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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15

The Rover Software of the VIPER Mission

The VIPER mission exhibits a unique set of operational and environmental constraints, which provide opportunities as well as impose unique challenges for a robotic surface mission.VIPER Rover Software architecture and design targets these constraints in innovative ways to meet the mission’s technical and operational requirements. In this presentation we describe the design of VIPER’s rover software and present early results from its realization.

Flight software↗

Mars Commercial-Compatible Initial Human-Precursor Surveying and Instrument-Deployment Concepts

Water is a critical resource need for future human exploration and habitation of Mars and other planetary environments. An integral scientific question in the search for life outside of Earth is: What are the constraints on life in planetary environments? One of the most critical features of habitable environments is the availability of water - both as an environment for prebiotic chemistry, abiogenesis, and life; and as a vehicle for generating geo- and electro- chemical systems that can support metabolism. Seeking evidence of life prior to human arrival is important both to preserve signs of any existing or past evidence of Martian life, reducing the risks of unintentional forward contamination of Martian environments, and to potentially protect the health of any human crews. Looking forward towards Mars, future human exploration will require a rapid, but thorough, initial survey of any local “area of operations” on Mars to determine the spatial distribution, quantity, and quality (e.g., salt/mineral/organic content) of any local water, as well as to evaluate any signs of current or extinct life. We will discuss several candidate field survey methodologies, involving humans, a teamed instrument platform and a surveying/sampling rover. These are proposed to be validated in a given terrestrial Mars analog environment exhibiting varying distributions of water (ice, permafrost, rock-bound) to evaluate the constraints on life. Commercial space exploration brings the future possibility of unprecedented mass, power and in situ instrument capability, potentially enabling thorough exploration of the geology, hydrology and astrobiology of a km-radius study-zone around a future Mars human/commercial space landing site. We propose to study several representative planetary surface precursor-survey architectures and mission concepts (that are commercial-Mars-compatible), and to test and compare them in field application. We will examine some of the performance issues, using given metrics and controls, of spacesuited humans using handheld and standalone instruments, vs. a robotic human-tended rover/drill, robot arm and instruments. The latter rover-based architecture can in turn be viewed in terms of returned-to-base sample in-situ analyses vs sample analysis performed on a standalone instrument platform deployed away from the primary area of operations.

astrobiology↗

Sizing and Design Tool for Tall Lunar Tower

Tall lunar towers enable direct collection of solar energy using solar panels that can generate power exceeding 50kW. Tall lunar towers also support solar reflectors and concentrators for solar farms, which enable various mission architectures on the lunar surface. The Tall Lunar Tower project at NASA Langley Research Center is focused on the design, modeling, fabrication, and testing of an assembled tall lunar tower engineering development unit. This paper presents the development of a sizing and design tool for the tall lunar tower. The predicted frequency and buckling responses of the tall lunar tower from the tool are compared with the results obtained from finite element analysis.

Solar Tower↗

Sizing and Design Tool for Tall Lunar Tower

Tall lunar towers enable direct collection of solar energy using solar panels that can generate power exceeding 50kW. Tall lunar towers also support solar reflectors and concentrators for solar farms, which enable various mission architectures on the lunar surface. The Tall Lunar Tower project at NASA Langley Research Center is focused on the design, modeling, fabrication, and testing of an assembled tall lunar tower engineering development unit. This paper presents the development of a sizing and design tool for the tall lunar tower. The predicted frequency and buckling responses of the tall lunar tower from the tool are compared with the results obtained from finite element analysis.

Solar Tower↗

Methods of growing single crystals using solid-solid transformation of a glass

The present invention includes methods of promoting single crystal growth via solid-solid transformation of an appropriate glass, while avoiding the gaseous or liquid phase. In certain embodiments, in the all-solid-state glass-to-crystal transformation of the invention, extraneous nucleation is avoided relative to crystal growth via spatially localized laser heating and optional inclusion of a suitable glass former in the composition. The ability to fabricate patterned single-crystal architecture on a glass surface was demonstrated, providing a new class of micro-structured substrate for low cost epitaxial growth and active planar devices, for example.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Environmental Control and Life Support (ECLS) System Options for Mars Transit and Mars Surface Missions

The NASA led Artemis campaign will take humanity back to the Moon and serve as an analog for continued deep space exploration to Mars. Artemis utilizes crewed vehicles and habitats on both the Lunar surface and in Lunar orbit. The exploration of the Lunar surface and buildup of a basecamp is meant to be a “Mars forward” approach to testing and refining new technologies and techniques for living and working far outside of Low Earth Orbit (LEO) and preparing for future Mars missions. The Lunar Surface Habitat is planned as a primary element for long duration crew habitation on the Moon and will be the primary testbed for ECLS system hardware in a partial gravity environment. The Mars Transit Habitat will be the crew vehicle for the roundtrip from Earth to Mars and spend a significant amount of time docked to the Gateway outfitting and testing its systems prior to making the first Mars mission transit. The Mars Transit Habitat will utilize closed loop ECLS system technologies while a Mars Surface Habitat could use either open loop, closed loop, or a mix of both. Better understanding the needs of both these system architectures operating for extended periods in the Lunar environment and outside LEO will help to establish the ECLS system architecture for the future Mars surface mission. There are many aspects to consider such as length of crew stay, level of autonomy and dormancy between crewed missions, power requirements, system mass, and overall system reliability and maintainability. Other considerations will include Mars gravity vs. Lunar gravity, Mars atmospheric pressure vs. hard vacuum, and possible use of in-situ resource utilization.

ECLSS↗

Environmental Control and Life Support (ECLS) System Options for Mars Transit and Mars Surface Missions

The NASA led Artemis campaign will take humanity back to the Moon and serve as an analog for continued deep space exploration to Mars. Artemis utilizes crewed vehicles and habitats on both the Lunar surface and in Lunar orbit. The exploration of the Lunar surface and buildup of a basecamp is meant to be a “Mars forward” approach to testing and refining new technologies and techniques for living and working far outside of Low Earth Orbit (LEO) and preparing for future Mars missions. The Lunar Surface Habitat is planned as a primary element for long duration crew habitation on the Moon and will be the primary testbed for ECLS system hardware in a partial gravity environment. The Mars Transit Habitat will be the crew vehicle for the roundtrip from Earth to Mars and spend a significant amount of time docked to the Gateway outfitting and testing its systems prior to making the first Mars mission transit. The Mars Transit Habitat will utilize closed loop ECLS system technologies while a Mars Surface Habitat could use either open loop, closed loop, or a mix of both. Better understanding the needs of both these system architectures operating for extended periods in the Lunar environment and outside LEO will help to establish the ECLS system architecture for the future Mars surface mission. There are many aspects to consider such as length of crew stay, level of autonomy and dormancy between crewed missions, power requirements, system mass, and overall system reliability and maintainability. Other considerations will include Mars gravity vs. Lunar gravity, Mars atmospheric pressure vs. hard vacuum, and possible use of in-situ resource utilization.

ECLSS↗

The role of binding modules in enzymatic poly(ethylene terephthalate) hydrolysis at high-solids loadings

In nature, enzymes that deconstruct biological polymers, such as cellulose and chitin, often exhibit multi-domain architectures, comprising a catalytic domain and a non-catalytic binding module; the latter serves to increase the enzyme concentration at the substrate surface. This multi-domain architecture has been shown to improve the hydrolysis of poly(ethylene terephthalate) (PET) using engineered cutinase enzymes. Here, we examine the role of accessory binding modules at industrially relevant PET solids loadings necessary for cost-effective enzymatic recycling. Using a thermostable variant of leaf compost cutinase (LCC), we produced synthetic fusion constructs of LCC with five type A carbohydrate-binding modules (CBMs). At solids loadings below 10 wt%, the CBMs improve aromatic monomer yield from PET, but above this threshold, conversion extents up to 97% are reached with no added benefits from the presence of CBM fusions. This suggests that fusion constructs with the herein studied CBMs are not necessary for industrial enzymatic PET recycling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quantum bus of metal nanoring with surface plasmon polaritons

We develop an architecture for distributed quantum computation using quantum bus of plasmonic circuits and spin qubits in self-assembled quantum dots. Deterministic quantum gates between two distant spin qubits can be reached by using an adiabatic approach in which quantum dots couple with highly detuned plasmon modes in a metallic nanoring. Plasmonic quantum bus offers a robust and scalable platform for quantum optics experiments and the development of on-chip quantum networks composed of various quantum nodes, such as quantum dots, molecules, and nanoparticles.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Towards ultra-stiff materials: Surface effects on nanoporous materials

The significant rise in the strength and stiffness of porous materials at nanoscale cannot be described by conventional scaling laws. This letter investigates the effective Young's modulus of such materials by taking into account surface effect in a microcellular architecture designed for an ultralight material whose stiffness is an order of magnitude higher than most porous materials. We find that by considering the surface effects the predicted stiffness using Euler-Bernoulli beam theory compares well to experimental data for spongelike nanoporous gold with random microstructures. Analytical results show that, of the two factors influencing the effective Young's modulus, the residual stress is more important than the surface stiffness.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Sol–gel synthesis of MCM-41 silicas and selective vapor-phase modification of their surface

Silica particles with uniform hexagonal mesopore architecture were synthesized by template directed sol–gel condensation of tetraethoxysilane or mixture of tetraethoxysilane and (3-chloropropyl)triethoxysilane in a water–ethanol–ammonia solution. Selective functionalization of exterior surface of parent materials was carried out by postsynthetic treatment of template-filled MCM-41 and Cl-MCM-41 with vapors of (3-chloropropyl)triethoxysilane and 1,2-ethylenediamine in vacuum. The chemical composition of obtained mesoporous silicas was estimated by IR spectroscopy and chemical analysis of surface products of reactions. Characteristics of porous structure of resulting materials were determined from the data of X-ray, low-temperature nitrogen ad-desorption and transmission electron microscopy measurements. Obtained results confirm invariability of highly ordered mesoporous structure of MCM-41 and Cl-MCM-41 after their selective postsynthetic modification in vapor phase. It was proved that proposed method of vapor-phase functionalization of template-filled starting materials is not accompanied by dissolution of the template and chemical modification of pores surface. This provides preferential localization of grafted functional groups onto the exterior surface of mesoporous silicas. - Graphical abstract: Sol–gel synthesis and postsynthetic chemical modification of template-filled MCM-41 and Cl-MCM-41 with (3-chloropropyl)triethoxysilane and 1,2-ethylenediamine in vapor phase. Display Omitted - Highlights: • Synthesis of MCM-41 silica by template directed sol–gel condensation. • Selective vapor-phase functionalization of template-filled silica particles. • Preferential localization of grafted groups onto the exterior surface of mesoporous silicas.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Lamellar {gamma}-AlOOH architectures: Synthesis and application for the removal of HCN

Using hexadecyl trimethyl ammonium bromide (CTAB) as a structure-directing agent and precipitator, the complete synthesis of lamellar {gamma}-AlOOH architectures was successfully accomplished via a hydrothermal route. Different product structures were obtained by varying the molar ratio of aluminum nitrate and CTAB. Several techniques, including X-ray powder diffraction, Fourier transform infrared spectroscopy, field-emission scanning electron microscopy, transmission electron microscopy, and differential scanning calorimetry thermal analysis, were used to characterize the products. The effects of CTAB concentration, reaction temperature and time, and the molar ratio of Al{sup 3+}/CTAB on the product morphologies were investigated. The nitrogen adsorption and desorption measurements indicated that the {gamma}-AlOOH architectures possess a Brunauer-Emmett-Teller surface area of approximately 75.02 m{sup 2}/g. It was also demonstrated that 10 mg {gamma}-AlOOH architectures can remove 45.3% of the HCN (1.68 {mu}g/mL) from model wastewater. When 0.03 mg/cig {gamma}-AlOOH architectures were combined with cigarette paper, 8.12% of the present HCN was adsorbed. These results indicate that lamellar {gamma}-AlOOH architectures may be a potential adsorbent for removing HCN from highly toxic pollutant solutions and harmful cigarette smoke. Highlights: Black-Right-Pointing-Pointer Hexadecyl trimethyl ammonium bromide (CTAB) was used as a structure-directing agent and precipitator. Black-Right-Pointing-Pointer Hydrothermal treatment enables growth of lamellar {gamma}-AlOOH architectures. Black-Right-Pointing-Pointer Lamellar {gamma}-AlOOH architectures were demonstrated to exhibit high BET surface area and excellent adsorptive capacity. Black-Right-Pointing-Pointer HCN in contaminated water and cigarette smoke can be effectively removed by the prepared lamellar {gamma}-AlOOH superstructures.

36 MATERIALS SCIENCE↗

The influence of surface preparation on low temperature HfO{sub 2} ALD on InGaAs (001) and (110) surfaces

Current logic devices rely on 3D architectures, such as the tri-gate field effect transistor (finFET), which utilize the (001) and (110) crystal faces simultaneously thus requiring passivation methods for the (110) face in order to ensure a pristine 3D surface prior to further processing. Scanning tunneling microscopy (STM), x-ray photoelectron spectroscopy (XPS), and correlated electrical measurement on MOSCAPs were utilized to compare the effects of a previously developed in situ pre-atomic layer deposition (ALD) surface clean on the InGaAs (001) and (110) surfaces. Ex situ wet cleans are very effective on the (001) surface but not the (110) surface. Capacitance voltage indicated the (001) surface with no buffered oxide etch had a higher C{sub max} hypothesized to be a result of poor nucleation of HfO{sub 2} on the native oxide. An in situ pre-ALD surface clean employing both atomic H and trimethylaluminum (TMA) pre-pulsing, developed by Chobpattana et al. and Carter et al. for the (001) surface, was demonstrated to be effective on the (110) surface for producing low D{sub it} high C{sub ox} MOSCAPs. Including TMA in the pre-ALD surface clean resulted in reduction of the magnitude of the interface state capacitance. The XPS studies show the role of atomic H pre-pulsing is to remove both carbon and oxygen while STM shows the role of TMA pre-pulsing is to eliminate H induced etching. Devices fabricated at 120 °C and 300 °C were compared.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Glass heating panels and method for preparing the same from architectural reflective glass

Electrodes are positioned in intimate contact with an outer surface of a thin electrically insulating protecting layer of architectural reflective glass. Application of a voltage of sufficient magnitude substantially destroys the insulating layer located beneath the electrodes. A subsequent application of voltage results in a passage of current through the underlying thin, light reflective metal or metal oxide layer and in concomitant output of heat.

Shlichta, P. J.↗

Electrode Modification by Laser Ablation to Overcome Mechanical and Scalability Limitations of Solid-State Prealkylation of Electrode Architectures

In this work, laser ablation of Si electrode surfaces is utilized to provide localized strain relief during the Solid State Prealkylation of Electrode Architectures (SPEAR) process, in addition to volumetric expansion relief in the form of free volume channels across the electrode. A hexagonal mesh patterning was employed via laser ablation, where the hexagonal diameter (pitch) was varied from 250 to 1000 µm. It was demonstrated that these channels serve as expansion voids, accommodating the increase in electrode thickness observed during SPEAR and preventing cracking at the electrode surface. Optical microscopy and Raman mapping confirm that Li diffusion is the rate-limiting solid-state process, requiring a 24 h rest period to achieve homogeneous LixSi alloying through the electrode bulk. Electrochemical evaluations in full cells show that a 1000 μm pitch pattern yields a high initial discharge capacity of 2485 mA h g–1 and 86.4% capacity retention after 80 cycles, whereas smaller pitches (<500 μm) result in lithium plating at 4.1 V in full cells paired with NMC 811 due to excessive current collector exposure from the ablation process. XPS analysis reveals that the laser treatment modifies the electrode surface by increasing the Si–O and C–O species, changing the SEI composition observed via an increase in fluorophosphates upon cycling.

Musgrove, Amanda [ORNL] (ORCID:0009000220910389)↗

Mars Surface Tunnel Element Concept

When the first human visitors on Mars prepare to return to Earth, they will have to comply with stringent planetary protection requirements. Apollo Program experience warns that opening an EVA hatch directly to the surface will bring dust into the ascent vehicle. To prevent inadvertent return of potential Martian contaminants to Earth, careful consideration must be given to the way in which crew ingress their Mars Ascent Vehicle (MAV). For architectures involving more than one surface element-such as an ascent vehicle and a pressurized rover or surface habitat-a retractable tunnel that eliminates extravehicular activity (EVA) ingress is an attractive solution. Beyond addressing the immediate MAV access issue, a reusable tunnel may be useful for other surface applications, such as rover to habitat transfer, once its primary mission is complete. A National Aeronautics and Space Administration (NASA) team is studying the optimal balance between surface tunnel functionality, mass, and stowed volume as part of the Evolvable Mars Campaign (EMC). The study team began by identifying the minimum set of functional requirements needed for the tunnel to perform its primary mission, as this would presumably be the simplest design, with the lowest mass and volume. This Minimum Functional Tunnel then becomes a baseline against which various tunnel design concepts and potential alternatives can be traded, and aids in assessing the mass penalty of increased functionality. Preliminary analysis indicates that the mass of a single-mission tunnel is about 237 kg, not including mass growth allowance.

Rucker, Michelle A.↗