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At least 271 records · Page 15

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NASA NTRS1972

Predicting spacecraft self-contamination in space and in a test chamber

The self-contamination of a spacecraft, defined as the return and deposition of outgassed molecules on its critical surfaces, was investigaed. Theoretical relations for the flux, density, and pressure of the emitted gas as a function of altitude, radius, and distance from the spacecraft surface were developed. The flux of these outgassed molecules which return to the emitting surface was also obtained and shown to be dependent on altitude, dimensions, and on the magnitude of outgassing. The rate of condensation and the time for the formation of a monolayer of the returning molecules can be calculated. The self-contamination of a spacecraft undergoing vacuum chamber test was also analyzed and compared to the equivalent parameters for the orbital conditions.

Scialdone, J. J.↗

NASA NTRS1972

Predicting spacecraft self-contamination in space and in a test chamber

The self-contamination of spacecraft (defined as the return and deposition of outgassed molecules on its critical surfaces, either in orbit or while undergoing vacuum) is considered. Theoretical relations for the flux, density, and pressure of the emitted gas as a function of altitude, radius, and distance from the spacecraft surface are developed. The flux of the outgassed molecules that return to the emitting surface is also obtained and shown to be dependent on altitude, spacecraft dimensions, and the magnitude of outgassing. The rate of condensation and the time for the formation of a monolayer of the returning molecules can be calculated. The self-contamination of spacecraft undergoing vacuum chamber test is also theoretically examined and compared with the equivalent parameters for orbit conditions. It is concluded that, depending on the dimensions of the spacecraft relative to those of the chamber and the wall capture coefficient, ground tests conducted in the more usual space simulation chambers can provide returning fluxes and self-contamination comparable to those occurring in space up to an altitude of about 400 km. For higher altitudes and return fluxes less than 0.001 of those emitted, the chamber test can produce a greater contamination. In this case, the ground results can be related to those obtained in space, provided that the wall capture coefficient is known or if the ratio of returned to emitted flux at the spacecraft surface is measured.

Scialdone, J. J.↗

NASA NTRS1972

The evaporation of various lubricant fluids in vacuum.

The weight-loss rate in vacuum of 18 lubricating liquids and greases is reported for temperatures up to 120 C. Eleven types of 'medium-viscosity' (20 to 52 centistokes at 40 C) fluids were studied. In addition, a variety of perfluoro ether liquids having viscosities of 350 to 500 centistokes at 40 C were investigated, as were some commercial greases based on these liquids. The results showed that a methylchlorophenyl silicone, a high-viscosity-index perfluoro ether research fluid, and a polyoctene have suitably low outgassing properties for long-term space applicaitons requiring a medium-viscosity lubricant. Perfluoro ether greases also displayed low outgassing, but batch-to-batch variation was great. Mass spectrometer measurements indicated that the outgassed species were characterized by much lower molecular weights than that expected for the liquids. This suggests that lubricant transfer techniques which rely on evaporation from a reservoir may not be desirable for long-term space applications.

Hamilton, D. B.↗

NASA NTRS1974

Gas flow analysis during thermal vacuum test of a spacecraft

The self-contamination of the IMP-H spacecraft, while it was undergoing thermal and solar vacuum tests, has been investigated in conjunction with the outgassing evaluation and detection of molecular flow anomalies occurring in the test chamber. The pressures indicated by two tubulated ionization gauges were used to calculate flow kinetics in the vacuum chamber. The fluxes of emitted molecules and chamber wall reflected molecules were monitored during the entire test. Representative equations and graphs are presented. Test results indicate that from 3 to 9 of every 100 emitted molecules returned to the spacecraft surface; that self-contamination by noncondensable gases was more severe than that by condensable gases; and that outgassing of the spacecraft was approximately 1.18 x 0.01 g/s after 10 hours and 1.18 x 0.001 after 90 hours of vacuum exposure. Testing deficiencies have been identified, and the type and location of instruments required to measure the outgassing, the degree of contamination, and return flow are discussed.

Scialdone, J. J.↗

NASA NTRS1974

Transient desorption of water vapor - A potential source of error in upper atmosphere rocket experiments

Results of measurements of the outgassing rates of samples of materials and surface finishes used on the outer skins of rocket-borne experiment packages in simulated rocket ascents. The results showed outgassing rates for anodized aluminum in the second minute of flight which are two to three orders of magnitude higher than those given in typical tables of outgassing rates. The measured rates for aluminum with chromate conversion surface coatings were also abnormally high. These abnormally high initial rates fell quickly after about five to ten minutes to values comparable with those in the published literature. It is concluded that anodized and chromate conversion coatings on the aluminum outer surfaces of a sounding rocket experiment package will cause gross distortion of the true water vapor environment.

Kendall, B. R. F.↗

NASA NTRS1975

Test evaluation of potential heat shield contamination of an Outer Planet Probe's atmospheric sampling system

An Outer Planets Probe which retains the charred heatshield during atmospheric descent must deploy a sampling tube through the heatshield to extract atmospheric samples for analysis. Once the sampling tube is deployed, the atmospheric samples ingested must be free of contaminant gases generated by the heatshield. Outgassing products such as methane and water vapor are present in planetary atmospheres and hence, ingestion of such species would result in gas analyzer measurement uncertainties. This paper evaluates the potential for, and design impact of, the extracted atmospheric samples being contaminated by heatshield outgassing products. Flight trajectory data for Jupiter, Saturn and Uranus entries are analyzed to define the conditions resulting in the greatest potential for outgassing products being ingested into the probe's sampling system. An experimental program is defined and described which simulates the key flow field features for a planetary flight in a ground-based test facility. The primary parameters varied in the test include: sampling tube length, injectant mass flow rate and angle of attack. Measured contaminant levels predict the critical sampling tube length for contamination avoidance. Thus, the study demonstrates the compatibility of a retained heatshield concept and high quality atmospheric trace species measurements.

Kessler, W. C.↗

NASA NTRS1976

The parameters of a VCM test for the selection of space materials

Materials for space applications must have low outgassing rates at normal operating temperatures and the outgassing products should include a minimum of condensables at the temperatures of nearby surfaces. A screening method, developed years ago, consists of holding a material sample at 398 K (125 C) for 24 hours and measuring its percentage total mass loss (TML) and the percentage volatile condensable mass (VCM) accreted on a 298 K (25 C) collector. In general, the material is acceptable if the TML is less than 1 percent and the VCM is less than 0.1 percent. This paper presents an analysis of the test and its results. It shows that the results of TML and VCM can be used to provide data on outgassing rates and to derive an 'equivalent activation energy' for the material. The energy variables are needed for the calculation of pressure in compartments, the molecular contamination of critical surfaces, and other problems in molecular flow and surface physics. The analysis points out the criticality of the test and its limits with regards to the detection of condensables from certain materials.

Scialdone, J. J.↗

NASA NTRS1978

Techniques used for limiting degradation products of polymeric materials for use in the space environment

Techniques are discussed for limiting or controlling the degradation products (outgassing) of polymeric materials in the space environment. One technique, now ASTM E-595-77, is used to screen out those materials which lose greater than 1% Total Mass Loss when in vacuum for 24 hours at 125 C and which have more than 0.10% Collected Volatile Condensable Materials condensing on a collector surface at 25 C. Examples of silicone materials which are high and low in outgassing are given. The numerous mechanical motions in spacecraft experiments require liquid lubricants which also might degrade in space. Labyrinth seals and barrier films are utilized to limit the degradation of or from these lubricants. A recoverable in-flight experiment has been proposed for making definitive measurements of how effective these techniques are in limiting the amounts and escape paths of outgassed molecules.

Vest, C. E.↗

NASA NTRS1977

Kinetics data for diffusion of outgas species from RTV 560

A detailed analytical and experimental study was made of the outgassing behavior of RTV 560 silicone rubber. The four outgas species which predominate in the temperature range of 285 K to 425 K were separately identified. The initial concentration of these species in the parent material and their bulk volatilities were determined. The diffusion coefficients and activation energy for diffusion of the two major species were deduced from outgassing rate data. It is shown that by using these data in a diffusion theory model, the outgassing rates of these major species can be predicted for arbitrary geometry and any temperature within the range studied.

Liu, C. K.↗

NASA NTRS1982

A preliminary assessment of the self-induced environment and contamination of the Space Telescope

Preliminary estimates for the internal pressures and surface contamination of the Space Telescope were made. The calculations for the transient pressures in the aft-shroud and telescope compartments considered two large communicating volumes that contain gaseous sources and sinks. The outgassing sources in the aft shroud consist of several scientific instruments, paints, insulations, and graphite-epoxy structures. With the exception of the instruments, these sources also exist in the telescope compartment. the outgassing functions were generated from ample test results at various temperatures and from internal pressure measurements in a vacuum test of one of the instruments. The venting occurs through combinations of series and parallel passages in both compartments. The calculated time constant of the two volumes and their respective passages, with the telescope protective door closed, is a few seconds, which is slightly less than that of the shuttle bay volume with the bay doors closed. With the telescope door closed, the pressures in the two compartments should decay to about 1OE-5 torr in about 200 hours. The contaminant deposits were assessed on the basis of expected partial pressures of the contaminant fraction of the outgassing. These pressures and the activation energies of the source materials were used to calculate the adsorbed and condensed deposits on the surfaces as a function of time.

Scialdone, J. J.↗

NASA NTRS1981

Spacecraft contamination prediction and testing techniques

Techniques used in the prediction of spacecraft contamination for the Galileo Jupiter Orbiter and in the determination of the effects of such contamination are presented. Following a quick-look assessment of the contributions of ground-based initial contaminant loading, launch vehicle interface effects, vacuum-exposed outgassing deposition and attitude control thruster impingement and venting to the spacecraft contamination burden, the evaluations centered on the effects of the attitude control thruster on the scan platform optics, including calculations of thruster flowfields and a high-fidelity computer simulation of contaminant distribution. The evaluations revealed a considerable problem with thruster contamination, which could be solved by the use of a thrust shield and the avoidance of thruster operation at certain scan platform orientations. The effects of the various possible contaminants on spacecraft thermal and optical system performances were also investigated in studies of the optical transmittance of deposited monomethyl hydrazine nitrate, vacuum optical degradation due to contaminant outgassing and re-emission outgassing, and an operational satellite contaminant monitor on the NOAA-C satellite. It is concluded that with a good evaluation and testing program, contamination control may become a necessary portion of system design procedures, and recommendations for the implementation of various practices and tests to minimize contamination effects are presented.

Jeffery, J. A.↗

NASA NTRS1986

A study of the possible effect of a thermal post cure on the mechanical properties of the 404 carbon-phenolic ring of the space shuttle solid rocket motor nozzle

Erratic pockets of erosion have occurred on the inner perimeter of the 404 rocket nozzle ring during liftoff firing. It is thought that it may be caused by pockets of volatile matter entrapped during manufacture. A thermal post cure was suggested as a possible means of outgassing such pockets, if they in fact do exist. To confirm an outgassing during a post cure and to establish a working upper temperature limit, thermal gravimetric and differential calorimetric analyses were made on a number of samples from two 404 rings supplied by the manufacturer. Continuous weight loss was observed over the temperature range explored (750 F) indicating outgassing, and a strong exothermic reaction occurs beginning about 390 F. Thus, an upper post cure temperature of 350 F is recommended. To determine the possible effect of a post cure on physical properties, the following tests will be made on matched sets of cured and post cured material: x-radiography (internal structure), linear dimensions, weight, porosity, cross ply thermal expansion, drop and double notch shear strengths, and tensional strength in the ply direction.

Giardini, A. A.↗

NASA NTRS1986

Physical interpretations from the motions of comets Halley and Giacobini-Zinner

For comets Halley and Giacobini-Zinner (GZ), the model of the rocket-like, outgassing forces affecting the comet motion is shown to be consistent with the vaporization of water ice from the comet nuclei. For comet GZ, the dramatic time dependence of the outgassing forces suggests that this comet's spin axis passed through the orbit plane in the mid 1960's. Modeling of Halley's motion over two millennia indicates that the comet is rotating in a direct sense, with no obvious long-term time dependence in the average outgassing forces. The precession of the spin pole axis is not apparent. Secular changes in the comet's angular elements show no evidence for a ring of comet-like material beyond the orbit of Neptune. An obvious 1986 postperihelion bias in comet Halley's observation residuals is modeled by assuming a radial center-of-light/center-of-mass offset.

Yeomans, D. K.↗

NASA NTRS1990

Spacecraft thermal blanket cleaning: Vacuum bake of gaseous flow purging

The mass losses and the outgassing rates per unit area of three thermal blankets consisting of various combinations of Mylar and Kapton, with interposed Dacron nets, were measured with a microbalance using two methods. The blankets at 25 deg C were either outgassed in vacuum for 20 hours, or were purged with a dry nitrogen flow of 3 cu. ft. per hour at 25 deg C for 20 hours. The two methods were compared for their effectiveness in cleaning the blankets for their use in space applications. The measurements were carried out using blanket strips and rolled-up blanket samples fitting the microbalance cylindrical plenum. Also, temperature scanning tests were carried out to indicate the optimum temperature for purging and vacuum cleaning. The data indicate that the purging for 20 hours with the above N2 flow can accomplish the same level of cleaning provided by the vacuum with the blankets at 25 deg C for 20 hours, In both cases, the rate of outgassing after 20 hours is reduced by 3 orders of magnitude, and the weight losses are in the range of 10E-4 gr/sq cm. Equivalent mass loss time constants, regained mass in air as a function of time, and other parameters were obtained for those blankets.

Scialdone, John J.↗

NASA NTRS1992

Organic contamination of LDEF

A brown stain of varying thickness was present on most of the exterior surface of the retrieved Long Duration Exposure Facility (LDEF). Tape lifts of Earth-end LDEF surfaces taken in Feb. 1990 showed that the surface particle cleanliness immediately after retrieval was very good, but faint footprints of the tape strips on the tested surfaces indicated a very faint film was removed by the tape. Solvent wipes of these surfaces showed that the stain was not amenable to standard organic solvent removal. Infrared spectra of optical windows from tray E5 and scrapings indicate that the film is primarily of organic composition, but is not similar to the oil that seeped from tray C12. Very dark and heavy deposits of the stain are present at openings and vents to the interior of the LDEF. Heavy brown and blue-green deposits are present in the interior of LDEF where sunlight penetrated through cracks and vent openings. Photographs of the deintegrated LDEF graphically show the stain distribution. The exterior of the LDEF had significant areas painted with a white polyurethane paint for thermal control, and almost all of the interior was painted with a black polyurethane paint for thermal control. The brown staining of the LDEF is consistent with long-term outgassing of hydrocarbons from these paints followed by rapid solar-ultraviolet-induced polymerization of the outgassed hydrocarbons when the outgassed molecules stuck to surfaces exposed to sunlight.

Harvey, Gale A.↗

NASA NTRS1992

Spacecraft thermal blanket cleaning - Vacuum baking or gaseous flow purging

The mass losses and the outgassing rates per unit area of three thermal blankets consisting of various combinations of Mylar and Kapton, with interposed Dacron nets, were measured with a microbalance using two methods. The blankets at 25 deg C were either outgassed in vacuum for 20 hours, or were purged with a dry nitrogen flow of 3 cu. ft. per hour at 25 deg C for 20 hours. The two methods were compared for their effectiveness in cleaning the blankets for their use in space applications. The measurements were carried out using blanket strips and rolled-up blanket samples fitting the microbalance cylindrical plenum. Also, temperature scanning tests were carried out to indicate the optimum temperature for purging and vacuum cleaning. The data indicate that the purging for 20 hours with the above N2 flow can accomplish the same level of cleaning provided by the vacuum with the blankets at 25 deg C for 20 hours. In both cases, the rate of outgassing after 20 hours is reduced by 3 orders of magnitude, and the weight losses are in the range of 10E-4 gr/sq cm. Equivalent mass loss time constants, regained mass in air as a function of time, and other parameters were obtained for those blankets.

Scialdone, John J.↗

NASA NTRS1994

Self contamination effects in the TAUVEX UV Telescope: Ground testing and computer simulation

The contamination effects due to outgassing from construction materials of the TAUVEX (Tel Aviv University UV Telescope) were evaluated using a combination of ground testing and computer simulations. Tests were performed from the material level of the system level including: (1) High sensitivity CVCM(10(exp -3 percent) measurements of critical materials. (2) Optical degradation measurements of samples specially contaminated by outgassing products at different contamination levels. (3) FTIR studies of chemical composition of outgassed products on above samples. (4) High resolution AFM studies of surface morphology of contaminated surfaces. The expected degradation of TAUVEX performance in mission was evaluated applying a computer simulation code using input parameters determined experimentally in the above tests. The results have served as guidelines for the proper selection of materials, cleanliness requirements, determination of the thermal conditions of the system and bakeout processes.

Lifshitz, Y.↗

NASA NTRS1994

He, Xe and Ne isotopes in a steady-state mass transport model and implications about terrestrial volatiles

We present a model of the steady-state transport assuming three reservoirs: a lower mantle (P) with a relatively undepleted inventory of U, Th, Pu, I, He, Ne, Xe, Ar; an upper mantle that has been extensively outgassed (D); and the atmosphere. There is mass transport at a rate M(sub PD) by plumes from the lower mantle, a fraction of which is outgassed directly into the atmosphere, while the remainder feeds matter and associated nuclei into D. D is well outgassed at spreading centers and has material containing atmospheric gases added to it by subduction. In the case of He, there is no subduction component. The approach follows the treatment of Kellogg and Wasserburg. A summary of the pertinent equations and constraints was reported earlier. The U, Th and Pu in P are estimated for Earth models from refractory element abundances in meteorites. In this model the inventory of rare gases in D is governed by the simple mixing of components from P (both radiogenic and original) with distinctive atmospheric components. In addition, alpha decay and spontaneous fission of U, and (alpha, n) reaction on oxygen from energetic alpha particles produce radiogenic/nuclear daughter products in D. These include (4)He, (136)Xe and (21)Ne. (40)K in D generates excess radiogenic (40)Ar.

Wasserburg, G. J.↗