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A series of organometallic and organic salts, in which the cation has been designed to have a large molecular hyperpolarizability, has been prepared. Variation of the counterion (anion) in many cases leads to materials with large powder second harmonic generation (SHG) efficiencies, the highest of which is roughly 2000 times that of a urea reference.
Organic dyes are known to show the resonant type of nonlinear optical properties, including phase conjugation. In the present work, disodium fluorescein in methanol is used as an organic nonlinear medium for degenerate four wave mixing at 532 nm to see the intensity dependence of the phase conjugate signal at different concentrations of the solution. It is observed that the maximum reflectivity of the signal occurs in a concentration range of 5 x 10(exp -3)/cu cm to 1.2 x 10(exp -2) g/cu cm. It is also observed that the intensity of the signal drops suddenly to less than half of its maximum outside the concentration range mentioned above. An investigation of the phase conjugate signal intensity by changing the delay time between probe signal and the forward pump is also examined. Briefly discussed is the possibility of population grating in dye liquids as a source of enhancing the third order susceptibility besides the other techniques mentioned in reference. The experiment is done by beam splitting the second harmonic (532 nm) of Nd:YAG laser, Q-switched at 20 pulses/sec (pulse width is approximately 8 and 200 mJ per pulse).
Second- and third-order nonlinear optical properties of some newly synthesized organic molecules and polymers are reported. Powder second-harmonic-generation efficiencies of up to 200 times urea have been realized for asymmetric donor-acceptor acetylenes. Third harmonic generation chi(3)s have been determined for a series of small conjugated molecules in solution. THG chi(3)s have also been determined for a series of soluble conjugated copolymers prepared using ring-opening metathesis polymerization. The results are discussed in terms of relevant molecular and/or macroscopic structural features of these conjugated organic materials.
A fast and nonintrusive velocity and temperature diagnostic based on oxygen absorption is presented. The system uses a GaAlAs tunable diode laser, ramped and modulated in wavelength at high frequency. Detection is performed at twice the modulating frequency, leading to second harmonic absorption lineshapes. Velocity is inferred from the wavelength shift of the absorption line center due to the Doppler effect. Temperature is determined by comparing experimental and calculated lineshapes. Capabilities of the technique for studies of transient high-speed flows are demonstrated in shock tube experiments. Good agreement is obtained with predicted temperatures and velocities when pressure-induced shifts are accounted for.
Results are presented of observations (made with the Hard X-Ray Burst Spectrometer on the SMM and with the Itapetinga antenna) that unambiguously show associations of hard X-ray bursts with RS-type III bursts between 16:46 UT and 16:52 UT on July 9, 1985. The comparison between the hard X-ray and the radio observations shows a clear association, in at least 13 cases, of the hard X-ray and the decimetric RS bursts. On the average, the X-ray peaks were delayed from the peak of the RS bursts at 1.6 Ghz by about 400 msec. It is shown that, if the time comparisons are made between the peak of the radio pulse and the start of the X-ray burst, the delays are consistent with an electron travel time with a velocity of about 0.3 c from the 800 MHz plasma level to the lower corona, assuming that the radio emission is at the second harmonic.
Measurements of magnetic fields in the sun's atmosphere using radio observations are discussed. Radio measurements of magnetic fields in the chromosphere and the corona are indirect. In the chromosphere, these are based upon the measurement of polarization of active regions at millimeter wavelengths. In the transition region and the corona, the properties of gyroresonance radiation of active regions at centimeter wavelengths are used. Total intensity and polarization maps and modeling are used to determine which harmonic (second or third) is predominant in the active region emission. A direct method of measuring coronal magnetic fields using cyclotron line emission is discussed, and the relevant data as presently available are presented.
Distant observations of intense auroral kilometric radiation (AKR) are discussed in light of the increased maximum AKR power flux registered by the 3D radio-mapping instrument on ISEE 3. Only AKR events that contain the highest frequency signals are selected, and during spacecraft rotation the spacecraft antenna gain is employed to increase the dynamic range of the instrument. The technique is found to result in the screening of false signals created by instrument overloading as well as the detection of genuine second-harmonic AKR signals while the spacecraft was 17 R(E) from earth. A very strong power flux of fundamental AKR is also reported, exceeding 3 x 10 to the -13th W/sq m/Hz at 360 kHz. The most intense source-region values detected by Isis I and Viking measurements are compared to the strong signal, and the signal is concluded to be the combined signal of a number of sources.
The second- and third-order nonlinear optical properties of acridine yellow-doped lead-tin fluorophosphate (LTF) glass have been directly studied by measurement of surface enhanced second harmonic generation and third harmonic generation. The three photon excitation fluorescence is also observed. Based on these results, the large nonlinearities of the acridine LTF system which is a new nonlinear optical material are experimentally demonstrated.
The results of a series of experiments on efficient second-harmonic generation in a fiber with a Eu(2+)-doped aluminosilicate core are reported. The fiber was prepared by the seeding method with CW mode-locked radiation at 1.06 micron and produced ultrastable peak conversion efficiencies of 0.001 during mode-locked readout. Experiments were performed to determine the IR preparation intensity dependence, the stability of the output, and the type of erasure mechanisms which occur. The results are compared with those of germanosilicate fibers and some similarities and differences are discussed.
Semiconductor-diode laser-pumped solid-state lasers have properties that are superior to other lasers for the applications of coherent communication and remote sensing. These properties include efficiency, reliability, stability, and capability to be scaled to higher powers. We have demonstrated that an optical phase-locked loop can be used to lock the frequency of two diode-pumped 1.06 micron Nd:YAG lasers to levels required for coherent communication. Monolithic nonplanar ring oscillators constructed from solid pieces of the laser material provide better than 10 kHz frequency stability over 0.1 sec intervals. We have used active feedback stabilization of the cavity length of these lasers to demonstrate 0.3 Hz frequency stabilization relative to a reference cavity. We have performed experiments and analysis to show that optical parametric oscillators (OPO's) reproduce the frequency stability of the pump laser in outputs that can be tuned to arbitrary wavelengths. Another measurement performed in this program has demonstrated the sub-shot-noise character of correlations of the fluctuations in the twin output of OPO's. Measurements of nonlinear optical coefficients by phase-matched second harmonic generation are helping to resolve inconsistency in these important parameters.
Fluctuation properties of squeezed photon beams generated in three wave mixing processes such as second harmonic generation, degenerate and nondegenerate parametric oscillations, and homodyne detection are studied in terms of photon sequences recorded by a photodetector.
Second harmonic conversion efficients of 3 x 0,0001 in tantalum-doped silica fibers prepared by the seeding technique are reported. A series of experiments were conducted to characterize the frequency doubling in this fiber and to compare the results to the behavior observed in germanosilicate and rare earth-doped aluminosilicate fibers.
Magnetic field measurements made with the AMPTE CCE spacecraft are used to investigate the distribution of ULF energy in the inner magnetosphere. The data base is employed to examine the spatial distribution of ULF energy. The spatial distribution of wave power and spectral structures are used to identify several pulsation types, including multiharmonic toroidal oscillations; equatorial compressional Pc 3 oscillations; second harmonic poloidal oscillations; and nightside compressional oscillations. The frequencies of the toroidal oscillations are applied to determine the statistical radial profile of the plasma mass density and Alfven velocity. A clear signature of the plasma pause in the profiles of these average parameters is found.
The purpose of this research was to develop a reliable submillimeter wave spectrometer for space-borne high frequency spectral line work. The emphasis was on improving the efficiency of frequency multipliers to limit the system components to rugged, low power consumption solid-state devices. This research has allowed Millitech to develop increased efficiency and performance in Millitech's existing line of submillimeter components and systems. Millitech has fabricated and tested a complete solid-state spectrometer front end for use at 560 GHz (the 1(sub 10) to 1(sub 01) transition of water vapor). The spectrometer was designed with the rigors of flight conditions in mind. The spectrometer uses a phase-locked, solid-state Gunn diode oscillator as the local oscillator, employing a tripler to produce about 3 mW of power at 285 GHz, and a low noise second harmonic waveguide mixer which requires less than 2 mW of LO power. The LO (and the signal) is injected into the mixer by means of a quasioptical diplexer. The measured system noise temperature is 2800 K (DSB) over 400 MHz. The whole spectrometer front end is compact (21 cm by 21 cm by 24 cm), light (7.4 kg), and has a power consumption of less than 8 W. Other topics explored in this work include compact frequency agile phase lock loops, optical filters, and InP Gunn oscillators for low noise applications. As a result of this research, the improvement in the design of multipliers and harmonic mixers will allow their use as the LO power for a variety of satellite-borne receivers operating in the 200 to 600 GHz frequency range.
This report presents the formulation of the optimal low- and medium-thrust orbit transfer control problem and methods for numerical solution of the problem. The problem formulation is for final mass maximization and allows for second-harmonic oblateness, atmospheric drag, and three-dimensional, non-coplanar, non-aligned elliptic terminal orbits. We setup some examples to demonstrate the ability of two indirect methods to solve the resulting TPBVP's. The methods demonstrated are the multiple-point shooting method as formulated in H. J. Oberle's subroutine BOUNDSCO, and the minimizing boundary-condition method (MBCM). We find that although both methods can converge solutions, there are trade-offs to using either method. BOUNDSCO has very poor convergence for guesses that do not exhibit the correct switching structure. MBCM, however, converges for a wider range of guesses. However, BOUNDSCO's multi-point structure allows more freedom in quesses by increasing the node points as opposed to only quessing the initial state in MBCM. Finally, we note an additional drawback for BOUNDSCO: the routine does not supply information to the users routines for switching function polarity but only the location of a preset number of switching points.
Development of a high-power tube suitable to power a Ka-band (34.5-GHz) antenna transmitter located at the Goldstone, California, tracking station is continuing. The University of Maryland Laboratory for Plasma Research and JPL are conducting a joint effort to test the feasibility of phase locking a second-harmonic gyrotron both by direct injection at the output cavity and by using a priming cavity to bunch the electrons in the beam. This article describes several design options and the results of computer simulation testing.
A microstrip measurement system has been designed to analyze packaged GaAs Schottky barrier diodes under small and large signal conditions. The nonlinear equivalent circuit parameters of the diode are determined using a small signal test method that analyzes the diode's scattering parameters at various bias levels. The experimental results of a 2.45 GHz diode are verified using a nonlinear circuit simulation program based on a multireflection algorithm. A 35 GHz rectenna has been built using a microstrip patch antenna and Ka-band mixer diode. The measured efficiency was 29 percent at 120 mW input power. A frequency selective surface is designed using an equivalent circuit model to reduce the second harmonic radiations for a 2.45 GHz rectenna. Theoretical results are found to be in fairly good agreement with experiments.
A novel tunable diode laser spectrometer operating at 8-28 microns is described. A blocked impurity band Si:As chip is employed as detector. This device operates in this wavelength range with high detectivity and adequate frequency response for the high-sensitivity techniques used. A combination of sweep averaging and second-harmonic detection at 22 kHz yielded signal-to-noise ratios of 1200 at wavelengths above 20 microns. The sensitivity and spectral resolution achieved are an order of magnitude better than those of Fourier instruments in this range, with an improvement in instrument time response of about 3000. Several molecular bands of CO2 and N2O are observed for what is, to our knowledge, the first time with this instrument. Examples of spectral line measurements are presented.