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At least 271 records · Page 15

Reweighting the Sivers function with jet data from STAR

The reweighting procedure that using Bayesian statistics incorporates the information contained in a new data set, without the need of re-fitting, is applied to the quark Sivers function extracted from Semi-Inclusive Deep Inelastic Scattering (SIDIS) data. We exploit the recently published single spin asymmetry data for the inclusive jet production in polarized pp collisions from the STAR Collaboration at RHIC, which cover a much wider x region compared to SIDIS measurements. The reweighting method is extended to the case of asymmetric errors and the results show a remarkable improvement of the knowledge of the quark Sivers function.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Spatiotemporal and Statistical Mapping of Transition Metal Equilibria in Alkaline Media

Transition metal dissolution and redeposition (D/R) kinetics in alkaline media play a critical role in various chemical and electrochemical processes. Competitive reaction kinetics between different transition metals can modulate individual metal behavior in these processes. To date, these phenomena have remained largely unmeasured, and even when captured, they are difficult to statistically characterize due to their dynamic nature, simultaneous occurrence, and spatially heterogeneous nature. Here, in this study, we develop a statistical analysis framework based on in situ and operando X-ray fluorescence microscopy (XFM) to investigate the relative D/R kinetics of multiple transition metals in alkaline media. By employing statistical analysis, we quantify the spatial distribution of D/R species and assess the rate at which the system reaches equilibrium under varying reaction conditions. We show that pH does not simply change the rate of dissolution and redeposition, but reorganizes the cross-element kinetic correlations among Ni, Fe, and Mn and accelerates the spatial equilibration of D/R events, as quantified through correlation analysis, reaction-rate estimation, probability function distributions, and texture-based monitoring statistics. Additionally, we demonstrate how modifying the solvent environment can influence D/R kinetics, providing a pathway for tuning materials synthesis and process optimization. Our study offers valuable insights into the complex interplay between different transition metals and provides a reliable statistical framework for spatial analysis of diverse imaging data sets, enabling deeper extraction of latent information across multiple modalities.

36 MATERIALS SCIENCE↗

Cu site differentiation in tetracopper(I) sulfide clusters enables biomimetic N 2 O reduction

Copper clusters feature prominently in both metalloenzymes and synthetic nanoclusters that mediate catalytic redox transformations of gaseous small molecules. Such reactions are critical to biological energy conversion and are expected to be crucial parts of renewable energy economies. However, the precise roles of individual metal atoms within clusters are difficult to elucidate, particularly for cluster systems that are dynamic under operating conditions. Here, we present a metal site-specific analysis of synthetic Cu 4 (μ 4 -S) clusters that mimic the Cu Z active site of the nitrous oxide reductase enzyme. Leveraging the ability to obtain structural snapshots of both inactive and active forms of the synthetic model system, we analyzed both states using resonant X-ray diffraction anomalous fine structure (DAFS), a technique that enables X-ray absorption profiles of individual metal sites within a cluster to be extracted independently. Using DAFS, we found that a change in cluster geometry between the inactive and active states is correlated to Cu site differentiation that is presumably required for efficient activation of N 2 O gas. More precisely, we hypothesize that the Cu δ+ ∙∙∙Cu δ- pairs produced upon site differentiation are poised for N 2 O activation, as supported by computational modeling. These results provide an unprecedented level of detail on the roles of individual metal sites within the synthetic cluster system and how those roles interplay with cluster geometry to impact the reactivity function. We expect this fundamental knowledge to inform understanding of metal clusters in settings ranging from (bio)molecular to nanocluster to extended solid systems involved in energy conversion.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Demographic Information Incorporated Household Energy Consumption Analysis

The high energy consumption from residential buildings provides them large potential to participate in demand response programs. To design appropriate demand response programs for residential buildings, it is important for electric utilities to know the energy consumption characteristics for different types of households so that utilities can send requests to the groups with a higher possibility to successfully respond. In this paper, we develop a load model to generate synthetic load profiles for different types of households incorporating demographical information including Current Population Survey data set and American Time Use Survey data set. The details of each data set and the details of the load models are presented. The synthetic household load profiles are generated by the load model and clustered into different groups based on state, age, number of occupants, income level, and city of the household. The average energy consumption characteristics for different groups of households are analyzed and compared, which will help electric utilities issue demand response signals to appropriate households.

building loads↗

Experimental evaluation of respiratory droplet spread to rooms connected by a central ventilation system

This article presents results from an experimental study to ascertain the transmissibility of the SARS-CoV-2 virus between rooms in a building that are connected by a central ventilation system. Respiratory droplet surrogates made of mucus and virus mimics were released in one room in a test building and measurements of concentration levels were made in other rooms connected via the ventilation system. The paper presents experimental results for different ventilation system configurations, including ventilation rate, filtration level (up to MERV-13), and fractional outdoor air intake. The most important finding is that respiratory droplets can and do transit through central ventilation systems, suggesting a mechanism for viral transmission (and COVID-19 specifically) within the built environment in reasonable agreement with well-mixed models. We also find the deposition of these droplets on room walls to be negligibly small. Furthermore, the energy use impact of the different configuration settings is also quantified to help inform intelligent building operation that can simultaneously address energy use and occupant health.

60 APPLIED LIFE SCIENCES↗

Experimental Results for Large Particle Separation from Non-Newtonian Slurries Using Tapered Bump Arrays

Lateral displacement arrays are useful for separating particles such as blood cells and sand from carrier fluids. These arrays consist of staggered posts, which allow smaller particles to follow streamlines and larger particles to flow around the posts and migrate to one side. This migration increases the particle concentration in one direction and depletes the particle concentration in the other direction allowing particle separation to occur. Experiments were conducted to separate large particles in non-Newtonian yield stress slurries using tapered bump arrays. The non-Newtonian slurry used was composed of a bentonite kaolin blend with the inclusion of larger diameter particles. These experiments were conducted to evaluate the performance of particle separation using a tapered array of staggered posts as configured in a bump array for non-Newtonian yield stress slurries, an application that has not been explored experimentally. A theory for large particle separation was developed for slurries that exhibit Bingham or Cross rheology. The results of these experiments are described. This information could be applied in industrial settings such as separation of particles from nuclear waste slurries including those to be processed at the Hanford site, where removing large particles from waste streams is important to processing.

slurry, solids removal, deterministic lateral disp↗

Vibrational processing of a dynamic structural flight system: A multichannel spectral estimation approach

Dynamic testing of large flight vehicles (rockets) is not only complex, but also can be very costly. These flights are infrequent and can lead to disastrous effects if something were to fail during the flight. The development of sensors coupled to internal components offers a great challenge in reducing their size, yet still maintaining their precision. Sounding rockets provide both a viable and convenient alternative to the more costly vehicular flights. Some of the major objectives are to test various types of sensors for monitoring components of high interest as well as investigating real-time processing techniques. Signal processing presents an extreme challenge in this noisy multichannel environment. The estimation and tracking of modal frequencies from vibrating structures is an important set of features that can provide information about the components under test; therefore, high resolution multichannel spectral processing is required. Finally, the application of both single channel and multichannel techniques capable of producing reliable modal frequency estimates of a vibrating structure from uncertain accelerometer measurements is discussed.

42 ENGINEERING↗

Comparative Study of Differentially Private Data Synthesis Methods

When sharing data among researchers or releasing data for public use, there is a risk of exposing sensitive information of individuals in the data set. Data synthesis is a statistical disclosure limitation technique for releasing synthetic data sets with pseudo individual records. Traditional data synthesis techniques often rely on strong assumptions of a data intruder’s behaviors and background knowledge to assess disclosure risk. Differential privacy (DP) formulates a theoretical approach for a strong and robust privacy guarantee in data release without having to model intruders’ behaviors. Efforts have been made aiming to incorporate the DP concept in the data synthesis process. Here, we examine current DIfferentially Private Data Synthesis (DIPS) techniques for releasing individual-level surrogate data for the original data, compare the techniques conceptually and evaluate the statistical utility and inferential properties of the synthetic data via each DIPS technique through extensive simulation studies. Our work sheds light on the practical feasibility and utility of the various DIPS approaches, and suggests future research directions for DIPS.

97 MATHEMATICS AND COMPUTING↗

Effects of Vegetation on Fluxes of Nitric Oxide, Nitrogen Dioxide, and Nitrous Oxide in a Mixed Deciduous Forest Clearing

Atmosphere-terrestrial exchange of nitrogen oxides, such as nitric oxide (NO), nitrogen dioxide (NO2) and nitrous oxide (N2O), plays an important role in controlling atmospheric composition and the radiative forcing of Earth’s atmosphere. In this study, the impact of vegetation ground cover on NOx (NOx = NO + NO2) and N2O fluxes in a deciduous forest clearing was studied using dynamic flow chambers located on three experimental plots with differing vegetation ground cover. Microbial emissions of NO and N2O were observed throughout the measurement period, while NO2 was exclusively deposited. Vegetation had no observable impact on NO2 deposition. Under dry conditions, total measured nitrogen emissions were numerically similar across all plots, although the N2O:NO ratio was higher for plots containing plants. Vegetation elevates soil water content through enhanced water retention, a condition that favors denitrification and more N2O production, relative to NO. Two rain events induced pulses of NO and N2O that were higher for bare soil compared to the vegetated plots. Lower NO and N2O emissions in plant-containing chambers stemmed from enhanced root uptake of N following rewetting, which diminished the amount of N substrate available for microbial NO and N2O production. The sensitivity of soil N emissions to vegetation ground cover highlights the need for more studies that investigate this effect over a wide range of ecosystems and to include vegetation effects in future parameterizations of soil NOx and N2O used in atmospheric models. This dataset includes processed data collected from 4 dynamic flux chambers and 17 sensors. Data includes ambient gas measurements made 1 m from the surface and soil flux measurements of NO, NO2, N2O, ozone (O3) and carbon dioxide (CO2). Also included is a suite of meteorological (air temperature, humidity, pressure) and soil parameters (water filled pore space, soil temperature). Refer to the readme for more information about each of the data sets.

54 ENVIRONMENTAL SCIENCES↗

Reweighting the quark Sivers function with STAR jet data

The Bayesian reweighting procedure is applied for the first time to a TMD distribution, the quark Sivers function extracted from SIDIS data. By exploiting the recent published single spin asymmetry data for the inclusive jet production in p^\uparrow p p ↑ p collisions from the STAR collaboration at RHIC, we show how such a procedure allows to incorporate the information contained in the new data set, without the need of re-fitting, and to explore a much wider x x region compared to SIDIS measurements. The reweighting method is also extended to the case of asymmetric errors, and the results show a significant improvement on the knowledge of the quark Sivers function.

Flore, Carlo↗

Ordovician-Cambrian Units: Hierarchical Evaluation of Geologic Carbon Storage Resource Estimates

The Indiana Geological and Water Survey (IGWS) led subtask 1.1 to assess the regional distribution and estimate the storage capacity of Ordovician-Cambrian stratigraphic units located within the partnership region. A comprehensive data set of wireline logs and petrophysical information was used to generate these interpretations. These data include core analysis for porosity and permeability, mercury injection capillary pressure (MICP), and existing well data including location and stratigraphic information. This report includes storage resource estimates (SREs) for three potential storage reservoirs(limestone and dolostone from the Upper Ordovician Trenton Limestone/Black River Group and equivalent units, the Middle Ordovician St. Peter Sandstone, and primary target reservoir rocks of the Lower Ordovician and Upper Cambrian Knox Supergroup and equivalent units) calculated using six methodologies: (1) a fixed value of porosity of 10 percent in all units evaluated; (2) a unique average porosity (per well) from wireline-derived porosity (neutron, sonic, and/or density porosity for each unit); (3) porosity values from core analysis; (4) a depth-dependent porosity model (Knox Supergroup only); (5) porosity based on a model based on petrophysical facies; and (6) SREs using National Energy Technology Laboratory’s CO2 Storage prospeCtive Resource Estimation Excel aNalysis (CO2-SCREEN beta V2). All methods used the same values for thickness for each unit. However, the areal extent of each assessment was limited by the data available for each method. Estimated volumes were calculated in 1-by-1 kilometer grid cells and summarized as county and total stratigraphic unit volumes. The resultant SREs mass are displayed using boxplots, which allow for comparing data statistics (mean values and variability) between methods. Differences observed in SRE results from the six methods are mainly attributable to differences in the data and conceptual models used to interpret or estimate porosity in each method. Based on this systematic variability between methods, it is inferred that methods 1, 4, and 6 are best used for regional-scale reconnaissance estimates of storage capacity while methods 2, 3, and 5 are more appropriate for local scales where more data is required. All estimates are data-density dependent and different methods require different amounts of data for reasonable assessments. ArcMap 10.5.1 software was used to portray SREs to help visualize spatial variance of estimates for each methodology, and more importantly, to highlight those areas having the greatest total storage potential estimates.

01 COAL, LIGNITE, AND PEAT↗

A Parallel Computing Infrastructure for Building Energy Simulation

In order to study grid-interactive efficient buildings, Pacific Northwest National Laboratories (PNNL) needs an infrastructure for urban-scale building energy modeling. Such an infrastructure should be fast, scalable, and easy-to-use. Given a set of data from the Energy Information Administration’s Commercial Building Energy Consumption Survey (CBECS) and tool to translate survey data into simulation inputs, this project aimed to conduct the simulation of the entire dataset in parallel. Before running the simulations, the necessary software was bundled into a container for use on the PNNL supercomputing network. Then, the parallel simulation workflow was designed using GNU Make, a file creation software, and submitted to a supercomputing partition which could run hundreds of simulations simultaneously. The EnergyPlus simulations output hourly electric meter data for each CBECS sample, which represents the electricity consumption of similar commercial buildings across the United States. Analyzing and visualizing the meter data is important to the future of the work, and this project wrote code to make common analysis methods simple, fast, and accessible. Moving forwards, the model will need to be expanded to include data from other sources and its accuracy will need to be improved and eventually validated.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

MCNP Intrinsic Source Constructor (MISC): A User’s Guide

The MCNP Intrinsic Source Constructor (MISC) facilitates the construction of MCNP source definition cards for radioactive materials. Given a material nuclide specification, either weight or atom fractions of those nuclides, and either a weight or atom density of the material, MISC will construct the source spectrum distribution of a specified particle type. MISC also calculates the absolute number of particles emitted per second per unit mass or volume. Furthermore, if decay chain information is available in the data sets selected by the user, the initial isotopes specified by the user can be approximately decayed to the resulting isotopes after a specified amount of time.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Limitations in Advanced Measurement Systems: An Overview for Power Systems

Measurements have been an essential part of managing the electric power system from the beginning. Surprisingly, today’s measurements are not always particularly trustworthy. Countless factors can influence measurement in real-world conditions. In this report, we look at the measurement system as a comprehensive information acquisition system with complicated interdependencies setting the limiting factors and affecting system performance. The first chapter provides an overview of the whole system and introduces the key elements of the limitations checklist. The second part of the document is a component checklist for measurement system limitations that concisely describes effects, common remedies, and underlying factors.

42 ENGINEERING↗

Extended Low Load Boiler Operation to Improve Performance and Economics of an Existing Coal Fired Power Plant (Final Report)

The overall goal is to improve the performance and economics of existing coal fired power plants by extending low load boiler operation to lower loads than is currently achievable. The objective of this program is to develop and validate sensor hardware and analytical algorithms to lower plant operating expenses (OPEX) for the currently operating pulverized coal utility boiler fleet. Coal fired utility boilers are increasingly under grid dispatch pressure. In some cases, the coal fired cost of generation is noncompetitive with respect to natural gas generation and subsidized renewable sources. To remain profitable and remain fully compliant with existing environmental regulations, the installed coal fired fleet must find technologies which allow it to move into a more flexible cyclic load dispatch model. Today the installed coal fired utility fleet must be cost of generation competitive, fully emissions compliant, and responsive to the variability inherent in renewable energy generation sources. In the Phase I of the project, GE Steam Power, Inc. (GE) performed modeling of different operating scenarios for low load operation using an existing full plant dynamic model developed for a 660MW steam power plant. Sensors and analytic algorithms to enable a stable and steady coal supply for low load pulverizer operation were identified and tested at the Pulverizer Development Facility (PDF) at GE’s Clean Energy Center in Bloomfield, Connecticut. Sensors and analytic algorithms to enable stable combustion for low load operation were identified and tested at the 15 MWth Industrial Scale Burner facility (ISBF) at GE’s Clean Energy Center. A concept was developed to test the sensors and control algorithms, down selected after testing, at a full-scale coal fired power plant. A budget estimate was then developed, and the concept was implemented at an existing utility power plant. The specific objectives of the experimental work were to: • Identify and select sensors and analytic algorithms for monitoring coal pulverizer operation at lower loads to provide stable operation and appropriate coal fineness at lower coal throughput; Identify and select sensors and analytic algorithms for a Boiler Flame Stability Monitor to better balance air and fuel at each burner. This enables a reduction in a coal boiler’s safe low load power level while maintaining stable flame characteristics; Develop a concept in Phase I for low load operation of a full-scale power plant and develop a budget estimate for testing and execute the test plan at an existing plant in Phase II; Validate the capability of the extended low load boiler system to extend the minimum load operating point in a safe and reliable manner on an existing full-scale utility boiler. At the completion of this experimental study, GE has developed a set of sensors and analytic algorithms, down selected after testing, that have the potential to enable safe low load operation of a utility boiler. GE has also identified a host site for testing these identified sensors and analytic algorithms. GE has generated a full set of deliverables that provide sufficient information to proceed with the next step of testing at a host site. This includes a potential host site and budget estimate for concept testing at host site. In the Phase II of the project, a series of field tests were completed to validate the extended low load boiler operation, which consisted of detailed engineering, installation, commissioning, and testing the additional sensors and analytics for the coal-fired combustion system on an existing full-scale utility boiler. The optimization work has been supported by the host plant and endorsed by their engineering and operation staff.

01 COAL, LIGNITE, AND PEAT↗

County Land-Use Regulations for Solar Energy Development in Colorado

We present a survey of county-level policies on ground-mounted solar development across Colorado, including both solar-specific ordinances as well as general land-use code that might be applicable in counties without solar-specific policies. This report provides an accessible reference for stakeholders interested in identifying counties with particular regulations or in analyzing the diversity of regulations across Colorado. We defined a set of search criteria to find information on solar definitions and classifications, permitting processes, and use-specific requirements in each of Colorado's 64 counties. With those criteria, we reviewed relevant ordinances, land-use code, and comprehensive and master plans. If any uncertainties were identified, we contacted county officials for clarification. The findings are categorized and mapped to illustrate the distribution of key policies adopted across Colorado's counties on the following topics: solar definitions, solar siting policy documentation, categorization of PV systems for permitting, 1041 permitting, solar on agricultural land, panel height restrictions, fencing requirements, vegetation management, visual impacts, decommissioning plans, and financial assurance for decommissioning. Additionally, we identify and discuss policies that might impact the deployment of agrivoltaics, a dual land use combining both agriculture and solar on the same land, which might not fit neatly in existing zoning definitions and solar-specific regulations.

14 SOLAR ENERGY↗

Workshop Summary: Bridging the Gap Between Atmospheric Science and Grid Integration

The need for dedicated, accurate, expertly curated weather data is increasingly important as the share of variable renewable energy increases on the power system. Projections for futures with very high (50+% annual energy) shares of variable generation require ongoing assessment of data requirements from industry stakeholders in their power system operation and planning contexts. In March 2024, NREL organized a workshop entitled "Bridging the Gap Between Atmospheric Science and Grid Integration Workshop", which brought atmospheric scientists and power system experts together to refine the requirements of atmospheric datasets for grid integration, and to describe a holistic approach to creating new and regularly updated national scale wind datasets for power system planning and operations. The results of this workshop are being used to inform the near-term development and a longer-term strategy for DOE to produce relevant wind resource datasets and inform wider use of wind/solar/load data sets in power system planning. This presentation provides an overview of a preworkshop survey, an assessment of current state of the art of national-scale datasets for wind resource assessment and grid integration, insights on appropriate uses of the WTK-LED, power system perspectives on data needs, as well as recommended next steps as discussed in the workshop and how these steps support longer-term strategies.

17 WIND ENERGY↗

A Reduced-form Cost Model for Prefeasibility Analysis of Hydropower at Non-Powered Dams

This study presents a reduced-form model to support a better understanding of the capacity potential and drivers of costs for hydropower development at U.S. non-powered dams (NPD), which are existing dams that are not currently used for hydropower. With information on nineteen reference sites, a set of reduced-form design and cost equations were estimated to enable rapid assessments of aggregate costs and their components for a large number of NPD sites. The model was then applied to 36,000+ potential U.S. NPD sites using the limited data commonly available. Although the cost estimates span a wide range, there exists a significant amount of U.S. NPD hydropower capacity potential, which are considered cost-competitive in the current market using baseline technologies.

13 HYDRO ENERGY↗