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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

Cryogenic Gellant and Fuel Formulation for Metallized Gelled Propellants: Hydrocarbons and Hydrogen with Aluminum

An experimental program to determine the viability of nanoparticulate gellant materials for gelled hydrocarbons and gelled liquid hydrogen was conducted. The gellants included alkoxides (BTMSE and BTMSH) and silica-based materials. Hexane, ethane, propane and hydrogen were gelled with the newly-formulated materials and their rheological properties were determined: shear stress versus shear rate and their attendant viscosities. Metallized hexane with aluminum particles was also rheologically characterized. The propellant and gellant formulations were selected for the very high surface area and relatively-high energy content of the gellants. These new gellants can therefore improve rocket engine specific impulse over that obtained with traditional cryogenic-fuel gellant materials silicon dioxide, frozen methane, or frozen ethane particles. Significant reductions in the total mass of the gellant were enabled in the fuels. In gelled liquid hydrogen, the total mass of gellant was reduced from 10-40 wt percent of frozen hydrocarbon particles to less that 8 wt percent with the alkoxide.

Wong, Wing↗

New Pathways and Metrics for Enhanced, Reversible Hydrogen Storage in Boron-Doped Carbon Nanospaces

This project, since its start in 2007—entitled “Networks of boron-doped carbon nanopores for low-pressure reversible hydrogen storage” (2007-10) and “New pathways and metrics for enhanced, reversible hydrogen storage in boron-doped carbon nanospaces” (2010-13)—is in support of the DOE's National Hydrogen Storage Project, as part of the DOE Hydrogen and Fuel Cells Program’s comprehensive efforts to enable the widespread commercialization of hydrogen and fuel cell technologies in diverse sectors of the economy. Hydrogen storage is widely recognized as a critical enabling technology for the successful commercialization and market acceptance of hydrogen powered vehicles. Storing sufficient hydrogen on board a wide range of vehicle platforms, at energy densities comparable to gasoline, without compromising passenger or cargo space, remains an outstanding technical challenge. Of the main three thrust areas in 2007—metal hydrides, chemical hydrogen storage, and sorption-based hydrogen storage—sorption-based storage, i.e., storage of molecular hydrogen by adsorption on high-surface-area materials (carbons, metal-organic frameworks, and other porous organic networks), has emerged as the most promising path toward achieving the 2017 DOE storage targets of 0.055 kg H2/kg system (“5.5 wt%”) and 0.040 kg H2/liter system.

08 HYDROGEN↗

Collaborative Research: Large Scale Intensity Mapping of Neutral Hydrogen with the Tianlai Pathfinders

This program developed new analysis methods for current and upcoming cosmological hydrogen 21cm intensity mapping data from the Tianlai experiment, located in a radio quiet area of Western China. Such mapping provides important clues to the evolution of gas and galaxies in the early universe. The experiment measured the three-dimensional large-scale structure of the universe via hydrogen emission from distant galaxies. The primary goal was to develop ways to handle the large foreground signal, which has been previously quantified in a pathfinder 21cm program conducted on NSF's Green Bank Telescope.

79 ASTRONOMY AND ASTROPHYSICS↗

2017 DOE Vehicle Technologies Office Annual Merit Review

The 2017 U.S. Department of Energy (DOE) Hydrogen and Fuel Cells Program and Vehicle Technologies Office (VTO) Annual Merit Review and Peer Evaluation Meeting (AMR) was held June 5-9, 2017, in Washington, DC. The review encompassed work done by the Hydrogen and Fuel Cells Program and VTO: 263 individual activities were reviewed for VTO by 191 reviewers. Exactly 1,241 individual review responses were received for the VTO technical reviews. The objective of the meeting was to review the accomplishments and plans for VTO over the previous 12 months, and provide an opportunity for industry, government, and academia to give inputs to DOE with a structured and formal methodology. The meeting also provided attendees with a forum for interaction and technology information transfer.

33 ADVANCED PROPULSION SYSTEMS↗

2016 DOE Vehicle Technologies Office Annual Merit Review

The 2016 U.S. Department of Energy (DOE) Hydrogen and Fuel Cells Program and Vehicle Technologies Office (VTO) Annual Merit Review and Peer Evaluation Meeting (AMR) was held June 6-9, 2016, in Washington, DC. The review encompassed work done by the Hydrogen and Fuel Cells Program and VTO: 226 individual activities were reviewed for VTO, by 171 reviewers. A total of 1,044 individual review responses were received for the VTO technical reviews. The objective of the meeting was to review the accomplishments and plans for VTO over the previous 12 months, and provide an opportunity for industry, government, and academia to give inputs to DOE with a structured and formal methodology. The meeting also provided attendees with a forum for interaction and technology information transfer.

33 ADVANCED PROPULSION SYSTEMS↗

Hydrogen Research at Florida Universities

This final report describes the R&D activities and projects conducted for NASA under the 6-year NASA Hydrogen Research at Florida Universities grant program. Contained within this report are summaries of the overall activities, one-page description of all the reports funded under this program and all of the individual reports from each of the 29 projects supported by the effort. The R&D activities cover hydrogen technologies related to production, cryogenics, sensors, storage, separation processes, fuel cells, resource assessments and education. In the span of 6 years, the NASA Hydrogen Research at Florida Universities program funded a total of 44 individual university projects, and employed more than 100 faculty and over 100 graduate research students in the six participating universities. Researchers involved in this program have filed more than 20 patents in all hydrogen technology areas and put out over 220 technical publications in the last 2 years alone. This 6 year hydrogen research program was conducted by a consortium of six Florida universities: Florida International University (FIU) in Miami, Florida State University (FSU) and Florida A&M University (FAMU) in Tallahassee, University of Central Florida (UCF) in Orlando, University of South Florida (USF) in Tampa, and University of Florida (UF) in Gainesville. The Florida Solar Energy Center (FSEC) of the University of Central Florida managed the research activities of all consortium member universities except those at the University of Florida. This report does not include any of the programs or activities conducted at the University of Florida, but can be found in NASA/CR-2008-215440-PART 1-3.

Block, David L.↗

Non-Electric Applications of Generation IV Reactors: Accelerating Economy-Wide Decarbonization via Nuclear Energy

This presentation covers the role of nuclear energy in support net-zero solutions, highlighting work within the US DOE Integrated Energy Systems, Light Water Reactor Sustainability, and Hydrogen at Scale programs. The discussion will also introduce the recently-establishing Generation-IV International Forum (GIF) interim task force on non-electric applications of nuclear heat (NEaNH-iTF). This work is presented within a special invited webinar organized by the GIF Education and Training Working Group and the International Atomic Energy Agency.

08 HYDROGEN↗

Optimizing Active Sites for High CO Selectivity during CO 2 Hydrogenation over Supported Nickel Catalysts

The undesired formation of CH 4 during the hydrogenation of CO 2 remains a great challenge with direct impact on selectivity towards CO or CH 3 OH. In this study, the selectivity of a supported Ni catalyst prepared by traditional impregnation method was found to change after a first CO 2 hydrogenation reaction cycle from 100 to 800 °C. The usually high CH 4 formation was suppressed leading to full selectivity towards CO. This behavior was also observed after the catalyst was treated under methane or propane atmospheres at elevated temperatures. In-situ spectroscopic studies revealed that the accumulation of carbon species on the catalyst surface at high temperature leads to a nickel carbide-like phase. The catalyst regains its high selectivity to CH 4 production after carbon depletion from the surface of the Ni particles by oxidation. However, the selectivity readily shifts back towards CO formation after a new temperature programmed CO 2 hydrogenation cycle. The fraction of weakly adsorbed CO species increases on the carbide-like surface when compared to a clean nickel surface, explaining the higher selectivity towards CO formation. This easy protocol of changing the surface of a common Ni catalyst to gain selectivity represents an important step for the commercial use of CO 2 hydrogenation to CO process together with Fischer-Tropsch applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Invisible Flame Imaging

Stennis Space Center uses more than one million gallons of liquid hydrogen per month in its rocket testing program. Firefighters responding to a hydrogen fire had to give the area "the broom test" to determine the presence and location of a fire. This technique has significant safety and accuracy shortfalls. Stennis then developed technology to visually assess the presence, location and extent of hydrogen fires. SafetyScan, LLC. is now manufacturing FIRESCAPE, the first affordable commercial product for invisible (or ashless) fire imaging based on the original technology, to aid firefighters in seeing the invisible flames from alcohol and hydrogen fires during the day and even through smoke. The hand-held device weighs five pounds, is used like a pair of binoculars and can run for up to two hours before recharging.

Source record↗

NASA's Hydrogen Outpost: The Rocket Systems Area at Plum Brook Station

"There was pretty much a general knowledge about hydrogen and its capabilities," recalled former researcher Robert Graham. "The question was, could you use it in a rocket engine? Do we have the technology to handle it? How will it cool? Will it produce so much heat release that we can't cool the engine? These were the questions that we had to address." The National Aeronautics and Space Administration's (NASA) Glenn Research Center, referred to historically as the Lewis Research Center, made a concerted effort to answer these and related questions in the 1950s and 1960s. The center played a critical role transforming hydrogen's theoretical potential into a flight-ready propellant. Since then NASA has utilized liquid hydrogen to send humans and robots to the Moon, propel dozens of spacecraft across the universe, orbit scores of satellite systems, and power 135 space shuttle flights. Rocket pioneers had recognized hydrogen's potential early on, but its extremely low boiling temperature and low density made it impracticable as a fuel. The Lewis laboratory first demonstrated that liquid hydrogen could be safely utilized in rocket and aircraft propulsion systems, then perfected techniques to store, pump, and cleanly burn the fuel, as well as use it to cool the engine. The Rocket Systems Area at Lewis's remote testing area, Plum Brook Station, played a little known, but important role in the center's hydrogen research efforts. This publication focuses on the activities at the Rocket Systems Area, but it also discusses hydrogen's role in NASA's space program and Lewis's overall hydrogen work. The Rocket Systems Area included nine physically modest test sites and three test stands dedicated to liquid-hydrogen-related research. In 1962 Cleveland Plain Dealer reporter Karl Abram claimed, "The rocket facility looks more like a petroleum refinery. Its test rigs sprout pipes, valves and tanks. During the night test runs, excess hydrogen is burned from special stacks in the best Oklahoma oil field tradition." Besides the Rocket Systems Area, Plum Brook Station also included a nuclear test reactor, a large vacuum tank, a hypersonic wind tunnel, and a full-scale upper-stage rocket stand. The Rocket Systems Area operated from 1961 until NASA shut down all of Plum Brook in 1974. The center reopened Plum Brook in the late 1980s and continues to use several test facilities. The Rocket Systems Area, however, was not restored. Today Plum Brook resembles a nature preserve more than an oil refinery. Lush fields and forests separate the large test facilities. Until recently, the abandoned Rocket Systems Area structures and equipment were visible amongst the greenery. These space-age ruins, particularly the three towers, stood as silent sentinels over the sparsely populated reservation. Few knew the story of these mysterious facilities when NASA removed them in the late 2000s.

Rocket Systems↗

Metallic Membrane Materials Development for Hydrogen Production from Coal Derived Syngas

The goals of Office of Clean Coal are: (1) Improved energy security; (2) Reduced green house gas emissions; (3) High tech job creation; and (4) Reduced energy costs. The goals of the Hydrogen from Coal Program are: (1) Prove the feasibility of a 40% efficient, near zero emissions IGCC plant that uses membrane separation technology and other advanced technologies to reduce the cost of electricity by at least 35%; and (2) Develop H{sub 2} production and processing technologies that will contribute {approx}3% in improved efficiency and 12% reduction in cost of electricity.

01 COAL, LIGNITE, AND PEAT↗

Catalytic ignition of hydrogen and oxygen propellants

An experimental program was conducted to evaluate the catalytic ignition of gaseous hydrogen and oxygen propellants. Shell 405 granular catalyst and a monolithic sponge catalyst were tested. Mixture ratio, mass flow rate, propellant temperature, and back pressure were varied parametrically in testing to determine the operational limits of the catalytic igniter. The test results show that the gaseous hydrogen and oxygen propellant combination can be ignited catalytically using Shell 405 catalyst over a wide range of mixture ratios, mass flow rates, and propellant injection temperatures. These operating conditions must be optimized to ensure reliable ignition for an extended period of time. A cyclic life of nearly 2000, 2 sec pulses at nominal operating conditions was demonstrated with the catalytic igniter. The results of the experimental program and the established operational limits for a catalytic igniter using the Shell 405 catalyst are presented.

Zurawski, Robert L.↗

Catalytic ignition of hydrogen and oxygen propellants

An experimental program was conducted to evaluate the catalytic ignition of gaseous hydrogen and oxygen propellants. Shell 405 granular catalyst and a monolithic sponge catalyst were tested. Mixture ratio, mass flow rate, propellant temperature, and back pressure were varied parametrically in testing to determine the operational limits of the catalytic igniter. The test results show that the gaseous hydrogen and oxygen propellant combination can be ignited catalytically using Shell 405 catalyst over a wide range of mixture ratios, mass flow rates, and propellant injection temperatures. These operating conditions must be optimized to ensure reliable ignition for an extended period of time. A cyclic life of nearly 2000, 2 sec pulses at nominal operating conditions was demonstrated with the catalytic igniter. The results of the experimental program and the established operational limits for a catalytic igniter using the Shell 405 catalysts are presented.

Zurawski, Robert L.↗

Selective Hydrogenation of Acetylene to Ethylene over Bimetallic Catalysts

Ni/α-Al 2 O 3 catalyst and a series of bimetallic catalysts including Pd–Ag, Ni–Pd, Ni–Zn, Ni–Ag, and Ni–Ga were synthesized, characterized, and tested in selective hydrogenation of acetylene to ethylene. The bimetallic catalyst Ni–Ga exhibited almost the same ethylene selectivity compared to Pd–Ag based catalyst. The effect of the Ni/Ga ratio on the catalytic activity and selectivity to ethylene in acetylene hydrogenation was evaluated. Characterization by transmission electron microscopy, X-ray diffraction, hydrogen temperature-programmed reduction, and X-ray photoelectron spectroscopy was carried out to identify active phases on Ni–Ga based catalysts, which was correlated with catalytic performance and the reaction mechanism occurring over the catalyst. Here, the presence of Ga in Ni–Ga lattice structure confined the movement of dissociated H* and reduced the adsorption binding energy of ethylene, which could prevent overhydrogenation of acetylene.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Preparation of Ni—Mo/γ-Al{sub 2}O{sub 3} Catalysts by Vacuum Impregnation and Their Use for Hydrodesulfurization of Dibenzothiophene

A dual metal Ni—Mo/γ-Al{sub 2}O{sub 3} catalyst was prepared by saturated impregnation and H{sub 2} reduction pretreatment on γ-Al{sub 2}O{sub 3} support with Ni as the active component and Mo as the promoter. The support and catalysts were characterized using x-ray diffraction, hydrogen temperature-programmed reduction, and scanning electron microscopy. The catalytic properties for the reaction of dibenzothiophene (DBT) were investigated in a high-pressure reactor. The hydrodesulfurization (HDS) activity was comparable with those of advanced desulfurization catalysts FHUDS-5 and FHUDS-6. The Ni—Mo catalyst had excellent dispersion characteristics on the support. Synergism between Ni and Mo was greatest at a Ni/Mo molar ratio of 2:1. The DBT conversion on Ni—Mo/γ-Al{sub 2}O{sub 3} catalyst reached 100% at a reaction temperature of 300°C, pressure of 4 MPa, and reaction time of 150 min. The Ni—Mo/γ-Al{sub 2}O{sub 3}atalyst was significantly more active than the aforementioned two commercial FHUDS catalysts for HDS of DBT.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

H2A Production Model Updates

The H2A model has provided the DOE Fuel Cell Technologies Program with a technology neutral cost calculator for: Development of cost targets for hydrogen production technologies, DOE Program assessment of progress toward goals, Researchers to compare process options

13 HYDRO ENERGY↗

Divanadium substituted keggin [PV 2 W 10 O 40 ] on non-reducible supports-Al 2 O 3 and SiO 2 : synthesis, characterization, and catalytic properties for oxidative dehydrogenation of propane

Molecular metal oxide cluster, K 5 [α-1,2-PV 2 W 10 O 40 ] (PV 2 W 10 ), was found to have intrinsic catalytic activity for the oxidative dehydrogenation of propane with high selectivity (> 80%) to propylene at low propane conversion (0.3%). Synthesis of dispersed PV 2 W 10 in non-reducible supports, γ-Al 2 O 3 and SiO 2 , was done by incipient wetness impregnation. The supported catalysts were characterized by IR, Raman spectroscopy, nitrogen adsorption, x-ray powder diffraction (PXRD), elemental analysis, hydrogen temperature-programmed reduction (H 2 –TPR), and ammonia temperature-programmed desorption (NH 3 –TPD). Catalytic testing of the supported PV 2 W 10 at equimolar cluster concentration revealed that when supported in γ-Al 2 O 3 it is more active (sevenfold increase in propane conversion) but in SiO 2 it is more selective to propylene (94%). The observed performance was due to both an increase in reducibility and higher concentration of strong acid sites for PV 2 W 10 supported in γ-Al 2 O 3 versus SiO 2 . Lastly, PV 2 W10 was shown to remain intact under reaction conditions indicating its thermal and oxidative stability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗