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At least 271 records · Page 15

An intercomparison of nitrogen-containing species in Nimbus 7 LIMS and SAMS data

Odd-nitrogen chemistry and transport are analyzed using a two-dimensional model and Nimbus 7 data. The Nimbus 7 data include: measurements of O3, NO2, HNO3, H2O, and temperature by the LIMS instrument; N2O, CH4, and temperature measurements by the SAMS instrument; and O3 data from the SBUV instrument. The characteristics of the two-dimensional model used in the study, a modified Guthrie et al. (1984) model, are described. NO2 and HNO3 are calculated using the two-dimensional model, and the computed data are compared with the LIMS NO2 and HNO3 measurements. The model uncertainties are computed based on the photochemical equilibrium assumption, and the role of stratospheric dynamics in determining NO2 and HNO3 is discussed. It is observed that there is good correlation between the LIMS and model data in the upper stratosphere; however, the data do not correspond in the lower stratosphere. The effect of nitrogen sources, such as lightning, on the stratospheric odd nitrogen distribution is examined.

Jackman, Charles H.↗

An analysis and intercomparison of VLBI nutation estimates

Nutation estimates from long duration VLBI experiments conducted by the Deep Space Network and reduced at JPL were compared with similar estimates from the IRIS/Polaris data reduced at Harvard. The two series were found to have an rms difference of 1.6 milliarcsec or less, and both exhibited the existence of seasonal errors in the IAU 1980 nutation theory. Most of the observed seasonal discrepancies could be removed by changing the period of the free core resonance to 431.5 solar days. The VLBI data constrain the resonance damping time to be at least one decade, and possibly much longer. Any free core nutation has an amplitude of less than 1 milliarcsec. Crude estimates of the atmospheric forcing of this resonance indicate that meteorological forcing could easily explain the observed free core nutation.

Eubanks, T. M.↗

Intercomparison of polar motion measurements during the MERIT period

Polar motion estimates obtained by satellite laser ranging (SLR) and VLBI are analyzed and compared. The JPL Kalman filter was utilized to smooth the polar motion estimates. Variations in the smoothing residuals for the X and Y components of polar motion for SLR and VLBI are examined. It is observed that the rms differences between the SLR and VLBI estimates for X and Y are about 2-3 marcsec. Power spectra of the differences are studied in order to measure possible periodic systematic errors. The data reveal that the SLR and VLBI polar motion data have a rms difference of about 15-20 marcsec and no significant systematic errors.

Steppe, J. A.↗

An intercomparison technique for measuring thermal attachment cross sections and rate constants in distinct final channels

A new technique is introduced for comparing negative-ion signal rates in which a common ion is produced by dissociative attachment in a series of molecules. Measurements are carried out at electron energies less than 100 MeV and at resolutions of 6-8 MeV (FWHM). The technique is demonstrated by detection of the Cl(-) signal in CFCl3, CCl4, CF2Cl2, 1,1,2-C2Cl3F3, 1,1,1-C2Cl3F3 and C2Cl4. Measurements for 1,1,1-C2Cl3F3 show that there is a significant open channel, other than Cl(-) formation, which accounts for about 60 percent of negative-ion formation in thermal-multiple-collision (swarm) experiments. Channel cross sections and rate constants are given for the process Cl(-)/1,1,1-Cl2Cl3F3, as well as in C2Cl4, for the separate channels Cl(-)/C2Cl4 and C2Cl4(-)/C2Cl4.

Alajajian, S. H.↗

Intercomparison among plasma wake models for plasmaspheric and ionospheric conditions

The angular distributions of ions in the wake of a body moving through a space plasma computed from three different models are compared in order to investigate wake current depletion ratios under conditions simulating the topside ionosphere and plasmasphere. Results demonstrate the importance of taking into account the thermal flux at low Mach numbers and the angular acceptance of ion detectors in making theory-experiment comparisons. For all models considered, gradients in the angular variations of the fluxes are shown to be steeper near the wake-ambient interface than closer to the maximum rarefaction region.

Samir, U.↗

Intercomparison of satellite-derived cloud analyses for the Arctic Ocean in spring and summer

Several methods of deriving Arctic cloud information, primarily from satellite imagery, have been intercompared. The comparisons help in establishing what cloud information is most readily determined in polar regions from satellite data analysis. The analyses for spring-summer conditions show broad agreement, but subjective errors affecting some geographical areas and cloud types are apparent. The results suggest that visible and thermal infrared data may be insufficient for adequate cloud mapping over some Arctic surfaces.

Mcguffie, K.↗

Intercomparison of solar total irradiance data from recent spacecraft measurements

Earth Radiation Budget Experiment solar total irradiance data obtained by the solar monitors of the NOAA 9 and 10 spacecraft are presently compared with those obtained by the Solar Maximum Mission's Active Cavity Irradiance Monitor 1, as well as sounding rockets and the Nimbus 7 Earth Radiation Budget channel 10C. A disparity is noted among total irradiance values obtained in near-simultaneous measurements with absolute pyrheliometers of similar design and operational modes which (1) indicates the uncertainty associated with currently available instruments, and (2) recommends intercalibration of electrically self-calibrating pyrheliometers from spacecraft.

Mecherikunnel, A. T.↗

Intercomparison of synthetic- and real-aperture radar observations of Arctic sea ice during winter MIZEX '87

Active microwave measurements were made of various sea ice forms in March and April 1987 during the Marginal Ice Zone Experiment, at 1, 5, 10, 18, and 35 GHz using a synthetic aperture radar (SAR) and helicopter and ship-based scatterometers. The X-band (9.8 GHz) SAR data were compared to the scatterometer data and it was determined that for 5 GHz and higher frequencies both the SAR and scatterometers can differentiate open water, new ice (5 to 30 cm), first-year ice with rubble (0.60 -1.5 m), and multiyear ice. The analysis further confirmed that the C-band (5 GHz) SAR's flying on ESA ERS-1 and Radarsat will differentiate the mentioned ice types.

Schuchmann, R. A.↗

Intercomparison of satellite laser ranging accuracy of three NASA stations through collocation

The accuracy of laser ranging has been evaluated through comparisons of simultaneous LAGEOS satellite-borne laser ranging data received at three NASA tracking stations in support of the Crustal Dynamics project. Single-shot satellite ranging precisions of 8, 14, and 30 mm have been demonstrated at the three ground stations, with a stability better than 3 mm. The data-processing software used were POLYQUICK and GEODYN; a consistent degree of agreement between the three stations of less than 1 cm is obtained.

Varghese, T.↗

An intercomparison of results from ferrous sulphate and photolytic converter techniques for measurements of NO(x) made during the NASA GTE/CITE 1 aircraft program

Two techniques designed for measurements of NO(x (NO + NO2) were intercompared during aircraft flights made in the spring of 1984 in the middle free troposphere over the eastern Pacific Ocean and southwestern U.S. One NO chemiluminescence instrument was equipped with a ferrous sulphate converter, another with a photolytic converter. The ferrous sulphate-equipped instrument was apparently much less specific for NO2. It registered levels about three times larger than the photolytic converter and gave NO2/NO ratios that were much larger than photochemical calculations would indicate as reasonable. Additionally, the results imply that active NO(x) was only 10-20 percent of the total odd nitrogen in the middle free troposphere.

Ridley, B. A.↗

Intercomparison of NO column measurements during MAP/GLOBUS 1985

Simultaneous NO column measurements made in France in September, 1985, using several techniques, are compared with one another. The observed NO distributions vary significantly from day to day. It is shown that NO measurements using IR or UV absorption are self-consistent and show good agreement with predictions from a one-dimensional photochemical model. In situ chemiluminescent measurements produced NO columns which were systematically higher than those predicted.

Mckenzie, R. L.↗

An intercomparison of mesospheric ozone profiles determined by the UVSP and SAGE II solar occultation experiments

A comparison is made of individual UVSP and SAGE II mesospheric ozone profiles between 50 and 70 km altitude as determined by the solar occultation technique. The generally good agreement between the two data sets below about 57 km leads to the conclusion that they may be considered as complementary, thus extending the effective altitude range of both. Comparison of the long-term ozone trend at 55.5 km shows a systematic difference of a few percent between the two measurements.

Aikin, A. C.↗

An intercomparison of measurement systems for vapor and particulate phase concentrations of formic and acetic acids

During June 1986, eight systems for measuring vapor phase and four for measuring particulate phase concentrations of formic acid (HCOOH) and acetic acid (CH3COOH) were intercompared in central Virginia. HCOOH and CH3COOH vapors were sampled by condensate, mist, Chromosorb 103 GC resin, NaOH-coated annular denuders, NaOH-impregnated quartz filters, K2CO3 and NaCO3-impregnated cellulose filters, and Nylasorb membranes. Atmospheric aerosol was collected on Teflon and Nuclepore filters using both hi-vol and lo-vol systems to measure particulate phase concentrations. Performances of the mist chamber and K2CO3-impregnated filter techniques were evaluated using zero air and ambient air spiked with HCOOH(g) and CH3COOH(g), and formaldehyde from permeation sources. The advantages and drawbacks of these methods are reported and discussed.

Keene, William C.↗

Intercomparison and interpretation of satellite-derived directional albedos over deserts

Issues related to the dependence of planetary albedo upon solar zenith angle are studied using Nimbus-7, GOES, and Meteosat data over deserts. Geographical variations of the planetary albedo are isolated from the albedo's solar zenith angle dependence. An atmospheric solar radiation model is coupled with desert surface bidirectional reflectance measurements to test the consistency of satellite-derived directional planetary albedos. Consideration is given to the use of narrowband versus broadband instruments, the impact of desert aerosols on the directional planetary albedo, and potential differences in the directional planetary albedo associated with different types of deserts. The results show that the directional planetary albedo is dominated by the directional surface albedo, although surface brightness influences the atmospheric limb brightening and limb darkening processes.

Cess, Robert D.↗

Two-Dimensional Intercomparison of Stratospheric Models

A detailed record is provided for the examination of fundamental differences in photochemistry and transport among atmospheric models. The results of 16 different modeling groups are presented for several model experiments.

Jackman, Charles H.↗

Report of the 1988 2-D Intercomparison Workshop, chapter 3

Several factors contribute to the errors encountered. With the exception of the line-by-line model, all of the models employ simplifying assumptions that place fundamental limits on their accuracy and range of validity. For example, all 2-D modeling groups use the diffusivity factor approximation. This approximation produces little error in tropospheric H2O and CO2 cooling rates, but can produce significant errors in CO2 and O3 cooling rates at the stratopause. All models suffer from fundamental uncertainties in shapes and strengths of spectral lines. Thermal flux algorithms being used in 2-D tracer tranport models produce cooling rates that differ by as much as 40 percent for the same input model atmosphere. Disagreements of this magnitude are important since the thermal cooling rates must be subtracted from the almost-equal solar heating rates to derive the net radiative heating rates and the 2-D model diabatic circulation. For much of the annual cycle, the net radiative heating rates are comparable in magnitude to the cooling rate differences described. Many of the models underestimate the cooling rates in the middle and lower stratosphere. The consequences of these errors for the net heating rates and the diabatic circulation will depend on their meridional structure, which was not tested here. Other models underestimate the cooling near 1 mbar. Suchs errors pose potential problems for future interactive ozone assessment studies, since they could produce artificially-high temperatures and increased O3 destruction at these levels. These concerns suggest that a great deal of work is needed to improve the performance of thermal cooling rate algorithms used in the 2-D tracer transport models.

Jackman, Charles H.↗

An intercomparison of intraseasonal variability in general circulation models and observations

Low frequency oscillations appearing in three GCM seasonal cycle integrations are compared with the analyses of the European Center for Medium Range Weather Forecasting (ECMWF). All three models have the same resolution: 4 deg latitude by 5 deg longitude, with 9 levels. The dominant phase speeds and the differential vertical structure of the heating profiles in the GCMs are in general agreement with current theory involving the positive feedback between latent heating and moist static stability. All three GCMs fail to capture the detailed evolution in the different stages of the development and decay of the oscillation. The results suggest that an improvement in the boundary layer moisture processes may be crucial for a better simulation of the oscillation.

Park, Chung-Kyu↗