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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS2023

Establishing a Pathway to Greener Aviation

The burning and production of jet fuel in both commercial and regional planes at a high volume releases extreme levels of carbon emission as of its current state. This paper analyzes the implementation and benefits of three sustainable alternatives to traditional jet fuel: sustainable aviation fuel (SAF), hydrogen fuel cells, and electric batteries. A roadmap to show progress in reducing the carbon footprint of aviation is then proposed. The first phase of the roadmap involves the evolution of technology, validation, and testing of SAF-powered planes and the preliminary development of hydrogen production and propulsion and battery technology and the development of electric propulsion technologies. The second phase illustrates the widespread implementation of all three fuel sources where electric aviation will be enforced in short-range travel (30 min-3 hrs), medium-range aircraft (3-6 hrs) will use hydrogen fuel cells, and long-range (6+ hrs) airliners will utilize SAF. The third and final phase will enact the use of SAF and electric batteries for long-range applications while hydrogen fuel cells will dominate short- and medium-range aircraft. This roadmap, in combination with proper legislative action and corporate cooperation paired with public awareness, can help eliminate the usage of jet fuel in the aviation industry and replace it with three more sustainable and clean fuel sources.

green aviation↗
DOE OSTI2021

Ultrathin platinum nanowire based electrodes for high-efficiency hydrogen generation in practical electrolyzer cells

Significant reduction of noble metal catalyst loading and simplification of electrode fabrication are urgently needed in order to lower the cost of proton exchange membrane electrolyzer cells (PEMECs) for large-scale hydrogen production. Herein, we report an integrated electrode design comprising in-situ grown platinum nanowires (PtNW) on ultrathin titanium liquid/gas diffusion layers (LGDLs) via a cost-effective and green chemical synthesis approach. The ultrathin integrated PtNW electrodes showed a low cell voltage of 1.643 V and high efficiency of 90.08% at 1000 mA cm -2 using about 15 times lower catalyst loadings than a conventional catalyst-coated membrane in PEMEC tests. Ex-situ electrochemical characterizations and microscale visualizations further reveal that PtNW electrodes display highly efficient hydrogen evolution reactions and excellent electrode durability due to high active surface area, favorable bubble detachment, and structural stability. This work provides new insights into catalyst layer design and facile ultrathin electrode fabrication for more compact and low-cost PEM electrolyzers, fuel cells and other systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Design and Characterization of Metal Nanoparticle Infiltrated Mesoporous Metal–Organic Frameworks

The infiltration of palladium and platinum nanoparticles (NPs) into the mesoporous metal–organic framework (MOF) CYCU-3 through chemical vapor infiltration (CVI) and incipient wetness infiltration (IWI) processes was systematically explored as a means to design novel NP@MOF composite materials for potential hydrogen storage applications. We employed a traditional CVI process and a new "green" IWI process using methanol for precursor infiltration and reduction under mild conditions. Transmission electron microscopy-based direct imaging techniques combined with synchrotron-based powder diffraction (SPD), energy-dispersive X-ray spectroscopy, and physisorption analysis reveal that the resulting NP@MOF composites combine key NP and MOF properties. Room temperature hydrogen adsorption capacities of 0.95 and 0.20 mmol/g at 1 bar and 2.9 and 1.8 mmol/g at 100 bar are found for CVI and IWI samples, respectively. Additionally, hydrogen spillover and/or physisorption are proposed as the dominating adsorption mechanisms depending on the NP infiltration method. Mechanistic insights were obtained through the crystallographic means using SPD-based difference envelope density analysis, providing previously underexplored details on NP@MOF preparations. Consequently, important host–guest correlations influencing the global hydrogen adsorption properties are discussed, and they demonstrate that employing MOFs as platforms for NPs is an alternative approach to the development of versatile materials for improving current hydrogen storage technologies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Hydrogen from Carbonaceous Waste Material - Hydrogen Fuel Cells Prize Phase 2 Voucher: Cooperative Research and Development (Final Report)

NLR conducted a conceptual design study for scaling up biomass conversion technology from Green Fortress Engineering (GFE). GFE has proprietary technology where cellulosic biomass is thermally converted to a tar-free syngas. A ceramic membrane separation unit (MSU) previously developed with NLR can extract high-purity hydrogen from the syngas. The energy content of the retentate stream is sufficient to power the process with a gas-powered genset. Design details including mass and energy balances, process and instrumentation diagrams (P&ID), and major equipment schedules were delivered.

08 HYDROGEN↗
DOE OSTI2023

High throughput discovery of ternary Cu-Fe-Ru alloy catalysts for photo-driven hydrogen production

Light driven hydrogen production from the water splitting reaction has the ability to reduce dependence on fossil fuels in a green energy future. Here, we highlight the discovery of Cu x Ru y Fe 1-x-y nanoparticle catalysts for photo-driven hydrogen production. Through a high throughput experimental setup, robust data management pipelines and intentional experimental design, this study uncovered three highly active bimetallic systems for photo-driven hydrogen and identified a new trimetallic catalyst for this system. In most cases, the multimetallic catalysts outperformed the monometallics. Furthermore, this study highlights the expansive catalytic screening capabilities of this system in contrast to traditional catalytic selection processes through the discovery of distributions of particle compositions in binary and ternary mixtures of metals with high activity for hydrogen evolution.

08 HYDROGEN↗
DOE OSTI2021

The Storage of Marine Hydrokinetic Power through Hydrogen Production

Marine hydrokinetic (MHK) power is likely to play a crucial role in future energy diversification and remote energy supply efforts. Providing a means of direct energy storage for MHK power would provide additional benefits to applications in ship microgrids and remote communities. Hydrogen (H 2 ) has long been pursued as a means of green energy storage and can be generated through electrolysis of water in an electrolyzer. However, electrolyzer technology for H 2 production is currently only possible on the commercial scale using fresh water, also a precious resource in our society. The direct electrolysis of seawater would alleviate the fresh water constraints for a new H 2 feedstock and a seawater-fed electrolyzer could be powered locally at a MHK platform. Several technical challenges exist before efficient direct seawater electrolysis can be realized. This project was designed as a demonstration of efficient direct seawater electrolysis that limits chlorine evolution, avoids use of platinum (Pt) group metals and overcomes cathode fouling over long service times.

08 HYDROGEN↗
DOE OSTI2025

A Full-Cell Model for Direct Toluene Electro-Hydrogenation Electrolysis

Liquid organic hydrogen carriers (LOHCs) are organic molecules that undergo a hydrogenation/dehydrogenation cycle to enable storage and transportation of hydrogen fuel under ambient conditions. One promising LOHC candidate is toluene, which can be converted to methylcyclohexane (MCH) electrochemically, enabling a decarbonized process when green electricity is used. In this study, we developed a full-cell model for the direct electro-hydrogenation of toluene to MCH, utilizing a zero-gap membrane electrode assembly architecture. The model incorporates electrochemical kinetics, ionic transport, water transport across the membrane, and mass transport effects. Electrochemical kinetics are characterized using Tafel analysis on Pt/Ru catalyst. The model is validated against experimental data, including polarization curves, Faradaic efficiencies, and water crossover. A voltage breakdown analysis shows that the performance is dominated by kinetic losses, and the model is used to carry out a comparison of different toluene electro-hydrogenation reaction catalysts. Finally, a sensitivity analysis is conducted on key design parameters illustrating which can be modified to maximize electrolyzer performance. The cathode specific surface area and cathode porous transport layer thickness (PTL) have the largest impact on the current density, while the PTL thickness and Pt loading in the PTL have the largest impact on Faradaic efficiency.

Ehlinger, Victoria M. [Lawrence Livermore National↗
DOE OSTI2020

Benchmarking the Performance of the ReaxFF Reactive Force Field on Hydrogen Combustion Systems

A thorough understanding of the kinetics and dynamics of combusting mixtures is of considerable interest, especially in regimes beyond the reach of current experimental validation. The ReaxFF reactive force field method has provided a way to simulate large-scale systems of hydrogen combustion via a parametrized potential that can simulate bond breaking. This modeling approach has been applied to hydrogen combustion, as well as myriad other reactive chemical systems. In this work, we benchmark the performance of several common parametrizations of this potential against higher-level quantum mechanical (QM) approaches. We demonstrate instances where these parametrizations of the ReaxFF potential fail both quantitatively and qualitatively to describe reactive events relevant for hydrogen combustion systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Advances in Colloidal InP-Based Quantum Dots for Photocatalytic Hydrogen Evolution

Photocatalytic materials for hydrogen generation are typically categorized into UV-absorbing metal oxides and visible-range semiconductors such as chalcogenides or perovskites, which often incorporate toxic elements. To address environmental concerns of the latter group, indium phosphide (InP)-based quantum dots (QDs) have recently emerged as a less toxic alternative. These nanocrystals (NCs) benefit from a broadband and tunable absorption spectrum, which is well matched for solar photochemistry, and offer suitable electronic characteristics to drive photoinduced charge separation. This perspective provides a comprehensive summary of the recent advancements in developing InP-based NCs with a focus on photocatalytic hydrogen production. We discuss synthetic strategies that enhance the catalytic activity of these materials and highlight key challenges that must be addressed to enhance their performance. Finally, we explore future research directions aimed at improving photocatalytic efficiency and integrating InP-based QDs into practical solar-to-fuel conversion systems.

Hydrogen↗
NASA NTRS1975

Phenomenological treatments of cross-sections for proton and hydrogen impact below 1 keV on molecular nitrogen

An analytic independent-particle model is used to construct static potentials to describe the interaction of hydrogen-like ions with atoms and molecules. Parameters of the ion-atom potential are determined from ab initio total energy minimization procedure. The elastic scattering of He(+) from Ne and Ar is investigated as a test case and comparison is made with experiment. The model is then used in conjunction with low energy H(+)-N2 experimental data to construct differential and total cross-sections for the scattering of protons and hydrogen in the energy range of 10 eV to 1 keV from molecular nitrogen. Analytic forms are used to parametrize these cross-sections to facilitate their use in the calculation of energy deposition by protons and hydrogen atoms in atmospheric gases.

Porter, H. S.↗
DOE OSTI2025

Rapid synthesis of phase-engineered tungsten carbide electrocatalysts via flash joule heating for high-current-density hydrogen evolution

Fabricating durable and high-performance electrocatalysts operating at high current densities for industrial acidic hydrogen evolution remains a daunting challenge. Tailoring the phase composition of electrocatalysts is a promising strategy to harness synergistic effects and improve charge transfer, thereby optimizing their performance. Here, this work presents a fast, green method based on flash joule heating (FJH) to synthesize phase-engineered tungsten carbide electrocatalysts for the acidic hydrogen evolution reaction (HER) at high current densities. Tungsten carbide electrodes with varying FJH treatment durations (3, 10, 30, and 60 s) are fabricated to fine-tune the mixture of tungsten monocarbide (WC) and tungsten semicarbide (W 2 C) phases. Results show that samples with a 30-s treatment (TC-3) exhibit an optimal balance between these phases, leading to a low overpotential of 180.97 and 387 mV at current densities of 10 mA/cm 2 and 4 A/cm 2 , respectively. TC-3 exhibits significantly lower charge transfer resistance compared to the other electrocatalysts, which can be attributed to its optimal phase ratio. Notably, the TC-3 electrocatalyst remains stable for over 9 days at 4 A/cm 2 due to their controlled phases and excellent corrosion-resistant properties. This work highlights a new method to fabricate cost-effective, high-performance tungsten carbide electrocatalysts with well-controlled phase compositions.

Acidic hydrogen evolution reaction↗
DOE OSTI2024

Photocatalytic water splitting for large-scale solar-to-chemical energy conversion and storage

Sunlight-driven water splitting allows renewable hydrogen to be produced from abundant and environmentally benign water. Large-scale societal implementation of this green fuel production technology within energy generation systems is essential for the establishment of sustainable future societies. Among various technologies, photocatalytic water splitting using particulate semiconductors has attracted increasing attention as a method to produce large amounts of green fuels at low cost. The key to making this technology practical is the development of photocatalysts capable of splitting water with high solar-to-fuel energy conversion efficiency. Furthermore, advances that enable the deployment of water-splitting photocatalysts over large areas are necessary, as is the ability to recover hydrogen safely and efficiently from the produced oxyhydrogen gas. This lead article describes the key discoveries and recent research trends in photosynthesis using particulate semiconductors and photocatalyst sheets for overall water splitting, via one-step excitation and two-step excitation (Z-scheme reactions), as well as for direct conversion of carbon dioxide into renewable fuels using water as an electron donor. We describe the latest advances in solar water-splitting and carbon dioxide reduction systems and pathways to improve their future performance, together with challenges and solutions in their practical application and scalability, including the fixation of particulate photocatalysts, hydrogen recovery, safety design of reactor systems, and approaches to separately generate hydrogen and oxygen from water.

30 DIRECT ENERGY CONVERSION↗
NASA NTRS1980

Collisional excitation of interstellar molecules - Water

Rate constants for excitation of water molecules by collisions with He atoms have been obtained from extensive theoretical calculations. For ortho-H2O, rates are presented for all spectroscopic levels below 1000/cm and for kinetic temperatures to 500 K; for para-H2O, levels below 300/cm and kinetic temperatures to 250 K are included. It is suggested that rates of excitation by collisions with hydrogen molecules are similar to those for He atoms.

Green, S.↗
NASA NTRS1989

Cryogenic techniques for large superconducting magnets in space

A large superconducting magnet is proposed for use in a particle astrophysics experiment, ASTROMAG, which is to be mounted on the United States Space Station. This experiment will have a two-coil superconducting magnet with coils which are 1.3 to 1.7 meters in diameter. The two-coil magnet will have zero net magnetic dipole moment. The field 15 meters from the magnet will approach earth's field in low earth orbit. The issue of high Tc superconductor will be discussed in the paper. The reasons for using conventional niobium-titanium superconductor cooled with superfluid helium will be presented. Since the purpose of the magnet is to do particle astrophysics, the superconducting coils must be located close to the charged particle detectors. The trade off between the particle physics possible and the cryogenic insulation around the coils is discussed. As a result, the ASTROMAG magnet coils will be operated outside of the superfluid helium storage tank. The fountain effect pumping system which will be used to cool the coil is described in the report. Two methods for extending the operating life of the superfluid helium dewar are discussed. These include: operation with a third shield cooled to 90 K with a sterling cycle cryocooler, and a hybrid cryogenic system where there are three hydrogen-cooled shields and cryostat support heat intercept points.

Green, M. A.↗
DOE OSTI2022

Characteristics of U.S. Energy Production using Nuclear Fission

When considering potential energy production technologies for the future, a critical consideration centers on the question of “how green” the technology is. Here, the word “green” implies that the technology has a zero or minimal impact on the public and environment while still providing benefits by way of electricity, heat, and other products such as hydrogen and water. And, these potential impacts must be considered over the lifecycle of the technology deployment, from design, construction, operation, and disposition. Ideally, a green energy technology would be net-zero (i.e., having no to almost negligible contribution) on five key elements: 1. Greenhouse gas emissions, including carbon dioxide (CO 2 ), methane, nitrous oxide, and fluorinated gases such as ozone-depleting gases 2. Water consumption 3. Material resource consumption 4. Disposition of wastes 5. Public, flora, and fauna safety including deaths, health, and environmental impacts. Society would benefit from net-zero impacts of the five elements above while having low-cost energy. As society starts to replace fossil fuels in the energy mix, we need to consider the possible impacts of adopted technologies. We need a production approach that provides large quantities of energy while being safe, reliable, economical, and sustainable. In this report, we describe a variety of characteristics related to the five elements above to provide a fact-supported, science-based depiction of nuclear fission as an energy providing technology. By better understanding how fission power is nearly net-zero in the five elements above, we can position our thinking to align with the overarching goal to provide society with a low-impact energy source.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗