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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

A Fast, Accurate and Sensitive GC-FID Method for the Analyses of Glycols in Water and Urine

Glycols, specifically ethylene glycol and 1,2-propanediol, are some of the major organic compounds found in the humidity condensate samples collected on the International Space Station. The current analytical method for glycols is a GC/MS method with direct sample injection. This method is simple and fast, but it is not very sensitive. Reporting limits for ethylene glycol and 1,2-propanediol are only 1 ppm. A much more sensitive GC/FID method was developed, in which glycols were derivatized with benzoyl chloride for 10 minutes before being extracted with hexane. Using 1,3-propanediol as an internal standard, the detection limits for the GC/FID method was determined to be 50 ppb and the analysis only takes 7 minutes. Data from the GC/MS and the new GC/FID methods shows excellent agreement with each other. Factors affecting the sensitivity, including sample volume, NaOH concentration and volume, volume of benzoyl chloride, reaction time and temperature, were investigated. Interferences during derivatization and possible method to reduce interferences were also investigated.

Kuo, C. Mike↗

Diffusivities of Redox-Sensitive Elements in Basalt vs. Oxygen Fugacity Determined by LA-ICP-MS

Several diffusion experiments were conducted in a piston cylinder device across a range of oxygen fugacities (FMQ-3 FMQ-1.2, FMQ+6) at 1 GPa and 1300 C. This was done to explore the effects of oxygen fugacity (fO2) on diffusivity of redox sensitive trace elements. This allows investigation of how these elements diffuse across the fO2 range encountered in different reservoirs on planets and moons in our solar system. The University of Rochester LA-ICP-MS system was used for analysis of samples. Analyses were conducted using an Agilent 7900 quadrupole mass spectrometer connected to a Photon Machines 193 nm G2 laser ablation (LA) system equipped with a HelEx 2-volume sample chamber. Spots used were 35 micrometers circles spaced at 65 micrometers intervals. Laser fluence was 7.81 J/cm^2 with a rep rate of 10 Hz. The iolite software package was used to reduce data collected from laser ablation analysis of experiments with Si-29 used as the internal standard isotope. Iolite's global fit module was used to simultaneously fit elements' diffusivities in each experiment while keeping the Matano interface constant. Elements analysed include V, Nb, W, Mo, La, Ce, Pr, Sm, Eu, Gd, Ta, and W. Figures

Szumila, Ian↗

9- by 15-Foot Low-Speed Wind Tunnel Acoustic Free Field Evaluation; Part 1: Qualification Report Summary and Part 2: Anechoic Environment Characterization Field Test Report

This report describes test results from an assessment of the acoustically treated 9x15 Foot Low Speed Wind Tunnel at the NASA Glenn Research Center in Cleveland, Ohio in July of 2016. The tests were conducted in accordance with the recently adopted international standard ISO 26101-2012 on Qualification of Free Field Test Environments. This method involves moving a microphone relative to a source and comparing the sound pressure level versus distance measurements with theoretical inverse square law spreading.

propulsion↗

Seasonal Impact of Regional Outdoor Biomass Burning on Air Pollution in Three Indian Cities: Delhi, Bengaluru, and Pune

Air pollution in many of India's cities exceeds national and international standards, and effective pollution control strategies require knowledge of the sources that contribute to air pollution and their spatiotemporal variability. In this study, we examine the influence of a single pollution source, outdoor biomass burning, on particulate matter (PM) concentrations, surface visibility, and aerosol optical depth (AOD) from 2007 to 2013 in three of the most populous Indian cities. We define the upwind regions, or "airsheds," for the cities by using atmospheric back trajectories from the HYSPLIT model. Using satellite fire radiative power (FRP) observations as a measure of fire activity, we target pre-monsoon and post-monsoon fires upwind of the Delhi National Capital Region and pre-monsoon fires surrounding Bengaluru and Pune. We find varying contributions of outdoor fires to different air quality metrics. For the post-monsoon burning season, we find that a subset of local meteorological variables (air temperature, humidity, sea level pressure, wind speed and direction) and FRP as the only pollution source explained 39% of variance in Delhi station PM(sub 10) anomalies, 77% in visibility, and 30% in satellite AOD; additionally, per unit increase in FRP within the daily airshed (1000 MW), PM(sub 10) increases by 16.34 micrograms per cubic meter, visibility decreases by 0.097 km, and satellite AOD increases by 0.07. In contrast, for the pre-monsoon burning season, we find less significant contributions from FRP to air quality in all three cities. Further, we attribute 99% of FRP from post-monsoon outdoor fires within Delhi's average airshed to agricultural burning. Our work suggests that although outdoor fires are not the dominant air pollution source in India throughout the year, post-monsoon fires contribute substantially to regional air pollution and high levels of population exposure around Delhi. During 3-day blocks of extreme PM(sub 2.5) in the 2013 post-monsoon burning season, which coincided with statistically significant high fire activity, concentrations in Delhi averaged 304 micrograms per cubic meter, or more than 1000% above the 24-h PM(sub 2.5) guideline (25 micrograms per cubic meter) of the World Health Organization. These results suggest that providing viable alternatives to agricultural residue burning could help improve post-monsoon air quality for a growing population of 63 million (39% in urban areas) within Delhi's airshed.

Air quality; Outdoor fires; Crop residue burning; ↗

Effect of Control Mode and Load Rate on Fracture Toughness of Brittle Ceramics

The effects of control mode and rate on the fracture toughness of ceramics were measured by using chevron-notched flexure specimen in accordance with ASTM C1421. The use of stroke control gave consistent results with about 2% variation in measured fracture toughness for a very wide range of rates (0.005 to 0.5 mm/min). Use of strain or CMOD control gave an approximately 5% variation over a very wide range of rates, with the measurements being a function of rate. However, the effect was eliminated by use of dry nitrogen, implying a stress corrosion effect rather than a stability effect. With the use of nitrogen for strain control, fracture toughness values were within about 1% over a wide range of rates (1 to 80 micro-epsilon/sec.). CMOD or strain control did allow stable crack extension well past maximum load, and thus is preferred for energy calculations. The effort is being used to confirm recommendations in ASTM International standard C1421 on fracture toughness measurement.

control mode↗

Effect of Control Mode and Test Rate on Fracture Toughness of Advanced Ceramics

The effects of control mode and rate on the fracture toughness of ceramics were measured by using chevron-notched flexure specimen in accordance with ASTM C1421. The use of stroke control gave consistent results with about 2% variation in measured fracture toughness for a very wide range of rates (0.005 to 0.5 mm/min). Use of strain or CMOD control gave ~5% variation over a very wide range of rates, with the measurements being a function of rate. However, the effect was eliminated by use of dry nitrogen, implying a stress corrosion effect rather than a stability effect. With the use of nitrogen for strain control, fracture toughness values were within about 1% over a wide range of rates (1 to 80 /s). CMOD or strain control did allow stable crack extension well past maximum load, and thus is preferred for energy calculations. The effort is being used to confirm recommendations in ASTM International standard C1421 on fracture toughness measurement.

fracture toughness↗

Qualifying Bulk Metallic Glass Gear Materials for Spacecraft Applications

NASA is evaluating bulk metallic glass (BMG) gears for extreme environment (cryogenic) applications; e.g., Europa Lander. The main purpose of this report is to recommend a quality assurance (QA) protocol for the production of consistent and reliable gear castings. Currently, there are two, separate manufacturers involved; Materion Corporation produces re-melt stock and Visser Precision Cast, Inc. produces BMG castings. Division of the existing alloy specifications document into material supplier-specific documents is proposed. Until a composition-based specification is established, processability- and performance-based methodologies may be an option during manufacturing development. It is recommended that each of the documents has a distinct focus; the processing behavior of crystalline feedstock, and the mechanical behavior of amorphous castings. The report addresses the “gray area” in QA testing between these materials suppliers by outlining an equitable division of responsibilities. The use of a number of dedicated reference dies to produce witness materials for physical and mechanical property evaluation is strongly recommended. Allocation of QA tests between screen testing of gear castings, and formal testing of witness materials, including cryogenic properties, is also proposed. The most effective suite of tests for both physical and mechanical property determination are down-selected from available national and international standards. The contents of this report create a solid basis for selection of QA tests, thereby setting the stage for negotiations between the materials suppliers and the customer.This technical paper:a) provides recommendations to advance materials specifications document JPL D-56223,Rev. A from “draft” to “preliminary” status;b) proposes division of the current document into two supplier-specific documents;c) separates testing methods by “ingots/castings” and “witness materials”;d) classifies test methodology based on “processability” and “performance”;e) assembles candidate ASTM specifications for “screen testing” and “formal testing”;f) identifies standard tests compatible with evaluation of BMG flexspline gears;g) suggests division of responsibilities for processability and performance testing; andh) addresses the QA “gray area” between production of ingots and castings.The report recommends that:a) processability- and performance-based QA methods might be used in lieu ofcompositional specifications during manufacturing development only;b) reference dies be designed for “acceptance” and “qualification” castings;c) witness materials provide physical and mechanical property data;d) formal testing be conducted at ambient and cryogenic temperatures; ande) processing/properties be correlated with compositional variations.

Hales, Stephen J.↗

Differential Adaptive Stress Testing of Airborne Collision Avoidance Systems

The next-generation Airborne Collision Avoidance System (ACAS X) is currently being developed and tested to replace the Traffic Alert and Collision Avoidance System (TCAS) as the next international standard for collision avoidance. To validate the safety of the system, stress testing in simulation is one of several approaches for analyzing near mid-air collisions (NMACs). Understanding how NMACs can occur is important for characterizing risk and informingdevelopment of the system. Recently, adaptive stress testing (AST) has been proposed as a way to find the most likely path to a failure event. The simulation-based approach accelerates search by formulating stress testing as a sequential decision process then optimizing it using reinforcement learning. The approach has been successfully applied to stress test a prototype of ACAS Xin various simulated aircraft encounters. In some applications, we are not as interestedin the system's absolute performance as its performance relative to another system. Such situations arise, for example, during regression testing or when deciding whether a new system should replace an existing system. In our collision avoidance application, we are interested in finding cases where ACAS X fails but TCAS succeeds in resolving a conflict. Existing approaches do not provide an efficient means to perform this type of analysis. This paper extends the AST approach to differential analysis by searching two simulators simultaneously and maximizing the difference between their outcomes. We call this approach differential adaptive stress testing (DAST). We apply DAST to compare a prototype of ACAS X against TCAS and show examples of encounters found by the algorithm.

Lee, Ritchie↗

Deep Space Network: the Next 50 Years

In 2014, NASA’s Deep Space Network (DSN) celebrated its 50th year of enabling exploration of the Moon, Solar System planets, and beyond. During those 50 years, the DSN has grown along with the associated spacecraft flight systems, providing some 13 orders of magnitude communications systems improvement. It has also contributed to many of the world’s most important scientific discoveries and provided substantial technological spinoffs that have become part of everyday life on Earth. Studies of the next 25 years indicate that deep space missions will need an order of magnitude increased communications performance per decade - and this is likely to continue beyond that time. As exhibited by this meeting, another major change happening right now is the emergence of a standardized international community for tracking deep space missions. The future definitely involves increased international cooperation. This paper explains the near term plans already underway for the DSN. We also consider the plans and possibilities for deep space optical communications. Finally, we will discuss opportunities for international participation in the next 50 years of deep space exploration.

Deutsch, Leslie J.↗

SPICE Tools Supporting Planetary Remote Sensing

NASA's "SPICE" ancillary information system has gradually become the de facto international standard for providing scientists the fundamental observation geometry needed to perform photogrammetry, map making and other kinds of planetary science data analysis. SPICE provides position and orientation ephemerides of both the robotic spacecraft and the target body; target body size and shape data; instrument mounting alignment and field-of-view geometry; reference frame specifications; and underlying time system conversions.

Observation geometry↗

NASA-STD-7012 Leak Test Requirements: Potential Reference for ASNT Nondestructive Testing Handbook for Leak Testing

Developed in 2018-2019, NASA-STD-7012 Leak Test Requirements, has been drafted based mostly on the NASA technical requirement documents applicable to the International Space Station (ISS) hardware and payloads that were developed over the years taking into consideration many known references such as Leakage Testing Handbook prepared by General Electric for the Jet Propulsion Laboratory, the ASTM International standards for leak testing, and last, but not least, the ASNT Nondestructive Testing Handbook for Leak Testing. Thus, NASA-STD-7012 has a reference to the above-mentioned handbook in the leak test method/technique descriptions. However, there are some technical details that are described differently in NASA standard and ASNT Handbook. Those technical details are mostly related to the classification of the leak test methods/techniques, and also to tracer gas to working fluid (gas or liquid) leakage rate conversion methodology, and to some definitions used in the text of both NASA standard and ASNT Handbook. Those differences are going to be briefly described in this paper to let ASNT leak test experts decide if they want to refer to NASA-STD-7012 while working on the next edition of the ASNT Handbook, Volume 2 for Leak Testing.

Lvovsky, Oleg M.↗

Deep Space Network: The Next 50 Years

In 2014, NASA’s Deep Space Network (DSN) celebrated its 50th year of enabling exploration of the Moon, Solar System planets, and beyond. During those 50 years, the DSN has grown along with the associated spacecraft flight systems, providing some 13 orders of magnitude communications systems improvement. It has also contributed to many of the world’s most important scientific discoveries and provided substantial technological spinoffs that have become part of everyday life on Earth. Studies of the next 25 years indicate that deep space missions will need an order of magnitude increased communications performance per decade – and this is likely to continue beyond that time. As exhibited by this meeting, another major change happening right now is the emergence of a standardized international community for tracking deep space missions. The future definitely involves increased inter-national cooperation. This paper explains the near term plans already underway for the DSN. We also consider the plans and possibilities for deep space optical communications. Finally, we will discuss opportunities for international participation in the next 50 years of deep space exploration.

Deutsch, Leslie J.↗

3. Climbing to the Top of Mount Fuji: Uniting Theory and Observations of Oxygen Triple Isotope Systematics

The near-simultaneous discovery of both minor isotopes of oxygen in 1929 was a watershed moment for modern science, to say nothing of its impacts on isotope geochemistry. At the time, oxygen was the international standard for atomic weight, as it had been for over twenty-five years. However, chemists and physicists had grown fond of different definitions: physicists used the weight of the 16O atom, while chemists used half the weight of atmospheric oxygen (O2) to define the precise weight of 16 atomic mass units. While they usually avoided direct conflicts, these contrasting definitions found an unexpected impasse in the near-infrared absorption spectrum of atmospheric oxygen: it contained a series of faint lines that could not be explained by any known atmospheric constituents.

Laurence Y. Yeung↗

9- by 15-Foot Low-Speed Wind Tunnel Acoustic Free-Field Evaluation After Renovation Part 1: Test Report Summary Part 2: Anechoic Environment Characterization: Field Test Report

This report describes test results from an assessment of the acoustically treated 9- by 15-Foot Low Speed Wind Tunnel at the NASA Glenn Research Center in Cleveland, Ohio in June of 2019. The tests were conducted in accordance with the recently adopted international standard ISO 26101-2012 on Qualification of Free Field Test Environments. This method involves moving a microphone relative to a source and comparing the sound pressure level versus distance measurements with theoretical inverse square law spreading.

wind tunnel↗

One Step Plasma Passivation and Precision Cleaning

Over the past several years, Kennedy Space Center (KSC) researchers developed two solvent-free techniques for precision cleaning of ground support equipment (GSE) that possess low commodity requirements and produce small or no waste streams. During testing of low-pressure air plasma as one of these cleaning techniques, physical changes in the surface of stainless steel test pieces were observed; cursory testing revealed that the test part had developed a thick oxide layer on the surface compared to untreated parts. This result indicated that the plasma process might not only serve as a green technology for precision cleaning of parts, but it may also passivate the surface at the same time. Current methodology in use at KSC’s Components Refurbishment & Chemical Analysis (CRCA) Facility for passivation of corrosion-resistant steels for aerospace applications follows an SAE International Standard, AMS2700, where parts are submerged in either a nitric acid or nitric acid/sodium dichromate bath at predetermined temperatures and contact times. These baths require constant testing to ensure effective treatment, use corrosive and carcinogenic chemicals, and produce hazardous waste. The passivation bath is one of the multiple steps employed at the facility, while cleaning with multiple environmentally-unfriendly solvents comprise several more steps before parts are recertified to a specific cleanliness level in their clean room. Based on the behavior of the stainless steel surface during cleaning optimization studies, it was believed that the plasma technology could be extended to passivation, combining what is currently many steps into a single, solvent- and waste-free system.

Paul Hintze↗

NASA's Current Optical Communications Efforts

NASA continues to make significant investments in optical communications technology for near Earth and deep space applications. Optical communications will enable new science and exploration missions by providing high data rates and better navigation over long distances. Small low mass terminals, even at low data rates, is also extremelty beneficial to NASA. In 2021, NASA will launch the Laser Communications Relay Demonstration (LCRD) on a Department of Defense Space Test Program satellite. LCRD consists of two optical terminals in geosynchronous (GEO) orbit and two ground stations, and it is a joint project between NASA’s Goddard Space Flight Center (GSFC), the Jet Propulsion Laboratory, California Institute of Technology (JPL), and the Massachusetts Institute of Technology Lincoln Laboratory (MIT/LL). Also in 2021, GSFC and MIT/LL will fly the TeraByte InfraRed Delivery (TBIRD) 200 Gbps Cubesat Demo in Low Earth Orbit. In 2022, JPL will launch Psyche to a unique metal asteroid orbiting the Sun between Mars and Jupiter. Psyche will carry the Deep Space Optical Communications (DSOC) payload. In 2023, NASA will do a lunar flyby with the first crewed mission of the Orion spacecraft and it will carry the MIT/LL developed Optical to Orion (O2O) payload. In addition to these flight demonstrations of optical communications, NASA is also working with civil space agencies around the world to develop international standards for optical communications via the Interagency Operations Advisory Group (IOAG) and the Consultative Committee for Space Data Systems (CCSDS).

Bernard L Edwards↗

Spacecraft data and relay management using delay tolerant networking

NASA’s demonstration of the successful transmission of relay data through the orbiting Mars Odyssey, Mars Global Surveyor, and Mars Express by the Mars Exploration Rovers has shown not only the benefit of using a relay satellite for multiple landed assets in a deep space environment but also the benefit of international standards for such an architecture. As NASA begins the quest defined in the Vision for Exploration with robotic and manned missions to the Moon, continues its study of Mars, and is joined in these endeavors by countries world-wide, landed assets transmitting data through relay satellites will be crucial for completing mission objectives. However, this method of data delivery will result in increased complexity in routing and prioritization of data transmission as the number of missions increases. Also, there is currently no standard method among organizations conducting such missions to return these data sets to Earth given a complex environment. One possibility for establishing such a standard is for mission designers to deploy protocols which fall under the umbrella of Delay Tolerant Networking (DTN). These developing standards include the Bundle Protocol (BP) which provides a standard, secure, store and forward mechanism designed for high latency and asymmetric communication links and the Licklider Transmission Protocol (LTP) which is used to provide a reliable deep space link transmission service.

Torgerson, J. Leigh↗

The Evolution of the CCSDS Orbit Data Messages

The Consultative Committee for Space Data Systems (CCSDS) Orbit Data Messages (ODM) is undoubtedly the most successful and widely infused international standard developed by the CCSDS Navigation Working Group (NavWG). In 2004, the first version of the ODM was published after a development period of several years; before this, there was no CCSDS or ISO standard for the representation of a spacecraft trajectory. This paper will describe in detail the evolution of the CCSDS ODM through its several versions past, present, and future; its infusion into spacecraft operations in many if not most of the Earth's major space agencies; and some of the growing number of applications in which it is being utilized.

Oltrogge, Daniel L.↗