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At least 271 records · Page 15

Conditional Pseudo-Reversible Normalizing Flow for Surrogate Modeling in Quantifying Uncertainty Propagation

We introduce a conditional pseudo-reversible normalizing flow (PR-NF) that directly learns conditional probability distributions from noisy physical models to efficiently quantify both forward and inverse uncertainty propagation. Traditional surrogate modeling approaches approximate only the deterministic component of physical models, requiring separate noise characterization and computationally expensive sampling methods for inverse problems. Here, in this work, we develop the conditional PR-NF model to directly learn and efficiently generate samples from the conditional probability density functions (PDFs). The training process utilizes dataset consisting of input-output pairs without requiring prior knowledge about the noise and the function. Once trained, our model efficiently generates samples from conditional PDFs for any input within the training domain. Moreover, the pseudo-reversibility feature allows for the use of fully connected neural network architectures, which simplifies the implementation and enables theoretical analysis. We provide a rigorous convergence analysis of the conditional PR-NF model, showing its ability to converge to the target conditional PDF using the Kullback−Leibler divergence. To demonstrate the effectiveness of our method, we apply it to several benchmark tests and a real-world geologic carbon storage problem.

97 MATHEMATICS AND COMPUTING↗

Grain Boundary Segregation Suppresses Local Short‐Range Ordering in Nanocrystalline High‐Entropy Alloys

Multi-principal-element alloys like high-entropy alloys (HEAs) have potential applications in many engineering fields due to their unique mechanical/functional properties. While HEAs are generally considered random solid solutions, recent studies revealed that they are prone to short-range-ordering (SRO) due to the complex multi-pair-wise interactions among the constituent elements. Meanwhile, SROs' evolution can sometimes be deleterious, and it is necessary to have control over their evolution. Examining the AlCoCrFe-Zr model alloy, long-range ordering occurs following the expectation of enthalpic predictions. Advanced characterization techniques—transmission electron microscopy, high-energy synchrotron X-ray diffraction/pair distribution function, and atom probe tomography, reveal that SRO is suppressed in as-milled and GB-decorated NC-(AlCoCrFe)100-xZrx (x = 0–1.5 atomic %). Warren-Cowley coefficient calculations are further used to validate the suppression of SRO. Besides the low segregation enthalpies of Cr, Fe, and Zr, and the high-mixing enthalpy of Cr and Fe, the short diffusion path to GBs due to high-GB density in the NC-HEAs and the higher energy state of the GBs than the matrix promotes GB-segregation that further alters the matrix chemistry and consequently disfavors SRO formation within the matrix. Despite the GB-segregation of Cr, Fe, and Zr, the matrices and GBs remain in a random solid solution.

36 MATERIALS SCIENCE↗

An improved cloud retrieval algorithim using HIRS2-MSU radiance measurements

Cloud-top heights and cloud amounts are produced as part of the operational processing of polar-satellite data at the National Environmental Satellite Data and Information Service (NESDIS). These products were compared with similar products from the air force's real-time nephanalysis (RTNEPH), from the International Satellite Cloud Climatology Project, and from NASA Goddard's processing of satellite data. It was found that the amount of high-level cloud was too small in the NESDIS results, while the amount of low-level cloud was too large. An examination of the NESDIS algorithm revealed that the differences in cloud distributions were caused by the selection of channels used for the cloud retrievals. Cloud retrievals are most accurate at the levels at which the channels that are used are most sensitive. In addition, it was found that no one pair of channels was best at all levels. A new procedure was developed that varied the channels as a function of an initial estimate of the cloud height. This procedure produced improved cloud retrievals that were then compared with the RTNEPH results. The comparison showed that the two methods provide similar retrievals of cloud height and amount.

Mcmillin, Larry↗

The analysis of ensembles of moderately saturated interstellar lines

It is shown that the combined equivalent widths for a large population of Gaussian-like interstellar line components, each with different central optical depths tau(0) and velocity dispersions b, exhibit a curve of growth (COG) which closely mimics that of a single, pure Gaussian distribution in velocity. Two parametric distributions functions for the line populations are considered: a bivariate Gaussian for tau(0) and b and a power law distribution for tau(0) combined with a Gaussian dispersion for b. First, COGs for populations having an extremely large number of nonoverlapping components are derived, and the implications are shown by focusing on the doublet-ratio analysis for a pair of lines whose f-values differ by a factor of two. The consequences of having, instead of an almost infinite number of lines, a relatively small collection of components added together for each member of a doublet are examined. The theory of how the equivalent widths grow for populations of overlapping Gaussian profiles is developed. Examples of the composite COG analysis applied to existing collections of high-resolution interstellar line data are presented.

Jenkins, E. B.↗

Observation of $t\overline{t}$ production in the lepton+jets and dilepton channels in p+Pb collisions at $\sqrt{s_{\textrm{NN}}}$ = 8.16 TeV with the ATLAS detector

This paper reports the observation of top-quark pair production in proton-lead collisions in the ATLAS experiment at the Large Hadron Collider. The measurement is performed using 165 nb -1 of p+Pb data collected at $\sqrt{^sNN}$ = 8.16 TeV in 2016. Events are categorised in two analysis channels, consisting of either events with exactly one lepton (electron or muon) and at least four jets, or events with two opposite-charge leptons and at least two jets. In both channels at least one b-tagged jet is also required. Top-quark pair production is observed with a significance over five standard deviations in each channel. The top-quark pair production cross-section is measured to be σ $t\overline{t}$ =58.1 ± 2.0(stat.)$^{+4.8}_{-4.4}$(syst.) nb, with a total uncertainty of 9%. In addition, the nuclear modification factor is measured to be R pA = 1.090 ± 0.039(stat.)$^{+0.094}_{-0.087}$(syst.). The measurements are found to be in good agreement with theory predictions involving nuclear parton distribution functions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

CO 2 Capture Characteristics of Hyperbranched Poly(alkylene imine): A Molecular Dynamics Simulation Approach

This study explores the CO 2 capture characteristics of hyperbranched poly(ethylenimine) (HB-PEI) and poly- (propyleneimine) (HB-PPI) through molecular dynamics simulations using density functional theory-calibrated force fields. Key features such as density, free volume, glass transition temperature, CO 2 /H 2 O distribution, and molecular diffusion are systematically investigated to elucidate structure−function relationships under dry and hydrated conditions. HB-PEI demonstrates a slightly higher density and lower free volume compared to HB-PPI yet shows superior CO 2 capture due to the high amine concentration. Glass transition analysis indicates a higher thermal mobility in HBPEI, enhancing the CO 2 diffusivity. Pair correlation and coordination analyses confirm a stronger affinity of CO 2 with primary and secondary amines, particularly in hydrated environments where water competes with CO 2 for binding sites. Despite its more compact structure, HB-PEI outperformed HB-PPI in CO 2 and H 2 O transport, as confirmed by higher diffusion coefficients across all hydration levels. These findings highlight a critical balance among polymer architecture, amine accessibility, and hydration in designing next-generation solid amine sorbents for efficient direct air capture applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Designing a quantum-accurate machine-learning potential to enable large-scale simulations of deuterium under shock

Large-scale molecular dynamics of deuterium under shock can elucidate kinetic processes vital to the target design in inertial confinement fusion and high-energy-density experiments. However, modeling the complex evolution of this material from an insulating molecular state at ambient pressure to an ionized, atomic fluid under strong shock is beyond the capability of simple pair and even bond order potentials. We thus train a quantum-accurate and broadly transferable machine-learning interatomic potential for deuterium using the Chebyshev Interaction Model for Efficient Simulations framework. We show that due to an improved description of the molecular-to-atomic transition, our model is able to better reproduce the ab initio equation of state, radial distribution functions, and principal Hugoniot than bond order potentials. This represents an important step toward large-scale quantum-accurate and nonequilibrium simulations of complicated systems under dynamic changes including phase transitions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Solid earth as a recycling systems and the lateral growth of Precambrian North America

If plotted on mass vs time diagrams, geologic entities (for example, continental and oceanic crust, sediments, and mineral resources) display an exponential (power law) relationship, with entity per unit time increasing toward the present. This relationship is consistent with the concept of recycling and can be simulated mathematically. The approach is based on the plate tectonic theory and considers area-age or mass-age distributions of crystalline basement and sediments for major global tectonic realms. Each tectonic realm is characterized by a specific lifespan, which is an inverse function of its recycling rate. The estimated average half-area of half-mass ages are given. The corresponding parameters for continental crust are 690 Ma for K/Ar, and approximately 1200 Ma for Rb/St and U-Th/Pb dating pairs. Tectonic diversity preserved in the geologic record is therefore a function of time, with oceanic tectonic realms, because of their rapid recycling, underrepresented in the rocks older than approximately 300 Ma. The Sm/Nd isotopic systematic of sediments suggest that, for a near steady-state post-Archean sedimentary mass, recycling is approximately 90 + or - 5 percent cannibalistic. This yields an estimated upper limit on crust-mantle exchange via sediment subduction of approximately 1.1 + or - 0.5 x 10 g a(sup -1) considerably less than demanded by isotopic constraints. The discrepancy may indicate the existence of additional loci, such as orogenic belts, for significant crust-mantle interaction.

Veizer, Jan↗

Coherent γ *-nucleus scattering and coherent nuclear states

In the context of a McLerran-Venugopalan (MV) model for a large nucleus, coherent scattering of a virtual photon on that nucleus is evaluated in the A − = 0 gauge, the gauge appropriate for the target nucleus. The evaluation of the scattering in A − = 0 gauge is very intricate compared to the usual A + = 0 gauge evaluation natural for the scattering process, but has the advantage of directly giving the scattering in terms of a partonic description of the nucleus. In the limit where a tagged forward jet puts the dipole-nucleus scattering in the saturation regime the coherent reactions are equal to the inelastic reactions. In terms of the nuclear wave function the coherent reactions come from color singlet and zero total transverse momentum quark-antiquark pairs in the wave function and in the saturation regime the nuclear wave function is a coherent state for these pairs. In the saturation region half of all quarks (or antiquarks) come from zero momentum and color charge pairs.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Effective Forces Between Colloidal Particles

Colloidal suspensions have proven to be excellent model systems for the study of condensed matter and its phase behavior. Many of the properties of colloidal suspensions can be investigated with a systematic variation of the characteristics of the systems and, in addition, the energy, length and time scales associated with them allow for experimental probing of otherwise inaccessible regimes. The latter property also makes colloidal systems vulnerable to external influences such as gravity. Experiments performed in micro-ravity by Chaikin and Russell have been invaluable in extracting the true behavior of the systems without an external field. Weitz and Pusey intend to use mixtures of colloidal particles with additives such as polymers to induce aggregation and form weak, tenuous, highly disordered fractal structures that would be stable in the absence of gravitational forces. When dispersed in a polarizable medium, colloidal particles can ionize, emitting counterions into the solution. The standard interaction potential in these charged colloidal suspensions was first obtained by Derjaguin, Landau, Verwey and Overbeek. The DLVO potential is obtained in the mean-field linearized Poisson-Boltzmann approximation and thus has limited applicability. For more precise calculations, we have used ab initio density functional theory. In our model, colloidal particles are charged hard spheres, the counterions are described by a continuum density field and the solvent is treated as a homogeneous medium with a specified dielectric constant. We calculate the effective forces between charged colloidal particles by integrating over the solvent and counterion degrees of freedom, taking into account the direct interactions between the particles as well as particle-counterion, counterion-counterion Coulomb, counterion entropic and correlation contributions. We obtain the effective interaction potential between charged colloidal particles in different configurations. We evaluate two- and three-body forces in the bulk as well as study the influence of soft walls. We qualitatively explain the effects of the walls on the forces and demonstrate that many-body effects are negligible in our system. With adjustments in the parameters, the DLVO pair-potential can describe the results quantitatively. Besides electrostatic interactions, entropic depletion effects that arise from (hard-core) exclusion play an important role in determining the behavior of multi-component colloidal suspensions. A standard theory for depletion forces is due to Asakura and Oosawa and is based on the ideal gas approximation. To go beyond this approximation, we have studied entropic forces in molecular dynamics simulations of systems of hard spheres (the effects of the solvent have been ignored). The effective depletion forces for these systems can be found either from equilibrium distribution functions or from direct momentum transfer calculations. Our results obtained by either method show qualitative differences from the Asakura-Oosawa forces, indicating a longer range, higher value at contact and most importantly a more complicated structure, comprising of several maxima and minima. Our calculations include the determination of effective forces between two spheres, a hard sphere and a wall, and the behavior of a hard sphere near a step-edge and a corner. We also demonstrate that such entropic forces do not necessarily satisfy pairwise additivity.

Tehver, Riina↗

An outer gap model of high-energy emission from rotation-powered pulsars

We describe a refined calculation of high-energy emission from rotation-powered pulsars based on the outer gap model of Cheng, Ho, & Ruderman (1986 a, b). In this calculation, vacuum gaps form in regions near the speed-of-light cylinder of the pulsar magnetosphere along the boundary between the closed and open field line zones. We have improved upon previous efforts to model the spectra from these pulsars (e.g., Cheng et al. 1986b; Ho 1989) by following the variation in particle production and radiation properties with position in the outer gap. Curvature, synchotron, and inverse-Compton scattering fluxes vary significantly over the gap, and their interactions via photon-photon pair production build up the radiating charge populations at varying rates. We have also incorporated an approximate treatment of the transport particle and photon fluxes between gap emission zones. These effects, along with improved computations of the particle and photon distribution, provide very important modifications of the model gamma-ray flux. In paticular, we attempt to make specific predictions of pulse profile shapes and spectral variations as a function of pulse phase and suggest further extensions to the model which may provide accurate computations of the observed high-energy emissions.

Chiang, James↗

Stochastic estimation of organized structures in turbulent channel flow

Linear stochastic estimation is used to approximate the conditional vector fields associated with high Reynolds stress producing events in numerically simulated turbulent channel flow. Joint probability density distributions of u-v are presented for y(+) between 1.35 and 180, and at each position the u-v values that make the greatest contributions to the average uv3 are used to define conditional ejection- and sweep-type events. In the y-z plane the conditional fields appear to be pairs of counter-rotating vortices. When the conditional event defined by the weighted probability density function is specified at a point close to the wall, the spacing and size of these eddies are consistent with the accepted wall streak spacing. As this point moves outwards, the eddy size increases significantly. An abrupt change in the flow angle occurs in the buffer layer and may indicate transition from streamwise oriented wall layer structures to hairpin vortices characterizing the outer layer.

Moin, P.↗

Depth-resolved sagebrush root metabolomics, rhizosphere microbial communities, and geochemistry at the East River Watershed

This data set consists of results from soil nutrient profile, untargeted metabolomics, mass spec imaging, and amplicon sequencing. Data for soil nutrient profile includes common cations (Ca, Mg, Na, and K etc.) extracted from 3 digesting steps – ammonia acetate (for exchangeable cations), nitric acid (for acid dissolved fraction), and hydrofluoric acid/perchloric acid (HF/HClO4) for whole soil digestion. It also includes concentration of organic carbon, inorganic nitrogen (ammonia and nitrate) and phosphorus (Bray-1 P and nitric acid extract), and total nitrogen and phosphorus. Data for untargeted metabolomics includes metabolomic profile for root exudate/tissues and soil extracts from depths at surface soil to saprolite, that were measured using gas chromatography – mass spectrometry (GC-MS), and liquid chromatography – tandem mass spectrometry (LC-MS/MS). Data for mass spec imaging includes spatial distribution of metabolites that were detected and annotated with Fourier transformation ion cyclotron resonance mass spectrometer (FTICR-MS). Data for amplicon sequencing includes the base paired 16S and ITS ribosomal RNA sequences from Miseq Illumina sequencing. All samples were collected from 2 sampling campaign October 2022 and June 2023. Collectively, these datasets enable a mechanistic evaluation of how nutrient acquisition, especially nitrogen and phosphorus, differs between shallow roots operating in soil and deep roots functioning within the fractured bedrock zone. All files are provided as comma-separated values (CSV) fies (.csv) and (GZIP) file (.gz). The compressed .gz FASTQ files can be read directly in R using the dada2 package as part of the amplicon sequence analysis workflow. This work was supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231. This research was performed on a project award 60563 (https://dx.doi.org/10.46936/expl.proj.2022.60563/60008727) from the Environmental Molecular Sciences Laboratory, a DOE Office of Science User Facility sponsored by the Biological and Environmental Research program under Contract No. DE-AC05-76RL01830.

EARTH SCIENCE > AGRICULTURE > SOILS > CARBON↗

Annihilation radiation from a hot e/+/-e/-/ plasma

The radiation from electron-positron annihilations in a plasma of temperature above 10 to the 8th K is investigated as a possible source of the emission line at energies between 400 and 460 keV frequently seen in gamma-ray bursts. The annihilation rate and luminosity of an optically thin electron-positron plasma and the energy distribution of the resulting annihilation radiation are calculated by the use of a Monte Carlo technique as functions of temperature. Results indicate the annihilation spectrum to be peaked at an energy of 0.511 MeV plus a temperature-dependent blueshift, and the annihilation line to be significantly temperature-broadened. The widths of the observed burst emission lines set an upper limit of 3 x 10 to the 8th K on the temperature of any pair annihilation region in burst sources, which is considerably lower than the typical kinetic temperatures of the radiating particles. It is thus inferred that either the annihilation region is nonthermal, or spatially distinct from the burst site.

Ramaty, R.↗

Step-by-Step Simulation of Radiation Chemistry Using Green Functions for Diffusion-Influenced Reactions

Radiolytic species are formed approximately 1 ps after the passage of ionizing radiation through matter. After their formation, they diffuse and chemically react with other radiolytic species and neighboring biological molecules, leading to various oxidative damage. Therefore, the simulation of radiation chemistry is of considerable importance to understand how radiolytic species damage biological molecules [1]. The step-by-step simulation of chemical reactions is difficult, because the radiolytic species are distributed non-homogeneously in the medium. Consequently, computational approaches based on Green functions for diffusion-influenced reactions should be used [2]. Recently, Green functions for more complex type of reactions have been published [3-4]. We have developed exact random variate generators of these Green functions [5], which will allow us to use them in radiation chemistry codes. Moreover, simulating chemistry using the Green functions is which is computationally very demanding, because the probabilities of reactions between each pair of particles should be evaluated at each timestep [2]. This kind of problem is well adapted for General Purpose Graphic Processing Units (GPGPU), which can handle a large number of similar calculations simultaneously. These new developments will allow us to include more complex reactions in chemistry codes, and to improve the calculation time. This code should be of importance to link radiation track structure simulations and DNA damage models.

Plante, Ianik↗

Measurements of jet cross-section ratios in 13 TeV proton-proton collisions with ATLAS

Measurements of jet cross-section ratios between inclusive bins of jet multiplicity are performed in 140 fb -1 of proton-proton collisions with √s = 13 TeV center-of-mass energy, recorded with the ATLAS detector at CERN’s Large Hadron Collider. These ratios are constructed from double-differential cross-section measurements that are made in bins of jet multiplicity and other observables that are sensitive the energy scale and angular distribution of radiation due to the strong interaction in the final state. Additionally, the scalar sum of the two leading jets’ transverse momenta is measured triple differentially, in bins of the third jet’s transverse momentum and of jet multiplicity. These measurements are unfolded to account for acceptance and detector-related effects. The measured distributions are used to construct ratios of the inclusive jet-multiplicity bins, which have been shown to be sensitive to the strong coupling Formula Presented while being less sensitive than other observables to systematic uncertainties and parton distribution functions. The measured distributions are compared with state-of-the-art QCD calculations, including next-to-next-to-leading-order predictions for two- and three-jet events. These predictions are generally found to model the data well and perform best in bins with a modest requirement on the third jet’s transverse momentum. Significant differences between data and Monte Carlo predictions are observed in events with large rapidity gaps and invariant masses of the leading jet pair. Studies leading to reduced jet energy scale uncertainties significantly improve the precision of this work and are documented herein.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Measurement of isolated prompt photon production in pp and p–Pb collisions at the LHC

This paper presents the measurement of the isolated prompt photon inclusive production cross section in pp and p–Pb collisions by the ALICE Collaboration at the LHC. The measurement is performed in p–Pb collisions at centre-of-mass energies per nucleon pair of $\sqrt{s_{NN}}$ = 5.02 Te and 8.16 TeV, as well as in pp collisions at $\sqrt{s}$ = 5.02 TeV and 8 TeV. The cross section is obtained at midrapidity (|γ| < 0.7) using a charged-track based isolation momentum p$^{iso,~ch}_{T}$ < 1.5 GeV/c in a cone with radius R = 0.4. The data for both collision systems are well reproduced by perturbative QCD (pQCD) calculations at next-to-leading order (NLO) using recent parton distribution functions for free (PDF) and bound (nPDF) nucleons. Furthermore, the nuclear modification factor R pA for both collision energies is consistent with unity for p T > 20 GeV/c. However, deviations from unity (R pA < 1) of up to 20% are observed for p T < 20 GeV/c with limited significance, indicating the possible presence of nuclear effects in the initial state of the collision.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Non-Geiger-Mode Single-Photon Avalanche Detector with Low Excess Noise

This design constitutes a self-resetting (gain quenching), room-temperature operational semiconductor single-photon-sensitive detector that is sensitive to telecommunications optical wavelengths and is scalable to large areas (millimeter diameter) with high bandwidth and efficiencies. The device can detect single photons at a 1,550-nm wavelength at a gain of 1 x 10(exp 6). Unlike conventional single photon avalanche detectors (SPADs), where gain is an extremely sensitive function to the bias voltage, the multiplication gain of this device is stable at 1 x 10(exp 6) over a wide range of bias from 30.2 to 30.9 V. Here, the multiplication gain is defined as the total number of charge carriers contained in one output pulse that is triggered by the absorption of a single photon. The statistics of magnitude of output signals also shows that the device has a very narrow pulse height distribution, which demonstrates a greatly suppressed gain fluctuation. From the histograms of both pulse height and pulse charge, the equivalent gain variance (excess noise) is between 1.001 and 1.007 at a gain of 1 x 10(exp 6). With these advantages, the device holds promise to function as a PMT-like photon counter at a 1,550- nm wavelength. The epitaxial layer structure of the device allows photons to be absorbed in the InGaAs layer, generating electron/hole (e-h) pairs. Driven by an electrical field in InGaAs, electrons are collected at the anode while holes reach the multiplication region (InAlAs p-i-n structure) and trigger the avalanche process. As a result, a large number of e-h pairs are created, and the holes move toward the cathode. Holes created by the avalanche process gain large kinetic energy through the electric field, and are considered hot. These hot holes are cooled as they travel across a p -InAlAs low field region, and are eventually blocked by energy barriers formed by the InGaAsP/ InAlAs heterojunctions. The composition of the InGaAsP alloy was chosen to have an 80 meV valance band offset with InAlAs, which is high enough to hinder the transport of the already cooled holes. Being stopped by the energy barrier, holes are accumulated at the junctions to shield the electric field, resulting in a decrease of the electric field in the multiplication region. Because the impact ionization rate is extremely sensitive to the magnitude of the electric field, the field-screening effect drastically reduces the impact ionization rate and quenches the output signals. After the avalanche pulse signal is self-quenched, the accumulated holes at the InGaAsP/ InAlAs interface escape the energy barrier through thermal excitation and tunneling and finally leave the device. The device is thus reset and ready for subsequent photon detection. This recovery time is controlled by the height of the energy barrier and the hole-cooling rate.

Zhao, Kai↗