate the HI 'halo' of the molecular cloud. Our statistically derived 'background' and 'cloud' spectral profiles, as well as the spatial distribution of the HI halo emission distribution were compared to the results of a previous study which used conventional methods analyzing nearly the same data set.

Toth, L. V.↗

NASA NTRS1982

Asymmetric emission-line regions with out-flowing mass in QSOs and the z/ab/ at least equal to z/em/ systems

A heuristic asymmetrical model for a quasar emission-line region, with material streaming out, is described. The physical parameters are essentially the same as those of static models; the geometry turns out to be the dominant factor in determining the emission line profiles. Calculations are carried out for a variety of parameterized flow models and for the Blumenthal and Mathews (1975) theoretical model of a radiatively driven flow. The emission-line profiles are insensitive to the details of the acceleration, the filling factor, and the ionization profile. Absorption is assumed to take place in stationary matter in the QSO's galaxy or associated group or cluster, so that z(ab) is identified with the cosmological redshift. Due to the flow, the emission-lines are shifted with respect to the absorption-lines; in cases of a flow directed towards the observer systems with z(ab) at least equal to z(em) result. The distribution of absorption redshifts is symmetric about z(em).

Goldman, I.↗

DOE OSTI2022

Triple Emission of 5'-( para -R-Phenylene)vinylene-2-(2'-hydroxyphenyl)benzoxazole (PVHBO). Part I: Dual Emission from the Neutral Species

The effects of 5'-(para-R-phenylene)vinylene (PV) substituents on the emission properties of 2-(2'-hydroxyphenyl)benzoxazole (HBO) are analyzed using steady-state and time-resolved absorption and emission spectroscopies in addition to quantum chemical calculations. All members in the series of PVHBOs are capable of excited-state intramolecular proton transfer (ESIPT) with a solvent sensitivity that is typical of a HBO derivative to produce a normal (aka enol) emission and an excited-state tautomer (aka keto) emission. These two emission bands of the neutral dyes are discussed in the current paper. The intermolecular proton transfer, i.e., the deprotonation, of a PVHBO results in the third band of the triple emission, which is described in the succeeding paper. The placement of an electron-withdrawing substituent R on the PVHBO scaffold increases the intensity of the keto emission relative to the enol emission in hydrogen-bonding solvents. The R substituents do not significantly alter the wavelengths of the enol and keto emission bands, which are located in the blue and green regions, respectively, of the visible spectrum. The ultrafast time-resolved spectroscopies and quantum chemical calculations offer explanations on how the R group and the solvent affect the enol and keto emission properties (i.e., wavelength, lifetime, fluorescence quantum yield, and relative ratio of their emissions). Here, the key findings include the following: (1) the emission energies of both enol and keto forms are not sensitively dependent on the R substituent and (2) the solvent-engaged enol excited state is quenched more efficiently as the R substituent becomes more electron-withdrawing. A PVHBO acts as a fusion of HBO and stilbenoid that intersect at the hydroxyphenyl moiety. Depending on the solvent and other environmental conditions, PVHBOs may exhibit the ESIPT property of HBO or the substituent-dependent emission of stilbenoid. This paper and the succeeding article provide a photophysical model of PVHBOs to explain the wavelengths and relative abundances of the three emission bands (enol, keto, and anion) that these compounds are able to produce. Judicial selection of the environmental factors may drive the emission of a PVHBO into the spectral regions of blue, green, and, in a couple of cases, orange or red.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2012

Evaluation of Contrail Reduction Strategies Based on Aircraft Flight Distances

This paper evaluates a set of contrail reduction strategies based on the flight range of aircraft as contrail reduction strategies have different impacts on aircraft depending on how they plan to fly. In general, aircraft with longer flight distances cruise at the altitudes where contrails are more likely to form. The concept of the contrail frequency index is used to quantify contrail impacts. The strategy for reducing the persistent contrail formation is to minimize the contrail frequency index by altering the aircraft's cruising altitude. A user-defined factor is used to trade off between contrail reduction and extra CO2 emissions. A higher value of tradeoff factor results in more contrail reduction and extra CO2 emissions. Results show that contrail reduction strategies using various tradeo factors behave differently from short-range flights to long-range ights. Analysis shows that short-distance flights (less than 500 miles) are the most frequent flights but contribute least to contrail reduction. Therefore these aircraft have the lowest priority when applying contrail reduction strategies. Medium-distance flights (500 to 1000 miles) have a higher priority if the goal is to achieve maximum contrail reduction in total; long-distance flights (1000 to 1500 miles) have a higher priority if the goal is to achieve maximum contrail reduction per flight. The characteristics of transcontinental flights (greater than 1500 miles) vary with different weather days so the priority of applying contrail reduction strategies to the group needs to be evaluated based on the locations of the contrail areas during any given day. For the days tested, medium-distance ights contribute up to 42.6% of the reduction among the groups during a day. The contrail frequency index per 1,000 miles for medium-distance, long-distance, and transcontinental flights can be reduced by an average of 75%. The results provide a starting point for developing operational policies to reduce the impact of aviation on climate based on aircraft flight distances.

Chen, Neil Y.↗

NASA NTRS1993

Primary production control of methane emission from wetlands

Based on simultaneous measurements of CO2 and CH4 exchange in wetlands extending from subarctic peatlands to subtropical marshes, a positive correlation between CH4 emission and net ecosystem production is reported. It is suggested that net ecosystem production is a master variable integrating many factors which control CH4 emission in vegetated wetlands. It is found that about 3 percent of the daily net ecosystem production is emitted back to the atmosphere as CH4. With projected stimulation of primary production and soil microbial activity in wetlands associated with elevated atmospheric CO2 concentration, the potential for increasing CH4 emission from inundated wetlands, further enhancing the greenhouse effect, is examined.

Whiting, G. J.↗

DOE OSTI2025

On the Relationship Between Methane Production in Anaerobic Incubations of Peat Material and In Situ Methane Emissions

Anaerobic incubations of peat have been widely used to explore soil processes, but this in vitro technique raises many questions as to how well it reproduces in situ conditions. To investigate this, we conducted 60–100 days (+25 days pre‐incubation) anaerobic, temperature‐controlled incubation experiments across a temperature range of 1–26°C on samples from bog and fen habitats, at two different depths (9–19 and 25–35 cm). Here, we observed exponential increases in CO 2 and methane production with temperature in all conditions. We then compared field‐based measurements of methane emission with modeled expectations by extrapolating incubation‐determined methane production rates based on (a) soil temperature profiles, (b) the observed incubation temperature‐methane production relationship, and (c) seasonal thaw depth from each site. The resulting incubation‐extrapolated methane production agreed with measured emission rates within a factor of two at both sites and corresponded to 182 ± 54% and 59 ± 14% of the measured average yearly fluxes from the field for the bog and fen, respectively. The underestimation of fen methane fluxes may be due to the lack of living plant root‐derived dissolved organic carbon inputs in incubations, a key process in fens. Conversely, the overestimation in bogs could be attributed to methane oxidation in the field, which is absent in anaerobic incubation conditions. Nonetheless incubations predicted greenhouse gas emissions from a northern peatland within a factor of two.

Biological and medical sciences,Geosciences,Enviro↗

NASA NTRS1986

Highly ionized atoms in cooling gas

The ionization of low density gas cooling from a high temperature was calculated. The evolution during the cooling is assumed to be isochoric, isobaric, or a combination of these cases. The calculations are used to predict the column densities and ultraviolet line luminosities of highly ionized atoms in cooling gas. In a model for cooling of a hot galactic corona, it is shown that the observed value of N(N V) can be produced in the cooling gas, while the predicted value of N(Si IV) falls short of the observed value by a factor of about 5. The same model predicts fluxes of ultraviolet emission lines that are a factor of 10 lower than the claimed detections of Feldman, Brune, and Henry. Predictions are made for ultraviolet lines in cooling flows in early-type galaxies and clusters of galaxies. It is shown that the column densities of interest vary over a fairly narrow range, while the emission line luminosities are simply proportional to the mass inflow rate.

Edgar, R. J.↗

NASA NTRS1986

Highly ionized atoms in cooling gas

The ionization of low density gas cooling from a high temperature was calculated. The evolution during the cooling is assumed to be isochoric, isobaric, or a combination of these cases. The calculations are used to predict the column densities and ultraviolet line luminosities of highly ionized atoms in cooling gas. In a model for cooling of a hot galactic corona, it is shown that the observed value of N(N V) can be produced in the cooling gas, while the predicted value of N(Si IV) falls short of the observed value by a factor of about 5. The same model predicts fluxes of ultraviolet emission lines that are a factor of 10 lower than the claimed detections of Feldman, Bruna, and Henry. Predictions are made for ultraviolet lines in cooling flows in early-type galaxies and clusters of galaxies. It is shown that the column densities of interest vary over a fairly narrow range, while the emission line luminosities are simply proportional to the mass inflow rate.

Edgar, Richard J.↗

NASA NTRS1990

Radio continuum and far-infrared emission of spiral galaxies: Implications of correlations

Researchers present a study extending the correlation seen between radio continuum and far-infrared emissions from spiral galaxies to a lower frequency of 408 MHz and also as a function of radio spectral index. The tight correlation seen between the two luminosities is then used to constrain several parameters governing the emissions such as the changes in star formation rate and mass function, frequency of supernovae that are parents of the interstellar electrons and factors governing synchrotron radio emission.

Rengarajan, T. N.↗

DOE OSTI2022

Causality guided machine learning model on wetland CH 4 emissions across global wetlands

Wetland CH 4 emissions are among the most uncertain components of the global CH 4 budget. The complex nature of wetland CH 4 processes makes it challenging to identify causal relationships for improving our understanding and predictability of CH 4 emissions. In this study, we used the flux measurements of CH 4 from eddy covariance towers (30 sites from 4 wetlands types: bog, fen, marsh, and wet tundra) to construct a causality-constrained machine learning (ML) framework to explain the regulative factors and to capture CH 4 emissions at sub-seasonal scale. We found that soil temperature is the dominant factor for CH 4 emissions in all studied wetland types. Ecosystem respiration (CO 2 ) and gross primary productivity exert controls at bog, fen, and marsh sites with lagged responses of days to weeks. Integrating these asynchronous environmental and biological causal relationships in predictive models significantly improved model performance. More importantly, modeled CH 4 emissions differed by up to a factor of 4 under a +1°C warming scenario when causality constraints were considered. These results highlight the significant role of causality in modeling wetland CH 4 emissions especially under future warming conditions, while traditional data-driven ML models may reproduce observations for the wrong reasons. Our proposed causality-guided model could benefit predictive modeling, large-scale upscaling, data gap-filling, and surrogate modeling of wetland CH 4 emissions within earth system land models.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2022

Canadian and Alaskan Wildfire Smoke Particle Properties, Their Evolution and Controlling Factors, From Satellite Observations

The optical and chemical properties of biomass burning (BB) smoke particles greatly affect the impact that wildfires have on climate and air quality. Previous work has demonstrated some links between smoke properties and factors such as fuel type and meteorology. However, the factors controlling BB particle speciation at emission are not adequately understood nor are the factors driving particle aging during atmospheric transport. As such, modeling wildfire smoke impacts on climate and air quality remains challenging. The potential to provide robust, statistical characterizations of BB particles based on ecosystem type and ambient environmental conditions with remote sensing data is investigated here. Space-based Multi-angle Imaging SpectroRadiometer (MISR) observations, combined with the MISR Research Aerosol (RA) algorithm and the MISR Interactive Explorer (MINX) tool, are used to retrieve smoke plume aerosol optical depth (AOD) and to provide constraints on plume vertical extent; smoke age; and particle size, shape, light-absorption properties, and absorption spectral dependence. These tools are applied to numerous wildfire plumes in Canada and Alaska, across a range of conditions, to create a regional inventory of BB particle-type temporal and spatial distribution. We then statistically compare these results with satellite measurements of fire radiative power (FRP) and land cover characteristics, as well as short-term climate, meteorological, and drought information from the Modern-Era Retrospective analysis for Research and Applications (MERRA-2) reanalysis and the North American Drought Monitor. We find statistically significant differences in the retrieved smoke properties based on land cover type, with fires in forests producing the thickest plumes containing the largest, brightest particles and fires in savannas and grasslands exhibiting the opposite. Additionally, the inferred dominant aging mechanisms and the timescales over which they occur vary systematically between land types. This work demonstrates the potential of remote sensing to constrain BB particle properties and the mechanisms governing their evolution over entire ecosystems. It also begins to realize this potential, as a means of improving regional and global climate and air quality modeling in a rapidly changing world.

Katherine T. Junghenn Noyes↗

NASA NTRS1977

The impact of H2S emissions on future geothermal power generation - The Geysers region, California

The future potential for geothermal power generation in the Geysers region of California is as much as 10 times the current 502 MW(e) capacity. However, environmental factors such as H2S emissions and institutional considerations may play the primary role in determining the rate and ultimate level of development. In this paper a scenario of future geothermal generation capacity and H2S emissions in the Geysers region is presented. Problem areas associated with H2S emissions, H2S abatement processes, plant operations, and government agency resources are described. The impact of H2S emissions on future development and the views of effected organizations are discussed. Potential actions needed to remove these constraints are summarized.

Leibowitz, L. P.↗

DOE OSTI2020

Climate Sensitivity of Peatland Methane Emissions Mediated by Seasonal Hydrologic Dynamics

Peatlands are among the largest natural sources of atmospheric methane (CH 4 ) worldwide. Peatland emissions are projected to increase under climate change, as rising temperatures and shifting precipitation accelerate microbial metabolic pathways favorable for CH 4 production. However, how these changing environmental factors will impact peatland emissions over the long term remains unknown. Here, we investigate a novel data set spanning an exceptionally long 11 years to analyze the influence of soil temperature and water table elevation on peatland CH 4 emissions. We show that higher water tables dampen the springtime increases in CH 4 emissions as well as their subsequent decreases during late summer to fall. These results imply that any hydroclimatological changes in northern peatlands that shift seasonal water availability from winter to summer will increase annual CH 4 emissions, even if temperature remains unchanged. Furthermore, advancing hydrological understanding in peatland watersheds will be crucial for improving predictions of CH 4 emissions.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1976

Interferences in the chemiluminescent measurement of NO and NO2 emissions from combustion systems

Two factors which may affect the quantification of NO and NO2 concentrations when using chemiluminescent analysis are investigated. The first is the dependence of the chemiluminescent intensity on competing third body quenching reactions. Relative quenching efficiencies are determined as a function of third body concentration for six different species which are common products of combustion. A mathematical expression is derived which allows calculation of the actual concentration of NO given the indicated concentration of NO and the concentrations of the important third bodies. An example calculation is presented. The second factor which is investigated involves the conversion of low molecular weight nitrogen containing species, other than NO2, in commercial NOx converters. Conversion efficiencies for six species were determined using a commercial stainless steel catalyst at 923 K.

Matthews, R. D.↗

NASA NTRS1977

Interferences in chemiluminescent measurement of NO and NO2 emissions from combustion systems

Two factors that may affect the quantification of NO and NO2 concentrations when using chemiluminescent analysis are investigated. The first is the dependence of the chemiluminescent intensity on competing third body quenching reactions. Relative quenching efficiencies are determined as a function of third body concentration for six different species that are common products of combustion. A mathematical expression is derived that allows calculation of the actual concentration of NO, given the indicated concentration of NO and the concentrations of the important third bodies. An example calculation is presented. The second factor investigated involves the conversion to NO of low molecular weight nitrogen-containing species, other than NO2, in commercial NOx converters. Conversion efficiencies for six species are determined using a commercial stainless steel catalyst at 920 K.

Matthews, R. D.↗

NASA NTRS1995

A study of secondary electron emission effects for suppressing passive intermodulation interference in high power communication satellites

In this paper a study of secondary electron emission effects for suppressing passive intermodulation interference in high power communications satellites is studied. The test facility is described and the test results are provided. The effects of environmental factors on the secondary emission coefficient are given. It is found that certain refractory compounds are very promising in eliminating some of the passive intermodulation in satellite communications.

Bosisio, Renato G.↗

NASA NTRS1984

Ultraviolet and visible flare observations of EQ Pegasi B

EQ Peg AB (dM43+dM5.5e) was monitored in the visible at the Whipple Observatory and ultraviolet with IUE on September 2, 1981. In the visible spectrophotometry of EQ Peg B the H-beta emission strengthened by a factor of 2 relative to the nearby stellar continuum within a few minutes and decayed over an hour. This flare in EQ Peg B was coincident with the enhancement of ultraviolet emission lines of C IV 1550 A, He II 1640 A, and C II 1335 A in the combined light of EQ Peg AB. The ultraviolet fluxes during the flare can be interpreted as similar to those either in the thermal phases of large two-ribbon solor flares where radiative cooling balances thermal conduction or in gas cooling quickly from X-ray emitting temperatures. The appearance of the ultraviolet continuum at 1700-1900 A and ratio of H-alpha to H-beta fluxes during the flare are consistent with models producing these emissions in the chromosphere.

Baliunas, S. L.↗