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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
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NASA NTRS2018

Mallory Sico - JSC Pathways Intern

Description of tours in ES4, CO5, ER5, CC3 organizations. Presentation outlines aircraft and instrument repairs using visual images and designs.

Sico, Mallory C.↗
NASA NTRS2017

Pathways to Meteoritic Glycine and Methylamine

Glycine and methylamine are meteoritic water-soluble organic compounds that provide insights into the processes that occurred before, during, and after the formation of the Solar System. Both glycine and methylamine and many of their potential synthetic precursors have been studied in astrophysical environments via observations, laboratory experiments, and modeling. Despite these studies, the synthetic mechanisms for their formation leading to their occurrence in meteorites remain poorly understood. Typical 13C-isotopic values ((delta)13C) of meteoritic glycine and methylamine are 13C-enriched relative to their terrestrial counterparts; thus, analyses of their stable carbon isotopic compositions (13C/12C) may be used not only to assess terrestrial contamination in meteorites but also to provide information about their synthetic routes inside the parent body. Here, we examine potential synthetic routes of glycine and methylamine from a common set of precursors present in carbonaceous chondrite meteorites, using data from laboratory analyses of the well-studied CM2 Murchison meteorite. Several synthetic mechanisms for the origins of glycine and methylamine found in carbonaceous chondrites may be possible, and the prevalence of these mechanisms will largely depend on (a) the molecular abundance of the precursor molecules and (b) the levels of processing (aqueous and thermal) that occurred inside the parent body. In this work, we also aim to contextualize the current knowledge about gas-phase reactions and irradiated ice grain chemistry for the synthesis of these species through parent body processes. Our evaluation of various mechanisms for the origins of meteoritic glycine and methylamine from simple species shows what work is still needed to evaluate both the abundances and isotopic compositions of simpler precursor molecules from carbonaceous chondrites as well as the effects of parent body processes on those abundances and isotopic compositions. The analyses presented here combined with the indicated measurements will aid a better interpretation of quantitative analysis of reaction rates, molecular stability, and distribution of organic products from laboratory simulations of interstellar ices, astronomical observations, and theoretical modeling.

interstellar ice↗
NASA NTRS2018

Reworking and Diagenesis of Martian Soil: Pathway to Murray Formation Sediments?

In Gale crater, the Curiosity Mars rover has climbed over 300 meters of the Murray formation from the base of the Pahrump Hills to the crest of Vera Rubin Ridge. We discuss the possibility that fine-grained mudstone of the Murray formation is a diagenetic product of sediments with a chemical and mineralogical composition similar to present-day martian soil. Typical (low Ca-sulfate) Murray samples have Na2O, Al2O3, SiO2, SO3, TiO2 and FeOT concentrations within 10% (relative) of average martian soil. These oxides constitute ~85% of each sample. The Al/Si and Ti/Si ratios of Murray samples are comparable to average martian soil but distinct from other martian geologic units. Percentage difference in P2O5, Cl, K2O, Cr2O3, MnO, Ni, Zn, Br, and Ge between soil and Murray samples generally exceed 10%, but these elements and oxides amount to less than 4% of the samples. These constituents are highly variable in Murray mudstone and may reflect mobility in fluid interactions. Large discrepancies in MgO and CaO with ~50% lower concentrations in the Murray samples (~2% absolute differences) are indicative of open-system alteration if the Murray mudstone originated from soil-like material. Mineralogically, martian soil is dominated by plagioclase feldspar, pyroxenes, and olivine with minor hematite, magnetite, and Ca-sulfate. In comparison, Murray samples generally have less feldspar and pyroxene, little to no olivine, more iron oxides and Ca-sulfates, and Fe-containing phyllosilicates. If Murray mudstone originated from a Mars soil composition, aqueous alteration could have converted olivine and pyroxenes to iron oxides and phyllosilicates. Intermixed or zoned plagioclase feldspars could have lost a larger portion of calcic constituents, consistent with susceptibility to weathering, resulting in a change from ~An55 (soil) to ~An40 (Murray). This alteration could be consistent with the major element chemistry, including the small decrease in MgO and CaO. A subsequent influx of minor/trace elements and Ca-sulfate, e.g. from groundwater, would be required. In this diagenetic scenario, the bulk of the alteration would have been nearly isochemical, suggesting limited mineral segregation and aqueous alteration during transport from the drainage basin or a significant direct aeolian contribution to the Murray sediments.

Yen, Albert S.↗
NASA NTRS2019

Cosmic Pathways for Compact Groups in the Milli-Millennium Simulation

We detected 10 compact galaxy groups (CGs) at z=0 in the semianalytic galaxy catalog of Guo et al. for themilli-Millennium Cosmological Simulation (sCGs in mGuo2010a). We aimed to identify potential canonicalpathways for compact group evolution and thus illuminate the history of observed nearby CGs. By constructingmerger trees for z=0 sCG galaxies, we studied the cosmological evolution of key properties and compared themwith z=0 Hickson CGs (HCGs). We found that, once sCG galaxies come within 1 (0.5) Mpc of their mostmassive galaxy, they remain within that distance until z=0, suggesting sCG "birth redshifts." At z=0 stellarmasses of sCG most massive galaxies are within 1010M*/Me1011. In several cases, especially in the twofour- and five-member systems, the amount of cold gas mass anticorrelates with stellar mass, which in turncorrelates with hot gas mass. We define the angular difference between group members' 3D velocity vectors,vel, and note that many of the groups are long-lived because their small values of vel indicate a significantparallel component. For triplets in particular, vel values range between 20° and 40° so that galaxies are comingtogether along roughly parallel paths, and pairwise separations do not show large pronounced changes after closeencounters. The best agreement between sCG and HCG physical properties is for M* galaxy values, but HCGvalues are higher overall, including for star formation rates (SFRs). Unlike HCGs, due to a tail at low SFR and M*and a lack of M*1011Me galaxies, only a few sCG galaxies are on the star-forming main sequence

Tzanavaris, Panayiotis↗
NASA NTRS2016

Pathways Intern Report 2016

This report is to inform civil engineering students of what it might be like to work for NASA. The report covers the initial construction phases of the Central Campus Replacement Building, the Indian River Bridge Studies, and Construction Branch Management.

Cortes, Daniela↗
NASA NTRS2017

Lunar COTS Mission Concept: Using the Moon's Resources to Enable an Economical and Sustainable Pathway to Mars and Beyond

To support and enable future human missions to the surface of the Moon, a new plan was formulated to gradually develop an economical, evolvable and sustainable lunar infrastructure using a public/private partnerships between NASA and industry to share cost and risk in the development phase and ultimately transfer operation of these infrastructure services to its industry owners. These infrastructure services may include but are not limited to the following: lunar cargo transportation, power stations, energy storage devices, communication towers and relay satellites, and resource extraction operations. The plan is called the Commercial Orbital Transfer Services (COTS) Program, using NASA's well-proven Commercial Orbital Transportation Services (COTS) Program acquisition model.

Zuniga, A. F.↗
NASA NTRS2016

Lunar COTS: Using the Moon's Resources to Enable An Economical and Sustainable Pathway to Mars and Beyond

To support NASAs goal of sending humans to Mars, a new plan was constructed to develop and demonstrate cislunar capabilities and services in partnership with commercial industry using the well-proven Commercial Orbital Transportation Services (COTS) Program acquisition model. The NASA COTS Program was a very successful program that developed and demonstrated cost-effective commercial cargo transportation services to the International Space Station (ISS). As a result of NASAs COTS program, two new launch vehicles and spacecraft were developed and have been successfully performing cargo transportation missions to the ISS since 2012. The COTS acquisition strategy utilized a new model than normally accepted in traditional procurement practices. This new model used Space Act Agreements where NASA entered into partnerships with industry to jointly share cost, development and operational risks to demonstrate new capabilities for mutual benefit. This model proved to be very beneficial to both NASA and its industry partners as NASA saved significantly in development and operational costs, as much as tenfold, while industry partners successfully expanded their market share of the global launch transportation business for significant economic benefit. Using the COTS acquisition model as a basis, a new plan, notionally referred to as Lunar Commercial Orbital Transfer Services (or Lunar COTS), has been developed to determine the potential benefits and challenges of a new Lunar COTS plan[1]. The proposed plan includes low-cost, commercial-enabled missions to prospect for resources, determine the economic viability of extracting those resources and assess the value proposition of using these resources in future exploration architectures such as Mars. These missions would be accomplished in partnership with industry to meet these exploration goals but will also have the capability to carry payloads to meet science goals as well.

Zuniga, Allison↗
NASA NTRS2020

Investigating Relationships Between Geochemistry and Physical Grain Characteristics Along a Glacio-Fluvial-Aeolian Sediment Transport Pathway Using µXRF

Iceland’s basaltic volcanic rocks and glacial, fluvial, and aeolian landscapes resemble those studied on Mars, which makes it an ideal location to study the evolution of basaltic landscapes, the weathering and alteration of basaltic sediments in cold and wet environments, and the generation of a basaltic sedimentary record. The SAND-E: Semi-Autonomous Navigation for Detrital Environments project examines physical and chemical changes in sediments transported through basaltic fluvial and aeolian environments, and tests operational scenarios, which include a drone and a robotic rover instrumented with autonomous terrain analysis software. As part of the SAND-E project, we examined a glacial outwash plain at Skjaldbreiðauhraun, in SW Iceland. This study uses micro X-ray fluorescence (μXRF) to examine the chemical and physical properties of unconsolidated sediment-size fractions from 710 μm to < 63 μm along a downstream transect from a glacial sourced watershed. μXRF is ideally suited for this task because it maps elemental distributions at sub-grain scales thereby allowing a direct correlation between grainsize, grain shape, and chemistry. It is also a good analog technique for the Mars 2020 mission equipped with the PIXL (Planetary Instrument for X-ray Lithochemistry) that will be deployed at Jezero Crater, Mars.

Champion, E.↗
NASA NTRSDate not supplied

Elucidation of Electrolyte Decomposition Pathways in Li--O2 Batteries using Ab Initio Computations

Li-O2 batteries offer exciting possibilities for energy-storage applications requiring higher energy content than current Li-ion battery technologies. However, development of commercial Li-O2 batteries faces many challenges including electrolyte decomposition in order to realize the full potential of this emerging technology. In this work, we present ab initio calculations that probe the role of reactive oxygen species including singlet oxygen, superoxide, and peroxides on electrolyte decomposition for potential organic electrolytes for use in Li-O2 batteries. We investigate the influence that the harsh electrochemical environment near the cathode plays in promoting electrolyte decomposition by using increasingly detailed computational models. Our results highlight existing problems with organic electrolytes for Li-O2 battery development and suggest potential design strategies for reducing electrolyte decomposition.

Li-O2 Batteries↗