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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Local and global approaches to treat the torsional barriers of 4-methylacetophenone using microwave spectroscopy

The Fourier transform microwave spectrum of 4-methylacetophenone recorded from 8 GHz to 18 GHz under jet-cooled conditions has revealed large tunneling splittings arising from a low barrier to internal rotation of the ring methyl group and small splittings from a high torsional barrier of the acetyl methyl group. The large splittings are especially challenging to model, while the small splittings are difficult to analyze due to the resolution limit of 120 kHz. The combination of two methyl groups undergoing internal rotations caused each rotational transition to split into five torsional species, which were resolved and fitted using a modified version of the XIAM code and the newly devel- oped ntop code to a root-mean-square deviation close to measurement accuracy, providing an estimate of the V 3 potential barriers of about 22 cm -1 and 584–588 cm -1 for the ring and the acetyl methyl groups, respectively. The assignment was aided by separately fitting the five torsional species using odd-power order operators. Only one conformer in which all heavy atoms are located on a symmetry plane could be identified in the spectrum, in agreement with results from conformation analysis using quantum chemical calculations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1986

Overview of the NASA SETI Program

The NASA Search of Extraterrestrial Intelligence (SETI) program plan is to scan the microwave window from 1 to 10 GHz with existing radio telescopes and sophisticated signal processing equipment looking for narrow band features that might represent artificial signals. A microwave spectrometer was built and is being field tested. A pattern recognition computer to search for drifting continuous wave signals and pulse trains in the output spectra is being designed. Equipment to characterize the radio frequency interference environment was also built. The plan is to complete the hardware and software by FY-88. Then, with increased funding, this equipment will be replicated in Very Large Scale Integration form. Observations, both a complete sky survey and a search fo nearby solar type stars, will begin in about 1990. The hypothesis that very powerful signals exist or that signals are being beamed at us will be tested. To detect the kinds of signals radiated at distances of 100 light years will require a collecting area kilometers in diameter.

Oliver, B. M.↗
NASA NTRS2012

Mu-Spec: A High Performance Compact Spectrometer for Submillimeter Astronomy

We describe the Mu-Spec, an extremely compact high performance spectrometer for the submillimeter and millimeter spectral ranges. We have designed a fully integrated submillimeter spectrometer based on superconducting microstrip technology and fabricated its critical elements. Using low loss transmission lines, we can produce a fully integrated high resolution submillimeter spectrometer on a single four inch Si wafer. A resolution of 500 can readily be achieved with standard fabrication tolerance, higher with phase trimming. All functions of the spectrometer are integrated - light is coupled to the microstrip circuit with a planar antenna, the spectra discrimination is achieved using a synthetic grating, orders are separated using a built-in planar filter, and the light is detected using photon counting Microwave Kinetic Inductance Detectors (MKID). We will discus the design principle of the instrument, describe its technical advantages, and report the progress on the development of the instrument.

Hsieh, Wen-Ting↗
NASA NTRS2012

Micro-Spec: A High Performance Compact Spectrometer for Submillimeter Astronomy

We describe the micro-Spec, an extremely compact high performance spectrometer for the submillimeter and millimeter spectral ranges. We have designed a fully integrated submillimeter spectrometer based on superconducting microstrip technology and fabricated its critical elements. Using low loss transmission lines, we can produce a fully integrated high resolution submillimeter spectrometer on a single four inch Si wafer. A resolution of 500 can readily be achieved with standard fabrication tolerance, higher with phase trimming. All functions of the spectrometer are integrated - light is coupled to the micro strip circuit with a planar antenna, the spectra discrimination is achieved using a synthetic grating, orders are separated using a built-in planar filter, and the light is detected using photon counting Microwave Kinetic Inductance Detectors (MKID). We will discus the design principle of the instrument, describe its technical advantages, and report the progress on the development of the instrument.

Hsieh, Wen-Ting↗
DOE OSTI2021

Probing phonon softening in ferroelectrics by scanning probe microwave spectroscopy

Microwave measurements have recently been successfully applied to measure ferroelectric materials on the nanoscale, including detection of polarization switching and ferroelectric domain walls. In this study we discuss the question of whether scanning probe microscopy operating at microwave frequency can identify the changes associated with the soft phonon dynamics in a ferroic. The analytical expressions for the electric potential, complex impedance, and dielectric losses are derived and analyzed, since these physical quantities are linked to experimentally measurable properties of the ferroic. As a ferroic we consider virtual or proper ferroelectric with an optic phonon mode that softens at a Curie point. We also consider a decay mechanism linked to the conductance of the ferroic, thus manifesting itself as the dielectric loss in the material. Our key finding is that the influence of the soft phonon dispersion on the surface potential distribution, complex impedance, and dielectric losses are evidently strong in the vicinity (~10–30 K) of the Curie temperature. Additionally, we quantified how the spatial distribution and frequency spectra of the complex impedance and the dielectric losses react on the dynamics of the soft phonons near the Curie point. These results set the stage for characterization of polar phase transitions with nanoscale microwave measurements, providing a complementary approach to well established electromechanical measurements for fundamental understanding of ferroelectric properties as well as their applications in telecommunication and computing.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

A Study of the Conformational Isomerism of n-Propyl Nitrate by Microwave Spectroscopy

The rotational spectrum of n-propyl nitrate was measured in the frequency range between 6 to 18 GHz using a Balle-Flygare Fourier transform microwave jet/cavity spectrometer. Parent, 13C and 15N isotopologue transitions for the lower-energy anti-gauche (AG) conformer were found using this instrument. The search for spectra from other conformers was performed using a broadband chirped-pulse jet spectrometer. Transitions from the anti-anti (AA) conformer were observed in this manner. Parent, 13C and 15N isotopologue transitions for the AA conformer were rescanned using the cavity instrument to improve resolution and the signal-to-noise ratio. Rotational, centrifugal distortion, and nuclear electric quadrupole coupling constants for all conformers/isotopologues were fit using Pickett’s SPFIT program. The structure of n-propyl nitrate is discussed considering these results.

Orellana, Will D.↗
NASA NTRS1978

The experimental oceanographic satellite Seasat-A

The experimental Seasat-A satellite, scheduled for launch in 1978, is designed to provide measurements of sea-surface temperature, surface wind speed and direction, sea state and directional wave spectra. The instrument package of the satellite includes a highly precise radar altimeter, a wind-field scatterometer, a synthetic-aperture imaging radar, a scanning multifrequency microwave radiometer and a radiometer operating in the visual and infrared. Tides, currents and storm surges on the marine geoid may be monitored through analysis of range information from the radar altimeter and a satellite ephemeris; sea-ice reconnaissance is also planned.

Dunne, J. A.↗
NASA NTRS1991

Limits on Gaussian fluctuations in the cosmic microwave background at 19.2 GHz

The Northern Hemisphere data from the 19.2 GHz full sky survey are analyzed to place limits on the magnitude of Gaussian fluctuations in the cosmic microwave background implied by a variety of correlation functions. Included among the models tested are the monochromatic and Gaussian-shaped families, and those with power law spectra for n from -2 to 1. We place an upper bound on the quadrupole anisotropy of DeltaT/T less than 3.2 x 10 exp -5 rms, and an upper bound on scale-invariant (n = 1) fluctuations of a2 less than 4.5 x 10 exp -5 (95 percent confidence level). There is significant contamination of these data from Galactic emission, and improvement of our modeling of the Galaxy could yield a significant reduction of these upper bounds.

Boughn, S. P.↗
NASA NTRS2018

Comparisons of Bin and Bulk Microphysics Schemes in Simulations of Topographic Winter Precipitation with Radar and Radiometer Measurements

The Hebrew University Cloud Model (HUCM) bin scheme and the Thompson bulk scheme in the Weather Research and Forecasting (WRF) model are compared to assess biases often found in simulated brightness temperature and radar reflectivity. Compared to our preceding study that evaluated several bulk schemes in the WRF model, the current study obtains a reduction of the bias from excessive microwave scattering by precipitation ice for both HUCM bin and the Thompson bulk microphysics schemes for a topographic winter precipitation event associated with an atmospheric river. The Thompson particle size distributions (PSDs) and snow particle density assumption are implemented into the Goddard Satellite Data Simulator Unit (G‐SDSU) and have produced improvements. Despite the greater sophistication of the bin scheme in representing cloud and precipitation processes, the simulation with the Thompson bulk scheme is generally in better agreement with observations for this winter event. The explicitly resolved hydrometeor PSDs in HUCM enable analysis of mass spectra variations in response to changes in microphysics assumptions. Two HUCM sensitivity runs tested the enhancement of snow particle breakup and the influence of ice nuclei (IN) concentration. Higher IN concentration resulted in increased snow mass and broadened the spectrum toward small‐size particles. Modified snow mass spectra and resultant changes in graupel contributed to modifications in scattering and reflectivity simulations. The article demonstrates the bin scheme's capability to provide a new means to improve our understanding of uncertainties in mesoscale weather models and radiative transfer models.

microwave remote sensing↗
NASA NTRS1977

Seasat-A and the commercial ocean community

The Seasat-A program has been initiated as a 'proof-of-concept' mission to evaluate the effectiveness of remotely sensing oceanology and related meteorological phenomena from a satellite platform in space utilizing sensors developed on previous space and aircraft test programs. The sensors include three active microwave sensors; a radar altimeter, a windfield scatterometer, and a synthetic aperture radar. A passive scanning multifrequency microwave radiometer, visual and infrared radiometer are also included. All weather, day-night measurements of sea surface temperature, surface wind speed/direction and sea state and directional wave spectra will be made. Two key programs are planned for data utilization with users during the mission. Foremost is a program with the commercial ocean community to test the utility of Seasat-A data and to begin the transfer of ocean remote sensing technology to the civil sector. A second program is a solicitation of investigations, led by NOAA, to involve the ocean science community in a series of scientific investigations.

Montgomery, D. R.↗
NASA NTRS1983

Characteristics of gamma-ray line flares

Observations of solar gamma rays by the Solar Maximum Mission (SMM) demonstrate that energetic protons and ions are rapidly accelerated during the impulsive phase. To understand the acceleration mechanisms for these particles, the characteristics of the gamma ray line flares observed by SMM were studied. Some very intense hard X-ray flares without detectable gamma ray lines were also investigated. Gamma ray line flares are distinguished from other flares by: (1) intense hard X-ray and microwave emissions; (2) delay of high energy hard X-rays; (3) emission of type 2 and/or type 4 radio bursts; and (4) flat hard X-ray spectra (average power law index: 3.1). The majority of the gamma ray line flares shared all these characteristics, and the remainder shared at least three of them. Positive correlations were found between durations of spike bursts and spatial sizes of flare loops as well as between delay times and durations of spike bursts.

Bai, T.↗
NASA NTRS1985

Characteristics of gamma-ray line flares

Observations of solar gamma rays by the Solar Maximum Mission (SMM) demonstrate that energetic protons and ions are rapidly accelerated during the impulsive phase. To understand the acceleration mechanisms for these particles, the characteristics of the gamma ray line flares observed by SMM were studied. Some very intense hard X-ray flares without detectable gamma ray lines were also investigated. Gamma ray line flares are distinguished from other flares by: (1) intense hard X-ray and microwave emissions; (2) delay of high energy hard X-rays, (3) emission of type 2 and/or type 4 radio bursts; and (4) flat hard X-ray spectra (average power law index: 3.1). The majority of the gamma ray line flares shared all these characteristics, and the remainder shared at least three of them. Positive correlations were found between durations of spike bursts and spatial sizes of flare loops as well as between delay times and durations of spike bursts.

Bai, T.↗
NASA NTRS1989

Marine stratocumulus structure

Thirty-three Landsat TM scenes of California stratocumulus cloud fields were acquired as part of the FIRE Marine Stratocumulus Intensive Field Observations in July 1987. They exhibit a wide variety of stratocumulus structures. Analysis has so far focused upon the July 7 scene, in which aircraft from NASA, NCAR, and the British Meteorological Office repeatedly gathered data across a stratocumulus-fair weather cumulus transition. The aircraft soundings validate the cloud base temperature threshold determined by spatial coherence analysis of the TM thermal band. Brightness variations in the stratocumulus region exhibit a -5/3 power-law decrease of the wavenumber spectra for scales larger than the cloud thickness, about 200 m, changing to a -3 power at smaller scales. Observations by an upward-looking three-channel microwave radiometer on San Nicolas Island also show the -5/3 power-law in total integrated liquid water, suggesting that the largest-scale TM brightness variations are primarily due to variations in the liquid water. The Kolmogorov 5/3 power suggests that for some purposes liquid water in turbulent stratocumulus clouds may be treated as a passive scalar, simply reflecting variations in vertical velocity. This may be tested using the velocities measured by the aircraft.

Cahalan, Robert F.↗
NASA NTRS1992

Limits of Gaussian fluctuations in the cosmic microwave background at 19.2 GHz

The Northern Hemisphere data from the 19.2 GHz full sky survey are analyzed to place limits on the magnitude of Gaussian fluctuations in the cosmic microwave background implied by a variety of correlation functions. Included among the models tested are the monochromatic and Gaussian-shaped families, and those with power-law spectra for n values between -2 and 1. An upper bound is placed on the quadrupole anisotropy of Delta T/T less than 3.2 x 10 exp -5 rms, and an upper bound on scale-invariant (n = 1) fluctuations of a2 less than 4.5 x 10 exp -5 (95 percent confidence level). There is significant contamination of these data from Galactic emission, and improvement of the modeling of the Galaxy could yield a significant reduction of these upper bounds.

Boughn, S. P.↗
NASA NTRS2000

The Rotational Spectrum of Iodine Dioxide, OIO

The rotational spectra of OIO in its ground vibrational and first excited bending states have been observed for the first time. OIO was formed initially from the products of a microwave discharge in O2 passing over molecular iodine and later with greater yield in a DC discharge through a mixture of O2 and I2 vapor. OIO is an asymmetric prolate rotor (kappa = -0.690) with a (sup 2)B(sub 1) electronic ground state. Over 550 ground state transitions and over 160 transitions of the excited bending state have been included in the fits. The resulting parameters are well determined and will be compared to those recently published for OBrO and OClO. These will be interpreted in terms of the molecular geometry, harmonic force field, and electronic structure.

Miller, Charles E.↗
NASA NTRS1994

Measurements of anisotropy in the cosmic microwave background radiation at degree angular scales near the stars Sigma Herculis and Iota Draconis

We present results from two four-frequency observations centered near the stars Sigma Herculis and Iota Draconis during the fourth flight of the Millimeter-wave Anisotropy eXperiment (MAX). The observations were made of 6 deg x 0.6 deg strips of the sky with a 1.4 deg peak to peak sinusoidal chop in all bands. The full width at half maximum (FWHM) beam sizes were calculated 0.55 deg +/- 0.05 deg at 3.5/cm and a 0.75 deg +/- 0.05 deg at 6, 9, and 14/cm. Significant correlated structures were observed at 3.5, 6, and 9/cm. The spectra of these signals are inconsistent with thermal emission from known interstellar dust populations. The extrapolated amplitudes of synchrotron and free-free emission are too small to account for the amplitude of the observed structures. If the observed structures are attributed to cosmic microwave background (CMB) anisotropy with a Gaussian autocorrelation function and a coherence angle of 25 min, then the most probable values at Delta T/T(sub CMB) = 3.1 (sup +1.7 sub -1.3) x 10(exp -5) for the Sigma Herculis scan, and Delta T/T(sub CMB) = 3.3(sup +1.1 sub -1.1) x 10(exp -5) for the Iota Draconis scan (95% confidence upper, lower limits).

Clapp, A. C.↗
NASA NTRS2026

The Hyperspectral Microwave Photonic Instrument (HyMPI) and its NEDT Performance

This work presents an overview of a hyperspectral microwave-photonic spectrometer and demonstrates the system end-to-end noise equivalent delta temperature (NEDT) performance. The system aims at augmenting the remote sensing capability from space, with a focus on the Earth’s planetary boundary layer (PBL) thermal microwave (MW) spectral region (0-200 GHz). Combining a Photonic Integrated Circuit (PIC) channelizer and an application-specific integrated circuit (ASIC) spectrometer, the PIC & ASIC (PICASIC) module is capable of processing 40 GHz spectra at hyperspectral (4 MHz) resolution. The photonic technology is agnostic to the spectral region and multiple photonic modules can cover the entire 200 GHz spectrum. Measured results of the end-to-end system NEDT agree with predicted values confirming that the NEDT is primarily dominated by the noise figure of the MW front-end, with the optical link adding no significant noise. The data also demonstrate that a single module enables simultaneous super- and hyper-spectral resolution channel analysis across a 40 GHz range.

spectrometer↗
DOE OSTI2020

Automated Construction of Potential Energy Surfaces Suitable to Describe van der Waals Complexes with Highly Excited Nascent Molecules: The Rotational Spectra of Ar–CS( v ) and Ar–SiS( v )

Some reactions produce extremely hot nascent products which nevertheless can form sufficiently long-lived van der Waals (vdW) complexes—with atoms or molecules from a bath gas—as to be observed via microwave spectroscopy. Theoretical calculations of such unbound resonance states can be much more challenging than ordinary bound-state calculations depending on the approach employed. One encounters not just the floppy, and perhaps multiwelled potential energy surface (PES) characteristic of vdWs complexes, but in addition, one must contend with excitation of the intramolecular modes and its corresponding influence on the PES. Straightforward computation of the (resonance) rovibrational levels of interest, involves the added complication of the unbound nature of the wave function, often treated with techniques such as introducing a complex absorbing potential. Here, we have demonstrated that a simplified approach of making a series of vibrationally effective PESs for the intermolecular coordinates—one for each reaction product vibrational quantum number of interest—can produce vdW levels for the complex with spectroscopic accuracy. This requires constructing a series of appropriately weighted lower-dimensional PESs for which we use our freely available PES-fitting code AUTOSURF. The applications of this study are the Ar–CS and Ar–SiS complexes, which are isovalent to Ar–CO and Ar–SiO, the latter of which we considered in a previously reported study. Using a series of vibrationally effective PESs, rovibrational levels and predicted microwave transition frequencies for both complexes were computed variationally. A series of shifting rotational transition frequencies were also computed as a function of the diatom vibrational quantum number. The predicted transitions were used to guide and inform an experimental effort to make complementary observations. Comparisons are given for the transitions that are within the range of the spectrometer and were successfully recorded. Calculations of the rovibrational level pattern agree to within 0.2% with experimental measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗