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At least 271 records · Page 15

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DOE OSTI2024

Effects of Al concentration on the structure and conductivity of lithium lanthanum zirconium oxide

Cubic Li 7-3x Al x La 3 Zr 2 O 12 (LLZO) is a promising, next-generation solid electrolyte due to its stability with Li-metal and high bulk conductivity (~1 mS cm -1 ). However, the source of the high conductivity is not completely understood. In this work, we address this key knowledge gap through the integration of elemental analysis, neutron diffraction sensitive to Li and O atoms, and impedance spectroscopy to understand the structure–property correlations for LLZO. We show the metal–oxygen framework structure remains constant with variation in Al substitution, resulting in a constant activation energy of ~0.35 eV and little effect on the bulk conductivity. Instead, Li concentration, Al blocking and trapping of mobile defects, and Li–Li nearest neighbor interactions largely control the Al substituted LLZO bulk conductivity, resulting in decreases from 0.73 to 0.22 mS cm -1 as the Al concentration increases from 0.17 to 0.32 mol. These results differ from those of Ta substituted LLZO, where the framework structure and Li–Li site distances play large roles in controlling the conductivity. The increased understanding of the controlling factors of conductivity allows for greater ability to tailor the design of and substitution into the LLZO structure for improved conductivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

A resource adequacy assessment of correlated wide-area outages in the power grid

As the power grid is undergoing rapid transformations, numerous questions are emerging about its vulnerability to wide-area extreme events (WAEE), which could influence its operations. Relatively few analyses have been conducted to date regarding the impact of correlated outages during WAEEs on the grid’s ability to balance resources with demand. This study addresses this gap by conducting a resource adequacy analysis for a hurricane-inspired WAEE on a 2035 synthetic power grid system for the United States. A sensitivity analysis was also conducted to characterize the relative impact of weather on unserved energy. Our results indicate that although the magnitude and duration of the shortfalls vary depending on weather conditions, persistent shortfalls are observed in some regions. Initial explorations indicate a strong correlation between transmission-constrained regions and regions with persistent shortfalls. Future work could generate empirically-grounded representations for generator outages as well as conduct causal analyses of these shortfalls to improve understanding of drivers as well as possible mitigation strategies. Continued exploration of extreme weather impacts on the grid is important to develop more robust understanding of the reliability and resilience of our power systems, especially as they undergo rapid transformations.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2026

Unveiling in-gap states and Majorana zero modes in superconductor-topological insulator bilayer model

Interfaces between topological insulators and superconductors (SCs) are promising platforms for realizing Majorana zero modes (MZMs) via the superconducting proximity effect. We introduce a bilayer model consisting of the surface states of a three-dimensional topological insulator (3DTI) coupled to an 𝑠-wave superconductor and systematically study the role of interlayer tunneling strength (𝑡⊥) motivated by the recent growth of the Fe⁡(Te,Se)/Bi 2 ⁢Te 3 heterostructure. We find that increasing 𝑡⊥ shifts the proximity-induced (PrI) gap minimum away from the Γ point, giving rise to momentum-selective interference patterns that manifest as spatial oscillations in the in-gap states. We introduce an antidot with a magnetic vortex in the model and investigate the resulting in-gap states, including MZMs and Caroli–de Gennes–Matricon (CdGM) modes. With increasing hybridization strength, the energy separation between MZMs and CdGM states increases, enhancing the isolation of MZMs. Importantly, in the strong hybridization limit, the leading CdGM separation remains large in spite of the decrease in the PrI gap. Spin- and spatially resolved wavefunction analysis reveals angular momentum asymmetries absent in conventional 𝑠-wave systems. A direct comparison with a standalone 𝑠-wave superconductor confirms the emergence of distinct 𝑝-wave-like features in the bilayer geometry. Our results provide experimentally relevant predictions for tuning the stability of MZMs and their differentiation from the CdGM modes in SC-3DTI heterostructures and offer a theoretical framework for probing unconventional superconductivity in engineered topological systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2024

Social Media Analytics Relevant to TikTok - a Literature Review and Directions for Future Research

We have attempted to capture a sense of the scientific state of the art in studying social media platforms, including data collection from platforms, understanding platform behavior, known adversarial uses, and adverse content detection, classification, and quantification. Our coverage of the field is backed up by roughly two hundred citations, and it concludes with a comparative analysis and a list of apparent gaps and potential paths forward.

99 GENERAL AND MISCELLANEOUS↗

DOE OSTI2024

The Essence of Cryptol: A Denotational Cryptol Interpreter in Coq for Foundational Assurances for Quantum Resistant Cryptosystems

Systems of the utmost consequence need a means to establish authenticity of software and data. Cryptosystems implement authentication, but can be vulnerable to cryptographic and implementation attacks. With the threat of quantum cryptographic attacks, “post-quantum” cryptosystems (PQCs) must be henceforth used in these systems. However, the new cryptography needs new ways to, rigorously and machine-checkably, prove systems free of vulnerabilities. We propose a retargetable capability to rapidly instantiate proven correct postquantum cryptosystems through novel proof-carrying synthesis and proof-automation technique, extending those proven successful on existing systems. This capability is crucial to meeting the cryptographic requirements for future high-consequence systems. Since specifications for high consequence cryptography are presently captured in a domain specific language known as Cryptol. While this can enable convenient fully automated reasoning about Cryptol specificaitons and implementations via the Software Analysis Workbench (SAW), Cryptol has expressivity gaps, so that cryptosystems with probabilistic programming features like Falcon cannot be fully expressed in the language. Moreover, SAW’s automation fails for programs and specificaitons with inductive and recursive structure, as in the Sphincs+ PQC. Finally, Cryptol and SAW together represent some 200,000 lines of unverified Haskell, so that the any guarantees about high consequence cryptography are presently contingent on a large, unverified, yet trusted computing base. The first step of the larger project of agile, assured crpytography is therefore to provide a formal, mechanized semantics for Cryptol, so that the specifications expressed by cryptographers in Cryptol can be reasoned about and compiled into performant implementations with a foundational, machine checkable certificate of correctness. This report describes our work on this first step, culminating in the design of a certified denotational interpreter, in Coq, for core Cryptol.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2025

A Modelica Implementation of an Organic Rankine Cycle

Organic Rankine cycle (ORC) systems generate power from low-grade heat sources, such as geothermal sources and industrial waste heat. A key feature is that a working fluid is selected to match the temperature of the source. With the vast pool of candidate working fluids comes the challenge of developing a large number of robust thermodynamic media models. We implemented a subcritical ORC model in Modelica that uses working fluid data records and interpolation schemes in lieu of thermodynamic medium evaluation for energy recovery estimation. This is a component model that can be integrated into a larger energy system model. It does not require detailed thermodynamic, heat transfer, or machine analysis. Our ORC model fills a gap where working fluids are ready to choose or easy to add, and at the same time can be integrated into an energy system.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

NASA NTRS1992

Coarse-fine residual gravity cancellation system with magnetic levitation

Aircraft flight along parabolic trajectories have been proposed and executed in order to achieve low cost, near free fall conditions of moderate duration. This paper describes a six degree of freedom experiment isolation system designed to cancel out residual accelerations due to mechanical vibrations and errors in aircraft trajectory. The isolation system consists of a fine motion magnetic levitator whose stator is transported by a conventional coarse motion stage. The levitator uses wide gap voice coil actuators and has the dual purpose of isolating the experiment platform from aircraft vibrations and actively cancelling residual accelerations through feedback control. The course motion stage tracks the levitated platform in order to keep the levitator's coils centered within their matching magnetic gaps. Aspects of system design, an analysis of the proposed control strategy and simulation results are presented. Feasibility experiments are also discussed.

Salcudean, S. E.↗

NASA NTRS1993

Development and application of an empirical probability distribution for the prediction error of re-entry body maximum dynamic pressure

The relationship between actual and predicted re-entry maximum dynamic pressure is characterized using a probability density function and a cumulative distribution function derived from sounding rocket flight data. This paper explores the properties of this distribution and demonstrates applications of this data with observed sounding rocket re-entry body damage characteristics to assess probabilities of sustaining various levels of heating damage. The results from this paper effectively bridge the gap existing in sounding rocket reentry analysis between the known damage level/flight environment relationships and the predicted flight environment.

Lanzi, R. James↗

NASA NTRS2000

Aerodynamic Characteristics, Database Development and Flight Simulation of the X-34 Vehicle

An overview of the aerodynamic characteristics, development of the preflight aerodynamic database and flight simulation of the NASA/Orbital X-34 vehicle is presented in this paper. To develop the aerodynamic database, wind tunnel tests from subsonic to hypersonic Mach numbers including ground effect tests at low subsonic speeds were conducted in various facilities at the NASA Langley Research Center. Where wind tunnel test data was not available, engineering level analysis is used to fill the gaps in the database. Using this aerodynamic data, simulations have been performed for typical design reference missions of the X-34 vehicle.

Pamadi, Bandu N.↗

NASA NTRS2000

Aerodynamic Characteristics, Database Development and Flight Simulation of the X-34 Vehicle

Pamadi, Bandu N.↗

NASA NTRS2006

Bearing-Load Modeling and Analysis Study for Mechanically Connected Structures

Bearing-load response for a pin-loaded hole is studied within the context of two-dimensional finite element analyses. Pin-loaded-hole configurations are representative of mechanically connected structures, such as a stiffener fastened to a rib of an isogrid panel, that are idealized as part of a larger structural component. Within this context, the larger structural component may be idealized as a two-dimensional shell finite element model to identify load paths and high stress regions. Finite element modeling and analysis aspects of a pin-loaded hole are considered in the present paper including the use of linear and nonlinear springs to simulate the pin-bearing contact condition. Simulating pin-connected structures within a two-dimensional finite element analysis model using nonlinear spring or gap elements provides an effective way for accurate prediction of the local effective stress state and peak forces.

Knight, Norman F., Jr.↗

NASA NTRS2021

Liana optical traits increase tropical forest albedo and reduce ecosystem productivity

Lianas are a key growth form in tropical forests. Their lack of self-supporting tissues and their vertical position on top of the canopy make them strong competitors of resources. A few pioneer studies have shown that liana optical traits differ on average from those of colocated trees. Those trait discrepancies were hypothesized to be responsible for the competitive advantage of lianas over trees. Yet, in the absence of reliable modelling tools, it is impossible to unravel their impact on the forest energy balance, light competition, and on the liana success in Neotropical forests. To bridge this gap, we performed a meta-analysis of the literature to gather all published liana leaf optical spectra, as well as all canopy spectra measured over different levels of liana infestation. We then used a Bayesian data assimilation framework applied to two radiative transfer models (RTMs) covering the leaf and canopy scales to derive tropical tree and liana trait distributions, which finally informed a full dynamic vegetation model. According to the RTMs inversion, lianas grew thinner, more horizontal leaves with lower pigment concentrations. Those traits made the lianas very efficient at light interception and significantly modified the forest energy balance and its carbon cycle. While forest albedo increased by 14% in the shortwave, light availability was reduced in the understorey (−30% of the PAR radiation) and soil temperature decreased by 0.5°C. Those liana-specific traits were also responsible for a significant reduction of tree (−19%) and ecosystem (−7%) gross primary productivity (GPP) while lianas benefited from them (their GPP increased by +27%). This study provides a novel mechanistic explanation to the increase in liana abundance, new evidence of the impact of lianas on forest functioning, and paves the way for the evaluation of the large-scale impacts of lianas on forest biogeochemical cycles.

Félicien Meunier↗

NASA NTRS2022

Midwest Water Resources II: Evaluating Evapotranspiration with NASA Earth Observations and In Situ Observations to Understand Water Balance in Midwest Agriculture

Seasonal water variability in the midwestern United States extensively affects the agricultural community, as it impacts irrigation schedules, growing seasons, and overall ecosystem function. Evapotranspiration (ET) is a critical climatic variable in the water cycle and is used to evaluate spatiotemporal trends in drought and flood conditions. The NASA DEVELOP team partnered with the United States Department of Agriculture (USDA) Midwest Climate Hub, the Minnesota Department of Agriculture, the Illinois State Water Survey, and Michigan State University to compare remotely sensed ET products with in situ observations from January 2001 through December 2020. Remotely sensed actual ET (aET) data were sourced from NASA’s Terra Moderate Resolution Imaging Spectroradiometer (MODIS), and reference ET (refET) data were derived from the Gridded Surface Meteorological (gridMET) dataset. For in situ comparison, aET data were downloaded from the AmeriFlux database while refET data were collected from the Illinois Climate Network and Michigan State University’s Enviro-weather database. For a holistic assessment of ET, this project generated comparisons between remotely sensed and in situ observations, calculated descriptive statistics for validation between refET datasets, and spatially produced statistical validation maps regarding in situ sites. The temporal and spatial gaps of AmeriFlux data limited aET analysis. This comparative assessment of ET products across the Midwest can be used by project partners to assess regional water trends and guide future land management decisions.

Addison Pletcher↗

NASA NTRS2024

Ensuring Safe Decision-Making on the Moon and Mars: Cognitive Performance Assessment for Exploration Class Mission EVA

Extravehicular activity (EVA) is one of the most dangerous and cognitively demanding actions that astronauts can execute, and the cognitive demands associated with future partial gravity EVA on the Moon and Mars are expected to be higher compared to microgravity EVA currently conducted from the International Space Station (ISS). Decrements in cognitive performance present an important risk to crew safety during exploration mission class EVA. Yet there is currently insufficient data to characterize cognitive performance prior to, during, and following EVA. Furthermore, it is still unclear which cognitive domains are most important for conducting mission critical decisions with crew safety implications. To address this gap, we conducted a cognitive task analysis (CTA) of EVA to characterize the procedures, the cognitive demands required, and the critical safety decisions associated with decrements in cognitive performance. We used the applied cognitive task analysis method as outlined by Militello and Hutton (1998) and conducted interviews with subject matter experts (SMEs) in EVA at NASA Johnson Space Center in summer 2024. Interviews focused on exploration EVA and elicited feedback from SMEs on the cognitive skills required for specific EVA tasks including cognitive strategies, critical cues, and decision-making strategies. A cognitive demands table was assembled to consolidate and synthesize the information from all interviews. The information from this cognitive task analysis will inform ongoing work to identify the key cognitive domains for safe decision-making during exploration mission class EVA on the Moon and Mars. This work will importantly provide a link between cognitive domains identified in the cognitive task analysis and operationally-relevant performance metrics collected during spaceflight and simulation EVA that can be tracked and assessed by NASA mission operations. Ultimately, this work will aid in the development and application of exploration class cognitive performance monitoring capabilities to improve safe decision-making and inform EVA planning on future spaceflight missions to the Moon and Mars.

Steven R Anderson↗

NASA NTRSDate not supplied

Ensuring Safe Decision-Making on the Moon and Mars: Cognitive Performance Assessment for Exploration Class Mission EVA

Extravehicular activity (EVA) is one of the most dangerous and cognitively demanding actions that astronauts can execute, and the cognitive demands associated with future partial gravity EVAs on the Moon and Mars are expected to be higher compared to microgravity EVAs currently conducted from the International Space Station. Decrements in cognitive performance present an important risk to crew safety during exploration mission class EVA. Yet there is currently insufficient data to characterize cognitive performance prior to, during, and following EVA. Furthermore, it is still unclear which cognitive domains are most important for conducting mission critical decisions with crew safety implications. To address this gap, we conducted a cognitive task analysis (CTA) of EVA to characterize the procedures, the cognitive demands required, and the critical safety decisions associated with decrements in cognitive performance. We conducted a cognitive task analysis with 15 astronauts and subject matter experts in EVA operations and research. Interviews focused on surface exploration EVA and elicited feedback from experts on the cognitive skills required for specific EVA tasks, including cognitive strategies, critical cues, and decision-making strategies. A cognitive demands table was assembled to consolidate and synthesize the information from all interviews. The information from this cognitive task analysis informs ongoing exploration EVA for Moon to Mars. This work identifies the specific cognitive challenges that astronauts are likely to encounter during surface exploration EVA, and provides the foundation for: (1) prioritized and targeted cognitive performance measurement and functional performance tests, (2) EVA simulation design at varying levels of cognitive workload, and (3) the development of training and other technologies that can improve safe decision-making and inform EVA planning on future spaceflight missions to the Moon and Mars.

Steven R Anderson↗

NASA NTRS1977

Air-Gapped Structures as Magnetic Elements for Use in Power Processing Systems

Methodical approaches to the design of inductors for use in LC filters and dc-to-dc converters using air gapped magnetic structures are presented. Methods for the analysis and design of full wave rectifier LC filter circuits operating with the inductor current in both the continuous conduction and the discontinuous conduction modes are also described. In the continuous conduction mode, linear circuit analysis techniques are employed, while in the case of the discontinuous mode, the method of analysis requires computer solutions of the piecewise linear differential equations which describe the filter in the time domain. Procedures for designing filter inductors using air gapped cores are presented. The first procedure requires digital computation to yield a design which is optimized in the sense of minimum core volume and minimum number of turns. The second procedure does not yield an optimized design as defined above, but the design can be obtained by hand calculations or with a small calculator. The third procedure is based on the use of specially prepared magnetic core data and provides an easy way to quickly reach a workable design.

Ohri, A. K.↗

NASA NTRS1982

Flow through the tile gaps in the Space Shuttle Thermal Protection System

The problem of predicting aerodynamic loads on the insulating tiles of the Space Shuttle Thermal Protection System (TPS) is discussed and seen to require a method for predicting pressure and mass flux in the gaps between tiles. A mathematical model of the tile-gap flow is developed based upon a slow viscous (Stokes) flow analysis and is verified against available experimental data. This model derives the tile-gap pressure field from a solution of the two-dimensional Laplace equation; the mass flux vector is then calculated from the pressure gradient. The means for incorporating this model into a lumped-parameter network analogy for porous-media flow is also given. The flow model shows tile-gap mass flux to be very sensitive to the gap width indicating a need for coupling the TPS flow and tile displacement calculations. Finally recommendations are made concerning additional analytical and experimental work to improve TPS flow predictions.

Dwoyer, D. L.↗

DOE OSTI2026

Predicting Band-Gap of Inorganic Materials Using Neuromorphic Graph Learning

Predicting properties of inorganic materials is a heavily researched topic, with several new prediction approaches emerging as competitors. One such competitor is graph neural networks, which leverage the structure of the graph to aid in the prediction process. In this work, we propose integration of neuromorphic computation into the graph neural network pipeline. We call this approach Neuromorphic Graph Learning (NGL). We utilize the NGL approach to leverage evolutionary algorithms and a novel Spike Pipeline for Raster Analysis (SPIRE) for the prediction of band gap in inorganic materials.

Mulet, Ian [University of Tennessee (UT)]↗