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NASA NTRS2012

Real Time Space Weather Support for Chandra X-Ray Observatory Operations

NASA launched the Chandra X-ray Observatory in July 1999. Soon after first light in August 1999, however, degradation in the energy resolution and charge transfer efficiency of the Advanced CCD Imaging Spectrometer (ACIS) x-ray detectors was observed. The source of the degradation was quickly identified as radiation damage in the charge-transfer channel of the front-illuminated CCDs, by weakly penetrating ( soft , 100 500 keV) protons as Chandra passed through the Earth s radiation belts and ring currents. As soft protons were not considered a risk to spacecraft health before launch, the only on-board radiation monitoring system is the Electron, Proton, and Helium Instrument (EPHIN) which was included on Chandra with the primary purpose of monitoring energetic solar particle events. Further damage to the ACIS detector has been successfully mitigated through a combination of careful mission planning, autonomous on-board radiation protection, and manual intervention based upon real-time monitoring of the soft-proton environment. The AE-8 and AP-8 trapped radiation models and Chandra Radiation Models are used to schedule science operations in regions of low proton flux. EPHIN has been used as the primary autonomous in-situ radiation trigger; but, it is not sensitive to the soft protons that damage the front-illuminated CCDs. Monitoring of near-real-time space weather data sources provides critical information on the proton environment outside the Earth s magnetosphere due to solar proton events and other phenomena. The operations team uses data from the Geostationary Operational Environmental Satellites (GOES) to provide near-real-time monitoring of the proton environment; however, these data do not give a representative measure of the soft-proton (< 1 MeV) flux in Chandra s high elliptical orbit. The only source of relevant measurements of sub-MeV protons is the Electron, Proton, and Alpha Monitor (EPAM) aboard the Advanced Composition Explorer (ACE) satellite at L1, with real-time data provided by NOAA s Space Weather Prediction Center. This presentation describes the radiation mitigation strategies to minimize the proton damage in the ACIS CCD detectors and the importance of real-time data sources that are used to protect the ACIS detector system from space weather events.

O'Dell, Stephen L.↗

NASA NTRS1974

Optical measurement of interplanetary particulates from Pioneer 10

The spatial concentration and size distribution for particulates measured in situ by the asteroid/meteoroid detector on Pioneer 10 between 1.0 and 3.5 AU are presented. The size distribution includes particles of radii from about 35 microns to 10 cm. Extrapolation from the smallest particle sizes measured shows good agreement with the results of the particle penetration detector carried on the same spacecraft. Within the uncertainties of this experiment, a single size distribution seems appropriate for all but the smallest particles measured. There is evidence for the existence of a planetary sweeping effect in the vicinity of the Mars orbit. As calculated from the particle spatial distribution, the zodiacal light brightness is found to vary approximately as the inverse square of solar distance out to about 2.25 AU and then decrease more rapidly. The absolute value of the zodiacal light brightness as calculated from the particle spatial concentration is found to be too high by a factor of 10.

Soberman, R. K.↗

NASA NTRSDate not supplied

Low Cost Micro-Spectrometer for Resource Mapping on Mars

Scientific measurements within craters and along steep embankments on Mars pose extreme challenges since astronauts and rovers cannot access them. However, these areas offer the potential for thegreatest scientific return. NASA Langley Research Center (LaRC) has invented a deployable wireless micro-spectrometer [1-13] capable of accessing thosechallenging areas and, using telemetry, send measurements to a receiver safely outside those extreme environments. A prototype of the micro-spectrometer concept was fabricated and successfullytested for measurement of dopamine as a neural probe [14]. The bullet-sized micro-spectrometer concept can be designed for deployment by an astronaut, a rover, an aerial drone, or a lander, and the measurements broadcasted back to a receiver [13,15,16]. This device can also be installed on rovertires, under the astronaut’s boots, or a cane stick. The bullet-like consumable micro-spectrometer can penetrate soil to spectrally identify the components ofthe soil, such as water or minerals. The signals of the soil assay data are transmitted to a mother station through a telemetry system. The LaRC developed micro-spectrometer bullet consists of micro-spectrometer optics with an all imbedded burst-mode LED UV light source, a super-capacitor with control electronics, and telemetry electronics. Prototypes have been fabricated to demonstrate spectral assay of soil components. Further maturation of this technology would be necessary for demonstration on Mars. Future work includes a potential R&D program that includes other NASA Centers and industry partners interested in developing a business case that requires knowledge of the locations of extraterrestrial ice, for instance.

micro-spectrometer, mineral assay, resource mappin↗

DOE OSTI2022

The Structural Origin of Chiroptical Properties in Perovskite Nanocrystals with Chiral Organic Ligands

Abstract The authors investigate how chiral ligands attached to perovskite nanocrystal (PNC) surfaces structurally distort the perovskite lattice. Chiral electro‐optical properties of the resulting PNCs are demonstrated through the fabrication of a circularly polarized light (CPL) detector with a discrimination of up to 14% between left‐ and right‐handed CPL. Both experimental and electronic‐structure‐based simulations are combined to provide insights into the interactions (both structural and electronic) between chiral organic ligands and PNCs. The major finding is a centro‐asymmetric distortion of the surface lattice that penetrates up to five atomic unit cells deep into the PNCs, which is the likely cause of the chiral‐optical properties. Spin‐polarized transport through chiral‐PNCs results from the chiral‐induced spin selectivity effect and amplifies the discrimination between left and right‐handed CPL as is experimentally demonstrated in the detectors.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Studies of surface adsorbate electronic structure and femtochemistry at the fundamental length and time scales. Final report

The electronic structure and ultrafast (10-15 s-femtosecond timescale) electron dynamics were investigated for clean and atom/molecule covered metal surfaces. The studies were performed by scanning tunneling microscopy (STM) to measure the structure of adsorbed atoms and molecules on metal surfaces, and to investigate their electronic properties. The electronic structure of the observed molecular networks was calculated by electronic structure theory in collaboration with Prof. Jin Zhao, who is a long-time collaborator, a Professor at the University of Science and Technology of China, and holds an Adjunct Professorship at the University of Pittsburgh. We also investigated the electronic properties of C60 molecules when they are templated by corrugated black phosphorous surfaces. We found unexpected charge delocalization that is enabled by the templating. This research was done in collaboration with Professor Min Feng at the Wuhan University, and who also holds an Adjunct Professorship at the University of Pittsburgh. Moreover, the electronic structure and electron dynamics in metal surfaces were investigated by time-resolved photoemission electron spectroscopy. The focus of ultrafast spectroscopy has been on the plasmonic response of silver surfaces. One direction has been to develop multidimensional (energy, momentum, and time) photoelectron spectroscopy of the coherent response of solid surfaces. This method was applied to study the collective electron excitations known generally as plasmons, which screen optical fields from penetration into metals. Although this collective response has been known for more than 60 years and is used extensively to deposit optical energy into metals, how this happens is poorly known. We investigated the plasmonic response of silver at the point where the dielectric response passes through zero and bulk plasmon is excited by light. We discovered that the plasmon excitation decays by exciting electrons from the Fermi level of a metal, which is contrary to what is believed in the plasmonic science community. This research has been performed in collaboration with Dr. Marcel Reutzel, who was a postdoctoral fellow working on this research at the University of Pittsburgh, and now has a faculty position at the University of Göttingen in Germany. Prof. Branko Gumhalter from the Institute of Physics in Zagreb contributed on the theory of plasmonic decay processes. Furthermore, we investigated the Floquet engineering of electronic bands in metals leading to multiphoton photoemission and above threshold photoemission. Finally, we demonstrated that it is possible to change the electronic structure of metals by application of optical fields. Our studies indicated that this happens on subfemtosecond time scale and could potentially be used in ultrafast information processing and quantum computation. Related document information

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS1975

Hydrodynamic effects in the atmosphere of variable stars

Numerical models of variable stars are established, using a nonlinear radiative transfer coupled hydrodynamics code. The variable Eddington method of radiative transfer is used. Comparisons are for models of W Virginis, beta Doradus, and eta Aquilae. From these models it appears that shocks are formed in the atmospheres of classical Cepheids as well as W Virginis stars. In classical Cepheids, with periods from 7 to 10 days, the bumps occurring in the light and velocity curves appear as the result of a compression wave that reflects from the star's center. At the head of the outward going compression wave, shocks form in the atmosphere. Comparisons between the hydrodynamic motions in W Virginis and classical Cepheids are made. The strong shocks in W Virginis do not penetrate into the interior as do the compression waves formed in classical Cepheids. The shocks formed in W Virginis stars cause emission lines, while in classical Cepheids the shocks are weaker.

Davis, C. G., Jr.↗

DOE OSTI2020

Experimental demonstration and performance evaluation of a complex fenestration system for daylighting and thermal harvesting

Two significant design strategies for mitigating building energy consumption are daylight redirection and solar energy harvesting. Effective daylighting implementation enhances the amount of useful natural light within a space and offsets the need for electric lighting. Solar energy harvesting systems can mitigate energy costs from mechanical systems by managing incoming thermal loads or capturing solar energy that can be used to supplement thermal systems in the building. While there are many available façade-based technologies that can perform daylighting or solar thermal energy harvesting, there remains a limitation in available systems that can perform both of them simultaneously. This paper, describes the design and experimental demonstration of a Liquid Filled Prismatic Louver (LFPL) system, which combines both energy-saving strategies. The LFPL system was installed in a south-facing room in New York City and evaluated for indoor daylight penetration and potential for thermal energy harvesting. Daylight redirection is achieved through the prismatic louver geometry and proper orientation, whereas thermal energy harvesting is achieved through IR absorption from the liquid (e.g., water) within the prisms. Daylighting performance was evaluated by illuminance measurements at key locations within the space, whereas thermal harvesting performance was evaluated through temperature measurements and thermal imaging analysis. We show that the LFPL system, with all prismatic elements oriented at the same angle, achieve a 2-fold and 8-fold enhancement in daylight redirection to the ceiling, for prism orientations of 10° and 20°, respectively. We also demonstrate the system’s capability to adjust to specific lighting needs, within the space, through the dynamic individual orientation of prismatic elements; thus, achieving a concentrated ceiling illuminance enhancement of ~100 times and ~200 times at 2.5 and 4.3 m away from the window sill, providing workplane illuminance enhancement of 6 and 2 times more than in the case of the control room with regular windows. Furthermore, we illustrate a reduction of potential heating loads at locations close to the window from the combination of infrared absorption in the water volume and the redirection of the incoming solar radiation, leading to a reduction of the workplane temperature by an average of 7–10 °C.

14 SOLAR ENERGY↗

DOE OSTI2020

Tuning the Intrinsic Anisotropy with Disorder in the Ca K Fe 4 As 4 Superconductor

In this paper, we report on the anisotropy of the London penetration depth of CaKFe 4 As 4 , discussing how it relates to its electronic structure and how it modifies under introduction of disorder, both chemically induced (by Ni substitution) and irradiation induced (by 3.5-MeV protons). Indeed, CaKFe 4 As 4 is particularly suitable for the study of fundamental superconducting properties due to its stoichiometric composition, exhibiting clean-limit behavior in the pristine samples and having a fairly high critical temperature, T c ≈35 K. The London penetration depth λ L is measured with a microwave-coplanar-resonator technique that allows us to deconvolve the anisotropic contributions λ L,ab and λ L,c and obtain the anisotropy parameter γλ=λ L,c /λ L,ab . The γλ(T) found for the undoped pristine sample is in good agreement with previous literature and is here compared to ab initio density-functional-theory and Eliashberg calculations. The dependence of γλ(T) on both chemical and irradiation-induced disorder is discussed to highlight which method is more suitable to decrease the direction dependence of the electromagnetic properties while maintaining a high critical temperature. Lastly, the relevance of an intrinsic anisotropy such as γλ on application-related anisotropic parameters (critical current, pinning) is discussed in light of the recent employment of CaKFe 4 As 4 in the production of wires.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS1977

Apollo 16 white boulder consortium samples 67455 and 67475 - Petrologic investigation

The paper describes Apollo 16 samples 67455 and 67475 from a white boulder which seems to be an ejecta block that represents a major lithology of the ejecta stratigraphic section penetrated by the North Ray cratering event. The characteristics of 67455, a polymict white feldspathic impact ejecta breccia, might possibly indicate that this and other samples from near the North Ray Crater rim come from a different source area or at least a different part of the same source area than do other Apollo 16 light matrix breccias. Sample 67475 is an impact melt probably produced by the same event that produced 67455. The transport of this assemblage and the relation of the white boulder to ejecta from the Nectaris event are considered.

Minkin, J. A.↗

NASA NTRS2004

Subsurface Sampling and Sensing Using Burrowing Moles

Finding evidence for life on Mars will likely require accessing the subsurface since the Martian surface is both hostile to life and to preservation of biosignatures due to the cold dry conditions, the strong W environment, and the presence of strong oxidants. Systems are needed to probe beneath the sun and oxidant baked surface of Mars and return samples to the surface for analysis or to bring the instrument sensing underground. Recognizing this need, the European Space Agency incorporated a small subsurface penetrometer or Mole onto the Beagle 2 Mars lander. Had the 2003 landing been successful, the Mole would have collected samples from 1-1.5 m depth and delivered them to an organic analysis instrument on the surface. The de- vice called the Planetary Underground Tool (PLUTO), also measured soil mechanical and thermophysical properties. Constrained by the small mass and volume allowance of the Beagle lander, the PLUTO mole was a slender cylinder only 2 cm diameter and 28 cm long equipped with a small sampling device designed to collect samples and bring them to the surface for analysis by other instrument. The mass of the entire system including deployment mechanism and tether was 1/2 kg. sensor package underground to make in situ measurements. The Mars Underground Mole (MUM) is a larger Mole based on the PLUTO design but incorporating light collection optics that interface to a fiber optic cable in the tether that transmits light to a combined stimulated emission Raman Spectrometer and Short Wave Infrared (SWIR) reflectance Spectrometer with sensitivity from 0.7 to 2.5 micrometers. This instrument is called the Dual Spectral Sensor and uses a Digital Array Scanning Interferometer as the sensor technology, a type of fourier transform interferometer that uses fixed element prisms and thus is highly rugged compared to a Michaelson interferometer. Due to the size limitations of an on-Mole instrument compartment, and the availability of a tether, the sensor head, light sources, and control electronics for the instrument are on the surface. The DSS sensor is capable of sensing a wide range of minerals relevant to Mars Astrobiology objectives including hydrated minerals, clays, carbonates, sulfates, and ice. Additionally, Raman spectroscopy is effective for detecting organics. The MUM is designed to achieve a maximum depth of penetration of 5 m in Mars regolith and can be repeatedly deployed and retrieved. The ability to perform repeated sampling, combined with the low mass and power requirements, means that Moles could be incorporated into a rover mission as well as used on a stationary platform. The Mole mechanism is a pointed slender cylinder that advances into soil by way of an internal sliding hammer mechanism. Part of the energy released by the spring-loaded hammer with each shock is transferred to the Mole casing and from there to the soil, resulting in penetration by displacing and compressing the surrounding soil. A backwards-directed impulse as a re- action to each forward shock is transferred via a suppressor mass against a second weaker spring allowing forward motion without requiring reactive forces provided by the lander. The Mole tip can be opened to collect soil samples. The Mole casing is tethered to a supporting mechanism that supplies power. Components supporting the Mole on the surface include a launch tube, tether reel and winch for pulling in tether, in addition to the tether itself.

Stoker, C. R.↗

DOE OSTI2021

Temperature-dependent x-ray fluorescent response from thermographic phosphors under x-ray excitation

Phosphor thermometry has been successfully applied within several challenging environments. Typically, the thermographic phosphors are excited by an ultraviolet light source, and the temperature-dependent spectral or temporal response is measured. However, this is challenging or impossible in optically thick environments. In addition, emission from other sources (e.g., a flame) may interfere with the optical phosphor emission. Furthermore, a temperature dependent x-ray excitation/emission could alleviate these issues as x-rays could penetrate obscurants with no interference from flame luminosity. In addition, x-ray emission could allow for thermometry within solids while simultaneously x-ray imaging the structural evolution. In this study, select thermographic phosphors were excited via x-ray radiation, and their x-ray emission characteristics were measured at various temperatures. Several of the phosphors showed varying levels of temperature dependence with the strongest sensitivity occurring for YAG:Dy and ZnGa 2 O 4 :Mn. This approach opens a path for less intrusive temperature measurements, particularly in optically opaque multiphase and solid phase combustion environments.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2020

Comparison of Generation of Higher-Order Neutron Scattering Cross Sections

The generation of high-order neutron scattering cross sections consistent with high-fidelity simulations remains an area of active research. Popular options include generating cross sections from continuous energy Monte Carlo calculations or generating cross sections from a deterministic neutron transport calculation with high-fidelity tabulated cross sections. Both options present challenges. Monte Carlo simulations can naturally process continuous energy cross section data and allow for the general description of anisotropic neutron scattering given a scattering law. However, Monte Carlo simulations are inherently related to particle weighting and it has been suggested that this may be unacceptable for generating high-order neutron scattering cross sections. Deterministic neutron transport calculations can easily calculate high-order moments of the flux to appropriately calculate higher-order neutron scattering cross sections but are generally limited by discretization of space, energy, and angle. In this work, the trade-offs between generation of high-order neutron scattering cross sections via Monte Carlo and deterministic neutron transport methods are investigated. The methods implemented in the Monte Carlo computer program Serpent and the deterministic fast reactor neutron cross section generator MC2-3 are compared. Cross sections resulting from these methods are used in Rattlesnake, a deterministic neutron transport code developed by Idaho National Laboratory (INL), and results are compared to a reference continuous energy Monte Carlo calculation. Whereas previous work investigating the effects of anisotropic neutron scattering has focused on light water reactor (LWR) simulations, this work focuses on high-order neutron scattering cross sections as they relate to fast reactor simulations. To investigate the consequences of the Serpent and MC2-3 methodologies, a test problem is developed. The test problem is a one-dimensional geometry with fast reactor materials designed to demonstrate deep penetration and exacerbate the effects of high-order neutron scattering. Based on the results of the deep penetration test problem, it is concluded that P3 neutron scattering cross sections are sufficient to describe anisotropic scattering in fast reactor materials. Any neutron scattering of order higher than P3 offers negligible change in the eigenvalue of the test problem. Additionally, it is determined that the methodology as implemented in Serpent is applicable for generating high-order neutron scattering cross sections through at least P3 in fast reactor materials.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

DOE OSTI2022

Wavelength-selective specularly reflecting photovoltaic module and manufacture thereof

A photovoltaic module comprises a plurality of photovoltaic cells, and a polymeric film positioned on an incident light side of the plurality of photovoltaic cells, wherein the polymeric film transmits a range of wavelengths of the incident light spectrum and specularly reflects wavelengths outside of the range. An encapsulant layer is in contact with the polymeric film. The polymeric film may have a first surface area larger than a second surface area of the layer of photovoltaic cells. The polymeric film may have one or more through-holes so that encapsulant can penetrate through the through-holes at elevated temperature during lamination thereby bonding to a front glass of the photovoltaic module.

14 SOLAR ENERGY↗

DOE OSTI2021

Absorbing the Sun: Operational Practices and Balancing Reserves in Florida's Municipal Utilities

The Florida Reliability Coordinating Council (FRCC) power system is comprised of multiple balancing authorities ranging in size from Gainesville Regional Utilities (GRU) with a 2019 summer net firm demand of 429 MW to Florida Power & Light with a 2019 summer net firm demand of 22,510 MW; and including cooperative, municipal, and investor-owned utilities. As all of these balancing authorities are and have plants to continue installing significant quantities of utility-scale solar photovoltaics, one relevant question is how much operating reserves they will need to hold as solar penetrations increase. While there are estimates of how regulating and flexibility reserve requirements change with solar penetration, the literature almost exclusively focuses on large balancing authorities with sub-hourly dispatch. In this work we analyze how reserve needs change not only with solar photovoltaic penetration, but also balancing authority size and operational practices. We find that, measured as a fraction of load, smaller balancing authorities with less frequent load and solar forecasts and less frequent dispatch need more reserves. Such utilities' reserve needs also increase more with increasing solar deployment as compared to larger or more frequently dispatched balancing authorities. These impacts are most acute for GRU. We find that moving from day-ahead to hour-ahead load and solar forecasting and system dispatch could enable GRU to incorporate 32% solar generation with median reserves at 20% instead of 60% of load; and that median reserve needs could drop further to about 10% of load if Florida's municipal utilities formed a reserve sharing group and moved to sub-hourly dispatch.

14 SOLAR ENERGY↗

NASA NTRSDate not supplied

Micro-Spectrometer for Resource Mapping in Extreme Environments

Measurements and analyses of resources within permanently shadowed craters and along steep embankments on extraterrestrial surfaces pose extreme challenges since astronauts and rovers cannot access them. However, these areas offer the potential for the greatest scientific returns. Researchers at the NASA Langley Research Center (LaRC) invented a deployable wireless micro-spectrometer that can access those challenging areas and deliver telemetry data to a receiver safely outside those extreme environments. The micro-spectrometers are designed for deployment by an astronaut, a rover, or a lander flying overhead. This device can also be installed on rover tires, under the astronaut’s shoes, or on a cane stick. The bullet-like, expendable micro-spectrometer can penetrate into soil to spectrally identify the components of soil, such as water, He-3, or other minerals. The signals from the soil assay data are transmitted to a mother station through a telemetry system. This LaRC developed micro-spectrometer bullet consists of micro-spectrometer optics with an all-imbedded, burst-mode, light-emitting-diode ultraviolet (LED UV) light source, a super-capacitor with control electronics, and telemetry electronics. Prototypes have been fabricated to demonstrate a spectral assay of soil components. Further maturation of this technology would be necessary for demonstrations on the Moon.

micro-spectrometer↗

DOE OSTI2021

Absorbing the Sun: Operational Practices and Balancing Reserves in Florida's Municipal Utilities

balancing authority↗

NASA NTRS1976

Surficial geology of Mars: A study in support of a penetrator mission to Mars

Physiographic and surficial cover information were combined into unified surficial geology maps (30 quadrangles and 1 synoptic map). The surface of Mars is heterogeneous and is modified by wind, water, volcanism, tectonism, mass wasting and other processes. Surficial mapping identifies areas modified by these processes on a regional basis. Viking I mission results indicate that, at least in the landing site area, the surficial mapping based on Mariner data is fairly accurate. This area was mapped as a lightly cratered plain with thin or discontinuous eolian sediment. Analysis of lander images indicates that this interpretation is very close to actual surface conditions. These initial results do not imply that all surficial units are mapped correctly, but they do increase confidence in estimates based on photogeologic interpretations of orbital pictures.

Spudis, P.↗

DOE OSTI2023

High-Transmission Neutron Optical Devices Utilizing Micro-Machined Structures

Neutrons are a powerful probe in material science with unique penetrating abilities. A major challenge stems from the fact that neutron optical devices are limited to refractive indices on the order of n≈1±10−5. By exploiting advances in precision manufacturing, we designed and constructed micro-meter period triangular grating with a high-aspect ratio of 14.3. The manufacturing quality is demonstrated with white-light interferometric data and microscope imaging. Neutron-scattering experiment results are presented, showing agreement with refraction modelling. The capabilities of neutron Fresnel prisms and lenses based on this design are contrasted with existing neutron focusing techniques, and the path separation of a prism-based neutron interferometer is estimated.

Kapahi, Connor (ORCID:0000000160516859)↗