Search NASA⌕ Search

SEARCH · Search NASA

Results for “polymer coatings”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Long Duration Exposure Facility M0003-5 thermal control coatings on DoD flight experiment

The M0003-5 thermal control coatings and materials orbited on the LDEF M0003 Space Environment Effects on Spacecraft Materials were a part of a Wright Laboratories Materials Directorate larger experiment. They were selected from new materials which emerged from development programs during the 1978-1982 time frame. Included were materials described in the technical literature which were being considered or had been applied to satellites. Materials that had been exposed on previous satellite materials experiments were also included to provide data correlation with earlier space flight experiments. The objective was to determine the effect of the LDEF environment on the physical and optical properties of thermal control coatings and materials. One hundred and two specimens of various pigmented organic and inorganic coatings, metallized polymer thin films, optical solar reflectors, and mirrors were orbited on LDEF. The materials were exposed in four separate locations on the vehicle. The first set was exposed on the direct leading edge of the satellite. The second set was exposed on the direct trailing edge of the vehicle. The third and fourth sets were exposed in environmental exposure control canisters (EECC) located 30 degrees off normal to the leading and trailing edges. The purpose of the experiment was to understand the changes in the properties of materials before and after exposure to the space environment and to compare the changes with predictions based on laboratory experiments. The basic approach was to measure the optical and physical properties of materials before and after long-term exposure to a low earth orbital environment comprised of UV, VUV, electrons, protons, atomic oxygen, thermal cycling, vacuum, debris, and micrometeoroids. Due to the unanticipated extended orbital flight of LDEF, the thermal control coatings and materials in the direct leading and trailing edge were exposed for a full five years and ten months to the space environment and the canister materials were exposed for approximately one year to the full environment.

Hurley, Charles J.↗
DOE OSTI2025

Tuning Molecular Interactions between Peptoids and Substrates to Achieve Surface-Agnostic Coating

Achieving programmable and robust coatings that maintain functionality while adhering to various surface types with molecular-level tunability and programmable features remains challenging. In this study, we develop adaptable and stable surface-agnostic coatings (SACs) based on crystalline peptoid membranes by tuning interpeptoid and peptoid-substrate interactions. We utilize two complementary methods: (1) surfaceinduced assembly, where peptoid membranes form directly on substrates, and (2) depositing preformed peptoid crystalline membranes via an aqueous layer-by-layer (LbL) assembly technique. These strategies are applied to substrates with diverse surface chemistries and topographies, including mica, highly ordered pyrolytic graphite (HOPG), MoS 2 , sapphire, and porous membranes like porous alumina and polysulfide. Atomic force microscopy confirms the formation of peptoid coatings and reveals differences in assembly behavior across surfaces. Moisture vapor transport measurements serve as a proof-of-concept test for membrane continuity and tunable permeance. Together, these findings demonstrate the adaptability and programmability of peptoid-based SACs, enabling rational coating design on surfaces with diverse chemical and topographical features. Furthermore, this work opens pathways for using peptoid membranes as programmable surface modifiers in functional interfaces, protective coatings, and membrane platforms.

biomimetic polymers↗
DOE OSTI2025

Hydration and Restructuring of Polar Polymer Interfaces: Implications in Antifouling and Responsive Materials

Manipulating polymer interfaces is crucial for understanding how structure influences function in applications spanning biofouling prevention to energy storage. Moreover, observing how polymers adapt their microscopic structure to changes in their local environment can reveal essential properties that govern their performance in such applications, providing key insights into how to design more effective interfaces. Here, in this study, a series of “grafting-from” polymer brushes with side chains varying in charge, are probed by sum frequency generation (SFG) and modeled using all-atom molecular dynamics (MD) simulations to elucidate how chemical makeup and charge mediate interfacial restructuring in dry versus hydrated states. Results show that charge, in progressing from nonpolar to cationic to zwitterionic, results in dramatic changes in interfacial structure and overall hydration. While net neutral systems, regardless of bulk phase polarity, show minimal interfacial water structuring, the cationic species exhibits strong bulk water signals from the surface potential. Meanwhile, the polymer brushes themselves restructure in water differently independent of charge, impacting the functional groups that are presented to the aqueous phase. Nonpolar and cationic species for instance undergo a change in alkyl group orientations to accommodate hydrating water molecules, whereas the zwitterionic polymer becomes completely disordered in water. Overall, the structure-based behavior trends presented herein have implications in antifouling applications and responsive material interfaces.

biointerface↗
DOE OSTI2020

Polymer-derived SiC/C/Al environmental barrier coatings on carbon steel

Carbon steel is a widely used structural material; however, it lacks corrosion resistance in water environments. An alternative approach to overcome this challenge is to implement the deposition of inherently corrosion-resistant ceramic coatings. SiC/C/Al coatings were developed at 700°C, using polycarbosilane in combination with Al and C, which were included as active and passive fillers, respectively. Here, we show that it is necessary to use Al particle sizes below 10 µm for them to function as an active filler below 900°C. Owing to their laminar microstructure, these coatings showed a cohesive delamination with an adhesion strength of 10 MPa. Results demonstrated that these coatings were able to reduce the corrosion of carbon steel in saline water by 99.7%, with corrosion rates of 38.33 mpy for carbon steel, and 0.099 and 0.155 mpy for SiC/C and SiC/C/Al (10 µm) coatings, respectively.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Binder-Stabilized Carbon Fiber Hosts for High-Utilization Sodium–Polysulfide Flow Catholytes

Sodium-sulfur (Na-S) batteries hold promise as high-energy-density batteries for long-duration energy storage due to their high open circuit voltage and Earth-abundant active materials. However, low utilization of the sulfur active material limits the achievable specific capacity, especially when a liquid polysulfide catholyte is utilized. High-surface-area carbon materials demonstrate promise to increase sulfur utilization in a Na-S battery. To make the carbon host material applicable for a flow battery application, a binder is required to bind the carbon materials together and to a porous substrate. Here, we utilize a composite carbon paper electrode coated by polymer,carbon nanofibers (CNFs) and carbon black (CB). By varying the mass ratios of CNF to CB, we found that a 70/20/10 mass ratio of CNF/CB/binder provided the highest capacity (260 mAh g −1 compared to the baseline of 156 mAh g −1 ) and stable battery performance over 100 cycles. Analysis of the composite electrode and full cells reveals that the amount of CB in the composite electrode influences binder distribution, cell resistance, and full cell performance.

Lehmann, Michelle L. [Oak Ridge National Laborator↗
DOE OSTI2021

Application of Machine Learning to Improve Biobased Glucaric Acid Production (CRADA 504)

The Agile Biofoundry (ABF) is a multi-national lab consortium funded by the DOE Bioenergy Technologies Office that has developed a biofoundry that enables the rapid deployment of bioproducts into the market. Working with four ABF laboratory members (National Renewable Energy Laboratory (NREL), Pacific Northwest National Laboratory (PNNL), Lawrence Berkeley National Laboratory (LBNL), and Argonne National Laboratory (ANL)), Kalion will use advanced high throughput techniques, advanced analytics, and machine learning to optimize the production environment for glucaric acid. Low-cost, high-purity glucaric acid enables products in a wide range of fields to improve the chemical properties of products and applications ranging from water treatment, polymers & textiles, coatings, detergents, and pharmaceuticals. With its broad range of applications, glucaric acid has the potential to demonstrate how such bio-based materials offer great benefit to the US economy.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Application of Machine Learning to Improve Biobased Glucaric Acid Production: Cooperative Research and Development Final Report, CRADA Number CRD-20-17260

The Agile Biofoundry (ABF) is a multi-national lab consortium funded by the DOE Bioenergy Technologies Office that has developed a biofoundry that enables the rapid deployment of bioproducts into the market. Working with four ABF laboratory members (National Laboratory of the Rockies (NLR), Pacific Northwest National Laboratory (PNNL), Lawrence Berkeley National Laboratory (LBNL), and Argonne National Laboratory (ANL)), Kalion will use advanced high throughput techniques, advanced analytics, and machine learning to optimize the production environment for glucaric acid. Low-cost, high-purity glucaric acid enables products in a wide range of fields to improve the chemical properties of products and applications ranging from water treatment, polymers & textiles, coatings, detergents, and pharmaceuticals. With its broad range of applications, glucaric acid has the potential to demonstrate how such bio-based materials offer great benefit to the US economy.

09 BIOMASS FUELS↗
NASA NTRS1980

Process modifications for improved carbon fiber composites: Alleviation of the electrical hazards problem

Attempts to alleviate carbon-fiber-composite electrical hazards during airplane crash fires through fiber gasification are described. Thermogravimetric and differential scanning calorimetric experiments found several catalysts that caused fibers to combust when composites were exposed to test fires. Composites were tested in the 'Burn-Bang' apparatus and in high voltage electrical detection grid apparatus. In a standard three minute burn test modified composites released no fibers, while state-of-the-art composites released several hundred fiber fragments. Expected service life with and without catalytic modification was studied and electron microscopy and X-ray microanalysis furnished physical appearance and chemical composition data. An acrylic acid polymer fiber coating was developed that wet the carbon fiber surface uniformly with the catalyst, providing a marked contrast with the uneven coats obtained by solution-dipping.

Ramohalli, K.↗
NASA NTRS1985

Finite element simulation of temperature dependent free surface flows

The method of Engelman and Sani (1984) for a finite-element simulation of incompressible surface flows with a free and/or moving fluid interface, such as encountered in crystal growth and coating and polymer technology, is extended to temperature-dependent flows, including the effect of temperature-dependent surface tension. The basic algorithm of Saito and Scriven (1981) and Ruschak (1980) has been generalized and implemented in a robust and versatile finite-element code that can be employed with relative ease for the simulation of free-surface problems in complex geometries. As a result, the costly dependence on the Newton-Raphson algorithm has been eliminated by replacing it with a quasi-Newton iterative method, which nearly retains the superior convergence properties of the Newton-Raphson method.

Engelman, M. S.↗
NASA NTRS1991

Long Duration Exposure Facility experiment M0003 deintegration observations

The four trays of the M0003 materials experiment on LDEF contained over 1200 test articles from 19 subexperiments. The complete tests article complement represented a broad range of materials, including thin film optical coatings, paints, polymer sheets and tapes, adhesives, and composites, for use in various spacecraft applications including thermal control, structures, optics, and solar power. All of the test articles were examined individually using bright field, dark field, and Nomarski light microscopy techniques. The condition of the test articles were photo-documented and observed global and anomalous effects were recorded for the benefit of the subexperimenters.

Gyetvay, S. R.↗
NASA NTRS1992

Long Duration Exposure Facility experiment M0003 deintegration observation database

The four trays of the M0003 materials experiment on LDEF contained 1274 samples from 19 subexperiments. The complete sample complement represented a broad range of materials, including thin film optical coatings, paints, polymer sheets and tapes, adhesives, and composites, for use in various spacecraft applications including thermal control, structures, optics, and solar power. Since some subexperiments included duplicate samples exposed on the leading and trailing edge trays, for 9 week, 19 week, 40 week, and 68 month durations on both the leading and trailing edges, comparisons provided a valuable time history of degradation. During the deintegration of the subexperiments from the M0003 trays, each sample was examined using bright field, dark field, and Normarski light microscopy techniques. Over 3,000 color macrographs and photomicrographs were made of the condition of M0003 trays and the individual samples. Records of the condition of the samples, photographic records, and all available references of publications on postflight analyses on each sample were collected in a database. The photographs provide a visual comparison of the response of materials common to various subexperiments in different LDEF environments. Aerospace Corporation is distributing the database records and photographs and written records on materials of interest from the database is given in this presentation.

Gyetvay, S. R.↗
NASA NTRS1993

Low Earth orbital atomic oxygen environmental simulation facility for space materials evaluation

Simulation of low Earth orbit atomic oxygen for accelerated exposure in ground-based facilities is necessary for the durability evaluation of space power system component materials for Space Station Freedom (SSF) and future missions. A facility developed at the National Aeronautics and Space Administrations's (NASA) Lewis Research Center provides accelerated rates of exposure to a directed or scattered oxygen beam, vacuum ultraviolet (VUV) radiation, and offers in-situ optical characterization. The facility utilizes an electron-cyclotron resonance (ECR) plasma source to generate a low energy oxygen beam. Total hemispherical spectral reflectance of samples can be measured in situ over the wavelength range of 250 to 2500 nm. Deuterium lamps provide VUV radiation intensity levels in the 115 to 200 nm range of three to five equivalent suns. Retarding potential analyses show distributed ion energies below 30 electron volts (eV) for the operating conditions most suited for high flux, low energy testing. Peak ion energies are below the sputter threshold energy (approximately 30 eV) of the protective coatings on polymers that are evaluated in the facility, thus allowing long duration exposure without sputter erosion. Neutral species are expected to be at thermal energies of approximately .04 eV to .1 eV. The maximum effective flux level based on polyimide Kapton mass loss is 4.4 x 10 exp 6 atoms/((sq. cm)*s), thus providing a highly accelerated testing capability.

Stidham, Curtis R.↗
NASA NTRS1993

Long Duration Exposure Facility experiment M0003 deintegration observation data base

The four trays (2 leading edge and 2 trailing edge) of the M0003 materials experiment on the Long Duration Exposure Facility (LDEF) contained 1274 samples from 20 subexperiments. The complete sample complement represented a broad range of materials, including thin film optical coatings, paints, polymer sheets and tapes, adhesives, and composites, for use in various spacecraft applications, including thermal control, structures, optics, and solar power. Most subexperiments contained sets of samples exposed on both the leading and trailing edge trays of LDEF. Each individual sample was examined by high resolution optical microscope during the deintegration of the subexperiments from the M0003 trays. Observations of the post-flight condition of the samples made during this examination were recorded in a computer data base. The deintegration observation data base is available to requesters on floppy disk in 4th Dimension for the Macintosh format. Over 3,000 color macrographs and photomicrographs were shot to complement the observation records and to document the condition of the individual samples and of the M0003 trays. The photographs provide a visual comparison of the response of materials in leading and trailing edge LDEF environments. The Aerospace Corporate Archives is distributing photographs of the samples and hard copies of the database records to the general public upon request. Information on obtaining copies of the data base disks and for ordering photographs and records of specific samples or materials are given.

Gyetvay, S. R.↗
NASA NTRS1994

High temperature polymer dielectric film insulation

PFPI polymers were invented in the late 1970's. Assessment of emerging requirements has dictated that 300 C performance is the goal for next generation wire insulation. TRW PFPI as superior 300 C polymer candidates is presented. Included is a comparison of promising PFPI film properties with Kapton. Also included are the promising bulk polymer or coating properties.

Jones, Robert J.↗
NASA NTRS2001

Effects of Electrons, Protons, and Ultraviolet Radiation on Thermophysical Properties of Polymeric Films

The response of coated thin polymer films to ultraviolet (UV), electron and proton radiation simultaneously has been evaluated, with selected measurements in situ. Exposure was intended to simulate the electron and proton radiation environment near the Earth-Sun Lagrangian points (LI and L2) for five years and approximately 1000 equivalent solar hours (ESH) UV. These orbital environments are relevant to several potential missions such as the Next Generation Space Telescope and Geomagnetic Storm Warning, both of which may use thin film based structures for a sunshade and solar sail, respectively. The thin film candidates (12.5 micrometers thick) consisted of commercially available materials (Kapton(R) E, HN, Upilex(R) S, CP-1, CP-2, TOR-RC, and TOR-LMBP) that were metalized on one side with vapor deposited aluminum. All of the films are aromatic polyimides, with the exception of TORLMBP, which is a copoly(arylene ether benzimidazole). The films were exposed as second surface mirrors and the effects of the exposure on solar absorptance, thermal emittance, and tensile properties were determined. The in situ changes in solar absorptance from Kapton(R) and Upilex(R) were less than 0. 1, whereas the solar absorptance of TOR and CP films increased by more than 0.3 without saturating. The thermal emittance measurements also showed that the Kapton(R) and Upilex(R) materials increased only 1-2%, but the remaining materials increased 5-8%. Based on tensile property measurements made in air following the test, the failure stress of every type of polymer film decreased as a result of irradiation. The polymers most stable in reflectance, namely Upilex(R) and Kapton(R), were also the strongest in tension before irradiation, and they retained the greatest percentage of tensile strength. The films less stable in reflectance were also weaker in tension, and lost more tensile strength as a result of irradiation. The apparent failure strain (as a percent of original gage length) of every type of polymer film except TOR-RC, decreased as a result of irradiation.

Russell, Dennis A.↗