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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

Design of An Improved Miniature Ion Neutral Mass Spectrometer for NASA Applications

The ion optics of NASA's Ion Neutral Mass Spectrometer (INMS) sensor was simulated with three dimensional models of the open source, the quadrupole deflector, the exit lens system and the quadrupole mass analyzer to design more compact models with lower weight. Comparison of calculated transmission with experimental results shows good agreement. Transmission analyses with varying geometrical parameters and voltages throw light on possible ways of reducing the size of the sensor. Trajectories of ions of mass 1-99 amu were simulated to analyze and optimize transmission. Analysis of open source transmission with varying angle of attack shows that the angular acceptance can be considerably increased by programming the voltages on the ion trap/ collimator. Analysis of transmission sensitivity to voltages and misalignments of the quadrupole deflector rods indicate that increased transmission is possible with a geometrically asymmetrical deflector and a deflector can be designed with much lower sensitivities of transmission. Bringing the disks closer together can decrease the size of the quadrupole deflector and also increase transmission. The exit lens system can be redesigned to be smaller by eliminating at least one electrode entirely without loss of transmission. Ceramic materials were investigated to find suitable candidates for use in the construction of lighter weight mass spectrometer. A high-sensitivity, high-resolution portable gas chromatograph mass spectrometer with a mass range of 2-700 amu has been built and will be commercialized in Phase 3.

Swaminathan, Viji K.↗
NASA NTRS1997

X-Ray Spectroscopic Laboratory Experiments in Support of the X-Ray Astronomy Program

Our program is to perform a series of laboratory investigations designed to resolved significant atomic physics uncertainties that limit the interpretation of cosmic X-ray spectra. Specific goals include a quantitative characterization of Fe L-shell spectra; the development of new techniques to simulate Maxwellian plasmas using an Electron Beam Ion Trap (EBIT); and the measurement of dielectronic recombination rates for photoionized gas. New atomic calculations have also been carried out in parallel with the laboratory investigations.

Kahn, Steven M.↗
NASA NTRS1960

Ionospheric Measurements Using Environmental Sampling Techniques

Two rockets were flown to peak altitudes of 220 km in September 1959 to test various methods planned for future measurements of ionization parameters in the ionosphere, exosphere, and interplanetary plasma. The experiments used techniques which sample the ambient environment in the immediate vicinity of the research vehicle. Direct methods were chosen since indirect propagation techniques do not provide the temperatures of charged particles, are insensitive to ion densities, and cannot measure local electron densities under all conditions. Very encouraging results have been obtained from a preliminary analysis of data provided by one of the two flights. A new rf probe technique was successfully used to determine the electron density profile. This was indicated by its agreement with the results of a companion cw propagation experiment, particularly when the probe data were corrected for the effects of the ion sheath which surrounds the vehicle. The characteristics of this sheath were determined directly in flight by an electric field meter which provided the sheath field, and by a Langmuir probe which measured the total potential across the sheath. The electron temperatures deduced from the Langmuir probe data are greater than the neutral gas temperatures previously measured for the same location and season, but these measurements possibly were taken under different atmospheric conditions. Ion densities were calculated from the ion trap data for several altitudes ranging from 130 to 210 km and were found to be within 20 percent of the measured electron densities.

Bourdeau, R. E.↗
NASA NTRS1999

On Photospheric Fluorescence and the Nature of the 17.62 Angstrom Feature in Solar X-ray Spectra

The identification of the emission line feature at 17.62 Angstroms in solar x-ray spectra is re-examined. Using a Monte Carlo technique, we compute a realistic theoretical upper limit to the observed Fe L-alpha photospheric fluorescent line strength caused by irradiation from an overlying corona. These calculations demonstrate that the photospheric Fe L-alpha characteristic line is much too weak to account for the observed 17.62 Angstrom line flux. Instead, we identify this line with the configuration interaction 2s2p3p2P-2s2p6 2S transition in Fe XVIII seen in Electron Beam Ion Trap spectra and predicted in earlier theoretical work on the Fe XVIII x-ray spectrum.

Drake, Jeremy J.↗
NASA NTRS2000

Laboratory Astrophysics Using a Spare XRS Microcalorimeter

The XRS instrument on Astro-E is a fully self-contained microcalorimeter x-ray instrument capable of acquiring optimally filtering, and characterizing events for 32 independent pixels. With the launch of the Astro-E spacecraft, a full flight spare detector system has been integrated into a laboratory cryostat for use on the electron beam ion trap (EBIT) at Lawrence Livermore National Laboratory. The detector system contains a microcalorimeter array with 32 instrumented pixels heat sunk to 60 mK using an adiabatic demagnetization refrio,erator. The instrument has a composite resolution of 8eV at 1 keV and 12eV at 6 keV with a minimum of 95% quantum efficiency. This will allow high spectral resolution, broadband observations of collisionally excited plasmas which are produced in the EBIT experiment. Unique to our instrument are exceptionally well characterized 1000 Angstrom thick aluminum on polyimide infrared blocking filters. The detailed transmission function including the edc,e fine structure of these filters has been measured in our laboratory using an erect field grating spectrometer. This will allow the instrument to perform the first broadband absolute flux measurements with the EBIT instrument. The instrument performance as well as the results of preliminary measurements will be discussed. Work performed under the auspices of the U.S. D.o.E. by Lawrence Livermore National Laboratory under contract W-7405-ENG-48 and was supported by the NASA High Energy Astrophysics Supporting Research and Technology Program.

Audley, M. Damian↗
NASA NTRS2000

Laboratory Data for X-Ray Astronomy

Laboratory facilities have made great strides in producing large sets of reliable data for X-ray astronomy, which include ionization and recombination cross sections needed for charge balance calculations as well as the atomic data needed for interpreting X-ray line formation. We discuss data from the new generation sources and pay special attention to the LLNL electron beam ion trap experiment, which is unique in its ability to provide direct laboratory access to spectral data under precisely controlled conditions that simulate those found in many astrophysical plasmas. Examples of spectral data obtained in the 1-160 A wavelength range are given illustrating the type of laboratory X-ray data produced in support of such missions as Chandra, X-Ray Multi-Mirror telescope (XMM), Advanced Satellite for Cosmology and Astrophysics (ASCA) and Extreme Ultraviolet Explorer Satellite (EUVE).

Beiersdorfer, P.↗
NASA NTRS2001

Toward a Micro Gas Chromatograph/Mass Spectrometer (GC/MS) System

Miniature mass filters (e.g., quadrupoles, ion traps) have been the subject of several miniaturization efforts. A project is currently in progress at JPL to develop a miniaturized Gas Chromatograph/Mass Spectrometer (GC/MS) system, incorporating and/or developing miniature system components including turbomolecular pumps, scroll type roughing pump, quadrupole mass filter, gas chromatograph, precision power supply and other electronic components. The preponderance of the system elements will be fabricated using microelectromechanical systems (MEMS) techniques. The quadrupole mass filter will be fabricated using an X-ray lithography technique producing high precision, 5x5 arrays of quadrupoles with pole lengths of about 3 mm and a total volume of 27 cubic mm. The miniature scroll pump will also be fabricated using X-ray lithography producing arrays of scroll stages about 3 mm in diameter. The target detection range for the mass spectrometer is 1 to 300 atomic mass units (AMU) with are solution of 0.5 AMU. This resolution will allow isotopic characterization for geochronology, atmospheric studies and other science efforts dependant on the understanding of isotope ratios of chemical species. This paper will discuss the design approach, the current state-of-the art regarding the system components and the progress toward development of key elements. The full system is anticipated to be small enough in mass, volume and power consumption to allow in situ chemical analysis on highly miniaturized science craft for geochronology, atmospheric characterization and detection of life experiments applicable to outer planet roadmap missions.

Wiberg, D. V.↗
NASA NTRS2001

Charge Exchange Contribution to the Decay of the Ring Current, Measured by Energetic Neutral Atoms (ENAs)

In this paper we calculate the contribution of charge exchange to the decay of the ring current. Past works have suggested that charge exchange of ring current protons is primarily responsible for the decay of the ring current during the late recovery phase, but there is still much debate about the fast decay of the early recovery phase. We use energetic neutral atom (ENA) measurements from Polar to calculate the total ENA energy escape. To get the total ENA escape we apply a forward modeling technique, and to estimate the total ring current energy escape we use the Dessler-Parker-Sckopke relationship. We find that during the late recovery phase of the March 10, 1998 storm ENAs with energies greater than 17.5 keV can account for 75% of the estimated energy loss from the ring current. During the fast recovery the measured ENAs can only account for a small portion of the total energy loss. We also find that the lifetime of the trapped ions is significantly shorter during the fast recovery phase than during the late recovery phase, suggesting that different processes are operating during the two phases.

Jorgensen, A. M.↗
NASA NTRS2001

Thermal Desorption/GCMS Analysis of Astrobiologically Relevant Organic Materials

Several macromolecular organic materials, both biologically-derived (type II kerogen and humic acid) and abiotic in origin (Murchison insoluble organic material, cyanide polymer, and Titan tholin) were subjected to thermal desorption using a Chromatoprobe attachment on a Varian Saturn 2000 GCMS system. Each sample was heated sequentially at 100, 200, and 300 C to release volatile components. The evolved compounds were then separated on a Supelco EC-1 dimethylsilica GC column and detected by the Saturn 2000 ion trap mass spectrometer. The various types of macromolecular organic material subjected to thermal desorption produced distinctly different GCMS chromatograms at each temperature, containing fractions of both low and high chromatographic mobility. The relative amounts of detectable volatiles released at each temperature also differed, with type II kerogen and cyanide polymer containing the highest percentage of low-temperature components. In all the samples, the highest yield of released compounds occurred at 300 C. Only cyanide polymer evolved a homologous hydrocarbon series, suggesting that it is the only material among those examined that contains a truly polymeric structure. Pyrolysis/gas chromatography/mass spectrometry has been used extensively for analysis of terrestrial organic macromolecular materials, and was also part of the instrument package on the Viking landers. Thorough analysis by pyrolysis usually employs temperatures of 500 C or higher, which for in situ analyses can be problematic given spacecraft power and materials constraints. This study demonstrates that heating of organic materials of astrobiological relevance to temperatures as low as 200-300 C for short periods releases volatile components that can be analyzed by gas chromatography and mass spectrometry. Even in the absence of full pyrolysis, useful chemical information on samples can be obtained, and materials from different biological and abiological sources can be distinguished. The research described in this paper was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration.

McDonald, Gene D.↗
NASA NTRS2001

Ground-Based Investigations with the Cryogenic Hydrogen Maser

The room temperature hydrogen maser is an active atomic oscillator used as a high-frequency-stability local oscillator for radio astronomy, metrology, and spacecraft navigation, and in tests of fundamental physics. The cryogenic hydrogen maser (CHM) operates at 0.5 K, employing superfluid helium-coated walls to store the masing hydrogen atoms. We are investigating whether the CHM may provide better frequency stability than the room temperature hydrogen maser: one to three orders of magnitude improvement may be possible because of greatly reduced thermal noise and larger signal power. Exceptional frequency stability will be required for spacecraft tracking in future deep-space missions, for space-based tests of relativity and gravitation, and for local (i.e., flywheel) oscillators used with absolute frequency standards such as laser-cooled atomic fountains and linear ion traps. These new devices are passive high-resolution frequency discriminators. Alone, they cannot function as superior atomic clocks; their effective operation depends on being integrated with an active local oscillator with excellent short term stability - such as that possible with the CHM.

Walsworth, Ronald L.↗
NASA NTRS2002

Evaluation of Small Mass Spectrometer Systems

This work is aimed at understanding the aspects of designing a miniature mass spectrometer (MS) system. A multitude of commercial and government sectors, such as the military, environmental agencies and industrial manufacturers of semiconductors, refrigerants, and petroleum products, would find a small, portable, rugged and reliable MS system beneficial. Several types of small MS systems are evaluated and discussed, including linear quadrupole, quadrupole ion trap, time of flight and sector. The performance of each system in terms of accuracy, precision, limits of detection, response time, recovery time, scan rate, volume and weight is assessed. A performance scale is setup to rank each systems and an overall performance score is given to each system. All experiments involved the analysis of hydrogen, helium, oxygen and argon in a nitrogen background with the concentrations of the components of interest ranging from 0-5000 part-per-million (ppm). The relative accuracies of the systems vary from < 1% to approx. 40% with an average below 10%. Relative precisions varied from 1% to 20%, with an average below 5%. The detection limits had a large distribution, ranging from 0.2 to 170 ppm. The systems had a diverse response time ranging from 4 s to 210 s as did the recovery time with a 6 s to 210 s distribution. Most instruments had scan times near, 1 s, however one instrument exceeded 13 s. System weights varied from 9 to 52 kg and sizes from 15 x 10(exp 3)cu cm to 110 x 10(exp 3) cu cm.

Arkin, C. Richard↗
NASA NTRS2002

Evaluation of Small Mass Spectrometer Systems

Various mass analyzer systems were evaluated. Several systems show promise, including the Stanford Research Systems RGA-100, Inficon XPR-2, the University of Florida's Ion Trap, and the Compact Double Focus Mass Spectrometer. Areas that need improvement are the response time, recovery time, system volume, and system weight. Future work will investigate techniques to improve systems and will evaluate engineering challenges.

Arkin, C. Richard↗
NASA NTRS2003

Microcalorimeters for High Resolution X-Ray Spectroscopy of Laboratory and Astrophysical Plasmas

The proposal has three major objectives. The first focuses on advanced neutron-transmutation-doped (NTD)-based microcalorimeter development. Our goal is to develop an array of microcalorimeters with sub- 5 eV energy resolution that can operate with pile-up-free throughput of at least 100 Hz per pixel. The second objective is to establish our microcalorimeter as an essential x-ray diagnostic for laboratory astrophysics studies. We propose to develop a dedicated microcalorimeter spectrometer for the EBIT (electron beam ion trap). This instrument will incorporate the latest detector and cryogenic technology that we have available. The third objective is to investigate innovative ideas related to possible flight opportunities. These include compact, long lived cryo-systems, ultra-low temperature cold stages, low mass and low power electronics, and novel assemblies of thin windows with high x-ray transmission.

Silver, E.↗
NASA NTRS2002

Emission Line Spectra in the Soft X-ray Region 20 - 75 Angstroms

As part of a project to complete a comprehensive catalogue of astrophysically relevant emission lines in support of new-generation X-ray observatories using the Lawrence Livermore electron beam ion traps EBIT-I and EDIT-II, emission lines of argon and sulfur in the soft X-ray and extreme ultraviolet region were studied. Observations of Ar IX through Ar XVI and S VII through S XIV between 20 and 75 Angstrom are presented to illustrate our work.

Lepson, J. K.↗
NASA NTRS2002

Measurement of Metastable Lifetimes of Highly-Charged Ions

The present work is part of a series of measurements of metastable lifetimes of highly-charged ions (HCIs) which contribute to optical absorption, emission and energy balance in the Interstellar Medium (ISM), stellar atmospheres, etc. Measurements were carried out using the 14-GHz electron cyclotron resonance ion source (ECRIS) at the JPL HCI facility. The ECR provides useful currents of charge states such as C(sup(1-6)+), Mg(sup(1-6)+) and Fe(sup(1-17)+). In this work the HCI beam is focused into a Kingdon electrostatic ion trap for measuring lifetimes via optical decays.

Smith, Steven J.↗
NASA NTRS2002

Laboratory Study of the Diagnostic Utility of the 3C/3D Line Ratio in Fe XVII

Fe XVII X-ray emission is present in a multitude of sources, such as the corona of the Sun, Capella, and Procyon. Two of the strongest lines observed in these spectra are the resonance and intercombination lines located at 15.01 and 15.26 A, respectively. As part of the laboratory astrophysics program at the electron beam ion traps EBIT-I & EBIT-II located at the Lawrence Livermore National Laboratory we have measured this line ratio for the case where the relative abundance of Fe XVI to Fe XVII is approx. 1. Our results show that an Fe XVI innershell satellite line coincides with the intercombination line and can significantly reduce the relative intensity, R, of the resonance to intercombination line. The fact that the apparent relative intensity of the resonance and intercombination line in Fe XVII is sensitive to the strength of an Fe XVI innershell satellite, and therefore, tho relative abundance of Fe XVI to Fe XVII, makes the line ratio a diagnostic of temperature, and explains the anomalously low ratios observed in the solar and stellar coronae.

Brown, G. V.↗
NASA NTRS2001

Mass spectrometry in the U.S. space program: past, present, and future

Recent years have witnessed significant progress on the miniaturization of mass spectrometers for a variety of field applications. This article describes the development and application of mass spectrometry (MS) instrumentation to support of goals of the U.S. space program. Its main focus is on the two most common space-related applications of MS: studying the composition of planetary atmospheres and monitoring air quality on manned space missions. Both sets of applications present special requirements in terms of analytical performance (sensitivity, selectivity, speed, etc.), logistical considerations (space, weight, and power requirements), and deployment in perhaps the harshest of all possible environments (space). The MS instruments deployed on the Pioneer Venus and Mars Viking Lander missions are reviewed for the purposes of illustrating the unique features of the sample introduction systems, mass analyzers, and vacuum systems, and for presenting their specifications which are impressive even by today's standards. The various approaches for monitoring volatile organic compounds (VOCs) in cabin atmospheres are also reviewed. In the past, ground-based GC/MS instruments have been used to identify and quantify VOCs in archival samples collected during the Mercury, Apollo, Skylab, Space Shuttle, and Mir missions. Some of the data from the more recent missions are provided to illustrate the composition data obtained and to underscore the need for instrumentation to perform such monitoring in situ. Lastly, the development of two emerging technologies, Direct Sampling Ion Trap Mass Spectrometry (DSITMS) and GC/Ion Mobility Spectrometry (GC/IMS), will be discussed to illustrate their potential utility for future missions. c 2001 American Society for Mass Spectrometry.

NASA Discipline Environmental Health↗
NASA NTRS1988

Space Station atmospheric monitoring systems

A technology assessment study on atmospheric monitoring systems was performed by Battelle Columbus Division for the National Aeronautics and Space Administration's John F. Kennedy Space Center under Contract No. NAS 10-11033. In this assessment, the objective was to identify, analyze, and recommend systems to sample and measure Space Station atmospheric contaminants and identify where additional research and technology advancements were required. To achieve this objective, it was necessary to define atmospheric monitoring requirements and to assess the state of the art and advanced technology and systems for technical and operational compatibility with monitoring goals. Three technical tasks were defined to support these needs: Definition of Monitoring Requirements, Assessment of Sampling and Analytical Technology, and Technology Screening and Recommendations. Based on the analysis, the principal candidates recommended for development at the Space Station's initial operational capability were: (1) long-path Fourier transform infrared for rapid detection of high-risk contamination incidences, and (2) gas chromatography/mass spectrometry utilizing mass selective detection (or ion-trap) technologies for detailed monitoring of extended crew exposure to low level (ppbv) contamination. The development of a gas chromatography/mass spectrometry/matrix isolation-Fourier transform infrared system was recommended as part of the long range program of upgrading Space Station trace-contaminant monitoring needs.

Air Pollution, Indoor/analysis↗