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At least 271 records · Page 15

Mineral precipitation in north slope aufeis

The Canning and Shaviovik river aufeis fields were studied on the ground and with aircraft data. Powdered calcium carbonate (CaCO3) patches, a few cm in thickness, were found in discrete locations on both aufeis fields. This is indicative of chemical weathering of limestone bedrock which is known to underlie much of the eastern arctic coastal plain of Alaska. Spring or river water which remains unfrozen throughout much of the winter carries CaCO3 in solution; as the river ice freezes more deeply the CaCO3 in solution is forced upwards through cracks in the river ice. Upon exposure to the cold air CaCO3 is excluded as the water freezes, forming successive layers during aufeis growth. In the melt season CaCO3, slush/powder accumulates in patches on top of the ice as the aufeis melts downward.

Hall, D. K.↗

Direct observation of interface instability during crystal growth

The general aim of this investigation was to study interface stability and solute segregation phenomena during crystallization of a model system. Emphasis was to be placed on direct observational studies partly because this offered the possibility at a later stage of performing related experiments under substantially convection-free conditions in the space shuttle. The major achievements described in this report are: (1) the development of a new model system for fundamental studies of crystal growth from the melt and the measurement of a range of material parameters necessary for comparison of experiment with theory. (2) The introduction of a new method of measuring segregation coefficient using absorption of a laser beam by the liquid phase. (3) The comparison of segregation in crystals grown by gradient freezing and by pulling from the melt. (4) The introduction into the theory of solute segregation of an interface field term and comparison with experiment. (5) The introduction of the interface field term into the theories of constitutional supercooling and morphological stability and assessment of its importance.

Tiller, W. A.↗

Crystal Growth Research in Space

The objectives of this work are to develop growth techniques and theory leading to improved bulk growth of semiconductor single crystals. Ground based experiments will be complemented by experiments carried out in the low-g environment provided by the space shuttle. Analytical studies and laboratory investigations are being conducted to better define the causes of crystalline defects and inhomogeneities. The compound semiconductor lead-tin-telluride is being used as the modeling material. Theoretical techniques are being developed to predict the thermal and solutal fields which are present during bulk growth from a melt. Techniques for measuring the thermophysical properties of semiconductors at high temperatures have been developed. During the past year electrochemical etching techniques have been developed for delineation of inhomogeneous regions in crystals. Thermal diffusivity measurements have been completed for the solid and liquid phases of PbTe and PbSnTe. Preliminary results have been obtained on the effects on crystal morphology of gravity, interface shape and interaction between the melt and the container.

Crouch, R. K.↗

Coupled morphological and convective instabilities in a microgravity environment

The role of convection during crystal growth from the melt is discussed in terms of dimensionless groups of material parameters and control variables. The limitations of such analyses and of models in which the crystal-melt interface is treated as a rigid boundary are reviewed. The interaction of thermosolutal convective instabilities with morphological instabilities is discussed for unidirectional solidification, emphasizing suppression of convective instabilities in a microgravity environment and/or a static magnetic field.

Sekerka, R. F.↗

Noncontact temperature measurement: Requirements and applications for metals and alloys research

Temperature measurement is an essential capability for almost all areas of metals and alloys research. In the microgravity environment many of the science priorities that have been identified for metals and alloys also require noncontact temperature measurement capability. For example, in order to exploit the full potential of containerless processing, it is critical to have available a suitable noncontact temperature measurement system. This system is needed to track continuously the thermal history, including melt undercooling and rapid recalescence, of relatively small metal spheres during free-fall motion in drop tube systems. During containerless processing with levitation-based equipment, accurate noncontact temperature measurement is required to monitor one or more quasi-static samples with sufficient spatial and thermal resolution to follow the progress of solidification fronts originating in undercooled melts. In crystal growth, thermal migration, coarsening and other experiments high resolution thermal maps would be a valuable asset in the understanding and modeling of solidification processes, fluid flows and microstructure development. The science and applications requirements place several constraints on the spatial resolution, response time and accuracy of suitable instrumentation.

Perepezko, J. H.↗

Melt infiltration of silicon carbide compacts. II - Evaluation of solidification microstructures

Microstructural aspects of alloy solidification within the interstices of porous compacts of platelet-shaped single crystals of alpha-SiC, when the latter are infiltrated with a hot metal under pressure, have been described. Microstructural evidence is presented of selective reorientation of platelets and nonhomogeneous solute distribution under shear of pressurized melt, of constrained growth of primary solid within finite width zones, and of the modulation of coring due to microsegregation as a result of variations in the pore size of compacts.

Asthana, Rajiv↗

Process modelling for materials preparation experiments

The main goals of the research under this grant consist of the development of mathematical tools and measurement techniques for transport properties necessary for high fidelity modelling of crystal growth from the melt and solution. Of the tasks described in detail in the original proposal, two remain to be worked on: development of a spectral code for moving boundary problems, and development of an expedient diffusivity measurement technique for concentrated and supersaturated solutions. We have focused on developing a code to solve for interface shape, heat and species transport during directional solidification. The work involved the computation of heat, mass and momentum transfer during Bridgman-Stockbarger solidification of compound semiconductors. Domain decomposition techniques and preconditioning methods were used in conjunction with Chebyshev spectral methods to accelerate convergence while retaining the high-order spectral accuracy. During the report period we have further improved our experimental setup. These improvements include: temperature control of the measurement cell to 0.1 C between 10 and 60 C; enclosure of the optical measurement path outside the ZYGO interferometer in a metal housing that is temperature controlled to the same temperature setting as the measurement cell; simultaneous dispensing and partial removal of the lower concentration (lighter) solution above the higher concentration (heavier) solution through independently motor-driven syringes; three-fold increase in data resolution by orientation of the interferometer with respect to diffusion direction; and increase of the optical path length in the solution cell to 12 mm.

Rosenberger, Franz↗

An examination of anticipated g-jitter on Space Station and its effects on materials processes

This study is concerned with the effects of g-jitter, the residual acceleration aboard spacecraft, on selected classes of materials processes. In particular, the anticipated acceleration environment aboard Space Station Freedom (SSF) and its potential effects are analyzed, but the topic is covered with a sufficient level of generality as to apply to other processes and to other vehicles as well. Some of the key findings of this study include: The present acceleration specifications for SSF are inadequate to assure a quality level low-g environment. The local g vector orientation is an extremely sensitive parameter for certain key processes, but can not be controlled to within the desired tolerance. Therefore, less emphasis should be placed upon achieving a tight control of SSF attitude, but more emphasis should be focused on reducing the overall level of the g-jitter magnitude. Melt-based crystal growth may not be successfully processed in the relatively noisy environment of a large inhabited space structure. Growth from vapor or from solution appears more favorable. A smaller space structure and/or a free flyer can provide better alternatives in terms of g-jitter considerations. A high priority (including budgetary) should be given to coordinated efforts among researchers, SSF designers, and equipment contractors, to develop practical experiment-specific sensitivity requirements. Combined focused numerical simulations and experiments with well-resolved acceleration measurements should be vigorously pursued for developing reliable experiment-specific sensitivity data. Appendices provide an extensive cross-referenced bibliography, a discussion of the merits offered by g-jitter analysis techniques, as well as definitions of relevant nondimensional quantities and a brief description of available accelerometry hardware.

Nelson, Emily S.↗

Thermal Problems in Material processing of High-Temperature Materials

In this final report axial segregation in unsteady diffusion dominated directional solidification of a binary alloy with a planar solid-liquid interface profile is considered. The analysis is an extension of the work of Smith et al. to account for an arbitrary initial axial concentration profile. This situation is important in the experimental studies of growth of crystals in a microgravity environment in which the growth is from melts formed by re-melting crystals that have a known axial impurity profile. Three situations are discussed. There are the initial transient, a re-solidified crystal, and multipass solidification.

Korpela, Seppo A.↗

Use of Microgravity to Control the Microstructure of Eutectics

The long term goal of this project is to be able to control the microstructure of directionally solidified eutectic alloys, through an improved understanding of the influence of convection. Prior experimental results on the influence of microgravity on the microstructure of fibrous eutectics have been contradictory. Theoretical work at Clarkson University showed that buoyancy-driven convection in the vertical Bridgman configuration is not vigorous enough to alter the concentration field in the melt sufficiently to cause a measurable change in microstructure when the eutectic grows at minimum supercooling. Currently, there are four other hypotheses that might explain the observed changes in microstructure of fibrous eutectics caused by convection: (1) Disturbance of the concentration boundary layer arising from an off-eutectic melt composition and growth at the extremum; (2) Disturbance of the concentration boundary layer of a habit-modifying impurity; (3) Disturbance of the concentration boundary layer arising from an off-eutectic interfacial composition due to non-extremum growth; and (4) A fluctuating freezing rate combined with differences in the kinetics of fiber termination and fiber formation. We favor the last of these hypotheses. Thus, the primary objective of the present grant is to determine experimentally and theoretically the influence of a periodically varying freezing rate on eutectic solidification. A secondary objective is to determine the influence of convection on the microstructure of at least one other eutectic alloy that might be suitable for flight experiments.

Wilcox, William R.↗

Stability Analysis of Flow Induced by the Traveling Magnetic Field

Re-circulating flow in molten metal columns can be conveniently induced by the axisymmetric traveling magnetic field. A number of applications can benefit from this technique, such as mixing under microgravity environment, or crysta1 growth from metallic melts. For small magnetic field excitations, the flow is laminar and stationary. As the imposed field increases, a more complex flow will set up in the cylindrical column. Conditions for stable laminar flow are of importance for practical applications. In this work, a linear stability analysis is performed in order to determine the onset of the bifurcation in the system. Here the analysis is restricted to the axisymmetric modes and the low-frequency regime.

Mazuruk, Konstantin↗

Stability Analysis of Flow Induced by the Traveling Magnetic Field

Re-circulating flow in molten metal columns can be conveniently induced by the axisymmetric traveling magnetic field. A number of applications can benefit from this technique, such as mixing under microgravity environment, or.crysta1 growth from metallic melts. For small magnetic field excitations, the flow is laminar and stationary. As the imposed field increases, a more complex flow will set up in the cylindrical column. Conditions for stable laminar flow are of importance for practical applications. In this work, a linear stability analysis is performed in order to determine the onset of the bifurcation in the system. Here the analysis is restricted to the axisymmetric modes and the low-frequency regime.

Mazuruk, Konstantin↗

ISS-Experiments of Columnar-to-Equiaxed Transition in Solidification Processing

The main topic of the research project CETSOL in the framework of the Microgravity Application Promotion (MAP) programme of the European Space Agency (ESA) is the investigation of the transition from columnar to equiaxed grain growth during solidification. Microgravity environment allows for suppression of buoyancy-driven melt flow and for growth of equiaxed grains free of sedimentation and buoyancy effects. This contribution will present first experimental results obtained in microgravity using hypo-eutectic AlSi alloys in the Materials Science Laboratory (MSL) on-board the International Space Station (ISS). The analysis of the experiments confirms the existence of a columnar to equiaxed transition, especially in the refined alloy. Temperature evolution and grain structure analysis provide critical values for the position, the temperature gradient and the solidification velocity at the columnar to equiaxed transition. These data will be used to improve modeling of solidification microstructures and grain structure on different lengths scales.

Sturz, Laszlo↗

Surface Energy Balance Responses to Radiative Forcing in the Central Arctic From MOSAiC and Models

The Arctic surface energy budget (SEB) couples the atmosphere with the sea ice, making it useful for both studying surface processes as well as evaluating models. Improved understanding of atmosphere-ice interactions is required to improve models, requiring year-round observations to address seasonally dependent biases. This work uses novel observations from the MOSAiC expedition to quantify the responses of surface fluxes to radiative forcing over sea ice throughout a complete annual cycle. We identify two primary regimes of flux response: an ice growth regime in winter and an ice melt regime in summer. In the growth regime, changes in radiative forcing impact upwelling longwave, sensible heat, and subsurface heat fluxes, whereas in the melt regime changes in radiative forcing primarily alter the amount of melt and subsurface transmission because the surface temperature is fixed. These observed responses of surface fluxes to radiative forcing are used to evaluate seven weather forecast models during the ice growth regime. In most models, the responses of surface fluxes to radiative forcing do not match observations. Many models also have biased downwelling longwave. One model (the Coupled Arctic Forecast System; CAFS) adequately captures both the mean radiative forcing and the flux responses in winter. CAFS is further evaluated against observations spanning the full MOSAiC year, demonstrating sufficient agreement to provide a more generalized understanding of these SEB process relationships across the Arctic.

54 ENVIRONMENTAL SCIENCES↗

Growth of CuFeO 2 single crystals by the optical floating-zone technique

CuFeO 2 single crystals up to 50 mm in length and up to 10 mm in diameter were grown by the optical floating-zone method. Stoichiometric polycrystalline rods with a diameter of 6–12 mm were used as feed materials to produce crystals of sufficient size to be used as substrates for the growth of thin films of delafossites. For stable growth along the c-axis, low growth rates of 0.4 mm/h are necessary. Due to the incongruent melting behavior of CuFeO 2 , a stable melt zone requires adjustment of the lamp power during growth. The melting of CuFeO 2 is not simply incongruent because the thermodynamic equilibrium includes more than two solid phases and the melt; the gas phase is also involved. Finaly, the crystals were characterized by X-ray diffraction and X-ray fluorescence measurements.

36 MATERIALS SCIENCE↗

The impacts of warming on rapidly retreating high-altitude, low-latitude glaciers and ice core-derived climate records

Alpine glaciers in the low- and mid-latitudes respond more quickly than large polar ice sheets to changes in temperature, precipitation, cloudiness, humidity, and radiation. Many high-altitude glaciers are monitored by ground observations, aerial photography, and satellite-borne sensors. Regardless of latitude and elevation, nearly all nonpolar glaciers and ice caps are undergoing mass loss, which compromises the records of past climate preserved within them. Almost without exception, the retreat of these ice fields is persistent, and a very important driver is the recent warming of the tropical troposphere and oceans. Here we present data on the decrease in the surface area of four glaciers from low- to mid-latitude mountainous regions: the Andes of Peru and northern Bolivia, equatorial east Africa, equatorial Papua, Indonesia, and the western Tibetan Plateau. Climate records based on oxygen isotopic ratios (δ18O) measured in ice cores drilled from several glaciers in these regions reveal that the records from elevations below ~6000 m above sea level have been substantially modified by seasonal melting and the movement of meltwater through porous upper firn layers. Fortunately, δ18O records recovered from higher altitude sites still contain well-preserved seasonal variations to the surface; however, the projected increase in the rate of atmospheric warming implies that climate records from higher elevation glaciers will eventually also be degraded. A long-term ice core collection program on the Quelccaya ice cap in Peru, Earth's largest tropical ice cap, illustrates that the deterioration of its climate record is concomitant with the increase in mid-troposphere temperatures. The melting ice and resulting growth of proglacial lakes presents an imminent hazard to nearby communities. The accelerating melting of glaciers, if sustained, ensures the eventual loss of unique and irreplaceable climate histories, as well as profound economic, agricultural, and cultural impacts on local communities.

Low-latitude glaciers↗

Dendritic solidification in a binary alloy melt: Steady-state versus morphological stability theories

A model for dendritic growth in a binary alloy melt, in the presence of a positive temperature gradient in the liquid, is presented. The model describes satisfactorily the transition from a dendritic interface to a planar interface at very low and very large growth rates. A dendrite tip stability parameter is derived, strictly from steady state considerations, without resorting to a perturbation analysis. The estimates of the parameter agree with those obtained by models based on perturbation analyses.

Laymanan, V.↗

Large Area Silicon Sheet by EFG

Influences on ribbon quality which might be caused by various materials of construction which are used in the growth furnace were assessed. At the present level of ribbon quality, which has produced 8.5% to 9.5% efficient solar cells, no particular influence of any furnace part was detected. The experiments led to the suspicion that the general environment and the somewhat unoptimized materials handling procedures might be responsible for the current variations in ribbon quality and that, therefore, continuous work with this furnace under rather more stringent environmental conditions and operating procedures could perhaps improve materials quality to some extent. The work on the multiple furnace was continued with two multiple growth runs being performed. In these runs, the melt replenishment system performed poorly and extensive modifications to it were designed to make reliable melt feeding for five ribbon growth possible. Additional characterization techniques for wide ribbons, stress measurements, and growth dynamics experiments are reported.

Source record↗