Search NASA⌕ Search

SEARCH · Search NASA

Results for “mode shift”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Limit Cycle Oscillating Detonation Wave Behavior Analysis Within a Rotating Detonation Engine

Limit cycle oscillation (LCO) detonation wave behaviors are presented and analyzed for test times exceeding 20 s in a water-cooled rotating detonation engine (RDE). LCO detonation waves exhibit cyclic acceleration and deceleration, resulting in oscillating wave spacing at unique process conditions. In previous RDE studies, similar behaviors have been studied as microsecond-scale instabilities leading to ascending or descending modal transitions. In the current work, however, LCO waves are considered a persistent wave mode, occupying unique portions of the operational envelope adjacent to those of their equally spaced counterparts. These occurrences of LCO waves are repeatable, enduring behaviors. A method to generate shifted contour surfaces specifically intended to extract and analyze wave spacing variation through time, termed limit cycle oscillation visualization (LCOV) surfaces, is presented. LCOV surfaces transform data into the reference frame of a primary traveling wave and are used to analyze quasi-steady, short-timescale, and transitional LCO modes. Results are leveraged to understand the relationship between fill height, wave strength, local wave acceleration, and subsequent LCO wave spacing for individual wave sets. In conclusion, quasi-steady LCO waves display wave spacing oscillations between equal spacing values associated with ±1 wave across runs exceeding 18 s.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2023

Effect of negative triangularity on tearing mode stability in tokamak plasmas

Abstract The influence of negative triangularity (NT) of the plasma shape on the n = 1 (n is the toroidal mode number) tearing mode (TM) stability has been numerically investigated, with results compared to that of the positive triangularity (PT) counterpart. By matching the safety factor profile for a series of toroidal equilibria, several important plasma parameters, including the triangularity, the plasma equilibrium pressure, the plasma resistivity as well as the toroidal rotation, have been varied. The TM localized near the plasma edge is found to be more unstable in the NT plasmas as compared to the PT counterpart. The fundamental reason for this difference is the lack of favorable average curvature stabilization in NT configurations. Direct comparison of the Mercier index corroborates this conclusion. For the core-localized mode, where the difference in the local triangularity between NT and PT becomes small and the curvature stabilization is significantly reduced, larger Shafranov shift in the plasma core associated with the NT configuration results in more stable TM. The plasma toroidal flow generally stabilizes the TM in plasmas with both NTs and PTs. The flow stabilization is however weaker in the case of negative triangularity with finite plasma pressure.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Room‐Temperature Mid‐Infrared Detection Using Metasurface‐Absorber‐Integrated Phononic Crystal Oscillator

Mid-infrared (MIR) detectors find extensive applications in chemical sensing, spectroscopy, communications, biomedical diagnosis, and space exploration. Alternative to semiconductor MIR photodiodes and bolometers, mechanical-resonator-based MIR detectors show advantages in higher sensitivity and lower noise at room temperature, especially toward longer wavelength infrared. Here, uncooled room-temperature MIR detectors based on lithium niobate surface acoustic wave phononic crystal (PnC) resonators integrated with wavelength-and-polarization-selective metasurface absorber arrays are demonstrated. The detection is based on the resonant frequency shift induced by the local temperature change due to MIR absorptions. The PnC resonator is configured in an oscillating mode, enabling active readout and low-frequency noise. The 1-GHz oscillator-based MIR detector shows a relative frequency deviation of 5.24 × 10 −10 Hz −1/2 at an integration time of 50 µs, leading to an incident noise equivalent power of 197 pW Hz −1/2 when input 6-µm MIR light is modulated at 1.8 kHz, and a large dynamic range of 10 7 in incident MIR power. The device architecture is compatible with the scalable manufacturing process and can be readily extended to a broader spectral range by tailoring the absorbing wavelengths of metasurface absorbers.

Xi, Zichen [Virginia Polytechnic Inst. and State U↗
DOE OSTI2021

On the Regionality of Moist Kelvin Waves and the MJO: The Critical Role of the Background Zonal Flow

Abstract A global model with superparameterized physics is used to shed light on the observed regionality of convectively coupled Kelvin waves and the Madden‐Julian Oscillation (MJO). A series of aquaplanet simulations over zonally uniform sea‐surface temperatures is performed, in which the axisymmetric structure of the background zonal flow is altered through nudging, while maintaining a quasi‐fixed rainfall climatology. Results show that nudging at the equator to match profiles typical of the Indo‐Pacific or eastern Pacific sectors yields eastward‐moving tropical rain spectra typical of those sectors. Two different mechanistic pathways are identified as being responsible for this mean‐flow dependence, in addition to Doppler shifting effects. The first is through shifts of the Rossby wave critical line in the subtropical upper troposphere that affect the lateral forcing of Kelvin‐mode circulations at the equator by eastward and equatorward‐propagating eddies impinging on the tropics from higher latitudes. The second is through changes in the strength of the mean cyclonic shear in the lower tropical troposphere that affect the degree to which intraseasonal fluctuations in Kelvin‐mode zonal winds modulate the activity of higher‐frequency equatorial Rossby‐type eddies. In cases where the mean low‐level cyclonic shear is enhanced, the strength of this modulation, referred to as “shear‐induced eddy modulation” or SIEM, is also seen to be enhanced, such that MJO‐like modes of variability are rendered either unstable or near neutral, depending on the strength of the shear.

Tulich, S. N.↗
DOE OSTI2020

Facile and quantitative estimation of strain in nanobubbles with arbitrary symmetry in 2D semiconductors verified using hyperspectral nano-optical imaging

When layers of van der Waals materials are deposited via exfoliation or viscoelastic stamping, nanobubbles are sometimes created from aggregated trapped fluids. Though they can be considered a nuisance, nanobubbles have attracted scientific interest in their own right owing to their ability to generate large in-plane strain gradients that lead to rich optoelectronic phenomena, especially in the semiconducting transition metal dichalcogenides. Determination of the strain within the nanobubbles, which is crucial to understanding these effects, can be approximated using elasticity theory. However, the Föppl–von Kármán equations that describe strain in a distorted thin plate are highly nonlinear and often necessitate assuming circular symmetry to achieve an analytical solution. Here, we present an easily implemented numerical method to solve for strain tensors of nanobubbles with arbitrary symmetry in 2D crystals. The method only requires topographic information from atomic force microscopy and the Poisson ratio of the 2D material. We verify that this method reproduces the strain for circularly symmetric nanobubbles that have known analytical solutions. Finally, we use the method to reproduce the Grüneisen parameter of the E' mode for 1L-WS2 nanobubbles on template-stripped Au by comparing the derived strain with measured Raman shifts from tip-enhanced Raman spectroscopy, demonstrating the utility of our method for estimating localized strain in 2D crystals.

2D materials↗
DOE OSTI2024

Observation of maxon-like ultrasound in elastic metabeam

We observe maxon-like dispersion of ultrasonic guided waves in elastic metamaterials consisting of a rectangular beam and an array of cylindrical resonators. The pillars act as asymmetric resonators that induce a strong modal hybridization. We experimentally observe the strongly localized maxon mode with zero group velocity. Our study also demonstrates a unique feature of the maxon with a down-shifting peak frequency in space. To reveal the fundamental mechanism, we conduct comprehensive numerical studies on all frieze group symmetries and key geometric parameters.

Materials Science↗
DOE OSTI2024

Intercalation of quaternary ammonium cations as a key factor of electron storage in MoS2 thin films

Electrochemical intercalation of cations within two-dimensional transition metal dichalcogenides presents a promising route for tailoring their optoelectronic properties. We have now succeeded in modulating the optical properties of MoS2 thin films through electrochemical intercalation of quaternary ammonium cations. The spectroelectrochemical experiments conducted with varying sizes of the intercalant revealed the size-dependent stability of the intercalated MoS2 nanosheets. The observed absorption change of the exciton bands is reversible and arises from the storage of electrons in MoS2 nanosheets and the subsequent weakening of interlayer van der Waals interactions following cation intercalation. This structural change is evidenced by the emergence of A*1g out-of-plane Raman mode. Additionally, the photoelectron spectroscopy reveals the emergence of a lower binding energy component of Mo 3d and the shift in Fermi level to higher energies, confirming the presence of stored electrons in cation intercalated-MoS2. The underlying mechanism of intercalation-induced property modifications in MoS2 discussed in the present study is useful in developing strategies for energy conversion devices.

Physics↗
DOE OSTI2022

Simulation of a PCM Integrated Heat Pump Using Time-of-Use Utility Structure based Control Strategy for Demand Response

To mitigate the variation in demand on the electric grid, thermal energy storage (TES) is an alternative to electric batteries and constructing new peaking power plants. The aggressive carbon reduction goals of the United States are accelerating the electrification of building equipment. If space heating and cooling in the US were electrified using conventional heat pump technologies, the winter electric grid peak would approximately double. Integrating TES with heat pump (HP) enables electrification of space cooling and heating devices without overtaxing the grid.This paper evaluates the benefits of a novel phase change material (PCM) integrated heat pump configuration via simulation. A one-dimensional PCM heat exchanger model which discretizes the PCM tank and refrigerant tubes into small control volumes is developed. Each control volume can have different PCM temperatures, PCM properties, and heat transfer coefficients. The PCM tank is charged by a wrapped tank condenser and discharged by an internal refrigerant coil. The PCM heat exchanger model is integrated into DOE/ORNL Heat Pump Design Model for heat pump system simulation.To demonstrate the performance of the PCM integrated heat pump, a case study in Chicago was performed. A Time-of-Use utility structure-based control strategy is implemented to schedule the PCM tank charging and discharging mode switching. Compared with a conventional electric heat pump, the PCM integrated heat pump shows superior performance on load shifting and utility cost reduction. As a result, the proposed system demonstrates 24.6% utility saving for cooling application and 25.8% utility saving for heating application.

Li, Zhenning↗
DOE OSTI2024

Performance Assessment of a Dual-purpose HP-TES for a Typical Year Comparing Different Climate Zones

Complete electrification of heating and cooling systems in the United States would overload the existing electrical grid. To this end, recent research efforts have focused on energy storage as one way to reduce ever-increasing peak electricity demands. One such technology is heat pump integrated thermal-energy storage (HP-TES) systems, which can enable load-shifting and reduce demand during peak hours. In this work, a Modelica model of a 4-Ton, dual-mode (heating and cooling) HP-TES system using a room-temperature phase-change material (PCM) integrated through a secondary hydronic loop was developed and simulated for a typical meteorological year in Riverside, CA (ASHRAE Climate Zone 2B), and Chicago, IL (ASHRAE Climate Zone 5A), for a DOE small office prototype building. The COP improvement and demand reduction were analyzed during the time-of-use peak hours along with the required recharge cycle energy demand. A typical summer in Riverside, CA resulted in model-predicted peak COP increases of 50 – 100% compared to the baseline heat pump, especially at higher outdoor temperatures, coupled with maximum peak energy reductions of 22%. During shoulder and winter season simulations, heating energy savings were higher as outdoor temperatures dropped below the PCM phase change temperature. For Chicago, IL, backup heating was necessary to meet the required system capacity for very cold ambient conditions, resulting in winter peak energy savings between 16 – 60% when accounting for backup heating requirements. The recharge energy was found to be mostly below the baseline HP energy during the peak. With improved component selections and controls, the recharge energy may be reduced. The outcomes from the simulations can provide first-order estimates for potential peak energy savings, challenges, and required controls in any location before conducting any field testing.

25 ENERGY STORAGE↗
DOE OSTI2020

First-principles predictions of temperature-dependent infrared dielectric function of polar materials by including four-phonon scattering and phonon frequency shift

Recently, first-principles calculations based on density functional theory have been widely used to predict the temperature-dependent infrared spectrum of polar materials, but the calculations are usually limited to the harmonic frequency (0 K) and three-phonon scattering damping for the zone-center infrared-active optical phonon modes, and fail to predict the high-temperature infrared optical properties of materials such as sapphire (α–Al 2 O 3 ), GaAs, TiO 2 , etc., due to the neglect of high-order phonon scattering damping and phonon frequency shift. In this work, we implemented first-principles calculations to predict the temperature-dependent infrared dielectric function of polar materials by including four-phonon scattering and phonon frequency shift. The temperature-dependent phonon damping by including three- and four-phonon scattering as well as the phonon frequency shift by including cubic and quartic anharmonicity and the thermal expansion effect are calculated based on anharmonic lattice dynamics method. The infrared dielectric function of α–Al 2 O 3 is parameterized, and then the temperature-dependent infrared optical reflectance is determined. We find that our predictions agree better with the experimental data than the previous density functional theory-based methods. Lastly, this work will help to effectively predict the thermal radiative properties of polar materials at elevated temperature, which is generally difficult to measure, and will enable predictive design of new materials for radiative applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

A compendium of sphere path integrals

We study the manifestly covariant and local 1-loop path integrals on S d+1 for general massive, shift-symmetric and (partially) massless totally symmetric tensor fields of arbitrary spin s ≥ 0 in any dimensions d ≥ 2. After reviewing the cases of massless fields with spin s = 1, 2, we provide a detailed derivation for path integrals of massless fields of arbitrary integer spins s ≥ 1. Following the standard procedure of Wick-rotating the negative conformal modes, we find a higher spin analog of Polchinski’s phase for any integer spin s ≥ 2. The derivations for low-spin (s = 0, 1, 2) massive, shift-symmetric and partially massless fields are also carried out explicitly. Finally, we provide general prescriptions for general massive and shift-symmetric fields of arbitrary integer spins and partially massless fields of arbitrary integer spins and depths.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Simulation study of particle transport by weakly coherent mode in the Alcator C-Mod tokamak

A simulation study has been conducted of the physical mechanisms behind the weakly coherent mode (WCM) and its produced particle transport in the I-mode edge plasmas by using the BOUT++ code. The WCM is identified in our simulations by its poloidal and radial distributions as well as its frequency and wavenumber spectra. Its produced radial particle flux is calculated and compared with the experimental value. The good agreement indicates that the WCM is an important particle transport channel in the I-mode pedestal. It is found that the WCM can transport particles across the strong outer shear layer of the Er well established in the formation of I-mode, based on which a possible explanation is provided why I-mode does not feature a density pedestal. The key point lies in the change of the cross-phase between the electric potential and density fluctuations induced by the E × B Doppler shift. In the strong shear layer, although the electric potential fluctuation is significantly suppressed, the cross-phase is close to π/2, resulting in a strong drive of the density fluctuation and particle transport. To identify the physical nature of the WCM, a linear dispersion relation for drift Alfvén modes is derived in the slab geometry. A drift Alfvén wave instability is found to have similar dependence to the simulated linear instability behind the WCM on the resistivity and the parallel electron pressure gradient and thermal force terms in the parallel Ohm's law.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Sources of Subseasonal-To-Seasonal Predictability of Atmospheric Rivers and Precipitation in the Western United States

Atmospheric rivers (ARs) account for a large portion of winter precipitation in the western US. To evaluate the sources of AR and precipitation predictability at subseasonal-to-seasonal timescales, we examine the relationships between two climate modes, the El Niño/Southern Oscillation (ENSO) and Madden-Julian oscillation (MJO), and winter hydroclimate in the western US. Our analysis uses a large ensemble of the Weather Research and Forecast (WRF) model simulations from 1981 to 2017, facilitating the assessment of uncertainty in climate mode-AR relationship due to climate variability and short length of observations. Over the North Pacific basin, we find ENSO-related latitudinal shifts of ARs, but ENSO has little effect on basin-wide averaged AR frequency. Over the western US, there is some uncertainty in the ENSO-AR connection due to the impacts of ENSO indices and datasets. However, extreme El Niño events defined by the ENSO longitude index are consistently linked to increased landfalling AR activity. The MJO can lead to significantly enhanced or suppressed landfalling AR activity in the large-ensembles, depending on the phase of MJO and time lag, while observations are too short in length to robustly show this signal. ENSO substantially modulates the MJO-AR relationship, triggering variegated responses of landfalling ARs and AR precipitation in La Niña and El Niño years. Our findings highlight the need to evaluate concurrent effects of different climate modes on ARs and precipitation, and may shed light on a path toward more accurate subseasonal-to-seasonal prediction of ARs and precipitation over the western US.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Dynamic flux surrogate-based partitioned methods for interface problems

Loosely coupled partitioned methods for multiphysics problems treat each subproblem as a separate entity and advance them independently in time. In so doing these methods enable code reuse, increase concurrency and provide a convenient framework for plug-and-play multiphysics simulations. However, mathematically loosely coupled schemes are equivalent to a single step of an iterative solution method, which can compromise their accuracy and stability. We present a new data-driven partitioned method for coupled parametric PDEs that can improve upon the accuracy of traditional loosely coupled methods without incurring a performance penalty. To that end, we replace conventional field transfers across the interface by a surrogate for the dynamics of the interface flux exchanged between the subdomains. To develop this surrogate we apply dynamic mode decomposition to a non-standard staggered-in-time state, comprising the interface flux and small solution patches near the interface. The new approach shifts the main computational burden to an offline training phase, whereas application of the surrogate in the online phase amounts to a single matrix–vector multiplication. In conclusion, we provide stability analysis of the surrogate-based partitioned scheme and include numerical results that demonstrate its potential.

Dynamic mode decomposition (DMD)↗
DOE OSTI2022

High-Pressure Investigation of 2,4,6-Trinitro-3-bromoanisole (TNBA): Structural Determination and Piezochromism

Understanding phase transitions in energetic materials is crucial for developing predictive models of detonation. 2,4,6-Trinitro-3-bromoanisole (TNBA), an energetic material, was studied in its single-crystal form up to pressures of 45 GPa in a diamond anvil cell. The material was characterized by using X-ray, Raman, and optical transmission measurements. From single-crystal X-ray diffraction, the ambient structure of TNBA was determined which crystallizes in the P2 1 /c space group having four molecular units per unit cell. The X-ray data up to 9.2 GPa were fitted to a third-order Birch–Murnaghan equation of state by using the parameters K o = 13.2(2.4) GPa and K p = 5.1(1.4). Between 6.8 and 7.3 GPa, a phase transition was inferred in TNBA from concurrent fading of X-ray diffraction, disappearance of Raman peaks, increase in sample fluorescence, and discontinuous color change. The new phase was consistent with an amorphous state of at least partially intact molecules judging from the presence of higher-order Raman modes and irreversibility of the Raman spectra upon release. Piezochromism was observed with the translucent yellow TNBA gradually darkening and becoming opaque black at ~25 GPa. This correlated to the absorption edge gradually shifting to the red in the visible spectrum. Signs of two possible additional structural transitions were detected in the 32.4–41.0 GPa range as suggested by a jump in the absorption edge, the irreversible changes in the absorption spectrum upon release to ambient pressure, and by the lack of Raman modes in recovered samples. Here, the crystal and electronic structures of TNBA were also investigated up to 10 GPa by using DFT calculations and crystal structure prediction (CSP) simulations. In agreement with the experimentally observed transition at 7 GPa, the simulations at 10 GPa found a bevy of polymorphs lower in enthalpy and higher in density than P2 1 /c. The lowest calculated enthalpy structure was determined to be P2 1 2 1 2 1 , being in a different space group than the ambient experimental result.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Thickness-Tunable Self-Assembled Colloidal Nanoplatelet Films Enable Ultrathin Optical Gain Media

We propose and demonstrate construction of highly uniform, multilayered superstructures of CdSe/CdZnS core/shell colloidal nanoplatelets (NPLs) using liquid interface self-assembly. These NPLs are sequentially deposited onto a solid substrate into slabs having monolayer-precise thickness across tens of cm(2) areas. Because of near-unity surface coverage and excellent uniformity, amplified spontaneous emission (ASE) is observed from an uncharacteristically thin film having 6 NPL layers, corresponding to a mere 42 nm thickness. Furthermore, systematic studies on optical gain of these NPL superstructures having thicknesses ranging from 6 to 15 layers revealed the gradual reduction in gain threshold with increasing number of layers, along with a continuous spectral shift of the ASE peak (similar to 18 nm). These observations can be explained by the change in the optical mode confinement factor with the NPL waveguide thickness and propagation wavelength. This bottom-up construction technique for thickness-tunable, three-dimensional NPL superstructures can be used for large-area device fabrication.

Erdem, Onur↗
DOE OSTI2023

Neutron Coincidence Measurements of Uranium-233 Oxide

Renewed international interest in thorium-fueled advanced reactors has challenged the safeguards community to address future proliferation concerns. Thorium-based technology presents many benefits but does not eliminate the proliferation risks associated with producing and processing fissile material. A byproduct of thorium-fueled reactors is uranium-233, which is classified as a direct-use material. As a result, the development of new or improved methods to characterize and measure materials containing 233U must mirror the pace of development of reactors and facilities that produce such material. Research is underway to assess, develop, and test approaches for safeguarding nuclear materials within the thorium fuel cycle. Neutron signatures from the nondestructive assay (NDA) of materials containing 233U are being quantified to inform the potential characterization of these materials. Using a traditional neutron coincidence counter and a series of well-documented 233U oxide samples, initial measurements have been made to assess the feasibility of 233U characterization and discrimination from other uranium isotopes, primarily 235U, using a combination of measurement techniques and analysis methods. Data acquisition is performed in list mode, allowing for a variety of analyses to be performed on the raw data that is not available using traditional shift register technology. Measurements were performed in passive and active configurations to quantify the strength of signal and to validate simulations in support of this work. This paper presents and discusses the results of the initial measurements of 233U oxide performed at Oak Ridge National Laboratory.

Lockhart, Madeline↗
DOE OSTI2025

Fast Sideband Control of a Weakly Coupled Multimode Bosonic Memory

Circuit quantum electrodynamics (cQED) with superconducting cavities coupled to nonlinear circuits like transmons offers a promising platform for hardware-efficient quantum information processing. We address critical challenges in realizing this architecture by weakening the dispersive coupling while also demonstrating fast, high-fidelity multimode control by dynamically amplifying gate speeds through transmon-mediated sideband interactions. This approach enables transmon-cavity SWAP gates, for which we achieve speeds up to 30 times larger than the bare dispersive coupling. Combined with transmon rotations, this allows for efficient, universal state preparation in a single cavity mode, though achieving unitary gates and extending control to multiple modes remains a challenge. In this work, we overcome this by introducing two sideband control strategies: (1) a shelving technique that prevents unwanted transitions by temporarily storing populations in sideband-transparent transmon states and (2) a method that exploits the dispersive shift to synchronize sideband transition rates across chosen photon-number pairs to implement transmon-cavity SWAP gates that are selective on photon number. We leverage these protocols to prepare Fock and binomial code states across any of ten modes of a multimode cavity with millisecond cavity coherence times. We demonstrate the encoding of a qubit from a transmon into arbitrary vacuum and Fock state superpositions, as well as entangled NOON states of cavity mode pairs— a scheme extendable to arbitrary multimode Fock encodings. Furthermore, we implement a new binomial encoding gate that converts arbitrary transmon superpositions into binomial code states in $\qty{4}{\micro\second}$ (less than $1/\chi$), achieving an average post-selected final state fidelity of $\qty{96.3}{\percent}$ across different fiducial input states.

Huang, Jordan [Rutgers U., Piscataway]↗