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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 271 records · Page 15
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Reflectance and Thermal Infrared Spectroscopy of Mars: Relationship Between ISM and TES for Compositional Determinations

Reflectance spectroscopy has demonstrated that high albedo surfaces on Mars contain heavily altered materials with some component of hematite, poorly crystalline ferric oxides, and an undefined silicate matrix. The spectral properties of many low albedo regions indicate crystalline basalts containing both low and high calcium pyroxene, a mineralogy consistent with the basaltic SNC meteorites. The Thermal Emission Spectrometer (TES) experiment on the Mars Geochemical Surveyor has acquired critical new data relevant to surface composition and mineralogy, but in a wavelength region that is complementary to reflectance spectroscopy. The essence of the completed research was to analyze TES data in the context of reflectance data obtained by the French ISM imaging spectrometer experiment in 1989. This approach increased our understanding of the complementary nature of these wavelength regions for mineralogic determinations using actual observations of the martian surface. The research effort focused on three regions of scientific importance: Syrtis Major-Isidis Basin, Oxia Palus-Arabia, and Valles Marineris. In each region distinct spatial variations related to reflectance, and in derived mineralogic information and interpreted compositional units were analyzed. In addition, specific science questions related to the composition of volcanics and crustal evolution, soil compositions and pedogenic processes, and the relationship between pristine lithologies and weathering provided an overall science-driven framework for the work. The detailed work plan involved colocation of TES and ISM data, extraction of reflectance and emissivity spectra from areas of known reflectance variability, and quantitative analysis using factor analysis and statistical techniques to determine the degree of correspondence between these different wavelength regions. Identified coherent variations in TES spectroscopy were assessed against known atmospheric effects to validate that the variations are due to surface properties. With this new understanding of reflectance and emission spectroscopy, mineralogic interpretations were derived and applied to the science objectives of the three regions.

Boyce, Joseph↗
NASA NTRS1970

The effect of solid phase reactions on the ballistic properties of propellants

The combustion of NH4ClO4 composite propellants has been studied between 15 and 3000 psi. The emphasis in the program has been on determining the mechanisms by which the fuel components influence the burning rate of the composites. In order to have flexibility in the choice and concentration of the fuel component all combustion experiments were performed with pressed power strands. The fuels studied included those which affected the combustion mechanism of the composite primarily through their effect on: (1) the oxidizer decomposition mechanism and (2) the composite surface temperature. The combustion of pure and doped NH4ClO4 was studied using both pressed powder strands and pressed end burning motor grains. The experimental approach has been essentially a chemical one with emphasis on perturbing those reactions which occur on or immediately adjacent to the surface (zone of influence) of the composite.

Schmidt, W. G.↗
NASA NTRS1990

Characterization study of polycrystalline tin oxide surfaces before and after reduction in CO

Polycrystalline tin oxide surfaces have been examined before and after reduction in 40 Torr of CO at 100 and 175 C using Auger electron spectroscopy (AES), electron spectroscopy for chemical analysis (ESCA), ion scattering spectroscopy (ISS) and electron stimulated desorption (ESD). The changes in the surface composition and chemical states of the surface species generally are subtle for the reductive conditions used. However, significant changes do occur with regard to the amounts and the chemical forms of the hydrogen-containing species remaining after both the 100 and 175 C reductions.

Drawdy, Jean E.↗
NASA NTRS1989

Non-ideality near the monotectic composition of a miscibility-gap type system - Succinonitrile-water

Differential scanning calorimetry (DSC) of near monotectic succinonitrile-water solutions, fast-quenched in hydrophilic and hydrophobic DSC pans, indicate, by degree of undercooling, thst there may be significant dependence of final ingot microstructure on the pre-quench equilibration temperature. Partial molal-volume determinations from density data, along with DSC data, suggest the nature of temperature dependent component associations from 20 to 55 C in homogeneous solutions. The undercooling profile in a hydrophilic container is explained in terms of solution-composition shifts arising from the Gibbs surface excess. The evidence shows that temperature-dependent preferred component aggregates may modulate surface-composition gradients. Similar effects may be present through intermetallic compound formation in metallic monotectic alloys.

Frazier, D. O.↗
NASA NTRS1989

Physical properties of Aten, Apollo and Amor asteroids

Data available on the physical properties of a group of planet-crossing asteroids, the Aten, Apollo, and Amor objects (AAAO) (include data on the taxonomy, mineralogical surface composition, diameter, rotation rate, shape, and surface texture) are presented together with the type of observations used for obtaining these data. These data show that the population of the AAAO is diverse in all of their physical characteristics. This diversity implies that the AAAO come from multiple sources and had different evolutionary histories.

Mcfadden, Lucy-Ann↗
NASA NTRS2010

Monte Carlo Modeling of Sodium in Mercury's Exosphere During the First Two MESSENGER Flybys

We present a Monte Carlo model of the distribution of neutral sodium in Mercury's exosphere and tail using data from the Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft during the first two flybys of the planet in January and September 2008. We show that the dominant source mechanism for ejecting sodium from the surface is photon-stimulated desorption (PSD) and that the desorption rate is limited by the diffusion rate of sodium from the interior of grains in the regolith to the topmost few monolayers where PSD is effective. In the absence of ion precipitation, we find that the sodium source rate is limited to approximately 10(exp 6) - 10(exp 7) per square centimeter per second, depending on the sticking efficiency of exospheric sodium that returns to the surface. The diffusion rate must be at least a factor of 5 higher in regions of ion precipitation to explain the MASCS observations during the second MESSENGER f1yby. We estimate that impact vaporization of micrometeoroids may provide up to 15% of the total sodium source rate in the regions observed. Although sputtering by precipitating ions was found not to be a significant source of sodium during the MESSENGER flybys, ion precipitation is responsible for increasing the source rate at high latitudes through ion-enhanced diffusion.

Burger, Matthew H.↗
NASA NTRS2011

Observations of Al, Fe and Ca(+) in Mercury's Exosphere

We report 5-(sigma) tangent column detections of Al and Fe, and strict 3-(sigma) tangent column upper limits for Ca(+) in Mercury's exosphere obtained using the HIRES spectrometer on the Keck I telescope. These are the first direct detections of Al and Fe in Mercury's exosphere. Our Ca(-) observation is consistent with that reported by The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft.

Bida, Thomas A.↗
NASA NTRS2017

Seasonal Variations of Mercury's Magnesium Dayside Exosphere from MESSENGER Observations

The Ultraviolet and Visible Spectrometer channel of the Mercury Atmospheric and Surface Composition Spectrometer instrument aboard the MErcury Surface, Space ENvironment, GEochemistry, and Ranging spacecraft made near-daily observations of solar-scattered resonant emission from magnesium in Mercury's exosphere during the mission's orbital phase (March 2011-April 2015, approx.17 Mercury years). In this paper, a subset of these data (March 2013-April 2015) is described and analyzed to illustrate Mg's spatial and temporal variations. Dayside altitude profiles of emission are used to make estimates of the Mg density and temperature. The main characteristics of the Mg exosphere are (a) a predominant enhancement of emission in the morning (6 am-10 am) near perihelion, (b) a bulk temperature of approx. 6000 K, consistent with impact vaporization as the predominant ejection process, (c) a near-surface density that varies from 5/cu cm to 50/cu cm and (d) a production rate that is strongest in the morning on the inbound leg of Mercury's orbit with rates ranging from 1×10(exp 5)/sq cm/s to 8×10(exp 5)/sq cm/s.

Ultraviolet↗
NASA NTRSDate not supplied

Idea Evolution ... What's Next?

No research project lasts forever. Even the most wildly successful programs will eventually come to an end. The challenge in that moment, when a project ends, is how to take what was learned in that project and apply it to the next research activity you undertake. Although not always possible, information and insights from a project that is underway or coming to a close can be leveraged to identify a new research direction and advance existing tangentially related activities. In this presentation, a common thread will be followed through a series of sequential research projects where lessons learned in each activity were built into the next enabling each new research project to advance further and faster. Initial research focused on lunar dust adhesion mitigation coalesced into two major contributors to adhesion interactions; which were, not surprisingly, surface chemistry and topography. This knowledge was applied to addressing insect residue adhesion mitigation on commercial aircraft leading edge surfaces. Composite epoxy coatings formulated with controlled surface chemistry and topography were evaluated and led to identification of additional relevant considerations: dynamics and surface morphology. Collectively, these considerations were applied to address impact ice adhesion mitigation where further properties were elucidated: surface mechanical properties and durability. Seeking commonality between these research endeavors led to greater understanding of each new research objective and ultimately, identification of robust, viable pathways toward meaningful results.

Adhesion Mitigation↗
NASA NTRS2021

Compositional Study of Trans-Neptunian Objects at λ > 2.2 μm

Using data from the Infrared Array Camera on the Spitzer Space Telescope, we present photometric observations of a sample of 100 trans-Neptunian objects (TNOs) beyond 2.2 μm. These observations, collected with two broadband filters centered at 3.6 and 4.5 μm, were done in order to study the surface composition of TNOs, which are too faint to obtain spectroscopic measurements. With this aim, we have developed a method for the identification of different materials that are found on the surfaces of TNOs. In our sample, we detected objects with colors that are consistent with the presence of small amounts of water, and we were able to distinguish between surfaces that are predominantly composed of complex organics and amorphous silicates. We found that 86% of our sample have characteristics that are consistent with a certain amount of water ice, and the most common composition (73% of the objects) is a mixture of water ice, amorphous silicates, and complex organics. Twenty-three percent of our sample may include other ices, such as carbon monoxide, carbon dioxide, methane, or methanol. Additionally, only small objects seem to have surfaces dominated by silicates. This method is a unique tool for the identification of complex organics and to obtain the surface composition of extremely faint objects. Furthermore, this method will be beneficial when using the James Webb Space Telescope for differentiating groups within the trans-Neptunian population.

Trans-Neptunian objects↗
DOE OSTI2025

What more can be done with XPS? Highly informative but underused approaches to XPS data collection and analysis

Because of the importance of surfaces and interfaces in many scientific and technological areas, the use of x-ray photoelectron spectroscopy (XPS) has been growing exponentially. Although XPS is being used to obtain useful information about the surface composition of samples, much more information about materials and their properties can be extracted from XPS data than commonly obtained. This paper describes some of the areas where alternative analysis methods or experimental design can obtain information about the near-surface region of a sample, often information not available in other ways. Experienced XPS analysts are familiar with many of these methods, but they may not be known to new or casual XPS users, and sometimes, they have not been used because of an inappropriately assumed complexity. The information available includes optical, electronic, and electrical properties; nanostructure; expanded chemical information; and enhanced analysis of biological materials and solid/liquid interfaces. Many of these analyses can be conducted on standard laboratory XPS systems, with either no or relatively minor system alterations. Topics discussed include (1) considerations beyond the “traditional” uniform surface layer composition calculation, (2) using the Auger parameter to determine a sample property, (3) use of the D parameter to identify sp 2 and sp 3 carbon information, (4) information from the XPS valence band, (5) using cryocooling to expand range of samples that can be analyzed and minimize damage, and (6) using electrical potential effects on XPS signals to extract chemically resolved electrical measurements including band alignment and electrical property information.

Baer, Donald R. [Pacific Northwest National Labora↗
NASA NTRS1976

Estimates of the wind speeds required for particle motion on Mars

Threshold wind speeds for setting particles into motion on Mars are estimated by evaluating experimentally observed threshold friction velocities and determining the ratio of this velocity to the threshold wind speed at the top of earth's atmospheric boundary layer (ABL). Turning angles between the direction of the wind at the top of the ABL and the wind stress at the surface are also estimated. Detailed consideration is given to the dependence of the threshold wind speed at the top of the ABL on particle diameter, surface pressure, air temperature, atmospheric stability and composition, surface roughness, and interparticle cohesion. The results are applied to interpret a number of phenomena that have been observed on Mars and are attributable to aeolian processes. It is shown that: (1) minimum threshold wind speeds of about 50 to 100 m/sec are required to cause particle motion on Mars under 'favorable' conditions; (2) particle motion should be infrequent and strongly correlated with proximity to small topographical features; (3) in general, particle motion occurs more readily at night than during the day, in winter polar areas than equatorial areas around noon, and for H2O or CO2 ice particles than for silicate particles; and (4) the boundary between saltating and suspendible particles is located at a particle diameter of about 100 microns.

Pollack, J. B.↗
NASA NTRS1987

Composite Piston-Cap Structure

Design eliminates thermal stress between composite cap and metal piston. New, conically surfaced, composite piston-cap structure, passively retained in metallic piston, made from carbon/carbon material, machined to shape. Shape includes conical faces, conical extensions intersect at common vertex on cylindrical axis of piston body, allowing thermal-stress-free retention of cap at all temperatures. When assembly heated or cooled, metal expands or contracts radially from coincident vertex. Where metal makes contact with carbon/carbon cap, snugly fitting conical faces slide without interference. Since metal body free to expand, no thermal stress produced in metal body or carbon/carbon cap.

Taylor, Allan↗
NASA NTRS2018

Aubrite and Impact Melt Enstatite Chondrite Meteorites as Potential Analogs to Mercury

The MESSENGER (MErcury Sur-face, Space ENvironment, GEochemistry and Ranging) orbiter measured the Mercurian surface abundances of key rock-forming elements to help us better understand the planet's surface and bulk geochemistry. A major discovery is that the Mercurian surface and interior are characterized by an extremely low oxygen fugacity (ƒO2; Iron-Wüstite (IW) -7.3 to IW-2.6. This is supported by low Fe and high S abundances on the surface. This low ƒO2 causes a different elemental partioning from what is observed on Earth. Using surface composition, it was shown that the Mercurian surface mainly consists of normative plagioclase, pyroxene, olivine, and exotic sulfides, such as niningerite ((Mg,Mn, Fe)S) and oldhamite (CaS).

Wilbur, Z. E.↗
DOE OSTI2023

Multi-technique characterization of spray coated and roll-to-roll coated gas diffusion fuel cell electrodes

Here this work reports the characterization of catalyst layer (CL) structure and composition for a set of gas-diffusion electrodes (GDEs) fabricated by different coating methods with the goal of developing a better understanding of CL processing-structure-property-performance relationships. The CL coating techniques used in this study were ultrasonic spray coating, and two roll-to-roll (R2R) methods - gravure and slot die. Scanning transmission electron microscopy (STEM) coupled with X-ray energy dispersive spectroscopy (EDS) analysis of GDE cross-sections provided bulk information, while scanning electron microscopy (SEM) with EDS and X-ray photoelectron spectroscopy (XPS) were used to investigate the near surface and surface composition of the CLs that will be in direct contact with the membrane once the membrane electrode assembly (MEA) is constructed. This study demonstrates that common quantification parameters, namely the F:Pt ratio extracted from cross-sectional STEM-EDS maps and top-down CL measurements with SEM and XPS, along with roughness parameters quantified from SEM micrographs are useful parameters in explaining and potentially predicting performance trends. Additionally, it highlights the importance of understanding key CL surface properties for advancing the manufacturability of high-performance components for polymer electrolyte membrane (PEM) technologies.

30 DIRECT ENERGY CONVERSION↗
NASA NTRS1993

Radiation fluxes at the FIFE site

The main objective of the International Satellite Land Surface Climatology Project (ISLSCP) has been stated as 'the development of techniques that may be applied to satellite observations of the radiation reflected and emitted from the Earth to yield quantitative information concerning land surface climatological conditions'. The major field study, FIFE (the First ISLSCP Field Experiment), was conducted in 1987-89 to accomplish this objective. Four intensive field campaigns (IFC's) were carried out in 1987 and one in 1989. Factors contributing to observed reflected radiation from the FIFE site must be understood before the radiation observed by satellites can be used to quantify surface processes. Our last report (Walter-Shea et al., 1992b) focused on slope effects on incoming and outgoing shortwave radiation and net radiation from data collected in 1989. We report here on the final analysis of the slope data as well as results from thermal radiation studies conducted during the FIFE experiment. The specific areas reported are the following: (1) analysis of slope effects on measured reflectance values and estimates of surface albedo; (2) using remotely-measured surface temperatures as a means of estimating sensible heat flux from the Konza Prairie; (3) extracting canopy temperatures from remotely-measured composite surface temperatures; (4) modeling the measured composite temperature of partially vegetated surfaces; and (5) estimating gap distribution in partially vegetated surfaces from reflectance measurements.

Walter-Shea, Elizabeth A.↗
NASA NTRS1993

Remote sensing x ray fluorescence spectrometry for future lunar exploration missions

Measurement of discrete line X-ray emission from space can be used to obtain both qualitative and quantitative elemental surface composition information. Remote orbital X-ray elemental analysis is the measurement of characteristic X-rays following the interaction of solar X-rays with the surface of a given solid body. Thus, X-ray emission from a surface is strongly dependent on the incident solar spectrum as well as on the chemical composition of the surface. In this paper, the relationship between the solar flux and the major lunar element fluorescence and scattered X-ray flux is characterized. A model was developed to calculate lunar surface X-ray fluorescence emission spectra under a variety of solar conditions and, in particular, conditions that might be expected for a Lunar Scout mission proposed for 1995 or 1996. This time period should be during solar minimum.

Clark, Pamela E.↗