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Presence and distribution of heavy metal tolerant fungi in surface soils of a temperate pine forest
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Forestland owners' willingness to plant pine on non-forested land for woody bioenergy in Virginia
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Investigation of hydrothermal carbonization and chemical activation process conditions on hydrogen storage in loblolly pine-derived superactivated hydrochars
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Hydrodeoxygenation upgrading of pine sawdust bio-oil using zinc metal with zero valency
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A density dependent Drucker-Prager/Cap model for ring shear simulation of ground loblolly pine
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Effects of particle size, distribution, and morphology on bulk shear behavior of milled loblolly pine
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Arboriscoccus pini gen. nov., sp. nov., an endophyte from a pine tree of the class Alphaproteobacteria , emended description of Geminicoccus roseus , and proposal of Geminicoccaceae fam. nov.
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Insights into Mechanisms of Screw Feeder Plugging by Heated Pine Forestry Residues Using in-situ and Correlative Microscopy
Increasing concerns about global carbon emissions due to fossil fuel use has created interest in renewable fuel alternatives, such as lignocellulosic biomass. With an estimated global biomass production probability ten-fold higher than projected need, functionalizing and scaling biomass conversion processes, like pyrolysis, is a promising component of a diverse sustainable energy program (Kan, Strezov, & Evans, 2016). Pyrolysis reactors employed in biomass conversion often encounter the known problem of screw feeder plugging, halting work and reducing efficiency of biorefineries. Although the screw feeder is not heated directly, conductive heat transfer from the fluidized bed pyrolysis reactor creates a temperature gradient, where particles experience temperatures between 22°C and 500°C from the time they enter the feeder to being emptied into the reactor (Digman, Joo, & Kim, 2009; Nieminen & Folke, 1982). The impact of unintentional heating on this highly variable feedstock may result in particle morphology modification, surface texture transformation, and the evolution of viscous compounds and may contribute to screw feeder plugging (Haas, Nimlos, & Donohoe, 2009; Ingram et al., 2008). We hypothesized that particles of various anatomical fractions (including needles, branches, bark, cambium, and whitewood) will experience dramatic changes during this heating regime, which will be characterized by decreased particle size, increased surface roughness, degradation of key structural macromolecules, and generation of viscous compounds that would result in increased particle friction and cohesion, contributing to screw feeder plugging.
Surface Chemistry and Particle Morphology Changes in Pine Biomass under Indirect Thermal Gradients: Implications for Feed Screw Design
The conversion of biomass feedstocks into fuels and chemicals using fast pyrolysis is a promising approach to renewable energy. Feed screws that convey biomass to pyrolysis reactors, however, often encounter plugging. Indirect heating of the feed screw occurs due to contact with the pyrolysis chamber, resulting in a heating gradient ranging from ambient temperature (22 °C) to reactor temperature (500 °C). Given that major cell wall macromolecules, such as lignin, cellulose, and hemicellulose, begin to produce bio-oils and volatile resin acid compounds within this temperature gradient, we hypothesized that indirect heating during feed screw conveyance is sufficient to cause premature degradation of biomass. We characterized this degradation by observing increases in surface roughness, changes in overall particle morphology, and the production and deposition of bio-oils on biomass particle surfaces. Correlative analysis between optical in situ hot-stage microscopy, confocal Raman spectroscopy, and SEM analysis revealed that heating at temperatures as low as 375 °C caused significant increases in surface roughness, with large fissures forming between and within cell walls. Additionally, droplets of bio-oil were observed on particles, especially in the bark and cambium samples. This work suggests that these phenomena contribute to particle agglomeration, leading to feed screw plugging, and that engineering a solution to cool the feed screw could prevent particle agglomeration and reduce plugging incidents, thereby increasing biomass processing efficiency.
Effects of lignin structure on hydrodeoxygenation reactivity of pine wood lignin to valuable chemicals
Hydrodeoxygenation (HDO) of two dilute acid flow through pretreated softwood lignin samples, including residual lignin in pretreated solid residues (ReL) and recovered insoluble lignin in pretreated liquid (RISL), with apparent different physical and chemical structures, was comprehensively studied. A combination of catalysts (HY zeolite and Ru/Al 2 O 3 ) was employed to investigate the effects of lignin structures, especially condensed structures, on the HDO upgrading process. Results indicated that the condensed structure and short side chains in lignin hindered its HDO conversion under different reaction conditions, including catalyst loading and composition, hydrogen pressure, and reaction time. In addition to lignin structure, HY zeolite was found crucial for lignin depolymerization, while Ru/Al 2 O 3 and relatively high hydrogen pressure (4 MPa) were necessary for upgrading unstable oxy-compounds to cyclohexanes at high selectivity (>95 wt %). Since the lignin structure essentially affects its reactivity during HDO conversion, the yield and selectivity of HDO products can be predicted by detailed characterization of the lignin structure. Furthermore, the insights gained from this study in the fundamental reaction mechanisms based on the lignin structure will facilitate upgrading of lignin to high-value products for applications in the production of both fuels and chemicals.
Sunlight can turn smoldering pine wood smoke into a glass
Wildfires inject biomass burning organic aerosols (BBOA) into the atmosphere. During their lifetimes of weeks to months, they are exposed to ultraviolet (UV) irradiation. Viscosity and phase behaviour are essential properties for understanding their chemical and climate impacts. Here, we quantify changes in viscosity and phase behavior after UV exposure. After an atmospheric equivalent of 8.7 days of boundary layer UV exposure, BBOA develop a highly viscous (glassy) outer phase with a viscosity at least five orders of magnitude higher than unaged BBOA, which persists up to at least 58% relative humidity. High-resolution mass spectrometry indicates that UV-aging increases oxidation and molecular weight. Using our viscosity results, we predict that UV-aged BBOA are frequently glassy above ~2.5 km and can have viscosities up to eight orders of magnitude higher than unaged particles in some atmospheric regions, which may influence lifetimes of pollutants and brown carbon, and impact stratospheric ozone chemistry.
Productivity and cost estimates for incorporating tracked processors into conventional loblolly pine harvesting regimes in the Southeastern United States
Due to the recent encouragement for loggers to integrate tracked processors into their conventional harvest equipment regime in the Southeastern United States, this study aimed to provide loggers with an estimate of the additional productivity and operating costs that could be incurred. Since tracked processors have rarely been operated in this region, a comparison study was conducted to determine differences in productivity and operating costs between a less experienced operator versus a more experienced operator. The study indicated the less experienced operator was able to produce 67 green tonnes/hour while the more experienced operator produced 80 green tonnes/hour. Costs per tonne for the less experienced operator were approximately $\$ $2.18/tonne at the end of year 1 and decreased to $\$$1.92/tonne at the end of year 5, depicting a $\$$0.26/tonne difference within 5 years. The more experienced operator incurred costs of $\$ $1.82/tonne at the end of year 1 and $\$ $1.61/tonne at the end of year 5 for a total difference of $\$ $0.21/tonne. A sensitivity analysis demonstrated that extreme fluctuations in fuel or maintenance/repair prices had less than a $\$ $0.20 increase in the final cost/ tonne. An increase in production rates from 65 to 125 tonnes decreased the cost/tonne $\$ $0.90/tonne, and increasing utilization rates from 50% to 85% decreased the cost per tonne of the processor by $\$ $0.78 per tonne. These results indicated that operators should be less concerned with changes in fuel and maintenance costs and be more concerned with their production and utilization rates.