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Results for “resonance theory”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

A pulsed xenon megawatt arc plasma source

The exhaust of the source flowing into vacuum was measured by Thomson scattering diagnosis. Mean electron temperatures and densities were found to be 4-8 eV and of order ten to the 13th power cm/3 respectively over the 8 cm exhaust diameter at 30 cm from the source. Large shot to shot variations were noted. After a transient spike passes, these conditions persist during the power time of 125 microsecond. These exhaust conditions are marginal for evaluation of a proposed near resonant charge exchange pumped laser theory.

Michels, C. J.↗
NASA NTRS1973

Nonlinear gas oscillations in pipes. I - Theory.

The problem of forced acoustic oscillations in a pipe is studied theoretically. The oscillations are produced by a moving piston in one end of the pipe, while a variety of boundary conditions ranging from a completely closed to a completely open mouth at the other end are considered. The linear theory predicts large amplitudes near resonance and that nonlinear effects become crucially important. By expanding the equations of motion in a series in the Mach number, both the amplitude and waveform of the oscillation are predicted there. In both the open- and closed-end cases the need for shock waves in some range of parameters is found. The amplitude of the oscillation is different for the two cases, however, being proportional to the square root of the piston amplitude in the closed-end case and to the cube root for the open end.

Jimenez, J.↗
NASA NTRS1973

A pulsed xenon megawatt arc plasma source

The exhaust of the source flowing into vacuum was measured by Thomson scattering diagnosis. Mean electron temperatures and densities were found to be 4-8 eV and on the order of 10 trillion per cu cm respectively, over the 8 cm exhaust diameter at 30 cm from the source. Large shot to shot variations were noted. After a transient spike passes, these conditions persist during the power time of 125 microsec. These exhaust conditions are marginal for evaluation of a proposed near resonant charge exchange pumped laser theory.

Michels, C. J.↗
NASA NTRS1987

Theory and Design of Flight-Vehicle Engines

Papers are presented on such topics as the testing of aircraft engines, errors in the experimental determination of the parameters of scramjet engines, the effect of the nonuniformity of supersonic flow with shocks on friction and heat transfer in the channel of a hypersonic ramjet engine, and the selection of the basic parameters of cooled GTE turbines. Consideration is also given to the choice of optimal total wedge angle for the acceleration of aerospace vehicles, the theory of an electromagnetic-resonator engine, the dynamic characteristics of the pumps and turbines of liquid propellant rocket engines in transition regimes, and a hierarchy of mathematical models for spacecraft control engines.

Zhdanov, V. T.↗
NASA NTRS1994

Characteristics of finite amplitude stationary gravity waves in the atmosphere of Venus

This paper extends the study of stationary gravity waves generated near the surface of Venus reported previously by Young et al. to include finite amplitude effects associated with large amplitude waves. Waves are forced near the surface of Venus by periodic forcing. The height-dependent profiles of static stability and mean wind in the Venus atmosphere play a very important role in the evolution of the nonlinear behavior of the waves, just as they do in the linear wave solutions. Certain wave properties are qualitatively consistent with linear wave theory, such as wave trapping, resonance, and wave evanescence for short horizontal wavelenghts. However, the finite amplitude solutions also exhibit many other interesting features. In particular, for forcing amplitudes representative of those that could be expected in mountainous regions such as Aphrodite Terra, waves generated near the surface can reach large amplitudes at and above cloud levels, with clear signatures in the circulation pattern. At still higher levels, the waves can reach large enough amplitude to break, unless damping rates above the clouds are sufficient to limit wave amplitude growth. Well below cloud levels the waves develop complex flow patterns as the result of finite amplitude wave-wave interactions, and waves are generated having considerably shorter horizontal wavelenghts than that associated with the forcing near the surface. Nonlinear interactions can excite waves that are resonant with the background wind and static stability fields even when the primary surface forcing does not, and these waves can dominate the wave spectrum near cloud levels. A global map of Venus topographic slopes derived from Magellan altimetry data shows that slopes of magnitude comparable to or exceeding that used to force the model are ubiquitous over the surface.

Young, Richard E.↗
NASA NTRS2011

Conformational Structure of Tyrosine, Tyrosyl-Glycine, and Tyrosyl-Glycyl-Glycine by Double Resonance Spectroscopy

We investigated the variation in conformation for the amino acid tyrosine (Y), alone and in the small peptides tyrosine-glycine (YC) and tyrosine-glycine-glycine (YGG), in the gas phase by using UV-UV and IR-UV double resonance spectroscopy and density functional theory calculations. For tyrosine we found seven different conformations, for YG we found four different conformations, and for YGG we found three different conformations. As the peptides get larger, we observe fewer stable conformers, despite the increasing complexity and number of degrees of freedom. We find structural trends similar to those in phenylalanine-glycine glycine (FGG) and tryptophan-glycine-glycine (WGG)j however) the effect of dispersive forces in FGG for stabilizing a folded structure is replaced by that of hydrogen bonding in YGG.

Abo-Riziq, Ali↗
NASA NTRS1981

The tides of Io

A theory is developed for the origin and evaluation of the orbital resonances between the Galilean satellites Io, Europa and Ganymede as a result of the effects of dissipative tides in Jupiter and its satellites. Following a preliminary consideration of the consequences of tidal interaction for satellite orbits and a comprehensive Hamiltonian theory of the resonance interactions which allows terms up to third order in eccentricity to be included, a dynamic model of the origin and evolution of the resonance locks is presented in which the relative expansion of the orbits by tidal torques from Jupiter together with tidal dissipation in Io lead to the rapid driving out of Io until it is captured into a 2:1 resonance with Europa and the resonance with Ganymede is achieved. Consideration of the effects of other commensurabilities on the orbital evolution of the system reveals that second-order Laplace-like resonances would act to excite free eccentricites, while the resonances associated with the two-body 3:1 commensurability could not have been encountered. Analysis of the hypothesis that the Laplace relation is primordial shows that the bounds on the tidal dissipation of Jupiter still can not be relaxed. Recent determinations of the tidal dissipation in Jupiter are discussed, and it is noted that none is sufficiently small to be consistent with the high heat flux estimates for Io. Finally, the possibility of the observational determination of the tidal dissipation in Jupiter by the measurement of the secular acceleration of Io's main motion is considered.

Yoder, C. F.↗
NASA NTRS1979

A comparison of intense electrostatic waves near f-UHR with linear instability theory

Intense electrostatic waves near the upper hybrid resonance frequency (f-UHR) have recently been detected near but beyond the plasmapause between + or -50 deg magnetic latitude at all local times. The paper shows that the electrostatic waves observed with the ISEE 1 plasma wave receiver near f-UHR are in qualitative agreement with linear theory of multicyclotron harmonic emissions. The peak amplitudes and bandwidths observed are similar to those calculated for maximum spatial growth rates. Measurements on Hawkeye of similar waves suggest that the electric field polarization is also consistent with theory. For a wide range of plasma parameters, nonconvective instability or large spatial growth rates occur within the cyclotron band encompassing the cold upper hybrid frequency.

Kurth, W. S.↗
DOE OSTI2026

Casimir-Polder potential on an excited atom near an atomic array

We develop a microscopic description of the fluctuation-mediated Casimir-Polder (CP) shifts on a 'test' two-level atom placed near a two-dimensional atomic array of two-level atoms. We derive the resonant and off-resonant CP potentials experienced by the excited test atom using fourth-order perturbation theory, under the assumption that the test atom resonance is far detuned from those of the array atoms. The total potential on the test atom can be described as the sum of the pairwise resonant and off-resonant potentials resulting from its interaction with the individual atoms of the array. We analyze the asymptotic scaling of CP shifts as a function of the test atom-array separation, and its dependence on various system parameters: array spacing and size, and dipole orientation of the array atoms. Our results bridge the description of CP potential across two distinct regimes: (i) from a single-atom limit where we recover the well-known two-atom Van der Waals potential, (ii) to a macroscopic boundary limit, where we demonstrate new asymptotic scaling laws. We demonstrate that these scaling laws can be tuned via the microscopic parameters of the atomic array, establishing atomically-controlled arrays as a versatile platform for tailoring fluctuation-induced QED phenomena.

FOS: Physical sciences↗
DOE OSTI2024

Photodriven electron-transfer dynamics in a series of heteroleptic Cu(I)–anthraquinone dyads

Solar fuels catalysis is a promising route to efficiently harvesting, storing, and utilizing abundant solar energy. To achieve this promise, however, molecular systems must be designed with sustainable components that can balance numerous photophysical and chemical processes. To that end, here we report on the structural and photophysical characterization of a series of Cu(I)–anthraquinone-based electron donor–acceptor dyads. The dyads utilized a heteroleptic Cu(I) bis-diimine architecture with a copper(I) bis-phenanthroline chromophore donor and anthraquinone electron acceptor. We characterized the structures of the complexes using x-ray crystallography and density functional theory calculations and the photophysical properties via resonance Raman and optical transient absorption spectroscopy. The calculations and resonance Raman spectroscopy revealed that excitation of the Cu(I) metal-to-ligand charge-transfer (MLCT) transition transfers the electron to a delocalized ligand orbital. The optical transient absorption spectroscopy demonstrated that each dyad formed the oxidized copper–reduced anthraquinone charge-separated state. Unlike most Cu(I) bis-phenanthroline complexes where increasingly bulky substituents on the phenanthroline ligands lead to longer MLCT excited-state lifetimes, here, we observe a decrease in the long-lived charge-separated state lifetime with increasing steric bulk. The charge-separated state lifetimes were best explained in the context of electron-transfer theory rather than with the energy gap law, which is typical for MLCT excited states, despite the complete conjugation between the phenanthroline and anthraquinone moieties.

14 SOLAR ENERGY↗
DOE OSTI2023

Shifting and Splitting of Resonance Lines due to Dynamical Friction in Plasmas

We report a quasilinear plasma transport theory that incorporates Fokker-Planck dynamical friction (drag) and pitch angle scattering is self-consistently derived from first principles for an isolated, marginally unstable mode resonating with an energetic minority species. It is found that drag fundamentally changes the structure of the wave-particle resonance, breaking its symmetry and leading to the shifting and splitting of resonance lines. In contrast, scattering broadens the resonance in a symmetric fashion. Comparison with fully nonlinear simulations shows that the proposed quasilinear system preserves the exact instability saturation amplitude and the corresponding particle redistribution of the fully nonlinear theory. Even in situations in which drag leads to a relatively small resonance shift, it still underpins major changes in the redistribution of resonant particles. This novel influence of drag is equally important in plasmas and gravitational systems. In fusion plasmas, the effects are especially pronounced for fast-ion-driven instabilities in tokamaks with low aspect ratio or negative triangularity, as evidenced by past observations. The same theory directly maps to the resonant dynamics of the rotating galactic bar and massive bodies in its orbit, providing new techniques for analyzing galactic dynamics.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2022

A Cavity System for Seawater Dielectric Measurements at P-Band

This paper describes a new system for measuring the dielectric constant of seawater near 700 MHz. The purpose of this research is to obtain data at P-band for the dielectric constant of seawater that can be combined with previous L-band data for developing a model function valid from 500 MHz to 2000 MHz. A transmission-type cylindrical cavity has been constructed with the TM010 mode resonance occurring near 700 MHz. The seawater is introduced via a capillary quartz tube. The dimensions of the cavity have been determined by electromagnetic modelling. The model takes the cavity wall loss into account and can provide accurate estimation of resonance condition for both the empty cavity and cavity with seawater. The errors between the theory and measurement are about 0.07% for the resonant frequency and 0.4% for the quality factor, Q. The cavity design, experimental setup and measurement schedule will be presented in the paper.

Roger Lang↗
DOE OSTI2025

Magnetic polaron formation in EuZn2P2

Colossal magnetoresistance (CMR) has been observed across many Eu2+-based materials; however, its origin is not completely understood. Here we investigate the antiferromagnetic insulator EuZn2⁢P2 through single crystal x-ray diffraction, transmission electron microscopy, electrical transport, magnetization, dilatometry, and electron spin resonance measurements complemented by density functional theory calculations. Our electrical resistivity data reveal a large negative magnetoresistance, MR=[𝑅⁡(𝐻)−𝑅⁡(0)]/𝑅⁡(0), that reaches MR=−99.7% at 9 T near the antiferromagnetic ordering temperature 𝑇𝑁=23K. Dilatometry measurements show an accompanying field-induced lattice strain. Additionally, Eu2+ electron spin resonance reveals a strong ferromagnetic exchange interaction between Eu2+ and conduction electrons. Our experimental results in EuZn2⁢P2 are consistent with a magnetic polaron scenario and suggest magnetic polaron formation as a prevailing explanation of CMR in Eu2+-based compounds.

Cook, Matt [ORNL] (ORCID:0000000288777505)↗
NASA NTRS1993

Spiral density waves resonantly excited by a rapidly rotating bar

Recent observations at millimeter wavelengths have revealed bar-spiral structures in the central regions of several nearby spiral galaxies. Moreover, new infrared data and even COBE data seem to support the idea that there is a bar in the central regions of the Milky Way. All of these new findings have rekindled the interest in bar-driven spirals again. First, the mechanism that is responsible for exciting the spiral density waves near the resonances is reviewed, and then a theory to account for the highly nonlinear behavior of the gas associated with the waves is presented. The new results have again demonstrated that the 3 kpc arm phenomenon can be reproduced by a rapidly rotating bar in the galactic center. Similarly, in terms of the resonance excitation mechanism, the recent high-resolution radio observations of the bar-spiral structure in the central regions of nearby galaxies can be explained.

Yuan, Chi↗
NASA NTRS1991

Controllable surface-plasmon resonance in engineered nanometer epitaxial silicide particles embedded in silicon

Epitaxial CoSi2 particles in a single-crystal silicon matrix are grown by molecular-beam epitaxy using a technique that allows nanometer control over particle size in three dimensions. These composite layers exhibit resonant absorption predicted by effective-medium theory. Selection of the height and diameter of disklike particles through a choice of growth conditions allows tailoring of the depolarization factor and hence of the surface-plasmon resonance energy. Resonant absorption from 0.49 to 1.04 eV (2.5 to 1.2 micron) is demonstrated and shown to agree well with values predicted by the Garnett (1904, 1906) theory using the bulk dielectric constants for CoSi2 and Si.

Fathauer, R. W.↗
DOE OSTI2024

Acoustoelastic characterization of plates using zero group velocity Lamb modes

Acoustoelasticity, a characteristic of material anharmonicity, gives rise to a link between wave propagation velocity and the stress state in materials. Ultrasonic techniques to monitor this coupling, particularly with high sensitivity and in a noncontact manner, can have widespread application both in the quantification of applied and residual stress and in the characterization of nonlinear material behavior through measurement of higher order elastic constants. Here, we use a laser ultrasonic technique to excite and detect zero group velocity (ZGV) Lamb wave resonances in aluminum plates under uniaxial loading. A laser line source is used to excite these resonances at different orientations with respect to the applied load, and the signals are detected using an interferometer. The effects of stress and source orientation on ZGV resonance frequencies are validated using the theory of acoustoelastic Lamb wave propagation. In addition, a model-based inversion technique is used to extract Murnaghan's third-order elastic constants from measurements of the stress dependence of the first two ZGV modes generated parallel and perpendicular to the applied load. Laser generation and detection of ZGV resonances is shown to be an effective and powerful approach for the noncontact and nondestructive acoustoelastic characterization of elastic waveguides.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Tuning the reactivity of carbon surfaces with oxygen-containing functional groups

Oxygen-containing carbons are promising supports and metal-free catalysts for many reactions. However, distinguishing the role of various oxygen functional groups and quantifying and tuning each functionality is still difficult. Here we investigate the role of Brønsted acidic oxygen-containing functional groups by synthesizing a diverse library of materials. By combining acid-catalyzed elimination probe chemistry, comprehensive surface characterizations, 15N isotopically labeled acetonitrile adsorption coupled with magic-angle spinning nuclear magnetic resonance, machine learning, and density-functional theory calculations, we demonstrate that phenolic is the main acid site in gas-phase chemistries and unexpectedly carboxylic groups are much less acidic than phenolic groups in the graphitized mesoporous carbon due to electron density delocalization induced by the aromatic rings of graphitic carbon. The methodology can identify acidic sites in oxygenated carbon materials in solid acid catalyst-driven chemistry.

Zhou, Jiahua↗