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NASA NTRS2001

Single-Crystal Elastic Constants of Yttria (Y2O3) Measured to High Temperatures

Yttria, or yttrium sesquioxide (Y2O3), has been considered for use in nuclear applications and has gained interest relatively recently for use in infrared optics. Single crystals of yttria have been grown successfully at the NASA Glenn Research Center using a laser-heated float zone technique in a fiber and rod. Such samples allow measurement of the single-crystal elastic properties, and these measurements provide useful property data for the design of components using single crystals. They also yield information as to what degree the elastic properties of yttria ceramics are a result of the intrinsic properties of the yttria crystal in comparison to characteristics that may depend on processing, such as microstructure and intergranular phases, which are common in sintered yttria. The single-crystal elastic moduli are valuable for designing such optical components. In particular, the temperature derivatives of elastic moduli allow the dimensional changes due to heating under physical constraints, as well as acoustic excitation, to be determined. The single-crystal elastic moduli of yttria were measured by Brillouin spectroscopy up to 1200 C. The room-temperature values obtained were C(sub 11) = 223.6 + 0.6 GPa, C(sub 44) = 74.6 + 0.5 GPa, and C(sub 12) = 112.4 + 1.0 GPa. The resulting bulk and (Voigt-Reuss-Hill) shear moduli were K = 149.5 + 1.0 GPa and G(sub VRH) = 66.3 + 0.8 GPa, respectively. Linear least-squares regressions to the variation of bulk and shear moduli with temperature resulted in derivatives of dK/dT = -17 + 2 MPa/C and dG(sub VRH)/dT = -8 + 2 MPa/ C. Elastic anisotropy was found to remain essentially constant over the temperature range studied.

Sayir, Ali↗

NASA NTRS1993

Properties of Semiconducting Ru_2Ge_3

Transport properties of large single crystalline samples of Ru_2Ge_3 grown from the melt have been investigated in a 25-1000 C temperature range. A diffusionless transition between 500 and 550C from a high temperature tetragonal structure to a low temperature orthorhombic structure was clearly observed. Results showed that both the low temperature orthorhombic and the high temperature structural tetragonal phase are semiconductors. Some anisotropy of the transport coefficients was determined by measuring the samples in orientations parallel and perpendicular to the preferential direction of crystal growth. Large Seebeck coefficient (up to 400 microVK^(-1)) and low thermal conductivity (as low as 20x10^(-3) Wcm^(-1)K^(-1)) were achieved for the low temperature orthorhombic phase. Difficulties in preparing heavily doped samples and low Hall mobilities have limited values for the maximum figure of merit to 0.5 x 10^(-3) K^(-1) at 500 C.

Fleurial, Jean-Pierre↗

NASA NTRS1994

The streaming-trapped ion interface in the equatorial inner magnetosphere

Spacecraft measurements of core ions on L=4-7 field-lines typically show trapped ion distributions near the magnetic equator, and frequently indicate field-aligned ion streams at higher latitudes. The nature of the transition between them may indicate both the microphysics of hot-cold plasma interactions and overall consequences for core plasma evolution. We have undertaken a statistical analysis and characterization of this interface and its relation to the equatorial region of the inner magnetosphere. In this analysis, we have characterized such features as the equatorial ion flux anisotropy, the penetration of field-aligned ionospheric streams into the equatorial region, the scale of the transition into trapped ion populations, and the transition latitude. We found that most transition latitudes occur within 13 deg of the equator. The typical values of equatorial ion anisotropies are consistent with bi-Maxwellian temperature ratios of T(sub perpendicular)/T(sub parallel) in the range of 3-5. The latitudinal scales for the edges of the trapped ion populations display a rather strong peak in the 2-3 deg range. We also found that there is a trend for the penetration ratio, the anisotropy half width, and the transition scale length to decrease with a higher equatorial ion anisotropy. We may interpret these features in terms of Liouville mapping of equatorially trapped ions and the reflection of the incoming ionospheric ion streams from the equatorial potential peaks associated with such trapped ions.

Lin, J.↗

NASA NTRSDate not supplied

Thermophysical Property Measurements of Indium Iodide Crystals

InI single crystals are a promising room temperature detector material for X-rays and γ-rays. To improve crystal growth of the material by simulations, knowledge of thermophysical properties is essential, and since InI is orthorhombic, the anisotropy has to be taken into account. The temperature dependence of several thermophysical properties have been measured for InI, including the anisotropic thermal expansion, specific heat, and the thermal diffusivity in the b direction. The anisotropic thermal expansion coefficients, determined by X-ray diffraction, were α11=1.03·10-5 K-1, α22= 3.77·10-5 K-1, and α33 = 6.26·10-5 K-1. The specific heat, measured by DSC, was 0.226 J g-1 K-1 at 335K, with a temperature dependence of 9.582·10-5 J g-1 K-2. In the course of the X-ray diffraction and DSC measurements, it was shown that supposed phase changes, reported in older literature, are actually not phase changes but oxidation effects. The thermal diffusivity in the b direction, measured by the Xenon Flash method, was 0.288·10-6 m2s-1 at RT, decreasing to 0.253·10-6 m2 s-1 at 450K. In addition, the volume increase upon melting and the thermal expansion of the melt have been determined.

Martin Volz↗

NASA NTRS1987

Anisotropic transport in modulation-doped quantum-well structures

Anisotropic electron transport has been observed in GaAs modulation-doped quantum wells grown by molecular-beam epitaxy on a thick (001) Al(0.3)Ga(0.7)As buffer grown at 620 C. Thicker quantum wells (150, 200, and 300 A) show progressively less anisotropy, which vanishes for a 300-A quantum well. The degree of anisotropy is also reduced or eliminated by suspending growth of the Al(0.3)Ga(0.7)As for a period of 300 s prior to growing the GaAs quantum well. Growing the Al(0.3)Ga(0.7)As buffer at higher temperatures (680 C) also reduces the degree of anisotropy. Higher two-dimensional electron gas sheet densities result in less anisotropy.The anisotropy is eliminated by replacing the thick Al(0.3)Ga(0.7)As buffer with a periodic multilayer structure comprising 15 A of GaAs and 200 A of Al(0.3)Ga(0.7)As. The degree of anisotropy is related to the thickness and growth parameters of the Al(0.3)Ga(0.7)As layer grown just prior to the growth of the GaAs.

Radulescu, D. C.↗

NASA NTRS1990

COBE

Preliminary results are presented from COBE's three observational instruments. These are the FIRAS spectrum experiment, which surveyed over 98 percent of the sky, the IR background experiment, DIRBE which surveyed all of the sky, and the DMR anisotropy experiment. It is found that the cosmic microwave background is very close to a blackbody, with a temperature of 2.735 + or - 0.06 K. The only reliably detected background anisotropy is the 3.3 + or - 0.2 mK-amplitude dipole. The rms quadrupole anisotropy is less than 0.00003 with 95-percent confidence. DIRBE results indicate that the IRAS 60-100 micron diffuse-flux calibrations suffer from gain and offset errors.

Wright, Edward L.↗

NASA NTRS1990

Photophysics of poly(2,3,4,5,6-pentafluoro styrene) film

The temperature-dependent steady-state emission, emission polarization anisotropy, and fluorescence-kinetics of poly(2,3,4,5,6-pentafluoro styrene) film are reported. Two interconverting excited-state conformations of the chromophore have been identified. The fluorescence of the higher energy conformation results from excitation on the red edge of the polymer absorption band at temperatures below 180 K. The energy barrier for conversion of the high energy conformer to the lower energy conformer is estimated to be E/hc = 27 + or - 7/cm. Electronic energy migration is not evident in this polymer.

O'Connor, Donald B.↗

NASA NTRS1992

Melting of the Abrikosov flux lattice in anisotropic superconductors

It has been proposed that the Abrikosov flux lattice in high-Tc superconductors is melted over a significant fraction of the phase diagram. A thermodynamic argument is provided which establishes that the angular dependence of the melting temperature is controlled by the superconducting mass anisotropy. Using a low-frequency torsional-oscillator technique, this relationship has been tested in untwinned single-crystal YBa2Cu3O(7-delta). The results offer decisive support for the melting proposal.

Beck, R. G.↗

NASA NTRS1995

Gaussian statistics of the cosmic microwave background: Correlation of temperature extrema in the COBE DMR two-year sky maps

We use the two-point correlation function of the extrema points (peaks and valleys) in the Cosmic Background Explorer (COBE) Differential Microwave Radiometers (DMR) 2 year sky maps as a test for non-Gaussian temperature distribution in the cosmic microwave background anisotropy. A maximum-likelihood analysis compares the DMR data to n = 1 toy models whose random-phase spherical harmonic components a(sub lm) are drawn from either Gaussian, chi-square, or log-normal parent populations. The likelihood of the 53 GHz (A+B)/2 data is greatest for the exact Gaussian model. There is less than 10% chance that the non-Gaussian models tested describe the DMR data, limited primarily by type II errors in the statistical inference. The extrema correlation function is a stronger test for this class of non-Gaussian models than topological statistics such as the genus.

Kogut, A.↗

NASA NTRS1984

Cosmic background radiation anisotropies in universes dominated by nonbaryonic dark matter

Detailed calculations of the temperature fluctuations in the cosmic background radiation for universes dominated by massive collisionless relics of the big bang are presented. An initially adiabatic constant curvature perturbation spectrum is assumed. In models with cold dark matter, the simplest hypothesis - that galaxies follow the mass distribution leads to small-scale anisotropies which exceed current observational limits if omega is less than 0.2 h to the -4/3. Since low values of omega are indicated by dynamical studies of galaxy clustering, cold particle models in which light traces mass are probably incorrect. Reheating of the pregalactic medium is unlikely to modify this conclusion. In cold particle or neutrino-dominated universes with omega = 1, presented predictions for small-scale and quadrupole anisotropies are below current limits. In all cases, the small-scale fluctuations are predicted to be about 10 percent linearly polarized.

Bond, J. R.↗

NASA NTRS1990

Effect of the Great Attractor on the cosmic microwave background radiation

A map is presented of the anisotropy Delta T/T in cosmic microwave background (CMB) temperature of our region of the universe as viewed by a distant observer, predicted on the basis of the gravitational potential field. This field is calculated in the vicinity of the Local Group of galaxies from the observed peculiar velocities of galaxies under the assumption that the peculiar motions are induced by gravity. If the cosmological density parameter Omega is one, the gravitational potential field of the Great Attractor and surrounding regions produces a maximum Sachs-Wolfe anisotropy of Delta T/T = (1.7 + or - 0.3) x 10 to the -5th on an angular scale of 1 deg. Doppler and adiabatic contributions to this anisotropy are expected to be somewhat larger. If similar fluctuations in the gravitational potential are present elsewhere in the universe, the anisotropy present when the CMB was last scattered should be visible from the earth and should be detectable in current experiments.

Bertschinger, Edmund↗

NASA NTRS1990

Topology of microwave background fluctuations - Theory

Topological measures are used to characterize the microwave background temperature fluctuations produced by 'standard' scenarios (Gaussian) and by cosmic strings (non-Gaussian). Three topological quantities: total area of the excursion regions, total length, and total curvature (genus) of the isotemperature contours, are studied for simulated Gaussian microwave background anisotropy maps and then compared with those of the non-Gaussian anisotropy pattern produced by cosmic strings. In general, the temperature gradient field shows the non-Gaussian behavior of the string map more distinctively than the temperature field for all topology measures. The total contour length and the genus are found to be more sensitive to the existence of a stringy pattern than the usual temperature histogram. Situations when instrumental noise is superposed on the map, are considered to find the critical signal-to-noise ratio for which strings can be detected.

Gott, J. Richard, III↗

NASA NTRS2010

Five-Year Wilkinson Microwave Anisotropy Probe Observations: Data Processing, Sky Maps, and Basic Results

We present new full-sky temperature and polarization maps in five frequency bands from 23 to 94 GHz, based on data from the first five years of the Wilkinson Microwave Anisotropy Probe (WMAP) sky survey. The new maps are consistent with previous maps and are more sensitive. The five-year maps incorporate several improvements in data processing made possible by the additional years of data and by a more complete analysis of the instrument calibration and in-flight beam response. We present several new tests for systematic errors in the polarization data and conclude that W-band polarization data is not yet suitable for cosmological studies, but we suggest directions for further study. We do find that Ka-band data is suitable for use; in conjunction with the additional years of data, the addition of Ka band to the previously used Q- and V-band channels significantly reduces the uncertainty in the optical depth parameter, tau. Further scientific results from the five-year data analysis are presented in six companion papers and are summarized in Section 7 of this paper. With the five-year WMAP data, we detect no convincing deviations from the minimal six-parameter ACDM model: a flat universe dominated by a cosmological constant, with adiabatic and nearly scale-invariant Gaussian fluctuations. Using WMAP data combined with measurements of Type Ia supernovae and Baryon Acoustic Oscillations in the galaxy distribution, we find (68% CL uncertainties): OMEGA(sub b)h(sup 2) = 0.02267(sup +0.00058)(sub -0.00059), OMEGA(sub c)h(sup 2) = 0.1131 plus or minus 0.0034, OMEGA(sub logical and) = 0.726 plus or minus 0.015, ns = .960 plus or minus 0.013, tau = 0.84 plus or minus 0.016, and DELTA(sup 2)(sub R) = (22.445 plus or minus 0.096) x 10(exp -9) at k = 0.002 Mpc(exp -1). From these we derive sigma(sub 8) = 0.812 plus or minus 0.026, H(sub 0) = 70.5 plus or minus 1.3 kilometers per second Mpc(exp -1), OMEGA(sub b) = 0.0456 plus or minus 0.0015, OMEGA(sub c) = .228 plus or minus 0.013, OMEGA(sub m)h(sup 2) = 0.1358(sup +0.0037)(sub -0.0036), z reion = 10.9 plus or minus 1.4, and t(sub 0) = 13.72 plus or minus 0.12 Gyr. The new limit on the tensor-to-scalar ration is r less than 0.22 (95% CL), while the evidence for a running spectral index is insignificant, dn(sub s)/d ln k = -0.028 plus or minus 0.020 (68% CL). We obtain tight, simultaneous limits on the (constant) dark energy equation of state and the spatial curvature of the universe: -0.14 less than 1 + w less than 0.12 (95% CL) and -0.0179 less than OMEGA(sub k) less than 0.0081 (95% CL). The number of relativistic degrees of freedom, expressed in units of the effective number of neutrino species, is found to be N(sub eff) = 4.4 plus or minus 1.5 (69% CL), consistent with the standard value of 3.04. Models with N(sub eff) = 0 are disfavored at greater than 99% confidence. Finally, new limits on physically motivated primordial non-Gaussianity parameters are -9 less than f(sup local)(sub NL) less than 111 (95% CL) and -151 less than f(sup equal)(sub NL) less than 253 (95% CL) for the local and equilateral models, respectively.

Hinshaw, G.↗

NASA NTRS1971

Effect of stress on electron relaxation times in n-type silicon

Stress effects on electron relaxation time anisotropies in n-type Si, using high temperature piezoresistivity model for population transfer rates

Littlejohn, M. A.↗

NASA NTRS1987

The Large Deployable Reflector (LDR) - Plans and progress

The program history, scientific aims, design, and projected performance of the LDR, a 20-m-primary two-stage four-mirror orbiting sub-mm/FIR astronomical observatory under NASA development, are reviewed. It is shown that the LDR would provide capabilities complementary to those of IRAS, the Kuiper Airborne Observatory, the IRTF, the Hubble Space Telescope, and the planned Space IR Telescope Facility for observations of small-scale background anisotropies, high-redshift galaxies, and objects at temperatures of a few times 10 K or lower. The current design concept is illustrated with extensive drawings, diagrams, and tables of instrument parameters. Particular attention is given to the graphite-epoxy facing and Al-honeycomb core of the primary structure, the focal-plane instruments, and outstanding technological problems.

Swanson, Paul N.↗

NASA NTRS1992

A global potential energy surface for ArH2

We describe a simple analytic representation of the ArH2 potential energy surface which well reproduces the results of extensive ab initio electronic structure calculations. The analytic representation smoothly interpolates between the dissociated H2 and strong bonding limits. In the fitting process, emphasis is made on accurately reproducing regions of the potential expected to be important for high temperature (ca. 3000 K) collision processes. Overall, the anisotropy and H2 bond length dependence of the analytic representation well reproduce the input data.

Schwenke, David W.↗

NASA NTRS1993

A global potential energy surface for ArH2

Schwenke, David W.↗

NASA NTRS1990

Evaluation, development, and characterization of superconducting materials for space applications

The anisotropic electromagnetic features of a grain-aligned YBa2Cu3O(x) bulk sample derived from a process of long-time partial melt growth were investigated by the measurements of direct current magnetization (at 77 K) and alternating current susceptibility as a function of temperature, with the fields applied parallel and perpendicular to the c axis, respectively. The extended Bean model was further studied and applied to explain the experimental results. Upon comparison of the grain-aligned sample with pure single crystal materials, it is concluded that because of the existence of more effective pinning sites in the grain-aligned sample, not only its critical current density perpendicular to the c axis is improved, but the one parallel to the c axis is improved even more significantly. The anisotropy in the critical current densities in the grain-aligned sample at 77 K is at least one to two orders of magnitude smaller than in the pure single crystal. The measurement of anisotropy of alternating current susceptibility as a function of temperature, especially its imaginary part, shows that there are still some residues of interlayer weak links in the grain-aligned samples, but they are quite different from and far less serious than the weak links in the sintered sample.

Thorpe, Arthur N.↗