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Lunar Payloads to Constrain Exospheric Water through the NASA M-STAR program

Our understanding of water cycles on the Moon has significantly enhanced recent observations by Chang E-5, Lunar Prospector, and Chandrayaan-1 missions indicating the existence of an active water cycle on the Moon. In a new partnership between Delaware State University (DSU) and NASA Goddard Space Flight Center, enabled through the NASA’s M-STAR (MUREP Space Technology Artemis Research) program, we are developing low mass and power lunar rover payloads to enable long-duration human exploration missions. Payload technologies include wavelength modulation absorption spectroscopy to simultaneously detect water (H16OH) and isotopes (H16OD) in the (6700 nm) mid-infrared region using a closed path in compact Herriot cell optical design and wavelength modulation spectroscopy, and (2) Laser-induced breakdown spectroscopy (LIBS) to simultaneously detect and correlate water isotopes with characteristics elemental composition of lunar regolith. Due to the airless atmosphere of the Moon, we will utilize Artificial intelligence (AI) and Machine learning (ML) approaches to discriminate spectral interference with instrument drifts and correlate mid-IR trace gas profile with LIBS spectral information. This partnership will initiate a STEM engagement space program, e.g., Lander and CubeSat payload technology development for students and the next-generation NASA workforce for future lunar and Mars missions. DSU, a Historically Black University, prides itself in its proven excellence in teaching and research. It enrolls a diverse population of students (~5000) traditionally underrepresented in STEM disciplines. DSU has established itself at the forefront of optics and photonics research that transcends multidisciplinary fields of earth sciences, environmental, defense, and biomedical sensing applications.

water cycles↗
NASA NTRS2009

Lunar Neutral Exposphere Properties from Pickup Ion Analysis

Composition and structure of neutral constituents in the lunar exosphere can be determined through measurements of phase space distributions of pickup ions borne from the exosphere [1]. An essential point made in an early study [ 1 ] and inferred by recent pickup ion measurements [2, 3] is that much lower neutral exosphere densities can be derived from ion mass spectrometer measurements of pickup ions than can be determined by conventional neutral mass spectrometers or remote sensing instruments. One approach for deriving properties of neutral exospheric source gasses is to first compare observed ion spectra with pickup ion model phase space distributions. Neutral exosphere properties are then inferred by adjusting exosphere model parameters to obtain the best fit between the resulting model pickup ion distributions and the observed ion spectra. Adopting this path, we obtain ion distributions from a new general pickup ion model, an extension of a simpler analytic description obtained from the Vlasov equation with an ion source [4]. In turn, the ion source is formed from a three-dimensional exospheric density distribution, which can range from the classical Chamberlain type distribution to one with variable exobase temperatures and nonthermal constituents as well as those empirically derived. The initial stage of this approach uses the Moon's known neutral He and Na exospheres to deriv e He+ and Na+ pickup ion exospheres, including their phase space distributions, densities and fluxes. The neutral exospheres used are those based on existing models and remote sensing studies. As mentioned, future ion measurements can be used to constrain the pickup ion model and subsequently improve the neutral exosphere descriptions. The pickup ion model is also used to estimate the exosphere sources of recently observed pickup ions on KAGUYA [3]. Future missions carrying ion spectrometers (e.g., ARTEMIS) will be able to study the lunar neutral exosphere with great sensitivity, yielding the necessary ion velocity spectra needed to further analysis of parent neutral exosphere properties.

Hartle, R. E.↗
NASA NTRS2024

Temporary Atmospheres Produced By Human Activities on the Moon

Outgassing from materials, whether through the ascent/descent stages of lunar vehicles, airlock depressurizing, rover or astronaut suit outgassing, may cause an effect of unwanted accumulation of volatiles at the surface and exosphere. This is especially important at (or proximal) to permanently shadowed regions (PSRs) at the lunar poles. Herein, we provide estimates of expected outgassing from various human-landed objects on the Moon, including backpacks, airlocks, rovers, landers, trash and mining operations. Astronaut suits produce some level of oxygen outgassing (Helou et al., 2022), which may transport and condense in these PSRs, even in micro- cold traps (Glavin et al., 2010).We estimate the outgassing from drill mining and trash-to-gas conversion assuming a specific technology is operating. These outgassing systems can create local, temporary atmospheres in the vicinity (∼100 km radius) of the sources. The atmosphere may be particularly high within meters of the source. To obtain column densities for these temporary atmospheres, we first bracket ranges for the gas number loss as a function of time. We then derive the maximum distance traveled and the time the released molecules remain in the exosphere for a single ballistic hop, assuming the molecules are ejected from the surface of the object at its surface temperature. In some cases, such as the astronaut backpack and the rover, the temperature is that of the source. Given this information, an average and peak local exospheric density and column density can be estimated. We find that backpacks, airlock releases, and the Starship lander can create relatively high-density local atmospheres, with local near-lander outgassing water densities exceeding 107/cm3. This local water exosphere is over 106 times greater than the LADEE-derived lower limit of the natural water exosphere at ∼3/cm3. Thus, the anthropogenic temporary water exosphere will likely dominate the environment near the lander, making an assessment of the natural exospheric water environment difficult.

Rosemary M Killen↗
NASA NTRS2015

Understanding Temporal and Spatial Variability of the Lunar Helium Atmosphere Using Simultaneous Observations from LRO, LADEE, and ARTEMIS

Simultaneous measurements of helium in the exosphere of the Moon are made from the Lunar Reconnaissance Orbiter (LRO) Lyman Alpha Mapping Project (LAMP) and the Lunar Atmosphere and Dust Environment Explorer (LADEE) Neutral Mass Spectrometer (NMS) through the entire 5-month span of the LADEE mission. In addition, the ARTEMIS mission monitored the solar wind alpha particle flux to the Moon. Modeling the lunar helium exosphere, we relate the LAMP polar observations to the LADEE equatorial observations. Further, using the ARTEMIS alpha flux in the Monte Carlo model reproduces the temporal variations in helium density. Comparing the LAMP data to the LADEE data shows excellent agreement. Comparing those with the ARTEMIS data reveals that the solar wind alpha flux is the primary driver to variability in the helium exosphere throughout the LADEE mission. Using a decay time for exospheric helium of 5 days, we determine that the solar wind contributes 64 +/- 5% of the helium to the lunar exosphere. The remaining 36 +/- 5% is presumed to come from outgassing of radiogenic helium from the interior of the Moon. Furthermore, the model reproduces the measurements if 63 +/- 6% of the incident alpha particles are converted to thermalized helium atoms through the interaction between the alphas and the lunar surface. However, these values are dependent on both inferred source rates from LAMP and LADEE observations and on the assumed time constant of the exospheric decay rate.

Moon↗
NASA NTRS2014

The Lunar Atmosphere and Dust Environment Explorer (LADEE): Initial Science Results

On September 6, 2013, a near-perfect launch of the first Minotaur V rocket successfully carried NASA's Lunar Atmosphere and Dust Environment Explorer (LADEE) into a high-eccentricity geocentric orbit. LADEE arrived at the Moon on October 6, 2013, dur-ing the government shutdown. The spacecraft impact-ed the lunar surface on April 18, 2014, following a completely successful mission. LADEE's science objectives were twofold: (1) De-termine the composition and variability of the lunar atmosphere; (2) Characterize the lunar exospheric dust environment, and its variability. The LADEE science payload consisted of the Lunar Dust Experiment (LDEX), which sensed dust impacts in situ, for parti-cles between 100 nm and 5 micrometers; a neutral mass spectrometer (NMS), which sampled lunar exo-spheric gases in situ, over the 2-150 Dalton mass range; an ultraviolet/visible spectrometer (UVS) ac-quired spectra of atmospheric emissions and scattered light from tenuous dust, spanning a 250-800 nm wave-length range. UVS also performed dust extinction measurements via a separate solar viewer optic. The following are preliminary results for the lunar exosphere: (1) The helium exosphere of the Moon, first observed during Apollo, is clearly dominated by the delivery of solar wind He++. (2) Neon 20 is clearly seen as an important constituent of the exosphere. (3) Argon 40, also observed during Apollo and arising from interior outgassing, exhibits variations related to surface temperature-driven condensation and release, and is also enhanced over specific selenographic longi-tudes. (4) The sodium abundance varies with both lu-nar phase and with meteoroid influx, implicating both solar wind sputtering and impact vaporization process-es. (5) Potassium was also routinely monitored and exhibits some of the same properties as sodium. (6) Other candidate species were seen by both NMS and UVS, and await confirmation. Dust measurements have revealed a persistent "shroud" of small dust particles between 0.7 and sev-eral micrometers in size, present over the pre-dawn and morning sector of the Moon. This tenuous dust exosphere, with densities of approximately 10(exp -5) m(exp -3), appears to be sustained by the ejecta of micrometeoroid impacts.

lunar atmosphere↗