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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

Elimination of Class-9 Hazards in Lithium-ion Recycling (Final Report)

The objective of this project was based upon the FOA request to demonstrate replication of results of the innovation to different locations. The project demonstrated battery deactivation innovations on different battery formats, chemistries, and within various industrial settings. The successful deactivation process was demonstrated on mainstream applications as well as safety-outliers, such as batteries that may have a residual charge. Success of deactivation was shown through repeated observations that various treated batteries do not exhibit thermal runaway with exposure to excessive heating or nail penetration. Deactivation processing was successfully demonstrated on batteries from private industry, public transit authorities, and military formats accessed with support of the Defense Logistics Agency (DLA). Third party analysis of deactivated batteries is ongoing through use of voucher programs available through OnTo’s Made in America Phase II Battery Recycling Prize, and OnTo’s CalTestBed award; these activities support the future special permit or declassification of deactivation treated material that has a firm foundation in results from this project. The project demonstrated the potential for a service business to perform the activities of electrolyte removal and reactivity elimination from large electric vehicle batteries in a relevant environment such as a battery testing and repackaging, or public-transit electric bus service shop. This successful project provided the first description, demonstration, and basis to teach quality control and assurance of successful battery deactivation.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Blueprinting Electrified Transit System Implementation

To achieve a more affordable and reliable transportation system, we need to smartly upgrade our power systems and install a large number of charging stations, but conventional planning methods are not up to the task. By applying advanced simulation and optimization tools, we can design a smarter, more cost-effective electric transportation network. The initial focus was on public transit systems, demonstrating how this approach can deliver broader economic, reliability, and air quality benefits nationwide.

24 POWER TRANSMISSION AND DISTRIBUTION↗

[Activities of Colorado University]

During the report period we completed several studies and embarked on a new set of laboratory experiments. We also hired a new post-doctoral Research Associate, Momir Stepanovic, who has gradually assumed leadership in the laboratory work. The other person involved has been graduate student Brian Eichelberger, who will complete his Ph.D. based on this work by late spring of this year. We have also continued to collaborate with our previous postdoctoral Research Associate, Valery Le Page, through a consulting arrangement. In the following sections we summarize work that has been completed and either in print, in press, or in final stages of preparation for publication; current work being carried out in the laboratory; and plans for the coming year. Work completed in 2002: 1. Modeling the physical and chemical states of PAHs in the diffuse interstellar medium. 2. Hydrogenation and charge states of polycyclic aromatic hydrocarbons in diffuse clouds. 3. Laboratory studies of chemical reactions involving carbon chain anions.

Snow, Theodore P.↗

Curating NASA's Past, Present, and Future Extraterrestrial Sample Collections

The Astromaterials Acquisition and Curation Office (henceforth referred to herein as NASA Curation Office) at NASA Johnson Space Center (JSC) is responsible for curating all of NASA's extraterrestrial samples. Under the governing document, NASA Policy Directive (NPD) 7100.10E "Curation of Extraterrestrial Materials", JSC is charged with "...curation of all extra-terrestrial material under NASA control, including future NASA missions." The Directive goes on to define Curation as including "...documentation, preservation, preparation, and distribution of samples for research, education, and public outreach." Here we describe some of the past, present, and future activities of the NASA Curation Office.

McCubbin, F. M.↗

Advanced Curation Activities at NASA: Implications for Astrobiological Studies of Future Sample Collections

The Astromaterials Acquisition and Curation Office (henceforth referred to herein as NASA Curation Office) at NASA Johnson Space Center (JSC) is responsible for curating all of NASA's extraterrestrial samples. Under the governing document, NASA Policy Directive (NPD) 7100.10F JSC is charged with curation of all extraterrestrial material under NASA control, including future NASA missions. The Directive goes on to define Curation as including documentation, preservation, preparation, and distribution of samples for re-search, education, and public outreach. Here we briefly describe NASA's astromaterials collections and our ongoing efforts related to enhancing the utility of our current collections as well as our efforts to prepare for future sample return missions. We collectively refer to these efforts as advanced curation.

McCubbin, F. M.↗

Plasma Assisted Combustion and Chemical Processing: Chapter 9 - Plasma Diagnostics

Plasma dynamics and chemistry have a broad range of timescales from picoseconds to milliseconds. In addition, it involves nonequilibrium energy transfer between electrons, ions, electronically and vibrationally excited states, radicals, intermediate species, and reactants and products as well as surface charges and chemistry. To understand plasma physics and chemistry, it is essential to conduct time and space resolved, quantitative detection of nonequilibrium temperature distributions, electron energy and number density, electric field, and species concentrations. There are enormous publications and review articles on this subject. The focus of this chapter is to be placed on the most recent progress in gas phase plasma properties and chemistry, especially on optical emission spectroscopy, laser absorption spectroscopy, Faraday rotational spectroscopy, Raman and Thompson scattering, femtosecond and picosecond (fs/ps) coherent anti-Stokes Raman scattering (CARS) spectroscopy, and electric field-induced second harmonic generation methods.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA CORE: Central Operation of Resources for Educators-Educational Materials Catalog

The NASA Central Operation of Resources for Educators (CORE), established in cooperation with Lorain County Joint Vocational School, serves as the worldwide distribution center for NASA-produced educational materials. For a minimal charge, CORE will provide a valuable service to educators unable to visit one of the NASA Educator Resource Centers by making NASA educational audiovisual materials available through its mail order service. Through CORE's distribution network, the public has access to more than 200 videocassette, slide, and CD-ROM programs, chronicling NASA!s state-of-the-art research and technology. Through the use of these curriculum supplement materials, teachers can provide their students with the latest in aerospace information. NASAs educational materials on aeronautics and space provide a springboard for classroom discussion of life science, physical science, astronomy, energy, Earth resources, environment, mathematics, and career education.

Source record↗

Curating Nasa's Future Extraterrestrial Sample Collections: the Role of Advanced Curation

The Astromaterials Acquisition and Curation Office at NASA Johnson Space Center (JSC) (henceforth referred to herein as NASA Curation Office) is responsible for curating all of NASA's extraterrestrial samples. Under the governing document, NASA Policy Directive (NPD) 7100.10F "Curation of Extraterrestrial Materials," JSC is charged with "The curation of all extraterrestrial material under NASA control, including future NASA missions." The Directive goes on to define Curation as including "...documentation, preservation, preparation, and distribution of samples for re-search, education, and public outreach." Here we describe some of the ongoing efforts to ensure that the future activities of the NASA Curation Office are working towards a state of maximum proficiency.

McCubbin, Francis M.↗

Novel ceramic capacitors with ultrahigh energy density and efficiency (Final Technical Report)

Antiferroelectric ceramics are a special class of material that have shown great potential as the dielectric in electrical capacitors due to their high energy- and power-density. During each charge-discharge cycle, the ceramic undergoes transformation to a ferroelectric phase and resumes its antiferroelectric phase. The hysteresis associated with the transitions leads to a mediocre energy efficiency and service lifetime of antiferroelectric capacitors and, hence, their almost absence in commercial products. Under the support of this research project, we first formulated a universal lattice-compatibility theory that included electrostatic polarization energy along with elastic energy and thermal energy to understand the origin of the hysteresis in antiferroelectric oxides. Guided by this compatibility theory, we conducted high-throughput density functional theory (DFT) calculations to assess chemical modifiers and their effect on crystal structures of 400+ PbZrO 3 -based compositions. Down-selected compositions were experimentally validated for their suppressed hysteresis and higher energy efficiency. The verified low-hysteresis compositions were then expanded to an antiferroelectric ceramic library with nearly 500 new compositions (more than 1,500 samples) using high-throughput experiments involving ceramic synthesis and property screening. The large quantity of data generated (theory and experimental) in these tasks were processed by machine-learning techniques and identified trends were fed to the next iteration. In the end, we successfully discovered four compositions with near-zero hysteresis, yielding a world-record energy efficiency of 98.2% at an energy density of 3.0 J/cm 3 . Furthermore, our antiferroelectric ceramic capacitor reaches 79.5 million charge-discharge cycles lifetime, a factor of 80 enhancement over previous antiferroelectric ceramics with large hysteresis. These research accomplishments have not only met the milestones set in the SOPO, but also led to two patent filings, three journal publications (one of them was in Advanced Materials, impact factor 29.4), and nine oral presentations at various venues. Through the course of the project, three postdocs, four Ph.D. students, and one M.S. student were trained. In short, our project established a new methodology in searching next-generation functional ceramics on the fundamental side and discovered several high-efficiency antiferroelectric compositions for capacitors on the applied side. Once fabricated into the multilayer form for commercial applications, these ceramic capacitors can potentially enable the high temperature high power density DC-link capacitors that are critical for the next generation inverters in electric vehicles. The project also significantly contributed to the nation’s workforce development in the STEM fields.

36 MATERIALS SCIENCE↗

Research in geosciences policy

The general task was to look beyond the adverse physical impacts and to defining the policy problem. In order for policy actions to be effective, they must address the right policy problems, which will be different from and broader than the physical problems. We will work on defining the policy problems with a view to indicating how practical solutions might be implemented. In particular, public officials need advice on what should be said, and done, and for what purposes. That advice needs to be based on systematic analysis of: (1) the scholarly literature in the social sciences, and related disciplines; (2) the charging content of the policy debate at the center of attention; and (3) how citizens perceive and understand issues related to global change. We will conduct this analysis. Chapter 1 and 2 each reports work on defining the policy problem and analyzing the scholarly literature. Chapters 3 and 4, respectively, address the policy debate and citizen viewpoints in issues related to global change.

Brunner, Ronald D.↗

The NASA Space Environments and Effects Program (SEE): Over a Decade of Useful Products for Spacecraft Designers and Operators

SEE program management originated at LaRC in the early 1990's but was transferred to MSFC in FY 1995 and has remained at Marshall since that time, SEE uses 5 technical working groups and NRA's (three since 1994) to achieve its technical objectives. The SEE vision is to develop and maintain a preeminent program in SPACE ENVIRONMENTS AND EFFECTS which provides a coordinated national focus for innovative technology development to support design, development, and operation of spacecraft systems that will accommodate or mitigate effects due to the presence of the space environment. In working toward that goal, SEE has produced, through the years, over 30 major Space Environments and Effects Models and Databases, over 75 major Space Environments and Effects Publications, a website that has had over 112,000 hits since its inception (http://see.msfc.nasa.gov/), distribution of physical products that amounts to over a total of over 260 product deliveries, sponsorship of the last four international Spacecraft Charging Technology Conferences (the major subject matter conference in the world), and sponsorship of numerous technical standards and guidelines in the Space Environments area. Among the recent popular SEE products are the Electric Propulsion Interactions Code (EPIC), the NASA/Air Force Spacecraft Charging Analysis Program (NASCAP-2K), the Interactive Spacecraft Charging Handbook, the Cosmic Ray Effects on Microelectronics Code (CREME 96), the Spacecraft Contamination and Materials Outgassing Effects Knowledge base (SCMOEK), and the Lunar E-Library.

Ferguson, Dale C.↗

Drivers of Medicare Spending: A 15-Year Review of Radiation Oncology Charges Allowed by the Medicare Physician/Supplier Fee-for-Service Program Compared With Other Specialties

In 2019, the Centers for Medicare and Medicaid Services proposed a new radiation oncology alternative payment model aimed at reducing expenditures. We examined changes in aggregate physician Medicare charges allowed per specialty to provide contemporary context to proposed changes and hypothesize that radiation oncology charges remained stable through 2017.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Two-particle angular correlations in e + e - collisions to hadronic final states in two reference coordinates at Belle

We present the analysis of two-particle angular correlations using coordinate systems defined with the conventional beam axis and the event thrust axis. We propose the latter as a good representation for the correlation structure interpretation in the e + e - collision system. The e + e - collisions to hadronic final states at center-of-mass energies of $\sqrt{s}$ = 10.52 GeV and 10.58 GeV are recorded by the Belle detector at KEKB. In this paper, results on the first dataset are supplementary to the previous Belle publication [1]. At the same time, the latter is the first two-particle correlation measurement at collision energy on the Υ(4S) resonance and is sensitive to its decay products. Measurements are reported as a function of the charged-particle multiplicity. Finally, a qualitative understanding of the correlation structure is discussed using a combination of Monte Carlo simulations and experimental data.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Matter in general relativity

Two theories of matter in general relativity, the fluid theory and the kinetic theory, were studied. Results include: (1) a discussion of various methods of completing the fluid equations; (2) a method of constructing charged general relativistic solutions in kinetic theory; and (3) a proof and discussion of the incompatibility of perfect fluid solutions in anisotropic cosmologies. Interpretations of NASA gravitational experiments using the above mentioned results were started. Two papers were prepared for publications based on this work.

Ray, J. R.↗

Study of the Effects of the Electric Field on Charging Measurements on Individual Micron-size Dust Grains by Secondary Electron Emissions

The dust charging by electron impact is an important dust charging process in Astrophysical, Planetary, and the Lunar environments. Low energy electrons are reflected or stick to the grains charging the dust grains negatively. At sufficiently high energies electrons penetrate the grain leading to excitation and emission of electrons referred to as secondary electron emission (SEE). Available theoretical models for the calculation of SEE yield applicable for neutral, planar or bulk surfaces are generally based on Sternglass Equation. However, viable models for charging of individual dust grains do not exist at the present time. Therefore, the SEE yields have to be obtained by some experimental methods at the present time. We have conducted experimental studies on charging of individual micron size dust grains in simulated space environments using an electrodynamic balance (EDB) facility at NASA-MSFC. The results of our extensive laboratory study of charging of individual micron-size dust grains by low energy electron impact indicate that the SEE by electron impact is a very complex process expected to be substantially different from the bulk materials. It was found that the incident electrons may lead to positive or negative charging of dust grains depending upon the grain size, surface potential, electron energy, electron flux, grain composition, and configuration. In this paper we give a more elaborate discussion about the possible effects of the AC field in the EDB on dust charging measurements by comparing the secondary electron emission time-period (tau (sub em) (s/e)) with the time-period (tau (sub ac) (ms)) of the AC field cycle in the EDB that we have briefly addressed in our previous publication.

Tankosic, D.↗

Vertex-finding and reconstruction of contained two-track neutrino events in the MicroBooNE detector

In this work, we describe algorithms developed to isolate and accurately reconstruct two-track events that are contained within the MicroBooNE detector. This method is optimized to reconstruct two tracks of lengths longer than 5cm. This code has applications to searches for neutrino oscillations and measurements of cross sections using quasi-elastic-like charged current events. The algorithms we discuss will be applicable to all detectors running in Fermilab's Short Baseline Neutrino program (SBN), and to any future liquid argon time projection chamber (LArTPC) experiment with beam energies ~ 1 GeV. The algorithms are publicly available on a GITHUB repository. This reconstruction offers a complementary and independent alternative to the Pandora reconstruction package currently in use in LArTPC experiments, and provides similar reconstruction performance for two-track events.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

BLAST-Lite (Battery Lifetime Analysis and Simulation Tool - Lite) [SWR-22-69] Related to: BLAST aka: BLAST-Py

Battery Lifetime Analysis and Simulation Toolsuite (BLAST) provides a library of battery lifetime and degradation models for various commercial lithium-ion batteries from recent years. Degradation models are identified from publicly available lab-based aging data using NREL's battery life model identification toolkit. The battery life models predicted the expected lifetime of batteries used in mobile or stationary applications as functions of their temperature and use (state-of-charge, depth-of-discharge, and charge/discharge rates). Model implementation is in both Python and MATLAB programming languages. The MATLAB code also provides example applications (stationary storage and EV), climate data, and simple thermal management options. For more information on battery health diagnostics, prediction, and optimization, see NREL's Battery Lifespan webpage.

Smith, Kandler↗

Measuring Vibronic Coupling and Ultrafast Charge Delocalization on Nanocrystal Surfaces Using Ligand-Specific Vibrational Probes

The primary goal of this proposal was to measure and quantify how vibronic ligand-exciton interactions at the inorganic-organic interface of semiconductor nanocrystals (NCs) govern femtosecond non-radiative relaxation and charge delocalization mechanisms as a function of nanocrystal and ligand structures – including NC size, shape, and ligand identity. Molecular-scale chemical and physical properties and interactions of surface ligands dictate nanocrystal exciton dynamics on the femto-to-microsecond timescales. Improvements in synthesis, experimental, and theoretical characterizations have enhanced our understanding of NC photophysics. However, quantitative descriptions of complex ligand-exciton interactions at the NC surface have remained elusive, which limits elucidation of relaxation mechanisms that determine overall carrier transfer dynamics at the exciton-ligand interface. Thus, the central motivation for this proposal was to fill a significant knowledge gap for judicious selection of ligand-functionalized nanocrystals for targeted isolation and capture of charge carriers to drive selective organic photocatalytic transformations in NC photocatalysts and NC-assembled photonic materials. Our unique two-pronged experimental approach combining nanocrystal synthesis and ligand-specific nonlinear spectroscopy has resulted in (i) four peer-reviewed publications; (ii) 12+ invited and contributed posters and talks at national and international scientific meetings and seminars, (iii) two completed PhD theses, (iv) training of two postdoctoral researchers, three PhD students, and two undergraduate students, and (v) two manuscripts under preparation.

36 MATERIALS SCIENCE↗