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A New Method for Estimating the Single Scattering Phase Functions of Regolith Grains

Hapke's photometric model has been widely used in solar system remote sensing applications for nearly two decades. Recently, Hapke extended his model to describe the coherent-backscatter opposition effect and multiple-scattering by particles with anisotropic single particle phase functions (SPPF's). A practical difficulty for retrieving Hapke's model parameters from typical planet, satellite, and asteroid photometry data sets is that the model employs a large number of adjustable parameters (at least eight) that can be reliably constrained only for a small number of planetary data sets in which both disk-resolved and whole-disk observations are available from opposition to very large phase angles. The present work aims to reduce the number of adjustable parameters and preserve (or even enhance) the model's accuracy and usefulness by expressing Hapke's parameters in terms of more fundamental physical properties on which they mutually depend. The most difficult part of this task, described here, is to develop a simple method for computing the effective SPPF for structurally complex regolith grains from optical constants, grain-size distribution, and average regolith porosity. The development of light-scattering models for irregularly shaped particles is a large, complex subject and many sophisticated methods, such as Discrete Dipole Approximation (DDA) and Monte-Carlo simulations, have been explored elsewhere. Many of these methods are computationally intensive and probably impractical for routine substitution in Hapke's model. Here, progress is reported in developing a practical, semi-empirical method for estimating the directional scattering behavior (i.e. SPPF) of irregular regolith grains. The method employs Optical Transfer Function (OTF) techniques to model how the structural complexity of regolith particles broaden and attenuate the angular distribution of scattered light relative to that expected from ideal spherical particles of equivalent size and composition.

Helfenstein, P.↗

Characterization of carbonaceous aerosols during TRACER-CAT

Absorbing aerosols (AA) have an important impact on the global radiation budget and cloud properties. The composition and properties of AA can vary substantially throughout the atmosphere, depending on the particle source and the influence of chemical aging. Uncertainties associated with the radiative effects of AA remain substantial. A key contributor to this uncertainty is understanding the extent to which coatings in general, and water uptake especially, alters absorption by AA particles and how this depends on particle composition. We deployed new and existing experimental tools during the Tracking Aerosol Convection Interactions Experiment (TRACER) campaign in Houston, TX as part of the Carbonaceous Aerosols Thrust (CAT) to provide detailed characterization of aerosol optical, chemical, and physical properties. Our TRACER-CAT measurements complemented and expanded on the planned TRACER instrumentation, allowing for more detailed characterization of aerosol properties of relevance to cloud development (a core focus of TRACER), such as the composition of particles that can act as cloud condensation nuclei, than would otherwise be available. Our measurements have allowed for assessment of the relationship(s) between AA optical properties (with a focus on absorption) and the chemical and physical characteristics (including the mixing state of black carbon (BC) containing particles). These field observations occurred in collaboration with Los Alamos National Laboratory in summer 2022 during the TRACER intensive operating period. The instrumentation we co-deployed provided for measurement of (i) multi-wavelength dry aerosol absorption, scattering, and extinction, (ii) the size-dependent composition and abundance of sub-micron aerosol, differentiating between those particles that do and do not contain BC, (iii) BC-specific concentrations and size distributions, (iv) particle size, and (v) the first field measurements at an ARM site of the influence of RH on multi-wavelength absorption by ambient AA. We have leveraged the natural variability of the atmosphere and of aerosol sources in the Houston region to (i) specifically disentangle contributions to light absorption from BC, absorbing organic carbon (brown carbon), and coatings on BC, (ii) characterize the mixing state of BC and assess the factors that give rise to compositional differences between BC-containing and BC-free aerosol, and (iii) establish how water uptake influences absorption and how any such effect depends on particle composition and BC mixing state. Overall, our study contributed to the mission of the Atmospheric System Research program in multiple ways. Through the deployment of complementary, advanced instrumentation for characterization of a wide range of aerosol properties our work helped to maximize the scientific impact of the TRACER campaign. Our work also allowed for development of new insights into the relationship(s) between aerosol composition, hygroscopicity, and the mixing state of BC with aerosol optical properties. Through this, our work has provided knowledge that can improve understanding and model representation of aerosol processes as they affect the Earth’s radiation budget.

54 ENVIRONMENTAL SCIENCES↗

Asymmetry parameters of the phase function for densely packed scattering grains

Spatial correlation among densely packed particles can substantially change their single-scattering properties, thus making questionable the applicability of the independent scattering approximation in calculations of light scattering by planetary regoliths. The same problem arises in geophysics in light scattering computations for snow, frosts, and bare soil. In this paper, we use a dense-medium light-scattering theory based on the introduction of the static structure factor to calculate asymmetry parameters of the phase function for densely packed particles with real refractive indices 1.31 and 1.66, approximating water ice and soil particles, respectively, and imaginary refractive indices 0, 0.01, and 0.3. For sparsely distributed, independently scattering grains, the calculated asymmetry parameters are always positive and always larger than those for densely packed particles. For densely packed grains, the asymmetry parameters may be negative but only for radius-to-wavelength ratios from about 0.1 to about 0.4. With decreasing particle size, the calculated asymmetry parameters tend to zero independently of the compaction state. In the geometrical optics regime, the asymmetry parameters for densely packed scatterers are positive and very close to those for independently scattering grains. These results may have important implications for remote sensing of the Earth and solid planetary surfaces. In particular, it is demonstrated that negative asymmetry parameters derived with some approximate multiple-scattering theories may be physically irrelevant and can be the result of using an inaccurate bidirectional reflection function combined with the ill-conditionally of the inverse scattering problem.

Mishchenko, Michael I.↗

Effects of Melt Processing on Evolution of Structure in PEEK

We report on the effects of melt processing temperature on structure formation in Poly(ether-ether-ketone), PEEK. Real time Small Angle X-ray Scattering, SAXS, and thermal analysis are used to follow the melting behavior after various stages of processing. Assignment of peaks to structural entities within the material, the relative perfection of the crystals, and the possibility of their reorganization, are all influenced by the melt processing history. With the advent of high intensity synchrotron sources of X-radiation, polymer scientists gain a research tool which, when used along with thermal analysis, provides additional structural information about the crystals during growth and subsequent melting. PEEK is an engineering thermoplastic polymer with a very high glass transition temperature (145 C) and crystal melting point (337 C). PEEK has been the subject of recent studies by X-ray scattering in which melt and cold crystallization were followed in real-time. X-ray scattering and thermal studies have been used to address the formation of dual endothermic response which has been variously ascribed to lamellar insertion, dual crystal populations, or melting followed by re-crystallization. Another important issue is whether all of the amorphous phase is located in interlamellar regions, or alternatively whether some is located in "pockets" away from the crystalline lamellar stacks. The interpretation of scattering from lamellar stacks varies depending upon whether such amorphous pockets are formed. Some groups believe all of the amorphous phase is interlamellar. This leads to selection of a smaller thickness for the crystals. Other groups suggest that most amorphous phase is not interlamellar, and this leads to the suggestion that the crystal thickness is larger than the amorphous layer within the stacks. To investigate these ideas, we used SAXS and Differential Scanning Calorimetry to compare results of single and dual stage melt crystallization of PEEK using a treatment scheme involving annealing/crystallization at T(sub a1) followed by annealing at T(sub a2) where either T(sub a1) < T(sub a2) or T(sub a1) > T(sub a2). We proposed a model to explain multiple melting endotherms in PPS, treated according to one or two-stage melt or cold crystallization. Key features of this model are that multiple endotherms: (1) are due to reorganization/recrystallization after cold crystallization; and, (2) are dominated by crystal morphology after melt crystallization at high T. In other words, multiple distinct crystal populations are formed by the latter treatment, leading to observation of multiple melting. PEEK 45OG pellets (ICI Americas) were the starting material for this study. Films were compression molded at 400 C, then quenched to ice water. Samples were heated to 375 C in a Mettler FP80 hot stage and held for three min. to erase crystal seeds before cooling them to T(sub a1) = 280 C . Samples were held at T(sub a2) for a period of time, then immediately heated to 360 C. In the second treatment samples were held at T(sub a1) = 31 C for different crystallization times t(sub c) then cooled to 295 C and held 15 min. In situ (SAXS) experiments were performed at the Brookhaven National Synchrotron Light Source with the sample located inside the Mettler hot stage. The system was equipped with a two-dimensional position sensitive detector. The sample to detector distance was 172.7 cm and the X-ray wavelength was 1.54 Angstroms. SAXS data were taken continuously during the isothermal periods and during the heating to 360 C at 5 C/min. Each SAXS scan was collected for 30 sec. Since the samples were isotropic, circular integration was used to increase the signal to noise ratio. After dual stage melt crystallization with T(sub a1) < T(sub a2) the lower melting endotherm arises from holding at T(sub a1). During cooling a broad distribution of crystals forms, and the low-melting tail is perfected during T(sub al). Heating to T(sub a2) melts these imperfect crystals and allows others with greater average long spacing to form in their place. After dual stage crystallization with T(sub a1) > T(sub a2), the amount of space remaining for additional growth at T(sub a2) depends upon the holding time at T(sub a1). The long period of crystals formed at T(sub a2) is smaller than that formed at T(sub a1) due to growth in a now-restricted geometry. Perfection of crystals is seen as an increase of the intensity of the population scattering at higher s, while the intensity of the population scattering at lower s stays constant. During heating from below to above the minor endotherm, we see rapid decrease of the intensity of the X-ray scattering corresponding to the population of crystals scattering in the shoulder. Another important observation is that after the sample is annealed at 295 C, the shoulder intensity is restored once again. The population scattering at higher s remains longer before it disappears in the sample treated to the second stage of melt crystallization, compared to the sample crystallized with a single stage. This could be interpreted as an effect of continued perfection of the less perfect population, which is also reflected in the increased melting temperature of the smaller endotherm as the holding time at 295 C increases. In the corresponding DSC scans we see a shift in the area and the peak temperature of the lower melting endotherm with an increase of the annealing time.

Georgiev, Georgi↗

Polaris-PARCS Sensitivity Study on LWR Fuel Cycles: Polaris Input Options

This study is the first of a multi-phase effort to assess the sensitivity of light-water reactor (LWR) core-level prediction biases to changes in lattice-level calculation parameters. Prediction bias is the measured-to-predicted difference in a core-level quantity of interest (QOI) which can be estimated by comparing the simulation results with the plant-measured data for key nuclear parameters. The LWR two-step neutronics codes employed herein are the SCALE–Polaris lattice physics code (v6.3.1) and the Purdue Advanced Reactor Core Simulator (PARCS) nodal diffusion simulator (v3.4.2), both funded and used for confirmatory analysis to support licensing by the US Nuclear Regulatory Commission (NRC). Polaris–PARCS is used to model Watts Bar Unit 1 cycles 1–3 and Peach Bottom Unit 2 cycles 1–3. This study focuses on the impact of changes to Polaris input options such as scattering treatment or quadrature settings and how these input options induce changes in core-level quantities of interest (QOIs)bias. The report documents multiple bias assessments for different modeling choices and compares the bias magnitude to the QOI measurement uncertainties. Future companion reports will investigate the sensitivity of core-level LWR prediction bias to Polaris input options and Polaris-computed QOIs such as few-group assembly-homogenized cross sections to gain an understanding of the key drivers of prediction bias at lattice and core levels for application of a two-step LWR neutronics procedure in a licensing scenario.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Thermodynamic phase transitions of nematic order in magnetic helices

A nematic phase lacks translation order but has orientational order. Nematic phases have been discovered in a variety of systems, including liquid crystals, correlated materials, and superconductors. Here, we report on a magnetic nematic phase, where the basis components are composed of magnetic helices. We directly probed the order parameters associated with the magnetic helices using resonant soft x-ray scattering and find two distinct nematic phases with complex spatiotemporal signatures. Using x-ray correlation spectroscopy, we find that near the phase boundary between the two nematic phases, fluctuations coexist on multiple disparate timescales. Our micromagnetic simulations and density functional theory calculations show that the fluctuations occur concomitantly with a reorientation of the magnetic helices, indicating spontaneous symmetry breaking and the emergence of additional degrees of freedom. Our results provide a framework for characterizing exotic phases that can be extended to a broad class of physical systems.

36 MATERIALS SCIENCE↗

Airborne Spectral Measurements of Ocean Anisotropy during CLAMS

The Cloud Absorption Radiometer (CAR) aboard the University of Washington Convair CV-580 research aircraft obtained bidirectional reflectance-distribution function (BRDF) of Atlantic Ocean and Dismal Swamp between July 10 and August 2, 2001. The BRDF measurements (15 in total, 8 uncontaminated by clouds) obtained under a variety of sun angles and wind conditions, will be used to characterize ocean anisotropy in support of Chesapeake Lighthouse and Aircraft Measurements for Satellites (CLAMS) science objectives principally to validate products from NASA's EOS satellites, and to parameterize and validate BRDF models of the ocean. In this paper we present results of BRDF of the Ocean under different sun angles and wind conditions. The CAR is capable of measuring scattered light in fourteen spectral bands. The scan mirror, rotating at 100 rpm, directs the light into a Dall-Kirkham telescope where the beam is split into nine paths. Eight light beams pass through beam splitters, dichroics, and lenses to individual detectors (0.34-1.27 micron), and finally are registered by eight data channels. They are sampled simultaneously and continuously. The ninth beam passes through a spinning filter wheel to an InSb detector cooled by a Stirling cycle cooler. Signals registered by the ninth data channel are selected from among six spectral channels (1.55-2.30 micron). The filter wheel can either cycle through all six spectral bands at a prescribed interval (usually changing filter every fifth scan line), or lock onto any one of the six spectral bands and sample it continuously. To measure the BRF of the surface-atmosphere system, the University of Washington CV-580 had to fly in a circle about 3 km in diameter above the surface for roughly two minutes. Replicated observations (multiple circular orbits) were acquired over selected surfaces so that average BRF smooth out small-scale surface and atmospheric inhomogeneities. At an altitude of 600 m above the targeted surface area and with a 1 degree IFOV, the pixel resolution is about 10 m at nadir and about 270 m at an 80 deg. viewing angle from the CAR.

Gatebe, C. K.↗

The Role of a Neutron Component in the Photospheric Emission of Long Duration Gamma-Ray Burst Jets

Long-duration gamma-ray bursts (LGRBs), thought to be produced during core-collapse supernovæ, may have a prominent neutron component in the outflow material. If present, neutrons can change how photons scatter in the outflow by reducing its opacity, thereby allowing the photons to decouple sooner than if there were no neutrons present. Understanding the details of this process could therefore allow us to probe the central engine of LGRBs, which is otherwise hidden. Here, we present results of the photospheric emission from an LGRB jet, using a combination of relativistic hydrodynamic simulations and radiative transfer post-processing using the Monte Carlo Radiation Transfer (MCRaT) code. We control the size of the neutron component in the jet material by varying the equilibrium electron fraction Y e , and we find that the presence of neutrons in the GRB fireball affects the Band parameters α and E 0 , while the picture with the β parameter is less clear. In particular, the break energy E 0 is shifted to higher energies. Additionally, we find that increasing the size of the neutron component also increases the total radiated energy of the outflow across multiple viewing angles. Our results not only shed light on LGRBs, but are also relevant to short-duration gamma-ray bursts associated with binary neutron star mergers, due to the likelihood of a prominent neutron component in such systems.

Gamma-ray bursts↗

Recent Advances in Radar Polarimetry and Polarimetric SAR Interferometry

The development of Radar Polarimetry and Radar Interferometry is advancing rapidly, and these novel radar technologies are revamping Synthetic Aperture Radar Imaging decisively. In this exposition the successive advancements are sketched; beginning with the fundamental formulations and high-lighting the salient points of these diverse remote sensing techniques. Whereas with radar polarimetry the textural fine-structure, target-orientation and shape, symmetries and material constituents can be recovered with considerable improvements above that of standard amplitude-only Polarization Radar ; with radar interferometry the spatial (in depth) structure can be explored. In Polarimetric-Interferometric Synthetic Aperture Radar (POL-IN-SAR) Imaging it is possible to recover such co-registered textural plus spatial properties simultaneously. This includes the extraction of Digital Elevation Maps (DEM) from either fully Polarimetric (scattering matrix) or Interferometric (dual antenna) SAR image data takes with the additional benefit of obtaining co-registered three-dimensional POL-IN-DEM information. Extra-Wide-Band POL-IN-SAR Imaging - when applied to Repeat-Pass Image Overlay Interferometry - provides differential background validation and measurement, stress assessment, and environmental stress-change monitoring capabilities with hitherto unattained accuracy, which are essential tools for improved global biomass estimation. More recently, by applying multiple parallel repeat-pass EWB-POL-D(RP)-IN-SAR imaging along stacked (altitudinal) or displaced (horizontal) flight-lines will result in Tomographic (Multi- Interferometric) Polarimetric SAR Stereo-Imaging , including foliage and ground penetrating capabilities. It is shown that the accelerated advancement of these modern EWB-POL-D(RP)-IN-SAR imaging techniques is of direct relevance and of paramount priority to wide-area dynamic homeland security surveillance and local-to-global environmental ground-truth measurement and validation, stress assessment, and stress-change monitoring of the terrestrial and planetary covers. In addition, various closely related topics of (i) acquiring additional and protecting existing spectral windows of the Natural Electromagnetic Spectrum (NES) pertinent to Remote Sensing; (ii) mitigating against common "Radio Frequency Interference (RFI)" and intentional Directive Jamming of Airborne & Space borne POL-IN-SAR Imaging Platforms are appraised.

Boerner, Wolfgang-Martin↗

The PolCube CubeSat Polarimeter for Earth Science

PolCube is a 12U CubeSat + polarimeter instrument designed by NASA Langley and the Korea Astronomy and Space Science Institute (KASI) for Earth Science. PolCube is based on the PolCam polarimeter onboard the Korean Pathfinder Lunar Observatory (KPLO) that launched in August 2022. The objective of the PolCube instrument is to retrieve detailed fine-mode (pollution and smoke) and coarse-mode (sea-salt and dust) aerosol properties over the ocean for a range of light to heavy aerosol loadings using its polarimetric-imaging capability at multiple angles and wavelengths from 410 − 865 nm. An additional objective is to discriminate aerosols from thin clouds. We quantify the performance of aerosol and ocean remote sensing products from the PolCube polarimeter instrument using the Microphysical Aerosol Properties from Polarimetry (MAPP) remote sensing retrieval algorithm. PolCube’s accurate and high-resolution aerosol-retrieval products will provide unique spatial and temporal coverage of the Earth that can be used synergistically with other instruments, such as the PACE (Plankton, Aerosols, Clouds and Ecosystems) and GEMS (Geostationary Environmental Monitoring Spectrometer) mission to improve air-quality forecasting. We present the PolCube-MAPP retrieval algorithm, which used optimal estimation and artificial intelligence, as well as multiple powerful inherent optical property look-up-tables for the Earth’s aerosol, cloud, and hydrosol particles. We estimate that PolCube can retrieve total aerosol optical depth at 555 nm (AOD555) within ±0.068, fine-mode AOD555 within ±0.078, and fine-mode single-scattering albedo within ±0.036, where all uncertainties are expressed as one standard deviation (1σ).

Snorre Stamnes↗

Airborne Spectral Measurements of Surface-Atmosphere Anisotropy for Skukuza and Mongu Sites

The Cloud Absorption Radiometer (CAR) was flown aboard the University of Washington Convair CV-580 research aircraft and took measurements on 23 flights between August 15 and September 16. On 12 of those flights, BRF (bidirectional reflection function) measurements were obtained over different natural surfaces and ecosystems in southern Africa. The BRF measurements were done to characterize surface anisotropy in support of SAFARI 2000 science objectives principally to validate products from NASA's EOS (Earth Observing System) satellites, and to parameterize and validate BRF models. In this paper we present results of BRFs taken over two EOS validation sites: Skukuza tower, South Africa (25.0 S, 31.5 E) and Mongu tower, Zambia (15.4 S, 23.3 E). The CAR is capable of measuring scattered light in fourteen spectral bands. The scan mirror, rotating at 100 rpm, directs the light into a Dall-Kirkham telescope where the beam is split into nine paths. Eight light beams pass through beam splitters, dichroics, and lenses to individual detectors (0.34-1.27 microns), and finally are registered by eight data channels. They are sampled simultaneously and continuously. The ninth beam passes through a spinning filter wheel to an InSb detector cooled by a Stirling cycle cooler. Signals registered by the ninth data channel are selected from among six spectral channels (1.55-2.30 microns). The filter wheel can either cycle through all six spectral bands at a prescribed interval (usually changing filter every fifth scan line), or lock onto any one of the six spectral bands and sample it continuously. To measure the BRF of the surface-atmosphere system, the University of Washington CV-580 had to bank at a comfortable roll angle of approximately 20 degrees and fly in a circle about 3 km in diameter above the surface for roughly two minutes. Replicated observations (multiple circular orbits) were acquired over selected surfaces so that average BRF smooth out small-scale surface and atmospheric inhomogeneities. At an altitude of 600 m above the targeted surface area and with a 1 degree IFOV, the pixel resolution is about 10 m at nadir and about 270 m at an 80 degree viewing angle from the CAR.

Gatebe, C. K.↗

Airborne spectral Measurements of Surface-Atmosphere Anisotropy for Several Surfaces and Ecosystem over Southern Africa

The Cloud Absorption Radiometer (CAR) was flown aboard the University of Washington Convair CV-580 research aircraft and took measurements on 23 flights between August 15 and September 16. On 12 of those flights, BRF measurements were obtained over different natural surfaces and ecosystem in southern Africa. The BRF measurements were done to characterize surface anisotropy in support of SAFARI 2000 science objectives principally to validate products from NASA's EOS satellites, and to parameterize and validate BRF models. In this paper we present results of BRFs taken over two EOS validation sites: Skukuza tower, South Africa (25.0 deg S, 31.5 deg E) and Mongu tower, Zambia (15.4 deg S, 23.3 deg E). Additional sites are also considered and include, Maun tower, Botswana (20.0 deg S, 23.5 deg E), Sowa Pan, Botswana (20.6 deg S, 26.2 deg E) and Etosha Pan, Namibia (19.0 deg S, 16.0 deg E). The CAR is capable of measuring scattered light in fourteen spectral bands. The scan mirror, rotating at 100 rpm, directs the light into a Dall-Kirkham telescope where the beam is split into nine paths. Eight light beams pass through beam splitters, dichroics, and lenses to individual detectors (0.34-1.27 micrometers), and finally are registered by eight data channels. They are sampled simultaneously and continuously. The ninth beam passes through a spinning filter wheel to an InSb detector cooled by a Stirling cycle cooler. Signals registered by the ninth data channel are selected from among six spectral channels (1.55-2.30 micrometers). The filter wheel can either cycle through all six spectral bands at a prescribed interval (usually changing filter every fifth scan line), or lock onto any one of the six spectral bands and sample it continuously. To measure the BRF of the surface-atmosphere system, the University of Washington CV-580 had to bank at a comfortable roll angle of approximately 20 degrees and fly in a circle about 3 km in diameter above the surface for roughly two minutes. Replicated observations (multiple circular orbits) were acquired over selected surfaces so that average BRF smooth out small-scale surface and atmospheric inhomogeneities. At an altitude of 600 m above the targeted surface area and with a 1 deg IFOV, the pixel resolution is about 10 m at nadir and about 270 m at an 80 deg viewing angle from the CAR.

Gatebe, Charles K.↗

Atmospheric Instrument Systems and Technology in the Goddard Earth Sciences Division

Studies of the Earth’s atmosphere require a comprehensive set of observations that rely on instruments flown on spacecraft, aircraft, and balloons as well as those deployed on the surface. Within NASA’s Goddard Space Flight Center (GSFC) Earth Sciences Division-Atmospheres, laboratories and offices maintain an active program of instrument system development and observational studies that provide: 1) information leading to a basic understanding of atmospheric processes and their relationships with the Earth’s climate system, 2) prototypes for future flight instruments, 3) instruments to serve as calibration references for satellite missions, and 4) instruments for future field validation campaigns that support ongoing space missions. Our scientists participate in all aspects of instrument activity, including component and system design, calibration techniques, retrieval algorithm development, and data processing systems. The Atmospheres Program has well-equipped labs and test equipment to support the development and testing of instrument systems, such as a radiometric calibration and development facility to support the calibration of ultraviolet and visible (UV/VIS), space-borne solar backscatter instruments. This document summarizes the features and characteristics of 46 instrument systems that currently exist or are under development. The report is organized according to active, passive, or in situ remote sensing across the electromagnetic spectrum. Most of the systems are considered operational in that they have demonstrated performance in the field and are capable of being deployed on relatively short notice. Other systems are under study or of low technical readiness level (TRL). The systems described herein are designed mainly for surface or airborne platforms. However, two Cubesat systems also have been developed through collaborative efforts. The Solar Disk Sextant (SDS) is the single balloon-borne instrument. The lidar systems described herein are designed to retrieve clouds, aerosols, methane, water vapor pressure, temperature, and winds. Most of the lasers operate at some wavelength combination of 355, 532, and 1064 nm. The various systems provide high sensitivity measurements based on returns from backscatter or Raman scattering including intensity and polarization. Measurements of the frequency (Doppler) shift of light scattered from various atmospheric constitutes can also be made. Microwave sensors consist of both active (radar) and passive (radiometer) systems. These systems are important for studying processes involving water in various forms. The dielectric properties of water affect microwave brightness temperatures, which are used to retrieve atmospheric parameters such as rainfall rate and other key elements of the hydrological cycle. Atmosphere radar systems operate in the range from 9.6 GHz to 94 GHz and have measurement accuracies from -5 to 1 dBZ; radiometers operate in the 50 GHz to 874 GHz range with accuracies from 0.5 to 1 degree K; conical and cross-track scan modes are used. Our passive optical sensors, consisting of radiometers and spectrometers, collectively operate from the UV into the infrared. These systems measure energy fluxes and atmospheric parameters such as trace gases, aerosols, cloud properties, or altitude profiles of various species. Imager spatial resolution varies from 37 m to 400 m depending on altitude; spectral resolution is as small as 0.5 nm. Many of the airborne systems have been developed to fly on multiple aircraft.

Platnick, Steven E.↗

Voyager Photometry of Saturn's A Ring

Saturn's A Ring samples a wide range of dynamical environments, from the relatively unperturbed, optically thick inner region to the outer part of the ring, which contains numerous density waves. We analyze Voyager images of the A Ring to determine how the reflectivity of different radial regions varies with lighting and viewing geometry. We model our data with a classical radiative transfer code that includes the illumination of the rings by the Sun and Saturn. The particles in the inner and mid-A Ring have Bond albedos near 0.5 and are more backscattering than satellites of comparable albedo. The region outside the Encke Gap becomes progressively less backscattering with increasing radius. Particle properties change abruptly outside the Keeler Gap; particles here have an albedo near 0.6 and a Lambert-like phase function. In contrast with previous suggestions, the abundance of free, submicrometer "dust" is small throughout the entire A Ring; this conclusion holds even in the outermost A Ring, which is strongly perturbed by density waves. Models derived from low-phase data, assuming only macroscopic particles, correctly predict the highphase reflectivity of the outer A Ring and individual strong density waves in the mid-A Ring. However, the inner and mid-A Ring are typically darker at high phase by a factor of two than our models predict. This discrepancy may be due to the reduced multiple scattering from a layer in which the particles are more closely packed. We have also studied the quadrupole azimuthal brightness asymmetry of the A Ring. The asymmetry has a full amplitude of 35% in the mid-A Ring in low-phase Voyager 2 images. We present results on its behavior and possible implications for the structure of the rings. Finally, we compare our results with studies using other data sets to synthesize our current understanding of the nature of the A Ring.

Dones, Luke↗

Broadband Lidar Technique for Precision CO2 Measurement

Presented are preliminary experimental results, sensitivity measurements and discuss our new CO2 lidar system under development. The system is employing an erbium-doped fiber amplifier (EDFA), superluminescent light emitting diode (SLED) as a source and our previously developed Fabry-Perot interferometer subsystem as a detector part. Global measurement of carbon dioxide column with the aim of discovering and quantifying unknown sources and sinks has been a high priority for the last decade. The goal of Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) mission is to significantly enhance the understanding of the role of CO2 in the global carbon cycle. The National Academy of Sciences recommended in its decadal survey that NASA put in orbit a CO2 lidar to satisfy this long standing need. Existing passive sensors suffer from two shortcomings. Their measurement precision can be compromised by the path length uncertainties arising from scattering within the atmosphere. Also passive sensors using sunlight cannot observe the column at night. Both of these difficulties can be ameliorated by lidar techniques. Lidar systems present their own set of problems however. Temperature changes in the atmosphere alter the cross section for individual CO2 absorption features while the different atmospheric pressures encountered passing through the atmosphere broaden the absorption lines. Currently proposed lidars require multiple lasers operating at multiple wavelengths simultaneously in order to untangle these effects. The current goal is to develop an ultra precise, inexpensive new lidar system for precise column measurements of CO2 changes in the lower atmosphere that uses a Fabry-Perot interferometer based system as the detector portion of the instrument and replaces the narrow band laser commonly used in lidars with the newly available high power SLED as the source. This approach reduces the number of individual lasers used in the system from three or more to one - considerably reducing the risk of failure. It also tremendously reduces the requirement for wavelength stability in the source putting this responsibility instead on the Fabry-Perot subsystem.

Heaps, William S.↗

Portable, Low-Cost, Column Carbon Dioxide and Methane Measurements for Validating Satellite Observations in Remote Locations

We present a low-cost (~$10K per instrument), portable solution to ground-based validation of satellite observations for difficult to reach locations with precisions of 1 ppm XCO2 and 10 ppb XCH4 for hourly data products. While Total Carbon Column Observing Network (TCCON) is the gold-standard for ground validation, there are locations where a ground column validation data point would be useful but conditions are not conducive to a permanent station. Examples include wetlands, thawing permafrost, the tropics, the Amazon, sub-Saharan Africa, as well as locations without a power grid or with geopolitical conflict. In addition, the low-cost and portability mean a geographical region can be studied in depth with multiple instruments. This passive, sun-pointing instrument is a miniaturized, laser heterodyne radiometer (mini-LHR) that has been under development by our team since 2009. It can be operated either in tandem with AERONET (a global network of 500 instruments that measure aerosol optical depth), or as a stand-alone instrument with a low-cost (~$3K), light-weight sun tracker. One of the main benefits of the mini-LHR is that it can quickly reach remote locations and provide a validation measurement even if there is limited or no infrastructure at the site. The instrument weighs ~10 lbs, fits into a backpack, and is powered by two folding solar panels and a battery pack. In clear conditions, the instrument can be set-up in under an hour. Portability means that mini-LHRs can be easily moved for side-by-side comparisons with other mini-LHRs and with TCCON which simplifies assessing instrument bias as well as accuracy. Like TCCON, the mini-LHR points directly at the sun with a narrow field-of-view and is its insensitivity to cloud and aerosol scattering that is common to nadir-pointing passive satellite approaches. Here we present a collection of sample data sets to demonstrate performance from locations that vary in climate, altitude, solar zenith angle, hours of sun per day, etc., as well as data from side-by-side TCCON comparisons. Retrievals of CO2 and CH4 were completed using the NASA/Goddard's Planetary Spectrum Generator (PSG) that incorporates meteorological inputs from Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2) data set.

Wilson, Emily W.↗

UV Spectropolarimetry with Polstar: Massive Star Binary Colliding Winds

The winds of massive stars are important for their direct impact on the interstellar medium, and for their influence on the final state of a star prior to it exploding as a supernova. However, the dynamics of these winds is understood primarily via their illumination from a single central source. The Doppler shift seen in resonance lines is a useful tool for inferring these dynamics, but the mapping from that Doppler shift to the radial distance from the source is ambiguous. Binary systems can reduce this ambiguity by providing a second light source at a known radius in the wind, seen from orbitally modulated directions. From the nature of the collision between the winds, a massive companion also provides unique additional information about wind momentum fluxes. Since massive stars are strong ultraviolet (UV) sources, and UV resonance line opacity in the wind is strong, UV instruments with a high resolution spectroscopic capability are essential for extracting this dynamical information. Polarimetric capability also helps to further resolve ambiguities in aspects of the wind geometry that are not axisymmetric about the line of sight, because of its unique access to scattering direction information. We review how the proposed MIDEX-scale mission Polstar can use UV spectropolarimetric observations to critically constrain the physics of colliding winds, and hence radiatively-driven winds in general. We propose a sample of 20 binary targets, capitalizing on this unique combination of illumination by companion starlight, and collision with a companion wind, to probe wind attributes over a range in wind strengths. Of particular interest is the hypothesis that the radial distribution of the wind acceleration is altered significantly, when the radiative transfer within the winds becomes optically thick to resonance scattering in multiple overlapping UV lines.

Ultraviolet Astronomy↗

General Approach to Solving Spin Moiré Superstructures

Recently, a host of exciting magnetic textures such as topologically protected skyrmion lattices has been discovered in several bulk metallic lanthanide compounds. In addition to hosting skyrmion phases, a hallmark of this class of materials is the appearance of numerous spin textures characterized by superposition of multiple magnetic modulations: spin moiré superlattices. In order to understand the multitude of complex phases often present in these materials, we require a general-purpose experimental and theoretical framework. Here, we demonstrate such an approach in EuAg4⁢Sb2 by comprehensively characterizing and modeling its three complex zero-field magnetic textures. Systematic symmetry-breaking experiments using uniaxial strain determine that the ground-state incommensurate magnetic phase (ICM1) is single 𝑞, meaning the magnetic moments modulate along one magnetic propagation vector. In contrast, ICM2 and ICM3 are both double 𝑞, meaning they are formed from the superposition of two sinusoidal spin modulations, i.e., spin moiré superlattices. Further, through application of polarized small-angle neutron scattering and spherical neutron polarimetry, we demonstrate that ICM1 is a single-𝑞 cycloid and ICM2 and ICM3 are double-𝑞 vortex lattices. Despite the quasi-two-dimensional nature of EuAg4⁢Sb2, the modulations propagate out of the ab plane, leading to a shift of the spin texture between triangular lattice planes. Further, the ICM3 to ICM2 transition includes an unusual 45° rotation of the magnetic vortex lattice. Motivated by the coexistence of such drastically different phases in this compound, we conclude by developing a phenomenological model that sheds light on the energetic origins of these varied phases. Our experimental probes and theoretical modeling definitively characterize three different and tunable phases in one material and provide insight for the design of topological spin-texture materials.

Neves, Paul [Massachusetts Institute of Technology↗